1,2-cyclooctene
A
1,8-octanedial
B
dihydrogen peroxide
Conditions | Yield |
---|---|
With oxygen; ozone In acetic acid at 16℃; | A n/a B 100% |
With oxygen; ozone; Fe-(ll)-Kat In acetic acid at 16℃; | A n/a B 74% |
With oxygen; ozone; Mn-(ll)-Kat In acetic acid at 16℃; | A n/a B 71% |
Conditions | Yield |
---|---|
With (CH3(CH2)3)4NClO4; 1-methylimidazole In dichloromethane Electrolysis; electrolysis (10-30 min) of O2 in CH2Cl2-0.1 M Bu4NClO4 soln. in presence of 0.1 M benzoic acid and 1-methylimidazole, working electrode: polymer-coated (poly-(Ru(vbpy)3)(2+)) glassy-carbon, reference electrode: Ag/Ag(1+), potential -1.3 and -1.1 V; extn. with distd. H2O, colorimetric analysis; | 100% |
With (CH3(CH2)3)4NClO4 In dichloromethane Electrolysis; electrolysis (10-30 min) of O2 in CH2Cl2-0.1 M Bu4NClO4 soln. in presence of 0.1 M benzoic acid, working electrode: polymer-coated (poly-(Ru(vbpy)3)(2+)) glassy-carbon, reference electrode: Ag/Ag(1+), potential -1.3 V; extn. with distd. H2O, colorimetric analysis; | 99% |
With (CH3(CH2)3)4NClO4; 1-methylimidazole In dichloromethane Electrolysis; electrolysis (10-30 min) of O2 in CH2Cl2-0.1 M Bu4NClO4 soln. in presence of 0.1 M benzoic acid and 1-methylimidazole, working electrode: polymer-coated (poly-(Ru(vbpy)3)(2+)) glassy-carbon, reference electrode: Ag/Ag(1+), potential -1.0 V; extn. with distd. H2O, colorimetric analysis; | 97% |
oxygen
dihydrogen peroxide
Conditions | Yield |
---|---|
With perchloric acid In water at 20℃; Reagent/catalyst; Electrochemical reaction; | 100% |
With N21,N22-dimethyl-2,3,7,8,12,13,17,18-octaphenyl-5,10,15,20-tetrakis(4-trifluoromethylphenyl)porphyrin; trifluoroacetic acid In water; acetonitrile at 20℃; for 0.5h; Catalytic behavior; Solvent; Reagent/catalyst; Concentration; | 100% |
With diphenyl hydrazine In ethanol 0°C;; | 97% |
tris(benzene-1,2-dithiolate)molybdenum(VI)
B
dihydrogen peroxide
Conditions | Yield |
---|---|
In tetrahydrofuran Kinetics; not isolated, detected by UV; | A 100% B n/a |
tris(benzene-1,2-dithiolate)molybdenum(VI)
B
dihydrogen peroxide
Conditions | Yield |
---|---|
In tetrahydrofuran Kinetics; not isolated, detected by UV; | A 100% B n/a |
Conditions | Yield |
---|---|
With C57H42CoFe3N4 at 20℃; Catalytic behavior; Reagent/catalyst; Electrochemical reaction; | 100% |
With catalyst: Ba/carbon In perchloric acid aq. HClO4; Electrochem. Process; electroreduced on Ba/carbon in 0.1 M HClO4 (1 bar, 21+/-0.5°C, 1.2 V vs. RHE); | |
With catalyst: Ce/carbon In perchloric acid aq. HClO4; Electrochem. Process; electroreduced on Ce/carbon in 0.1 M HClO4 (1 bar, 21+/-0.5°C, 1.2 V vs. RHE); |
1,4-bis(trimethylsilyl)-2-methyl-1,4-cyclohexadiene
oxygen
dihydrogen peroxide
Conditions | Yield |
---|---|
In acetonitrile at 20℃; under 760.051 Torr; for 16h; Solvent; | 98% |
sulfuric acid
water
A
potassium hydrogensulfate
B
dihydrogen peroxide
Conditions | Yield |
---|---|
In sulfuric acid hydrolysis by heating; simultaneous distn. (by H2O vapor);; distn.; 40-60% aq. soln. of H2O2;; | A n/a B 95% |
In sulfuric acid aq. H2SO4; hydrolysis by heating; simultaneous distn. (by H2O vapor);; distn.; 40-60% aq. soln. of H2O2;; | A n/a B 95% |
In sulfuric acid hydrolysis by heating; simultaneous distn. (by H2O vapor);; distn.;; | A n/a B 92% |
B
dihydrogen peroxide
Conditions | Yield |
---|---|
With HBF4*Et2O In further solvent(s) HBF4*Et2O is added to a soln. of copper dioxygen compound in propionitrile at -80°C, mixt. is stirred for 15 min;; ether is added, ppt. is allowed to settle, supernatant is transferred toa soln. of KI in distd. H2O and EtCOOH, ppt. is washed (ether) and supernatant is transferred again, mixt. containing KI is stirred for 15 min at room temp. and titrated (Na2S2O3); | A 94% B n/a |
Conditions | Yield |
---|---|
With N-doped carbon nanoflowers Reagent/catalyst; Electrochemical reaction; | 94% |
In water Electrochemical reaction; | 41.5% |
With nitrogen doped porous carbon nanoparticle derived from zeolitic imidazolate framework Reagent/catalyst; Electrochemical reaction; | 14% |
Conditions | Yield |
---|---|
In sulfuric acid Electrolysis; oxyhydrogen gas-cel; electrolyt: 0.5 n H2SO4; electrode spaces separated by a clay-diaphragma; electrodes: platinated Pt calcinated for 2 1/2 h at 1200-1400°C; 1 mA current strength; reaction time: 45 min; ice cooling;; | 93.5% |
In sulfuric acid aq. H2SO4; Electrolysis; oxyhydrogen gas-cel; electrolyt: 0.5 n H2SO4; electrode spaces separated by a clay-diaphragma; electrodes: platinated Pt calcinated for 2 1/2 h at 1200-1400°C; 1 mA current strength; reaction time: 45 min; ice cooling;; | 93.5% |
In sulfuric acid Electrolysis; oxyhydrogen gas-cel; electrolyt: 0.5 n H2SO4; electrode spaces separated by a clay-diaphragma; electrodes: platinated Pt calcinated for 2 1/2 h at 1200-1400°C; 2 mA current strength; reaction time: 45 min; ice cooling;; | 86.3% |
sulfuric acid monohydrate
A
caro's acid
B
dihydrogen peroxide
C
Marshall's acid
Conditions | Yield |
---|---|
without water, -10°C; | A 93.5% B 1.4% C 5.1% |
without water, -10°C; | A 93.5% B 1.4% C 5.1% |
Conditions | Yield |
---|---|
In water Electrolysis; spark electrolysis of a 0.1n NaCl solution below 10°C, 40 mA under O2;; | 90% |
In water Electrolysis; spark electrolysis of a 0.1n NaCl solution below 10°C, 40 mA under O2;; | 90% |
In water Electrolysis; spark electrolysis of a 0.1n NaCl solution below 10°C, 40 mA under H2;; | 80% |
In water Electrolysis; spark electrolysis of a 0.1n NaCl solution below 10°C, 40 mA under H2;; | 80% |
A
(bis(2-quinolylmethyl)(2-pyridylmethyl)amine)(triphenylphosphino)copper(I) perchlorate
B
dihydrogen peroxide
Conditions | Yield |
---|---|
With HBF4*Et2O In further solvent(s) HBF4*Et2O is added to a soln. of copper dioxygen compound in propionitrile at -80°C, mixt. is stirred for 15 min; ether is added, ppt. is allowed to settle, supernatant is transferred toa soln. of KI in distd. H2O and EtCOOH, ppt. is washed (ether) and supernatant is transferred again, mixt. containing KI is stirred for 15 min at room temp. and titrated (Na2S2O3); | A 89% B n/a |
Conditions | Yield |
---|---|
In diethyl ether; dichloromethane to a soln. of Cu-complex in CH2Cl2 at -80°C under Ar (generated in situ from (((C5H4NCH2CH2)2NCH2)2(C6H3O)Cu2)PF6 and O2) was added 10 equiv. HPF6/Et2O (purple soln. instantly turned blue), mixt. stirred 15 min; addn. Et2O, pptn., washed (ether); | A n/a B 88% |
dihydrogen peroxide
Conditions | Yield |
---|---|
With HBF4 or HPF6 React. with excess HBF4 or HPF6.; | 88% |
hydrogenchloride
[RhCl(O2)(2,6-(C(Me)=NiPr)2C5H3N)]
dihydrogen peroxide
Conditions | Yield |
---|---|
In water detd. by iodometry; | 88% |
hydrogenchloride
[(6-t-butyl-phenyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine)Cu(I)]B(C6F5)4
oxygen
B
dihydrogen peroxide
Conditions | Yield |
---|---|
In diethyl ether under Ar; O2 bubbled through soln. of Cu complex in Et2O at -80°Cfor 10 s; excess O2 removed; HCl in Et2O added at -80°C; stirred for 30 min; warmed to room temp.; distd. H2O added; stirred at room temp. for 1 h; Et2O layer washed with pentane; ppt. recrystd. from THF-pentane; vac. dried; elem. anal.; | A 85% B 80% |
B
dihydrogen peroxide
Conditions | Yield |
---|---|
With 2HPF6*Et2O -80°C;; | A 77% B 81% |
Conditions | Yield |
---|---|
With sodium persulfate; tris(bipyridine)ruthenium(II) dichloride hexahydrate In aq. buffer for 2h; pH=10; pH-value; Irradiation; Inert atmosphere; Darkness; | A 8.8% B 80% |
With anthracene; cerium(IV) In sulfuric acid Electrochem. Process; the discharge of electrochemically generated holes at an anthracene/water interface at 400 μA cm**-2 in 0.28 M Ce(4+) in 12 M H2SO4; | |
With air; carbon nanodots-Co3O4-Fe2O3 photoanode pH=13.6; Irradiation; Electrochemical reaction; | |
With tetrakis(N-methy.4-pyridyl) porphyrin copper tetrakis(trifluoromethanesulfonate) In aq. phosphate buffer pH=7; Electrolysis; |
Conditions | Yield |
---|---|
With oxygen In sodium hydroxide Irradiation (UV/VIS); photolysis (254 nm) of an oxygen-satd. soln. of Pb compd. in aq. NaOH at room temp. (continuous stream of O2); not isolated; UV spect.; | A 80% B >1 |
dihydrogen peroxide
Conditions | Yield |
---|---|
With H(1+) In not given protonation;; | 80% |
3,5-Di-tert-butylcatechol
A
3,5-di-tert-butyl-o-benzoquinone
B
dihydrogen peroxide
Conditions | Yield |
---|---|
With [(6-chloro-N2,N2,N4,N4-tetrakis(pyridin-2-ylmethyl)-1,3,5-triazine-2,4-diamine)Cu(II)(-OH)2Cu(II)].(ClO4)2; oxygen In methanol at 25℃; pH=6; Kinetics; Mechanism; pH-value; | A n/a B 78% |
With [CoII(3,5-ditert-butylsemiquinonate)(hydrotris(3,5-dimethylpyrazolyl)borate)]; oxygen In toluene at 39.84℃; under 760.051 Torr; for 24h; pH=4.4; Inert atmosphere; | |
With [Cu{(5-pyrazinyl)tetrazolate}(1,10-phenanthroline)2](NO3)0.5(N3)0.5·2(H2O); oxygen In methanol at 25℃; for 0.75h; Catalytic behavior; Kinetics; Mechanism; |
Conditions | Yield |
---|---|
With [Cu(N,N-bis(2-pyridylmethyl)amine)](BF4)2 at 24.84℃; pH=6.7; Catalytic behavior; Reagent/catalyst; Electrolysis; | 77% |
With [Cu(N,N-bis(2-pyridylmethyl)amine)](BF4)2 at 24.84℃; for 0.0194444h; pH=6.7; Catalytic behavior; Reagent/catalyst; Electrolysis; | 67% |
With NiFe-layered double hydroxide derived mixed metal oxide(at)carbon nitride for 1.5h; pH=3; Kinetics; Reagent/catalyst; Irradiation; | 63% |
(2,6-bis(4,4-dimethyloxazolinyl)-3,5-dimethylphenyl)Ir(acetate)(OOH)
A
(2,6-bis(4,4-dimethyloxazolinyl)-3,5-dimethylphenyl)Ir(acetate)(H)
B
dihydrogen peroxide
Conditions | Yield |
---|---|
With sulfuric acid; oxygen at 20℃; under 2280.15 Torr; Inert atmosphere; | A n/a B 77% |
dihydrogen peroxide
Conditions | Yield |
---|---|
With HPF6*Et2O In dichloromethane react. with an excess of acid; further unidentified Cu(II) products; detn. by iodometric titration; | 75% |
Conditions | Yield |
---|---|
With N-hydroxyphthalimide; oxygen In ethyl acetate at 75℃; under 7600.51 Torr; for 12h; Temperature; Solvent; Reagent/catalyst; Pressure; Autoclave; Industrial scale; | A 75% B 57% |
[(bathocuproine)Pd(O2)]
acetic acid
(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate
B
dihydrogen peroxide
Conditions | Yield |
---|---|
In dichloromethane-d2 mixing palladium complex with acetic acid in CD2Cl2 in NMR tube for 5 min; detected by NMR; | A n/a B 73% |
[(bathocuproine)Pd(O2)]
sulfuric acid
A
(C6H5)2(CH3)2C6H2(C3HN)2*Pd(2+)*SO4(2-)=(C6H5)2(CH3)2C6H2(C3HN)2PdSO4
B
dihydrogen peroxide
Conditions | Yield |
---|---|
In not given | A n/a B 73% |
oxygen
B
dihydrogen peroxide
Conditions | Yield |
---|---|
With hydrogen cation In water Kinetics; Electrochem. Process; overvoltage of O2 reduction and H2O2 yield (catalytic effect) dependingon pH of soln. (1 - 8); cyclic voltammetry; voltammetry on glassy carbon rotating ring - disc electrode; | A n/a B 70% |
Conditions | Yield |
---|---|
In tetrachloromethane; water byproducts: H3PO4; to suspn. of P2O5 in CCl4 added aq. H2O2 (70 wt %) dropwise (mole ratio >0.9) at 2°C under stirring, monitoring of temp., stirred for 2 h; aq. phase sepd., CCl4 layer extd. (deionized H2O), combined aq. solns.; | 100% |
In tetrachloromethane; water byproducts: H3PO4; to suspn. of P2O5 in CCl4 added aq. H2O2 (90 wt %) dropwise (mole ratio >0.9) at 2°C under stirring, monitoring of temp., stirred for 2 h; aq. phase sepd., CCl4 layer extd. (deionized H2O), combined aq. solns.; | 99% |
In tetrachloromethane; water at 0℃; for 3h; |
dihydrogen peroxide
(S)-methyl 2-benzyloxy-4-methylpentanoate
(S)-4-methyl-2-(phenylmethoxy)valeric acid
Conditions | Yield |
---|---|
With hydrogenchloride In methanol; water | 100% |
With hydrogenchloride In methanol; water | 100% |
Conditions | Yield |
---|---|
With nitrogen In gas Kinetics; very rapid react. of metastable excited state N2 in Ar with H2O2 in discharge-flow apparatus, total gas pressure: 1-5 Torr; not isolated, detected by fluorescence spect.; | 100% |
In gas Irradiation (UV/VIS); OH produced by pulsed photolysis of H2O2 at 248 nm (KrF excimer laser); | |
iron(III) In water Kinetics; catalitic decompn. of H2O2 was studied; catalyst: Fe(3+)-ion; spectrophotometry; |
(ethene)[N,N,N-tris(2-pyridylmethyl-κN)amine-κN]rhodium(I) hexafluorophosphate
dihydrogen peroxide
Conditions | Yield |
---|---|
In methanol N2-atmosphere; addn. of 35% aq. H2O2 to Rh-complex, stirring at -10°C for 1 h; pptn. on Et2O addn., collection (filtration), washing (Et2O), drying (vac.); elem. anal.; | 100% |
Rh(C6H12(NCH3)3)(C8H12)(1+)*PF6(1-)=[Rh(C6H12(NCH3)3)(C8H12)]PF6
dihydrogen peroxide
Rh(C6H12(NCH3)3)(C8H12O)(1+)*PF6(1-)=[Rh(C6H12(NCH3)3)(C8H12O)]PF6
Conditions | Yield |
---|---|
In methanol N2-atmosphere; addn. of 35% aq. H2O2 to Rh-complex, stirring at room temp. for 1 h; pptn. on Et2O addn., collection (filtration), washing (Et2O), drying (vac.); elem. anal.; | 100% |
Conditions | Yield |
---|---|
With acetic acid In chloroform at 20℃; for 12h; Inert atmosphere; Cooling with ice; | 100% |
(1R,2R)-[cyclohexane-N,N'-diamine](ethanedioato-O,O')platinum(II)
water
dihydrogen peroxide
Conditions | Yield |
---|---|
at 20℃; for 24h; Darkness; | 100% |
at 20℃; under 760.051 Torr; Darkness; |
Conditions | Yield |
---|---|
In water a soln.of H2O2 in anthraquinone (from the prepn. of H2O2 by the anthraquinone-method) is stirred with an aq. soln. of borax-NaOH at 30°C,to the formed aq. phase NaOH is added;; isoln. from the aq. phase and mother liqour;; | 99.8% |
In water a soln.of H2O2 in anthraquinone (from the prepn. of H2O2 by the anthraquinone-method) is stirred with an aq. soln. of borax-NaOH at 30°C,to the formed aq. phase NaOH is added;; isoln. from the aq. phase and mother liqour;; | 99.8% |
With florisil In water 15 kg MgSiO3 and 107 kg of H2O2 (in form of 20, 30 or 40weight% H2O2-soln.) are added to 1263 l of a soln. (15°C) containing 139 kg NaOH and 665 kg borax; further addition of H2O2 (equal amount) at 20°C and slow cooling down to 0°C;; separation and drying of the pptd. salt;; |
Conditions | Yield |
---|---|
In water stirring H2O2 (from anthraquinone process) in anthraquinone with aq. borax-NaOH-soln. at 30°C, addn. of NaOH to the aq. layer containing Na-perborate, borax and H2O2, pptn.;; | 99.8% |
In water stirring H2O2 (from anthraquinone process) in anthraquinone with aq. borax-NaOH-soln. at 30°C, addn. of NaOH to the aq. layer containing Na-perborate, borax and H2O2, pptn.;; | 99.8% |
In water formation of a NaBO2-soln. from borax and NaOH, treatment with H2O2-vapor at 30-35°C, apparatus described;; |
dihydrogen peroxide
Conditions | Yield |
---|---|
In water at 70℃; for 2h; | 99.6% |
Conditions | Yield |
---|---|
With aq. NH3 In water add. of 30 % aq. H2O2 and aq. NH3 to Re powder, stirring (room temp., 1 h), addn. of further H2O2 until a clear sol. is obtained, then boiling to destroy excess H2O2, addn. of aq. NBu4Br; filtration, recrystn. (MeOH); elem. anal.; | 99% |
Conditions | Yield |
---|---|
In methanol TaCl5 and H2O2 stirred in ice-water bath, KOH added, MeOH added, cooled to 5-8°C, MeOH added; filtered, washed with MeOH, dried in air for 45 min to 1 h; | 99% |
[(η6-p-cymene)RuCl2(η1-bis(diphenylphosphino)methane)]
dihydrogen peroxide
[(η(6)-cymene)RuCl2(η(1)-Ph2PCH2P(O)Ph2)]
Conditions | Yield |
---|---|
In tetrahydrofuran Ru complex treated with H2O2 in THF; | 99% |
dihydrogen peroxide
Conditions | Yield |
---|---|
In dichloromethane Ar-atmosphere; slight excess of aq. H2O2, stirring (room temp., 2 h); concn., pptn. on pentane addn., collection (filtration), washing (pentane), drying (reduced pressure); elem. anal.; | 99% |
dihydrogen peroxide
Conditions | Yield |
---|---|
In ethanol; water (N2); refluxing the Fe salt and ligand in EtOH for 2 h, stirring (room temp., 60 h), addn. of aq. H2O2 (1 h), addn. of aq. NH4PF6; filtration (Celite), washing (H2O), dissoln. (MeCN), removal of solvent (vac.); elem. anal.; | 99% |
Conditions | Yield |
---|---|
In methanol; water 30 % H2O2 was added slowly to soln. (Co(PyAS)2)Cl in MeOH and stired in air for 2 days; solid was collected and dried under vac.; | 99% |
1,1'-diphenylphosphinooctamethylferrocene
dihydrogen peroxide
Fe(1,2-bis(diphenylphosphinoxide)-3,4,5-trimethylcyclopentadienyl)2
Conditions | Yield |
---|---|
In dichloromethane Ar-atmosphere; addn. of 15 drops of 30% H2O2 to Fe-complex soln., stirring for 30 min; washing (H2O), drying of org. layer (MgSO4), solvent removal, recrystn. (CH2Cl2/pentane); elem. anal.; | 99% |
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