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EAST CHEMSOURCES LIMITED

ITEMS INDEX TOP GRADE GRADE I GRADEⅡ THE VOLUME FRACTION OF HYDROGEN/10-2 ≥ 99.95 99.

4-Chlorotoluene

Cas:1333-74-0

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Hydrogen

Cas:1333-74-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Sinotech Import&Export Corporation

1.Type: Hydrogen Gas 2. Molecular formula: H2 3. Formula weight: 2.02 4. CAS: 1333-74-0 5. EINECS: 215-605-7 6. InChI: 1S/H2/h1H 7. Melting point: -259 degree Celsius 8. Boiling point: -253 degree Celsius 9. Another name:

Hydrogen Gas

Cas:1333-74-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Hydrogen gas distributor Order 1333-74-0 CAS NO.1333-74-0

Cas:1333-74-0

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High Purity hydrogen

Cas:1333-74-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Hydrogen Basic information Product Name: Hydrogen Synonyms: Dihydrogen;H2;hydrogen,compressed;hydrogen,highpurity;hydrogen,refrigeratedliquid(cryogenicliquid);hydro

1333-74-0 Hydrogen H2

Cas:1333-74-0

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 1333-74-0 with competitive price

Cas:1333-74-0

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

1333-74-0 Hydrogen H2 Application:1333-74-0 Hydrogen H2

1333-74-0 Hydrogen H2

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

1333-74-0 Hydrogen H2Appearance:white powder Storage:2-6℃ Package:normal package Application:1333-74-0 Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea LCL/FCL for large amount.

1333-74-0 Hydrogen H2

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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HENAN SUNLAKE ENTERPRISE CORPORATION

Our Services 1.Certificate Of Analysis (COA) 2.Material Safety Data Sheet (MSDS) 3.Route of synthesis (ROS) 4.Method of Aanlysis (MOA) 5.Nuclear Magnetic Resonance (NMR) 6.Packing pictures and loading video before loading 7.Free S

Hydrogen 1333-74-0 H2

Cas:1333-74-0

Min.Order:50 Gram

Negotiable

Type:Trading Company

inquiry

Qingdao Sigma Chemical Co., Ltd.

Qingdao Sigma Chemical Ltd is is a global chemical industry manufacturers and suppliers of pharmaceuticals and intermediates, peptide,Nootropis etc API, food and feed additives, herbal extracts, agrochemicals and fine chemicals etc. Our Labo

High Quality Hydrogen

Cas:1333-74-0

Min.Order:1 Gram

FOB Price: $1.0

Type:Trading Company

inquiry

Chengdu Taiyu Industrial Gases Co., Ltd.

Hydrogen H2 CAS No.: 1333-74-0 EINECS No.: 215-605-7 UN No.: UN1049 Purity: 99.995%-99.999% Dot Class: 2.1 Appearance: Colorless, flammable, odorless gas. Grade Standard: Industrial Grade, Medical Grade, Electronic Grade.

Hydrogen H2

Cas:1333-74-0

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

inquiry

Zibo Dijia Special Gas Co., Ltd.

With 99.9% high purity H2 gas, quality assurance, price concessions Appearance:colorless Port:Tianjin

Export standard H2-Hydrogen gas in cylinders

Cas:1333-74-0

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Fine Chemicals Co., Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & CommercialHenan Fine Chemicals Co., LTD. is a diversified technology - oriented integrated company, which mainly concentrates on fine chemicals. Our company is committed to becom

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Run-Biotech Co., Ltd.

Shanghai, Run-Biotech Co., Ltd is a leading domestic pharmaceutical, biopharmaceutical, and health care products R & D outsourcing services company. As an innovation-driven and customer-focused company, Run Biotech provides a broad and integrated por

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Minshang Biotechnology Co., Ltd

1333-74-0 Hydrogen H2 Application:1333-74-0

1333-74-0

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synova( Tianjin ) Chemical Technology Co,.Ltd

The company have effective management team, professional technical R & D personnel, the service spirit of customer oriented. We have long-term cooperation with famous domestic manufacturer, and excellent customer resources overseas. We are skilled in

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Skyrun Industrial Co.,Ltd

High main content, prompt shipment Application:Medical intermediate; Used in organic synthesis;

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fenjun Chemical Co Ltd.

1333-74-0 Hydrogen H2 Application:1333-74-0 Hydrogen H2

1333-74-0 Hydrogen H2

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

1333-74-0

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemical Co.Ltd

Manufacturer,strong R&D,professional team Storage:Store in a cool, dry place. Store in a tightly closed container. Package:according to your requirement Application:ZhiShang Chemical is owned by ZhiShang Group, is a professional new-type chemicals en

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

NovaChemistry

high purity Application:Drug intermediates Materials intermediates and active molecules

dihydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Sigma-Aldrich Chemie GmbH

Application:Hydrogen is a colourless, odourless, and flammable gas that is much lighter than air. It is used as a carrier gas in gas chromatography and as a fuel gas for flame ionization detectors (FID). Hydr...

Hydrogen

Cas:1333-74-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

water
7732-18-5

water

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
With aluminium; sodium hydroxide at 21℃; under 758 Torr; Product distribution / selectivity; Sealed tube;100%
With Ce0896Y0.05Nb0054O2 at 1499.84℃; under 0.00750075 Torr; Reagent/catalyst;100%
With bis(pentamethylcyclopentadienyl)iron(II); Mn(bpy)2Br2 In acetonitrile for 22h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Sealed tube;100%
methanol
67-56-1

methanol

A

carbon dioxide
124-38-9

carbon dioxide

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
With water at 20℃; pH=4.5; Quantum yield; UV-irradiation; Inert atmosphere;A n/a
B 100%
With water at 350℃; Catalytic behavior; Temperature; Flow reactor;A n/a
B 14%
With catalyst: TiO2/2percent-wt Pt In neat (no solvent) byproducts: formaldehyde; Irradiation (UV/VIS); photolysis (500 W Xe-lamp 350 and 400 nm, 25°C); IR spectroscopy, gas chromy.;
formic acid
64-18-6

formic acid

A

carbon dioxide
124-38-9

carbon dioxide

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
With sodium formate at 20℃; Catalytic behavior; Green chemistry; chemoselective reaction;A n/a
B 100%
With [pentamethylcyclopentadienyl*Ir(2,2′-bpyO)(OH)][Na] In water at 80℃; for 1h; Reagent/catalyst;A n/a
B 99%
With (1,2,3,4,5-pentamethylcyclopentadienyl)Ir[κ2(N,N’)-(S,S)-N-triflyl-1,2-diphenylethylenediamine] In 1,2-dimethoxyethane; water at 0℃; for 53h; Reagent/catalyst; Time; Temperature; Solvent;A n/a
B 85%
indium
7440-74-6

indium

water
7732-18-5

water

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
byproducts: In2O3; at 473°K and then at 673-773°K more;100%
caesium hydride

caesium hydride

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
vacuum, below 300°C;100%
In neat (no solvent) discoloration of CsH under influence of glow discharge with formation of H2;;
In neat (no solvent) discoloration of CsH under influence of glow discharge with formation of H2;;
rubidium hydride

rubidium hydride

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
vacuum, below 300°C;100%
In neat (no solvent) influence of glow discharge;;
In neat (no solvent) influence of glow discharge;;
acetic acid
64-19-7

acetic acid

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
Fe(I)2[μ-SCH2CH2OCH2CH2S-μ](CO)6 In tetrahydrofuran Electrolysis; under N2; electrolysis of MeCN soln. of Fe complex contg. CH3COOH at 2.30 V; detd. by chromatographic analysis;100%
[Fe(I)2(CO)6(μ-S-N,N-bis(thiomethyl)-p-methoxyaniline)] In acetonitrile Kinetics; Electrolysis; at -2.18 V (vs. Fc/Fc(+));90%
With tetra-n-butylammonium hexafluorophosphate; [CH3C(O)SCH2C(O)N(CH2SFe(CO)3)2] In acetonitrile Kinetics; Electrolysis; at -2.34 V (Fc/Fc(+)) for 0.5 h; gas chromy.;90%
[Fe(μ-S2(CH2)3)(CN)(CO)4(PMe3)](1-)
392334-61-1, 371241-08-6, 392333-87-8, 1226500-22-6

[Fe(μ-S2(CH2)3)(CN)(CO)4(PMe3)](1-)

sulfuric acid
7664-93-9

sulfuric acid

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In water Electrolysis; electrolysis of soln. of Fe2(CO)4(CN)(PMe3)S2(CH2)3 with 50 equiv. H2SO4at -1.2 V for 15 min; GC analysis;100%
vanadium sulfate

vanadium sulfate

A

hydrogen
1333-74-0

hydrogen

B

sulfur
7704-34-9

sulfur

Conditions
ConditionsYield
1690°C complete decompn.;A 100%
B n/a
red heat;A 7%
B n/a
400°C;
trifluoroacetic acid
76-05-1

trifluoroacetic acid

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
With potassium hexafluorophosphate; C27H29BrN5Pd(1+)*BF4(1-); tert-butylammonium hexafluorophosphate(V) In N,N-dimethyl-formamide Electrochemical reaction;100%
With [Mn(2,2’-bipyridine)3]+[(CO)3Mn(μ-phenylsulfide)3Mn(CO)3]- In acetonitrile Catalytic behavior; Mechanism; Electrolysis;95%
With [(cis-C2H2(PPh2)2)Ni(μ-H)(μ-S2C3H6)Fe(CO)(cis-C2H2(PPh2)2)]BF4 In acetonitrile Catalytic behavior; Inert atmosphere; Schlenk technique; Electrolysis;93%
ammonia
7664-41-7

ammonia

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
byproducts: N2; red heat;100%
decompn., heated porcelain pipe, 1100.degreeC;75.7%
With catalyst: Ru/SiC In gas Kinetics; byproducts: N2; NH3 decompd. in integrated ceramic microreactor at 450-1000°C; analyzed by gas chromatograph (Porapak N, TCD detector);
hydrogen iodide
10034-85-2

hydrogen iodide

A

hydrogen
1333-74-0

hydrogen

B

iodine
7553-56-2

iodine

Conditions
ConditionsYield
Kinetics; Irradiation (UV/VIS); in glass vessel or uviol vessel, wavelenght higher than 2540Å;;A 100%
B 100%
Kinetics; Irradiation (UV/VIS); at room temperature, in quartz vessel; equilibrium; wavelenght lower than 2540Å;;A 92.3%
B 92.3%
995 °C; part of a Mg-S-I water splitting cycle;A 31%
B 31%
tripotassiumdecaisobutylpentaaluminum

tripotassiumdecaisobutylpentaaluminum

hydrogen cation

hydrogen cation

A

Isobutane
75-28-5

Isobutane

B

potassium ion

potassium ion

C

hydrogen
1333-74-0

hydrogen

D

Al(OH)2(1+)

Al(OH)2(1+)

Conditions
ConditionsYield
With water In water acid hydrolysis with 20% HCl; quantities of the products determined;A n/a
B 100%
C n/a
D n/a
LaFe(1+)
111496-23-2

LaFe(1+)

cyclohexane
110-82-7

cyclohexane

A

LaFeC6H6(1+)

LaFeC6H6(1+)

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In gas reaction in a mass spectrometer; total pressure: 4E-6 Torr;A 100%
B 100%
ammonia borane complex
10043-11-5

ammonia borane complex

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
With [IrH2{(P(phenyl)2(o-C6H4CO))2H}] In tetrahydrofuran; water at 30℃; under 760.051 Torr; for 0.533333h; Catalytic behavior; Kinetics; Reagent/catalyst;100%
In neat (no solvent) at 50°C;;1.5%
With dihydrogen hexachloroplatinate In neat (no solvent) thermal decomposition of NH3BH3 milled with hydrogen hexachloroplatinate(IV) hydrate;
LaFe(1+)
111496-23-2

LaFe(1+)

propane
74-98-6

propane

A

LaFeC3H6(1+)

LaFeC3H6(1+)

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In gas reaction in a mass spectrometer; sample pressure 4E-7 Torr;A 100%
B 100%
(triphos)RhH3
100333-94-6

(triphos)RhH3

A

[(CH3C(CH2PPh2)3)Rh(CO)(H)]
124223-20-7, 101075-59-6

[(CH3C(CH2PPh2)3)Rh(CO)(H)]

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
With CO In dichloromethane-d2 Charging of a soln. of Rh-complex with CO (1 atm), soln. turns immediately bright yellow.; Monitored by (1)H-NMR.;A 100%
B n/a
methanol
67-56-1

methanol

{{(C5H5)2Y(μ-H)}3(μ3-H)}(1-)*Li(THF)4(1+)
90762-81-5

{{(C5H5)2Y(μ-H)}3(μ3-H)}(1-)*Li(THF)4(1+)

A

{{(C5H5)2Y(μ-OCH3)}3(μ3-H)}(1-)*{Li(THF)4}(1+)
111409-63-3

{{(C5H5)2Y(μ-OCH3)}3(μ3-H)}(1-)*{Li(THF)4}(1+)

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In tetrahydrofuran under inert gas; Y compound in THF and 3 equiv CH3OH combined at -195.8°C; warming to -78°C and stirring for 1.5 h; warming to room temp.; evapn. of the solvent; Y complex pptd. with toluene and centrifugated; chem. anal.;A 100%
B 100%
methanol
67-56-1

methanol

{{(C5H5)2Y(μ-H)}3(μ3-H)}(1-)*Li(THF)4(1+)
90762-81-5

{{(C5H5)2Y(μ-H)}3(μ3-H)}(1-)*Li(THF)4(1+)

A

{{(C5H5)2Y(μ-H)}{(C5H5)2Y(OCH3)}2(μ3-H)}(1-)*{Li(THF)4}(1+)
111435-10-0

{{(C5H5)2Y(μ-H)}{(C5H5)2Y(OCH3)}2(μ3-H)}(1-)*{Li(THF)4}(1+)

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In tetrahydrofuran under inert gas; Y compound in THF and 2 equiv CH3OH combined at -195.8°C; warming to -78°C and stirring for 1.5 h; warming to room temp.; evapn. of the solvent; Y complex pptd. with toluene and centrifugated; chem. anal.;A 100%
B 100%
methanol
67-56-1

methanol

{{(C5H5)2Y(μ-H)}3(μ3-H)}(1-)*Li(THF)4(1+)
90762-81-5

{{(C5H5)2Y(μ-H)}3(μ3-H)}(1-)*Li(THF)4(1+)

A

{{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+)
111435-08-6

{{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+)

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In tetrahydrofuran under inert gas; equiv. amts. of the Y compound in THF and CH3OH combined at -195.8°C; warming to -78°C and stirring for 1.5 h; warming to room temp.; evapn. of the solvent; Y complex pptd. with toluene and centrifugated; chem. anal.;A 100%
B 100%
methanol
67-56-1

methanol

{{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+)
111435-08-6

{{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+)

A

{{(C5H5)2Y(μ-H)}{(C5H5)2Y(OCH3)}2(μ3-H)}(1-)*{Li(THF)4}(1+)
111435-10-0

{{(C5H5)2Y(μ-H)}{(C5H5)2Y(OCH3)}2(μ3-H)}(1-)*{Li(THF)4}(1+)

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In tetrahydrofuran under inert gas; equiv. amts of the Y compound in THF and CH3OH combined at -195.8°C; warming to -78°C and stirring for 1.5 h; warming to room temp.; evapn. of the solvent; Y complex pptd. with toluene and centrifugated; chem. anal.;A 100%
B 100%
LaFe(1+)
111496-23-2

LaFe(1+)

2,3-dimethylbutane
79-29-8

2,3-dimethylbutane

A

LaFeC6H10(1+)

LaFeC6H10(1+)

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In gas reaction in a mass spectrometer; total pressure: 4E-6 Torr;A 100%
B 100%
LaFe(1+)
111496-23-2

LaFe(1+)

methyl cyclohexane
82166-21-0

methyl cyclohexane

A

LaFeC7H8(1+)

LaFeC7H8(1+)

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In gas reaction in a mass spectrometer; total pressure: 4E-6 Torr;A 100%
B 100%
(η(5):η(5)-fulvalene)Mo2(CO)6(H)2

(η(5):η(5)-fulvalene)Mo2(CO)6(H)2

A

(η(5):η(5)-fulvalene)Mo2(CO)6

(η(5):η(5)-fulvalene)Mo2(CO)6

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In tetrahydrofuran under N2, degassed soln. of ((C5H4)2)Mo2(CO)6H2 in THF kept at 20°C for 24 h; H2 detected by MS; soln. rotary evapd., filtered through alumina using acetone;A 100%
B n/a
5(CH3CH2)4N(1+)*Mo2Fe6S8(S(C6H5))9(5-)=((CH3CH2)4N)5Mo2Fe6S8(S(C6H5))9

5(CH3CH2)4N(1+)*Mo2Fe6S8(S(C6H5))9(5-)=((CH3CH2)4N)5Mo2Fe6S8(S(C6H5))9

thiophenol
108-98-5

thiophenol

A

{MoFe}(3-)

{MoFe}(3-)

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In N,N-dimethyl acetamide Kinetics; byproducts: Et4NSPh; under argon, to complex in DMA soln. of PhSH in DMA (500 equiv) was added, 25°C, 24 h, various yields of products for various ratios of educts; PhSSPh in DMA was added, products were not isolated;A n/a
B 100%
In acetonitrile Kinetics; byproducts: Et4NSPh; under argon, to complex in DMA soln. of PhSH in MeCN (1/1 molar ratio) was added, 25°C, 24 h, various yields of products for various ratios of educts; products were not isolated;A n/a
B 10%
In N,N-dimethyl acetamide byproducts: C6H5S(1-); Ar, excess PhSH; UV;A n/a
B >99
N-tert-butylaminoborane
7337-45-3

N-tert-butylaminoborane

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
With [IrH2{(P(phenyl)2(o-C6H4CO))2H}] In tetrahydrofuran; water Catalytic behavior; Kinetics; Thermodynamic data; Reagent/catalyst;100%
120-140°C;;
In neat (no solvent) at 10-15°C;
(biphenyl){Cr(CO)2}2(μ-dimethylphosphinomethane)
90502-53-7

(biphenyl){Cr(CO)2}2(μ-dimethylphosphinomethane)

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
under N2, high vac. line, swivel side arm is charged with acid (degassed), sample of metal complex is placed in the react. flask, acid is poured onto the complex (27°C), react. for 10 min; MS;100%
(PPh3)3CoH(N2)
21373-88-6, 16920-54-0

(PPh3)3CoH(N2)

2,2,2-trifluoroethyl benzoate
1579-72-2

2,2,2-trifluoroethyl benzoate

A

(trifluoroethoxo)tris(triphenylphosphine)cobalt(I)
99668-73-2

(trifluoroethoxo)tris(triphenylphosphine)cobalt(I)

B

benzoic acid benzyl ester
120-51-4

benzoic acid benzyl ester

C

nitrogen
7727-37-9

nitrogen

D

hydrogen
1333-74-0

hydrogen

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In toluene PhCOOCH2CF3 added to toluene soln. of CoH(N2)(PPh3)3, evacuated, stirred at 20°C for 2 days;A n/a
B 28%
C 100%
D 17%
E 32%
bis[bis(trimethylsilyl)amido][[(trimethylsilyl)methyl]stannyl]praseodymium*0.5(dimethoxyethane)

bis[bis(trimethylsilyl)amido][[(trimethylsilyl)methyl]stannyl]praseodymium*0.5(dimethoxyethane)

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

hydrogen
1333-74-0

hydrogen

C

praseodymium(III) chloride
10361-79-2

praseodymium(III) chloride

D

Chlor-tris<(trimethylsilyl)methyl>zinn
34570-67-7

Chlor-tris<(trimethylsilyl)methyl>zinn

E

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran mixt. od dry HCl (excess), Pr/Sn-complex and THF keeping dor 1 d at room temp., THF replacing by hexane in usual way; ppt. filtration of, hexane-soln. evapn. (vac.), residue crystn. twice (hexane, -70°C), GLC of volatiles;A 50%
B 87%
C 100%
D 76.2%
E 33.3%
18-crown-6 ether
17455-13-9

18-crown-6 ether

nido-NB10H13

nido-NB10H13

potassium triethylborohydride

potassium triethylborohydride

A

bis[(18-crown-6)potassium][undecahydro-7-aza-nido-undecaborate]

bis[(18-crown-6)potassium][undecahydro-7-aza-nido-undecaborate]

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In tetrahydrofuran byproducts: BEt3; molar ratio NB10H13:KBHEt3 1:2, cooling (-78°C), stirring (2 h, room temp.); evapn. (vac.), dissoln. (THF), crystn. (-40°C), recrystn. (CH3CN); elem. anal.;A 23%
B 100%
hydrogen
1333-74-0

hydrogen

oxygen
80937-33-3

oxygen

water
7732-18-5

water

Conditions
ConditionsYield
platinum In neat (no solvent) reaction at room temperature;;100%
platinum In neat (no solvent) reaction at room temperature;;100%
alpha-alumina impergnated with patinum nitrate and tin (II) chloride calcinated at 500C (0.08 wtpercent Pt; 0.08 wtpercent Sn) at 300℃; under 9000.9 Torr; Conversion of starting material; Gas phase;
hydrogen
1333-74-0

hydrogen

cadmium(II) oxide

cadmium(II) oxide

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
3h at 290-300°C, flowing hydrogen, react. start even at 282°C;100%
below temp. of sintering;
sulfur dioxide
7446-09-5

sulfur dioxide

hydrogen
1333-74-0

hydrogen

A

disulfur
23550-45-0

disulfur

B

hydrogen sulfide
7783-06-4

hydrogen sulfide

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2O; redn. of SO2 by H2 (1:2), SO2-conversion at 114°C practically 100%;;A 100%
B n/a
In neat (no solvent) byproducts: H2O; redn. of SO2 by H2 (1:2), SO2-conversion at 114°C practically 100%;;A 100%
B n/a
In neat (no solvent) byproducts: H2O; redn. of SO2 by H2, investigation of equilibrium constants;;
goethite

goethite

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In neat (no solvent) Isothermal heat treatment for 2 h at 400°C.;100%
hydrogen
1333-74-0

hydrogen

acetonitrile
75-05-8

acetonitrile

hydrogen cyanide
74-90-8

hydrogen cyanide

Conditions
ConditionsYield
In gas 600-850°C;100%
with H atom;
With catalyst: 19percent Cr2O3/Al2O3 byproducts: methane; react. at 875 K; monitored by gas chromy.;
[Ru(H)(Cl)(tris(m-sulfonatophenyl)phosphine)3]

[Ru(H)(Cl)(tris(m-sulfonatophenyl)phosphine)3]

Na(1+)*{BH4}(1-)*99H2O=Na{BH4}*99H2O

Na(1+)*{BH4}(1-)*99H2O=Na{BH4}*99H2O

hydrogen
1333-74-0

hydrogen

tris-(m-sulfonatophenyl)phosphine
91171-35-6

tris-(m-sulfonatophenyl)phosphine

[RuH2(tris(sulfonatophenyl)phosphine)4]*NaCl

[RuH2(tris(sulfonatophenyl)phosphine)4]*NaCl

Conditions
ConditionsYield
In water (Ar); slow H2 bubbling through Ru- and org.-compd. soln. with stirring (room temp., 10 min), NaBH4 addn.; cooling, evapn. to dryness, drying (vac., 2 h, 50°C);100%
[Ru(Cl)(μ-Cl)(tris(m-sulfonatophenyl)phosphine)2]2

[Ru(Cl)(μ-Cl)(tris(m-sulfonatophenyl)phosphine)2]2

Na(1+)*{BH4}(1-)*99H2O=Na{BH4}*99H2O

Na(1+)*{BH4}(1-)*99H2O=Na{BH4}*99H2O

hydrogen
1333-74-0

hydrogen

tris-(m-sulfonatophenyl)phosphine
91171-35-6

tris-(m-sulfonatophenyl)phosphine

[RuH2(tris(sulfonatophenyl)phosphine)4]*2NaCl

[RuH2(tris(sulfonatophenyl)phosphine)4]*2NaCl

Conditions
ConditionsYield
In water (Ar); slow H2 bubbling through Ru- and org.-compd. soln. with stirring (room temp., 10 min), NaBH4 addn.; cooling, evapn. to dryness, drying (vac., 2 h, 50°C);100%
Conditions
ConditionsYield
from As soln. with hydrogen developed on cathode;100%
from As soln. with hydrogen developed on cathode;100%
(triphos)RhH3
100333-94-6

(triphos)RhH3

hydrogen
1333-74-0

hydrogen

[(CH3C(CH2PPh2)3)Rh(CO)(H)]
124223-20-7, 101075-59-6

[(CH3C(CH2PPh2)3)Rh(CO)(H)]

Conditions
ConditionsYield
With CO In benzene-d6 High Pressure; Charging of Rh-complex soln. with CO/H2 (500 psi), heating in a high-pressure react. vessel for 4.5 h at 75°C.; Monitored by (1)H-NMR.;100%
With CO In benzene-d6 Charging of Rh-complex soln. with CO/H2 (1 atm).; Monitored by (1)H-NMR.;100%
FeRu(CO)6(σ-N,μ2-N`,η2-C=N`-1,4-di-isopropyl-1,4-diaza-1,3-butadiene)
90219-33-3

FeRu(CO)6(σ-N,μ2-N`,η2-C=N`-1,4-di-isopropyl-1,4-diaza-1,3-butadiene)

hydrogen
1333-74-0

hydrogen

1,2-ethanediylbis(isopropylamido)hexacarbonylironruthenium

1,2-ethanediylbis(isopropylamido)hexacarbonylironruthenium

Conditions
ConditionsYield
In dichloromethane-d2 Kinetics; soln. was pressurized with H2; conversion was monitored by 1H NMR;100%
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