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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Trimethylchlorosilane Manufacturer/High quality/Best price/In stock

Cas:75-77-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Shandong Xinhua Pharmaceutical Co.,Ltd

Appearance:Liquid colorless Storage:tightly from light Package:250kg/drum Transportation:sea Port:Qingdao

Trimethylchlorosilane

Cas:75-77-4

Min.Order:1000 Kilogram

Negotiable

Type:Manufacturers

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HANGZHOU YUNUO CHEMICAL CO.,LTD

moderate price & quick delivery Appearance:Colorless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application:Chlorotrimethylsilane have been u

CHLOROTRIMETHYLSILANE

Cas:75-77-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality chlorotrimethylsilane supplier in China

Cas:75-77-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay 98%min -----------------------------------------------------------------------------------------------

High purity Various Specifications Chlorotrimethylsilane CAS:75-77-4

Cas:75-77-4

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

inquiry

Hubei Vanz Pharm Co.,Ltd

1 high purity 2 able to provide COA/HNMR/HPLC 3 High quality 4 low price 5 Best service Appearance:liquid Storage:rm Package:bag/bottle/drum Application:pharmaceutical intermediate Transportation:common transportation Port:Shanghai, Wuhan

Trimethylchlorosilane

Cas:75-77-4

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

Price of trimethylchlorosilane CAS NO.75-77-4

Cas:75-77-4

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; ...... Appearance:Colorless liquid Storage:Store at RT. Package:170kg/drum

Factory supply Chlorotrimethylsilane CAS 75-77-4 with low price

Cas:75-77-4

Min.Order:170 Kilogram

FOB Price: $4.0 / 6.0

Type:Trading Company

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Hefei TNJ chemical industry co.,ltd

1,ISO Certificate 2,Factory price 3,Free sample and Fast delivery Appearance:Colorless transparent liquid Storage:All products should be stored at a dry and ventilated location away from fire and other dangerous goods, and should avoid direct sunl

Chlorotrimethylsilane,CAS 75-77-4

Cas:75-77-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Chlorotrimethylsilane

Cas:75-77-4

Min.Order:1

Negotiable

Type:Other

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

Chlorotrimethylsilane

Cas:75-77-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Chlorotrimethylsilane CAS 75-77-4 In stock

Cas:75-77-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: Chlorotrimethylsilane Synonyms: DOW CORNING(R) PRODUCT Z-1224;CHLOROTRIMETHYLSILANE;SILANE M3;TMCS;TMSCL;TRIMETHYLSILYL CHLORIDE;TRIMETHYL SILICON CHLORIDE;TRIMETHYLCHLOROSILANE CAS: 75-77-4 MF: C3H9ClSi

75-77-4 Chlorotrimethylsilane

Cas:75-77-4

Min.Order:1 Gram

FOB Price: $8900.0

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Trimethylchlorosilane Synonym: Chlorotrimethylsilane; Trimethylsilyl chloride; TMS. CAS No.: 75-77-4 Molecular Formula:(CH3)3SiCl Molecular Weight:108.65 Properties: Colorless, transparent liquid Applications: It is used a

Trimethylchlorosilane CAS:75-77-4

Cas:75-77-4

Min.Order:2 Metric Ton

FOB Price: $1.0

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

Advantages: Hubei XinRunde Chemical Co., Ltd is a renowned pharmaceutical manufacturer. We can offer high quality products at competitive price in quick delivery with 100% custom pass guaranteed. Never stop striving to offer our best s

Chlorotrimethylsilane Manufacturer 75-77-4 Organic Synthesis Intermediate

Cas:75-77-4

Min.Order:10 Gram

Negotiable

Type:Other

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen

Chlorotrimethylsilane organosilicon compounds

Cas:75-77-4

Min.Order:1 Kilogram

FOB Price: $15.0 / 20.0

Type:Trading Company

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Silane,chlorotrimethyl-/ LIDE PHARMA- Factory supply / Best price

Cas:75-77-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Kemi-Works Chemical Co., Ltd

75-77-4 Trimethylchlorosilane Molecular Formula:(CH3)3SiCl Molecular Weight:108.65 Properties:Colorless, transparent liquid Technical Specifications: Content of Trimethylchlorosilane(%):≥98.0 Refractive Index( ):1.389 Density(2

Trimethylchlorosilane

Cas:75-77-4

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

Trimethylchlorosilane CAS NO.75-77-4

Cas:75-77-4

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:75-77-4

Cas:75-77-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Appearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:By Sea/Air/Courier Port:Qingdao

Chlorotrimethylsilane 75-77-4

Cas:75-77-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

Trimethylchlorosilane

Cas:75-77-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 100000.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Chlorotrimethylsilane

Cas:75-77-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Chlorotrimethylsilane

Cas:75-77-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality chloro trimethyl silane

Cas:75-77-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Trimethylchlorosilane

Cas:75-77-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Name: Chlorotrimethylsilane. Synonym:(CH3)3SiCl;DOWCORNING(R)PRODUCTZ-1224;CHLOROTRIMETHYLSILANE;SILANEM3;TMCS;TMSCL;TRIMETHYLSILYLCHLORIDE;TRIMETHYLSILICONCHLORIDE CAS No: 75-77-4. Molecular formula: C3H9ClSi. Molecular weight: 108.64206.

Chlorotrimethylsilane manufacture

Cas:75-77-4

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

Chlorotrimethylsilane

Cas:75-77-4

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

chloro(trimethyl)silane

Cas:75-77-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Chlorotrimethylsilane

Cas:75-77-4

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

tetramethylsilane
75-76-3

tetramethylsilane

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

Conditions
ConditionsYield
With 1,2-dichloro-ethane; aluminium trichloride at 130℃; for 17h;100%
With hydrogenchloride; aluminium trichloride
With chlorine; iodine In tetrachloromethane at 30℃;
With hydrogenchloride
diethylchlorophosphine
686-69-1

diethylchlorophosphine

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

1-(1-tert-Butyl-2,2-diethyl-diphosphanyl)-2,2-dimethyl-propan-1-one
131551-67-2

1-(1-tert-Butyl-2,2-diethyl-diphosphanyl)-2,2-dimethyl-propan-1-one

Conditions
ConditionsYield
at 100℃; for 1h;A n/a
B 100%
Chloro(chloromethyl)dimethylsilane
1719-57-9

Chloro(chloromethyl)dimethylsilane

trimethylsilyl isocyanate
1118-02-1

trimethylsilyl isocyanate

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

(chloromethyl)isocyanatodimethylsilane
86845-05-8

(chloromethyl)isocyanatodimethylsilane

Conditions
ConditionsYield
for 9h; Heating;A 100%
B 95%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

(trimethylsilyl)acetyl chloride
63877-23-6

(trimethylsilyl)acetyl chloride

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

2-<(trimethylsilyl)oxy>propenenitrile
54276-53-8

2-<(trimethylsilyl)oxy>propenenitrile

Conditions
ConditionsYield
A 100%
B 76%
diethyl chlorophosphate
814-49-3

diethyl chlorophosphate

1-(Trimethylsilyl)imidazole
18156-74-6

1-(Trimethylsilyl)imidazole

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

1-(Diethoxyphosphinyl)imidazole
16913-98-7

1-(Diethoxyphosphinyl)imidazole

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
diethyl phosphorochloridothioate
2524-04-1

diethyl phosphorochloridothioate

1-(Trimethylsilyl)imidazole
18156-74-6

1-(Trimethylsilyl)imidazole

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

Imidazol-1-yl-phosphonothioic acid O,O-diethyl ester
107313-21-3

Imidazol-1-yl-phosphonothioic acid O,O-diethyl ester

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
diethyl phosphorochloridothioate
2524-04-1

diethyl phosphorochloridothioate

1-trimethylsilyl-1,2,4-triazole
18293-54-4

1-trimethylsilyl-1,2,4-triazole

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

[1,2,4]Triazol-1-yl-phosphonothioic acid O,O-diethyl ester

[1,2,4]Triazol-1-yl-phosphonothioic acid O,O-diethyl ester

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

tert-butyldimethylsilyl cyanide
56522-24-8

tert-butyldimethylsilyl cyanide

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide at 100 - 180℃; for 4h;A n/a
B 100%
A n/a
B 77%
methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

1-trimethylsilyl-1,2,4-triazole
18293-54-4

1-trimethylsilyl-1,2,4-triazole

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

1-Methanesulfonyl-1H-[1,2,4]triazole
75668-13-2

1-Methanesulfonyl-1H-[1,2,4]triazole

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
n-decanoyl chloride
112-13-0

n-decanoyl chloride

(trimethylsilyl)diphenylphosphine
17154-34-6

(trimethylsilyl)diphenylphosphine

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

(n-Decanoyl)diphenylphosphan
87361-17-9

(n-Decanoyl)diphenylphosphan

Conditions
ConditionsYield
In Petroleum ether for 0.5h;A n/a
B 100%
chloro-diphenylphosphine
1079-66-9

chloro-diphenylphosphine

1-(Trimethylsilyl)imidazole
18156-74-6

1-(Trimethylsilyl)imidazole

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

1-(di-phenylphosphino)imidazole
54877-59-7

1-(di-phenylphosphino)imidazole

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
diethyl phosphorylchloridite
589-57-1

diethyl phosphorylchloridite

1-(Trimethylsilyl)imidazole
18156-74-6

1-(Trimethylsilyl)imidazole

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

C7H13N2O2P
76089-86-6

C7H13N2O2P

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
1-(Trimethylsilyl)imidazole
18156-74-6

1-(Trimethylsilyl)imidazole

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

N-tosylimidazole
2232-08-8

N-tosylimidazole

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
1-(Trimethylsilyl)imidazole
18156-74-6

1-(Trimethylsilyl)imidazole

Diphenylphosphinic chloride
1499-21-4

Diphenylphosphinic chloride

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

1-(diphenylphosphinoyl)imidazole
71638-08-9

1-(diphenylphosphinoyl)imidazole

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
1-trimethylsilyl-1,2,4-triazole
18293-54-4

1-trimethylsilyl-1,2,4-triazole

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

1-(4-toluenesulfonyl)-1H-1,2,4-triazole
13578-51-3

1-(4-toluenesulfonyl)-1H-1,2,4-triazole

Conditions
ConditionsYield
In dichloromethane for 1h; Ambient temperature;A n/a
B 100%
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

(trimethylsilyl)diphenylphosphine
17154-34-6

(trimethylsilyl)diphenylphosphine

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

(n-Dodecanoyl)diphenylphosphan
87361-18-0

(n-Dodecanoyl)diphenylphosphan

Conditions
ConditionsYield
In Petroleum ether for 0.5h;A n/a
B 100%
undec-10-enoyl chloride
38460-95-6

undec-10-enoyl chloride

(trimethylsilyl)diphenylphosphine
17154-34-6

(trimethylsilyl)diphenylphosphine

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

Diphenyl(n-undec-10-enoyl)phosphan
87361-19-1

Diphenyl(n-undec-10-enoyl)phosphan

Conditions
ConditionsYield
In Petroleum ether for 0.5h;A n/a
B 100%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

cyanogen chloride
506-77-4

cyanogen chloride

C

S, SO2

S, SO2

Conditions
ConditionsYield
With thionyl chloride at 30 - 40℃; Product distribution; oth. reagent (SO2Cl2);A 100%
B 45%
C n/a
tetramethylsilane
75-76-3

tetramethylsilane

germaniumtetrachloride
10038-98-9

germaniumtetrachloride

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

chlorotrimethylgermane
1529-47-1

chlorotrimethylgermane

C

tetramethylgermane
865-52-1

tetramethylgermane

Conditions
ConditionsYield
aluminium bromide In neat (no solvent) molar ratio Me4Si/GeCl4 = 2/1, at 180°C for 2.75 h, cooled; NMR, mass spectra, chromy.;A 100%
B 18%
C 82%
aluminium bromide In neat (no solvent) molar ratio Me4Si/GeCl4 = 2/1, at 180°C for 4.5 h, cooled; NMR, mass spectra, chromy.;A 100%
B 23%
C 77%
aluminium bromide In neat (no solvent) molar ratio Me4Si/GeCl4 = 2/1, at 200°C for 3.5 h, cooled; NMR, mass spectra, chromy.;A 100%
B 13%
C 87%
tetramethylsilane
75-76-3

tetramethylsilane

germaniumtetrachloride
10038-98-9

germaniumtetrachloride

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

chlorotrimethylgermane
1529-47-1

chlorotrimethylgermane

C

dimethylsilicon dichloride
75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
aluminium bromide In neat (no solvent) molar ratio Me4Si/GeCl4 = 2/1, at 200°C for 15 h, cooled; NMR, mass spectra, chromy.;A 50%
B 100%
C 50%
bis(bis(trimethylsilyl)amino)ytterbium * 1,2-dimethoxyethane
90669-97-9

bis(bis(trimethylsilyl)amino)ytterbium * 1,2-dimethoxyethane

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

C

ytterbium(III) chloride
10361-91-8

ytterbium(III) chloride

D

ammonium chloride

ammonium chloride

Conditions
ConditionsYield
With hydrogenchloride In toluene condensing gaseous HCl with liquid nitrogen in an ampul containing toluene solution of (((CH3)3Si)2N)2Yb*CH3O(CH2)2OCH3; warming to room temperature; removing volatile compounds ((CH3)3SiCl, DME) by vac. condensation; vac. sublimation at 100°C (1E-2 mm): NH4Cl;;A 100%
B 90%
C 100%
D 92%
bis[bis(trimethylsilyl)amido][[(trimethylsilyl)methyl]stannyl]praseodymium*0.5(dimethoxyethane)

bis[bis(trimethylsilyl)amido][[(trimethylsilyl)methyl]stannyl]praseodymium*0.5(dimethoxyethane)

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

hydrogen
1333-74-0

hydrogen

C

praseodymium(III) chloride
10361-79-2

praseodymium(III) chloride

D

Chlor-tris<(trimethylsilyl)methyl>zinn
34570-67-7

Chlor-tris<(trimethylsilyl)methyl>zinn

E

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran mixt. od dry HCl (excess), Pr/Sn-complex and THF keeping dor 1 d at room temp., THF replacing by hexane in usual way; ppt. filtration of, hexane-soln. evapn. (vac.), residue crystn. twice (hexane, -70°C), GLC of volatiles;A 50%
B 87%
C 100%
D 76.2%
E 33.3%
dichloro(fluoro)(phenyl)silane
368-44-5

dichloro(fluoro)(phenyl)silane

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

1,1,1-trimethyl-3-phenyl-3-chloro-3-fluorodisilazane
1321987-17-0

1,1,1-trimethyl-3-phenyl-3-chloro-3-fluorodisilazane

Conditions
ConditionsYield
at 20℃;A n/a
B 100%
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

2-[(trimethylsilyl)oxy]benzoic acid trimethylsilyl ester
3789-85-3

2-[(trimethylsilyl)oxy]benzoic acid trimethylsilyl ester

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

2-chloro-2-methyl-4H-benzo[d][1,3,2]dioxasilin-4-one

2-chloro-2-methyl-4H-benzo[d][1,3,2]dioxasilin-4-one

Conditions
ConditionsYield
at 20℃; for 24h;A 100%
B 95%
dibutyltin chloride
683-18-1

dibutyltin chloride

1,3-diallyl-4-(trimethylsilyloxy)-2,6-dioxo-1,3,5-triazine
63226-47-1

1,3-diallyl-4-(trimethylsilyloxy)-2,6-dioxo-1,3,5-triazine

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

Bis(diallylisocyanurato)dibutyltin
80671-62-1

Bis(diallylisocyanurato)dibutyltin

Conditions
ConditionsYield
In neat (no solvent) mixt. heating (30-40 min, 120-160°C, distilling flask); exposition to vac. 1.33 hPa; elem. anal.;A >99
B 99.5%
trimethylsilanyl-acetic acid ethyl ester
4071-88-9

trimethylsilanyl-acetic acid ethyl ester

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

ethyl iodoacetae
623-48-3

ethyl iodoacetae

Conditions
ConditionsYield
With Iodine monochloride In tetrachloromethane for 0.5h; Ambient temperature;A n/a
B 99%
trimethylsilyl isocyanate
1118-02-1

trimethylsilyl isocyanate

N,N-diethylcarbamyl chloride
88-10-8

N,N-diethylcarbamyl chloride

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

diethylcarbamoyl isocyanate
40797-42-0

diethylcarbamoyl isocyanate

Conditions
ConditionsYield
With tin(IV) chloride at 100 - 120℃; for 5h;A 99%
B 90%
trimethylsilyl isocyanate
1118-02-1

trimethylsilyl isocyanate

N,N-Dimethylcarbamoyl chloride
79-44-7

N,N-Dimethylcarbamoyl chloride

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

dimethylcarbamoyl isocyanate
40797-41-9

dimethylcarbamoyl isocyanate

Conditions
ConditionsYield
With tin(IV) chloride at 100 - 120℃; for 5h;A 99%
B 90%
Phenyltrichlorosilane
98-13-5

Phenyltrichlorosilane

N-allyl-N'-trimethylsilylurea

N-allyl-N'-trimethylsilylurea

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

C7H5Cl2NOSi

C7H5Cl2NOSi

Conditions
ConditionsYield
Heating;A 99%
B n/a
4,4'-dimethoxydiphenylmethyl chloride
7525-23-7

4,4'-dimethoxydiphenylmethyl chloride

(R)-5-Oxo-1-trimethylsilanyl-pyrrolidine-2-carboxylic acid methyl ester

(R)-5-Oxo-1-trimethylsilanyl-pyrrolidine-2-carboxylic acid methyl ester

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

(R)-1-[Bis-(4-methoxy-phenyl)-methyl]-5-oxo-pyrrolidine-2-carboxylic acid methyl ester

(R)-1-[Bis-(4-methoxy-phenyl)-methyl]-5-oxo-pyrrolidine-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With trifluorormethanesulfonic acid at 130℃; for 0.25h;A n/a
B 99%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

Conditions
ConditionsYield
With sodium; lithium In tetrahydrofuran at 25 - 28℃; for 4h; Heating; Irradiation; ultrasound irrad. var. time, var. temperatures, var. metal purity;100%
With sodium; lithium In tetrahydrofuran at 25 - 28℃; for 4h; Irradiation;100%
With potassium fluoride; phosphorus; potassium In 5,5-dimethyl-1,3-cyclohexadiene at 90℃; for 12h; Reagent/catalyst; Temperature;97.3%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

Conditions
ConditionsYield
With pyridine hydrogenfluoride In 1,4-dioxane at 20℃; for 0.0833333h; Schlenk technique; Inert atmosphere;100%
With [((2-tBuNO)C6H4CH2)3N]TiF In tetrahydrofuran at 23℃; for 0.0833333h; Inert atmosphere;98%
With lithium fluoride In acetonitrile under 600 Torr; for 2h; Heating;80%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

Conditions
ConditionsYield
With hydrogenchloride at 20℃;100%
With sodium hydroxide In water at 30℃; for 0.416667h; Concentration; Temperature;99.97%
With styrene type I anion exchange resin In water at 45 - 75℃; for 2.5h; Concentration; Temperature; Inert atmosphere;93.8%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

trimethylsilyl perchlorate
18204-79-0

trimethylsilyl perchlorate

Conditions
ConditionsYield
With silver perchlorate In diethyl ether; dichloromethane-d2 Ambient temperature;100%
With silver perchlorate
With silver perchlorate In dichloromethane-d2 for 19h;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

ethyl acetoacetate
141-97-9

ethyl acetoacetate

ethyl 3-trimethylsiloxy-2-butenoate
13257-83-5

ethyl 3-trimethylsiloxy-2-butenoate

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran; hexane at 21 - 45℃; for 3h;100%
With triethylamine In tetrahydrofuran Ambient temperature;89%
Stage #1: chloro-trimethyl-silane; ethyl acetoacetate In tetrahydrofuran; hexane at 0 - 5℃; for 0.5h; Inert atmosphere;
Stage #2: With triethylamine In tetrahydrofuran; hexane at 0 - 20℃; Inert atmosphere;
87%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

4-trimethylsilylanisole
877-68-9

4-trimethylsilylanisole

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at 0 - 20℃; for 1h; Inert atmosphere;100%
Stage #1: 1-bromo-4-methoxy-benzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 20℃;
99%
Stage #1: 1-bromo-4-methoxy-benzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; Inert atmosphere; Schlenk technique;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 20℃; for 18h; Inert atmosphere; Schlenk technique;
96%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

S-phenyl hexanethioate
56974-15-3

S-phenyl hexanethioate

1-trimethylsiloxy-1-phenylthio-1-hexene
68117-64-6

1-trimethylsiloxy-1-phenylthio-1-hexene

Conditions
ConditionsYield
With lithium diisopropyl amide at -78℃;100%
Stage #1: S-phenyl hexanethioate With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 0.5h;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 60℃; for 1.5h;
76%
With lithium diisopropyl amide
With lithium diisopropyl amide 1.) THF, -78 deg C, 2.) THF, RT, 2h; Yield given. Multistep reaction;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

phenylacetylene
536-74-3

phenylacetylene

1-Phenyl-2-(trimethylsilyl)acetylene
2170-06-1

1-Phenyl-2-(trimethylsilyl)acetylene

Conditions
ConditionsYield
With lithium iodide at 80℃; for 24h; Reagent/catalyst; Solvent;100%
Stage #1: phenylacetylene With ethylmagnesium bromide In tetrahydrofuran at -78 - 0℃; Inert atmosphere;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
99%
With diethylzinc In hexane; acetonitrile at 80℃; for 20h; Solvent; Temperature; Time; Schlenk technique; Inert atmosphere;99%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

cyclopentanone
120-92-3

cyclopentanone

1-(trimethylsilyloxy)cyclopentene
19980-43-9

1-(trimethylsilyloxy)cyclopentene

Conditions
ConditionsYield
With triethylamine; sodium iodide In acetonitrile at 23℃; for 1.5h; Inert atmosphere;100%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 40℃; for 0.5h;98%
With magnesium In N,N-dimethyl-formamide at 15 - 25℃;94%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

stearic acid
57-11-4

stearic acid

octadecanoic acid, trimethylsilyl ester
18748-91-9

octadecanoic acid, trimethylsilyl ester

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 20℃; Inert atmosphere;100%
In benzene
In hexane for 5h; Reflux; Inert atmosphere;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

1-butyn-4-ol
927-74-2

1-butyn-4-ol

4-(trimethylsilyl)but-3-yn-1-ol
2117-12-6

4-(trimethylsilyl)but-3-yn-1-ol

Conditions
ConditionsYield
Stage #1: 3-Butyn-1-ol With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 1h;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 20℃; for 2h;
100%
Stage #1: 3-Butyn-1-ol With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Schlenk technique; Inert atmosphere;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 20℃; for 2h; Schlenk technique; Inert atmosphere;
100%
Stage #1: 3-Butyn-1-ol With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 20℃; for 2h;
98%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

benzeneacetic acid methyl ester
101-41-7

benzeneacetic acid methyl ester

(1-methoxy-2-phenylvinyloxy)trimethylsilane
40195-27-5

(1-methoxy-2-phenylvinyloxy)trimethylsilane

Conditions
ConditionsYield
With n-butyllithium; N-ethyl-N,N-diisopropylamine In tetrahydrofuran at -78 - 20℃; Inert atmosphere;100%
Stage #1: benzeneacetic acid methyl ester With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 2.1h; Inert atmosphere;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran at 20℃; Inert atmosphere;
100%
Stage #1: benzeneacetic acid methyl ester With lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 2h;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at 20℃;
91%
2-bromothiophene
1003-09-4

2-bromothiophene

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

2-bromo-5-trimethylsilylthiophene
18246-28-1

2-bromo-5-trimethylsilylthiophene

Conditions
ConditionsYield
Stage #1: 2-bromothiophene With lithium diisopropyl amide In tetrahydrofuran
Stage #2: chloro-trimethyl-silane In tetrahydrofuran
100%
Stage #1: 2-bromothiophene With n-butyllithium; diisopropylamine In tetrahydrofuran at -78 - 0℃; for 0.0833333h;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran at -78 - 20℃; for 0.5h;
91%
With lithium diisopropyl amide Yield given. Multistep reaction;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

(RS)-1-hydroxy-1-phenylpropan-2-one
90-63-1

(RS)-1-hydroxy-1-phenylpropan-2-one

methyl(α-trimethylsiloxybenzyl) ketone
26205-40-3

methyl(α-trimethylsiloxybenzyl) ketone

Conditions
ConditionsYield
With 1H-imidazole; dmap In diethyl ether100%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

diethyl (trichloromethyl)phosphonate
866-23-9

diethyl (trichloromethyl)phosphonate

O,O-diethyltrimethylsilylchloromethylphosphonate α-lithie
176100-94-0

O,O-diethyltrimethylsilylchloromethylphosphonate α-lithie

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at -90 - -85℃; for 0.25h;100%
With n-butyllithium In tetrahydrofuran; hexane at -80℃; for 0.25h;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

2-(3,4-dimethoxyphenyl)-2-hydroxyacetonitrile
6309-18-8

2-(3,4-dimethoxyphenyl)-2-hydroxyacetonitrile

2-(3,4-dimethoxyphenyl)-2-((trimethylsilyl)oxy)acetonitrile
95392-01-1

2-(3,4-dimethoxyphenyl)-2-((trimethylsilyl)oxy)acetonitrile

Conditions
ConditionsYield
With 1H-imidazole; dmap In diethyl ether100%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

diethoxyphosphoryl-acetic acid ethyl ester
867-13-0

diethoxyphosphoryl-acetic acid ethyl ester

ethyl P,P-bis(trimethylsilyl) phosphonoacetate
65868-40-8

ethyl P,P-bis(trimethylsilyl) phosphonoacetate

Conditions
ConditionsYield
at 100℃; for 168h; Inert atmosphere;100%
With potassium iodide In acetonitrile at 25 - 35℃; for 0.5h;
In chlorobenzene at 140℃; for 18h;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

diethyl chloromethylphosphonate
3167-63-3

diethyl chloromethylphosphonate

O,O-diethyltrimethylsilylchloromethylphosphonate α-lithie
176100-94-0

O,O-diethyltrimethylsilylchloromethylphosphonate α-lithie

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at -90 - -85℃; for 0.25h;100%
With n-butyllithium In tetrahydrofuran; hexane at -80℃; for 0.833333h;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

4-methoxymandelonitrile
33646-40-1

4-methoxymandelonitrile

2-(4-methoxyphenyl)-2-(trimethylsilyloxy)acetonitrile
66985-48-6

2-(4-methoxyphenyl)-2-(trimethylsilyloxy)acetonitrile

Conditions
ConditionsYield
With 1H-imidazole; dmap In diethyl ether100%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

(S)-3-hydroxymethyl-1,2,3,4-tetrahydroisoquinoline
18881-17-9, 62855-02-1, 62928-94-3, 63006-93-9

(S)-3-hydroxymethyl-1,2,3,4-tetrahydroisoquinoline

(S)-3-Trimethylsilanyloxymethyl-1,2,3,4-tetrahydro-isoquinoline
1025931-48-9

(S)-3-Trimethylsilanyloxymethyl-1,2,3,4-tetrahydro-isoquinoline

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran100%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

methyl 2,3-dideoxy-6-O-toluene-p-sulphonyl-α-D-erythro-hexopyranoside
34339-62-3

methyl 2,3-dideoxy-6-O-toluene-p-sulphonyl-α-D-erythro-hexopyranoside

Toluene-4-sulfonic acid (2R,3S,6S)-6-methoxy-3-trimethylsilanyloxy-tetrahydro-pyran-2-ylmethyl ester
92413-84-8

Toluene-4-sulfonic acid (2R,3S,6S)-6-methoxy-3-trimethylsilanyloxy-tetrahydro-pyran-2-ylmethyl ester

Conditions
ConditionsYield
With 1,1,1,3,3,3-hexamethyl-disilazane In pyridine Ambient temperature;100%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

(R,R)-2,3-butandiol
24347-58-8

(R,R)-2,3-butandiol

(R,R)-butanediol bis(trimethylsilyl) ether
125473-19-0

(R,R)-butanediol bis(trimethylsilyl) ether

Conditions
ConditionsYield
With 1H-imidazole In diethyl ether at 0 - 20℃;100%
With triethylamine In dichloromethane 5 deg C to room temperature;96%
With triethylamine In tetrahydrofuran at 20℃; for 20h;92%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

1,2-octandiol
1117-86-8

1,2-octandiol

1,2-bis(trimethylsilyloxy)octane
33968-37-5

1,2-bis(trimethylsilyloxy)octane

Conditions
ConditionsYield
With triethylamine In dichloromethane for 1h; Ambient temperature;100%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

pent-1-yn-5-ol
5390-04-5

pent-1-yn-5-ol

5-trimethylsilanyl-pent-4-yn-1-ol
13224-84-5

5-trimethylsilanyl-pent-4-yn-1-ol

Conditions
ConditionsYield
With n-butyllithium Inert atmosphere;100%
Stage #1: chloro-trimethyl-silane; pent-1-yn-5-ol With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 2h; Inert atmosphere;
Stage #2: With hydrogenchloride In water for 3h; Inert atmosphere;
100%
Stage #1: pent-1-yn-5-ol With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1.08333h; Inert atmosphere;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at 20℃;
100%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

5-hexyl-1-ol
928-90-5

5-hexyl-1-ol

6-trimethylsilanyl-hex-5-yn-1-ol
103437-52-1

6-trimethylsilanyl-hex-5-yn-1-ol

Conditions
ConditionsYield
Stage #1: 5-hexyl-1-ol With ethylmagnesium bromide
Stage #2: chloro-trimethyl-silane
Stage #3: With sulfuric acid In tetrahydrofuran
100%
Stage #1: 5-hexyl-1-ol With n-butyllithium In tetrahydrofuran at -78℃; Inert atmosphere;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran at -78 - 0℃; Inert atmosphere;
Stage #3: With hydrogenchloride In tetrahydrofuran; water at 0 - 20℃; Inert atmosphere;
100%
Stage #1: 5-hexyl-1-ol With dmap; n-butyllithium In tetrahydrofuran; diethyl ether; hexane at -78℃; for 1h; Inert atmosphere;
Stage #2: chloro-trimethyl-silane at -78 - 20℃; for 2h; Inert atmosphere;
99%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

allyl phenyl thioether
5296-64-0

allyl phenyl thioether

phenyl 1-(trimethylsilyl)prop-2-en-1-yl sulfide
78905-13-2

phenyl 1-(trimethylsilyl)prop-2-en-1-yl sulfide

Conditions
ConditionsYield
Stage #1: allyl phenyl thioether With n-butyllithium In tetrahydrofuran at -78℃;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran at -78 - 20℃;
100%
With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.333333h;93%
With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 3.5h;92%
With lithium diisopropyl amide In tetrahydrofuran at -78℃; Yield given;
Yield given. Multistep reaction;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

2,7-dibromonaphthalene
58556-75-5

2,7-dibromonaphthalene

2,7-naphthalenediylbis(trimethylsilane)
40490-26-4

2,7-naphthalenediylbis(trimethylsilane)

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran -78 deg C to -20 deg C;100%
With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1.08333h; Substitution;100%
With n-butyllithium
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

2,7-dibromonaphthalene
58556-75-5

2,7-dibromonaphthalene

(7-bromonaphthalen-2-yl)trimethylsilane
99642-47-4

(7-bromonaphthalen-2-yl)trimethylsilane

Conditions
ConditionsYield
Stage #1: 2,7-dibromonaphthalene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.333333h;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 20℃; for 2.25h;
100%
Stage #1: 2,7-dibromonaphthalene With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In diethyl ether; hexane at -78℃; for 1.83333h; Inert atmosphere;
Stage #2: chloro-trimethyl-silane In diethyl ether; hexane at -78℃; for 3h; Inert atmosphere;
81%
With n-butyllithium 1.) THF, hexane, -78 deg C, 20 min, 2.) THF, hexane, RT, 2 h; Yield given. Multistep reaction;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

benzyl 2-methylpropanoate
103-28-6

benzyl 2-methylpropanoate

((1-(benzyloxy)-2-methylprop-1-en-1-yl)oxy)trimethylsilane
480453-25-6

((1-(benzyloxy)-2-methylprop-1-en-1-yl)oxy)trimethylsilane

Conditions
ConditionsYield
With lithium hexamethyldisilazane at -78 - 20℃;100%
1.) THF, -78 deg C, 2.) HMPA, -78 deg C; Multistep reaction;
Stage #1: benzyl 2-methylpropanoate With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 20℃; for 20h; Inert atmosphere;
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