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Zhejiang Haizhou Pharmaceutical Co., Ltd.

Specificaiton: In-house; Certification: ISO 9001; US FDA and EDQM Approved Plant Appearance:Colourless liquid Storage:Preserve in ambient temperature Port:Shanghai, Ningbo, etc.

Hexamethyldisilane

Cas:1450-14-2

Min.Order:50 Gram

Negotiable

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

Hexamethyldisilane

Cas:1450-14-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hefei TNJ chemical industry co.,ltd

1. Quality Our products meet MSDS safe standard and we have ISO and other certificate so yan can get high quality products from our company. 2. Price We are the company which is the joint of trade and industry so we cao provide the competiti

Hexamethyldisilane/CAS 1450-14-2

Cas:1450-14-2

Min.Order:130 Kilogram

Negotiable

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Hexamethyldisilane

Cas:1450-14-2

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Hexamethyldisilane

Cas:1450-14-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; development of noble metal catalysts, synthesis of electronic chemical materials and general chemicals Imp&Exp trading business. The company

TIANFU-CHEM -Hexamethyldisilane

Cas:1450-14-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Hexamethyldisilane Synonym: HMD ; Hexamethyl disilylamine CAS No.:1450-14-2 Molecular formula:(CH3)3SiSi(CH3)3 Molecular Weight:146.37 Properties: Colorless, transparent liquid with pleasant fruit odour. It doesn't dissolve int

high quality Hexamethyldisilane HMD 1450-14-2

Cas:1450-14-2

Min.Order:2 Metric Ton

FOB Price: $1.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:white or off-white powder Storage:Store in sealed containers

Hexamethyldisilane with low price CAS:1450-14-2

Cas:1450-14-2

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Wuhan Kemi-Works Chemical Co., Ltd

1450-14-2 hexamethyldisilane 1.We have been specializing in special fine chemical for long, with strong R&D strength. 2.ISO9001. 3.We have been cooperating with oversea from Europe, USA, Korea, Japan etc... Appearance:Colorless, trans

hexamethyldisilane

Cas:1450-14-2

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Hexamethyldisilane CAS NO.1450-14-2

Cas:1450-14-2

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Hexamethyldisilane

Cas:1450-14-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Hexamethyldisilane(HMD)

Cas:1450-14-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

afine+HEXAMETHYLDISILANE

Cas:1450-14-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Ht--404 Hexamethyldisilane (Hmd)

Cas:1450-14-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

Hexamethyldisilane CAS NO.1450-14-2Appearance:Detailed see specifications Storage:Store in dry, dark and ventilated place. Package:according to customers' requirements Application:It is an important raw material and intermediates used in Organic Synt

Hexamethyldisilane CAS NO.1450-14-2

Cas:1450-14-2

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

moderate price & quick delivery Appearance:Colorless clear liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application:Synthesis of trimethyl sila

Hexamethyldisilane

Cas:1450-14-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

HexamethyldisilaneCAS NO.: 1450-14-2

Cas:1450-14-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: Hexamethyldisilane Synonyms: HEXAMETHYLDISILANE;HMD;DISILANE M6;(CH3)6Si2;1,1,1,2,2,2-Hexamethyldisilane;CH7280;disilane,hexamethyl-;Hecamethyldisilane CAS: 1450-14-2 MF: C6H18Si2 MW: 146.38 EINECS: 215-911-0 Product Categorie

Hexamethyldisilane 1450-14-2

Cas:1450-14-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

ProductName:Hexamethyldisilane Synonyms:HMD;Hecamethyldisilane;CH7280;hexamethyl-silane;DISILANE M6; (CH3)6Si2;disilane,hexamethyl;Disilane, hexamethyl-;hexamethyl-disilan; Me3Si-SiMe3;Permethyldisilane; Abbreviation: HMD CAS NO.: 1450-14

Hexamethyldisilane

Cas:1450-14-2

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

Disilane, 1,1,1,2,2,2-hexamethyl-

Cas:1450-14-2

Min.Order:0

Negotiable

Type:Other

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Hexamethyldisilane

Cas:1450-14-2

Min.Order:0

Negotiable

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Hexamethyldisilane

Cas:1450-14-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

high purity, manufacturer Application:Intermediate

Hexamethyldisilane

Cas:1450-14-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Hexamethyldisilane

Cas:1450-14-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Ht--404 Hexamethyldisilane (Hmd)

Cas:1450-14-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as: Frac

Hexamethyldisilane

Cas:1450-14-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 1450-14-2 with competitive price

Cas:1450-14-2

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Disilane, 1,1,1,2,2,2-hexamethyl-

Cas:1450-14-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Luyunjia Chemistry Xiamen Limited

Xiamen Luyunjia Trading Co.,Ltd Package:1kg/bag; 3256kg/drum, or as customer's request. Application:Xiamen Luyunjia Trading Co.,Ltd Transportation:DHL, EMS, FedEx, TNT, AIR, SEA Port:Beijing,Shanghai,Guangzhou ,China main port

HEXAMETHYLDISILANE

Cas:1450-14-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China

Hexamethyldisilane, 98% 1450-14-2

Cas:1450-14-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

Conditions
ConditionsYield
With sodium; lithium In tetrahydrofuran at 25 - 28℃; for 4h; Heating; Irradiation; ultrasound irrad. var. time, var. temperatures, var. metal purity;100%
With sodium; lithium In tetrahydrofuran at 25 - 28℃; for 4h; Irradiation;100%
With potassium fluoride; phosphorus; potassium In 5,5-dimethyl-1,3-cyclohexadiene at 90℃; for 12h; Reagent/catalyst; Temperature;97.3%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

C39H67FPSi2(1-)*Na(1+)

C39H67FPSi2(1-)*Na(1+)

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

C42H76FPSi3

C42H76FPSi3

Conditions
ConditionsYield
In diethyl ether Heating;A 68%
B 100%
benzophenone
119-61-9

benzophenone

(trimethylsilyl)potassium
56859-17-7

(trimethylsilyl)potassium

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

tetraphenylethane-1,2-diol
464-72-2

tetraphenylethane-1,2-diol

Conditions
ConditionsYield
In 1,2-dimethoxyethane for 12h; Ambient temperature;A 85%
B 80%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

Conditions
ConditionsYield
With sodium at 130 - 140℃; for 10h;A 84%
B n/a
1,1,3,3-tetramethylindan-2-thione
74768-58-4

1,1,3,3-tetramethylindan-2-thione

2,2-dimesitylhexamethyltrisilane
79184-72-8

2,2-dimesitylhexamethyltrisilane

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

C31H38SSi
110354-69-3

C31H38SSi

Conditions
ConditionsYield
In cyclohexane for 15h; Ambient temperature; Irradiation; low pressure mercury lamp;A n/a
B 82%
vanadocene monochloride

vanadocene monochloride

trimethylsilyl isothiocyanate
2290-65-5

trimethylsilyl isothiocyanate

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

C

bis(η5-cyclopentadienyl)vanadium diisothiocyanate

bis(η5-cyclopentadienyl)vanadium diisothiocyanate

Conditions
ConditionsYield
In toluene Heating at 120-150°C for 10 h.;A 73%
B 32%
C 76%
In toluene molar ratio V-complex/Me3SiNCS=1:2, evacuated sealed ampul (120-150°C, 10 h);A 73%
B 32%
C 76%
Benzylidenemalononitrile
2700-22-3

Benzylidenemalononitrile

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

Benzylmalononitrile
1867-37-4

Benzylmalononitrile

Conditions
ConditionsYield
With phenanthrene In acetonitrile for 43h; Irradiation; 300 W high pressure mercury lamp, λ>280 nm;A 75%
B 10%
hexachlorodisilane
13465-77-5

hexachlorodisilane

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

Conditions
ConditionsYield
In diethyl ether Si2Cl6 and 31% excess of Zn(CH3)2 in ether at 85°C in a closed tube;;74%
vanadocene

vanadocene

trimethylsilyl 2-iodobenzoate
59147-01-2

trimethylsilyl 2-iodobenzoate

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

bis(η5-cyclopentadiene)vanadium o-iodobenzoate

bis(η5-cyclopentadiene)vanadium o-iodobenzoate

Conditions
ConditionsYield
In toluene at 20℃; for 60h; Sealed tube;A n/a
B 69%
bis(trimethylsilyl)diphenylgermane
111655-78-8

bis(trimethylsilyl)diphenylgermane

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

trimethylphenylsilane
768-32-1

trimethylphenylsilane

C

1,1-diphenyl-3,4-dimethyl-1-germacyclopent-3-ene
5764-69-2

1,1-diphenyl-3,4-dimethyl-1-germacyclopent-3-ene

Conditions
ConditionsYield
In pentane Irradiation (UV/VIS); (N2), 1 h irradiated; gas chromatography; elem. anal., NMR, mass. spectra;A 68%
B 27%
C 61%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

2-(Bis-trimethylsilanyl-methyl)-1,1,1,3,3,3-hexamethyl-disilazane
72223-62-2

2-(Bis-trimethylsilanyl-methyl)-1,1,1,3,3,3-hexamethyl-disilazane

C

2-(Bis-trimethylsilanyl-methyl)-1,1,3,3,3-pentamethyl-1-trimethylsilanylmethyl-disilazane
138482-32-3

2-(Bis-trimethylsilanyl-methyl)-1,1,3,3,3-pentamethyl-1-trimethylsilanylmethyl-disilazane

Conditions
ConditionsYield
With lithium In tetrahydrofuran at 0℃; Yields of byproduct given;A 65%
B n/a
C n/a
methyl(phenyl)bis(trimethylsilyl)germane
134847-65-7

methyl(phenyl)bis(trimethylsilyl)germane

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

1,3,4-trimethyl-1-(trimethylsilyl)-1-germacyclopent-3-ene
134847-66-8

1,3,4-trimethyl-1-(trimethylsilyl)-1-germacyclopent-3-ene

C

(2,3-dimethyl-3-butenyl)methyl(trimethylsilyl){o-(trimethylsilyl)phenyl}germane
134847-67-9

(2,3-dimethyl-3-butenyl)methyl(trimethylsilyl){o-(trimethylsilyl)phenyl}germane

D

trimethylphenylsilane
768-32-1

trimethylphenylsilane

E

1,3,4-trimethyl-1-phenyl-1-germacyclopent-3-ene
51533-82-5

1,3,4-trimethyl-1-phenyl-1-germacyclopent-3-ene

Conditions
ConditionsYield
In pentane Irradiation (UV/VIS); (N2), 1.5 h irradiated; column chromatography; elem. anal., NMR, mass. spectra;A 60%
B 28%
C 5%
D 35%
E 55%
vanadocene

vanadocene

trimethylsilyl 2-iodobenzoate
59147-01-2

trimethylsilyl 2-iodobenzoate

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

η5-cyclopentadienevanadium bis-o-iodobenzoate
1428262-40-1

η5-cyclopentadienevanadium bis-o-iodobenzoate

C

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

Conditions
ConditionsYield
In toluene at 100℃; for 100h; Time; Sealed tube;A n/a
B 59%
C n/a
trimethylphenylsilane
768-32-1

trimethylphenylsilane

lithium trimethylstannyl
17946-71-3

lithium trimethylstannyl

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

trimethyl(phenyl)stannane
934-56-5

trimethyl(phenyl)stannane

C

hexamethyldistannane
661-69-8

hexamethyldistannane

D

trimethyl(trimethylstannyl)silane
16393-88-7

trimethyl(trimethylstannyl)silane

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
In tetrahydrofuran LiSnMe3 added to PhSiMe3 in THF, stirred at 24°C for 1 h or 50°C for 30 min, hydrolysis with water; org. layer extd. with ether, dried over Na2SO4; products determined by GLC;A 0%
B 0%
C 50%
D 0%
E 0%
1,1,1,4,4,4-hexakis(trimethylsilyl)butin-2
20932-80-3

1,1,1,4,4,4-hexakis(trimethylsilyl)butin-2

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

1,2-bis(trimethylsilyl)ethane
6231-76-1

1,2-bis(trimethylsilyl)ethane

C

1,1,4,4-tetrakis(trimethylsilyl) 1,2,3-butatriene
70641-35-9

1,1,4,4-tetrakis(trimethylsilyl) 1,2,3-butatriene

D

Bis(trimethylsilyl)ethyne
14630-40-1

Bis(trimethylsilyl)ethyne

Conditions
ConditionsYield
at 650℃; under 0.001 Torr; Further byproducts given;A 7%
B 5%
C 41%
D 16%
bis(trimethylsilyl)methane
2117-28-4

bis(trimethylsilyl)methane

bis-trifluoromethyl-aminooxyl
2154-71-4

bis-trifluoromethyl-aminooxyl

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

C

N,N-bis(trifluoromethyl)hydroxylamine
359-63-7

N,N-bis(trifluoromethyl)hydroxylamine

D

Perfluoro-2-azapropen
371-71-1

Perfluoro-2-azapropen

Conditions
ConditionsYield
With bis(trimethylsilyl)methane for 4h; Ambient temperature; Further byproducts given;A 15%
B 40%
C 33%
D 31%
bis(trimethylsilyl)methane
2117-28-4

bis(trimethylsilyl)methane

bis-trifluoromethyl-aminooxyl
2154-71-4

bis-trifluoromethyl-aminooxyl

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

C

N,N-bis(trifluoromethyl)hydroxylamine
359-63-7

N,N-bis(trifluoromethyl)hydroxylamine

D

O-Trimethylsilyl-bis-(trifluormethyl)-hydroxylamin
20485-84-1

O-Trimethylsilyl-bis-(trifluormethyl)-hydroxylamin

Conditions
ConditionsYield
for 4h; Ambient temperature; Further byproducts given;A 15%
B 40%
C 33%
D 21%
(dimethylphenylgermyl)trimethylsilane
37899-63-1

(dimethylphenylgermyl)trimethylsilane

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

trimethylsilan
993-07-7

trimethylsilan

C

trimethylphenylsilane
768-32-1

trimethylphenylsilane

D

dimethylphenylgermane
7366-21-4

dimethylphenylgermane

E

1,1,2,2-tetramethyl-1,2-diphenyldigermane
22702-72-3

1,1,2,2-tetramethyl-1,2-diphenyldigermane

Conditions
ConditionsYield
With methanol In benzene Irradiation (UV/VIS); irradiation of catenate in benzene containing an excess of methanol with a 110 W low pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;A <1
B n/a
C 37%
D <1
E <1
In cyclohexane Irradiation (UV/VIS); irradiation of catenate in cyclohexane with a 110 W low pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;A <1
B 4%
C 24%
D <1
E <1
tris(trimethylsilyl)silyllithium
4110-02-5

tris(trimethylsilyl)silyllithium

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

tetrakis(trimethylsilyl)silane
4098-98-0

tetrakis(trimethylsilyl)silane

C

2,2,3,3-tetrakis(trimethylsilyl)hexamethyltetrasilane
5181-43-1

2,2,3,3-tetrakis(trimethylsilyl)hexamethyltetrasilane

D

C6H18Li2Si3
130377-71-8

C6H18Li2Si3

Conditions
ConditionsYield
at 140 - 150℃;A n/a
B 10%
C 27%
D 35%
triethylsilane
617-86-7

triethylsilane

1-<(N,N-dimethylamino)methyl>-2-benzene
155570-15-3

1-<(N,N-dimethylamino)methyl>-2-benzene

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

2-(o-tolyl)-1,1,1-triethyl-3,3,3-trimethyltrisilane

2-(o-tolyl)-1,1,1-triethyl-3,3,3-trimethyltrisilane

C

o-tolyltris(trimethylsilyl)silane

o-tolyltris(trimethylsilyl)silane

D

2-<2-(N,N-dimethylamino)methylphenyl>-1,1,1-triethyl-3,3,3-trimethyltrisilane

2-<2-(N,N-dimethylamino)methylphenyl>-1,1,1-triethyl-3,3,3-trimethyltrisilane

Conditions
ConditionsYield
In cyclohexane for 1.66667h; Irradiation;A n/a
B 20%
C 33%
D 24%
2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

1-<(N,N-dimethylamino)methyl>-2-benzene
155570-15-3

1-<(N,N-dimethylamino)methyl>-2-benzene

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

o-tolyltris(trimethylsilyl)silane

o-tolyltris(trimethylsilyl)silane

C

1-<2-(N,N-dimethylaminomethyl)phenyl>-trimethylsilyl-3,4-dimethylsilacyclopent-3-ene

1-<2-(N,N-dimethylaminomethyl)phenyl>-trimethylsilyl-3,4-dimethylsilacyclopent-3-ene

Conditions
ConditionsYield
for 4.5h; Irradiation;A 33%
B 9%
C 16%
1-<(N,N-dimethylamino)methyl>-2-benzene
155570-15-3

1-<(N,N-dimethylamino)methyl>-2-benzene

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

2-(o-tolyl)-1,1,1-triethyl-3,3,3-trimethyltrisilane

2-(o-tolyl)-1,1,1-triethyl-3,3,3-trimethyltrisilane

C

o-tolyltris(trimethylsilyl)silane

o-tolyltris(trimethylsilyl)silane

D

2-<2-(N,N-dimethylamino)methylphenyl>-1,1,1-triethyl-3,3,3-trimethyltrisilane

2-<2-(N,N-dimethylamino)methylphenyl>-1,1,1-triethyl-3,3,3-trimethyltrisilane

Conditions
ConditionsYield
With triethylsilane In cyclohexane for 1.66667h; Irradiation;A n/a
B 20%
C 33%
D 24%
ethanol
64-17-5

ethanol

bis[2,4,6-tris((dimethylamino)methyl)phenoxy]bis(trimethylsilyl)silane
394739-08-3

bis[2,4,6-tris((dimethylamino)methyl)phenoxy]bis(trimethylsilyl)silane

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

[2,4,6-tris((dimethylamino)methyl)phenoxy]trimethylsilane
161787-77-5

[2,4,6-tris((dimethylamino)methyl)phenoxy]trimethylsilane

C

C20H41N3O2Si2

C20H41N3O2Si2

D

C32H58N6O3Si

C32H58N6O3Si

Conditions
ConditionsYield
at 120℃; for 48h;A 2%
B 33%
C 32%
D 31%
In cyclohexane for 4h; Product distribution; Irradiation;A 7%
B 23%
C 20%
D 6%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

phenyldi-n-butylchlorosilane
114953-59-2

phenyldi-n-butylchlorosilane

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

1-phenyl-1,1-di-n-butyltrimethyldisilane
114953-60-5

1-phenyl-1,1-di-n-butyltrimethyldisilane

Conditions
ConditionsYield
With potassium alloy; sodium In benzene for 144h; Heating;A n/a
B 32%
2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

bis[2,4,6-tris((dimethylamino)methyl)phenoxy]bis(trimethylsilyl)silane
394739-08-3

bis[2,4,6-tris((dimethylamino)methyl)phenoxy]bis(trimethylsilyl)silane

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

[2,4,6-tris((dimethylamino)methyl)phenoxy]trimethylsilane
161787-77-5

[2,4,6-tris((dimethylamino)methyl)phenoxy]trimethylsilane

C

[3,5-bis-dimethylaminomethyl-2-(3,4-dimethyl-1-trimethylsilanyl-2,5-dihydro-1H-silol-1-yloxy)-benzyl]-dimethyl-amine

[3,5-bis-dimethylaminomethyl-2-(3,4-dimethyl-1-trimethylsilanyl-2,5-dihydro-1H-silol-1-yloxy)-benzyl]-dimethyl-amine

D

{3,5-bis-dimethylaminomethyl-2-[3,4-dimethyl-1-(2,4,6-tris-dimethylaminomethyl-phenoxy)-2,5-dihydro-1H-silol-1-yloxy]-benzyl}-dimethyl-amine

{3,5-bis-dimethylaminomethyl-2-[3,4-dimethyl-1-(2,4,6-tris-dimethylaminomethyl-phenoxy)-2,5-dihydro-1H-silol-1-yloxy]-benzyl}-dimethyl-amine

Conditions
ConditionsYield
at 120℃; for 168h; Product distribution;A 3%
B 32%
C 29%
D 2%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

tris(trimethylsilyl)amine
1586-73-8

tris(trimethylsilyl)amine

Conditions
ConditionsYield
With potassium graphite; Co2(2,2,2-tri(diisopropylphosphinomethylamino)triphenylamine(-3H)); nitrogen In tetrahydrofuran at 25.84℃; under 760.051 Torr; for 12h; Catalytic behavior; Kinetics; Reagent/catalyst; Inert atmosphere;A n/a
B 30%
With trans-[Mo[N2]2(depf)2]; nitrogen; lithium In tetrahydrofuran at 22 - 24℃; under 760.051 Torr; for 100h;A 16.53 mmol
B 0.55 mmol
With trans-[Mo[N2]2(depf)2]; nitrogen; sodium In TETRAHYDROPYRANE at 22 - 24℃; under 760.051 Torr; for 100h;A 0.29 mmol
B 1.08 mmol
adamantane-2-thione
23695-65-0

adamantane-2-thione

2,2-dimesitylhexamethyltrisilane
79184-72-8

2,2-dimesitylhexamethyltrisilane

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

C28H36SSi

C28H36SSi

Conditions
ConditionsYield
In cyclohexane for 15h; Ambient temperature; Irradiation; low pressure mercury lamp;A n/a
B 29%
ferrocenium hexafluorophosphate

ferrocenium hexafluorophosphate

(C5H5)2Nb(Si(CH3)3)Cl

(C5H5)2Nb(Si(CH3)3)Cl

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

{(C5H5)2Nb(CH2Si(CH3)3)Cl}(1+)*PF6(1-)={(C5H5)2Nb(CH2Si(CH3)3)Cl}PF6
106420-40-0

{(C5H5)2Nb(CH2Si(CH3)3)Cl}(1+)*PF6(1-)={(C5H5)2Nb(CH2Si(CH3)3)Cl}PF6

Conditions
ConditionsYield
With CH2Cl2 In dichloromethane addn. of cold (-78°C) CH2Cl2 to mixt. of Cp2Nb(SiMe3)Cl and (Cp2Fe)PF6 in 1:1 molar ratio cooled to -78°C under inert atm., allowed to warm to room temp.; further products; evapd., extd. (Et2O), evapn. gave Cp2Fe (NMR, IR); residue extd. (CH2Cl2), soln. filtered, concd., cooling to -45°C gave cryst. target product (elem.anal.); crystn. (MeCN) of residue gave (Cp2NbCl2)PF6 (IR); others products analyzed by GC;A <1
B 28%
(dimethylphenylgermyl)trimethylsilane
37899-63-1

(dimethylphenylgermyl)trimethylsilane

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

A

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

B

trimethylphenylsilane
768-32-1

trimethylphenylsilane

Conditions
ConditionsYield
In cyclohexane Irradiation (UV/VIS); irradiation of catenate in cyclohexane containing an excess of 2,3-dimethylbutadiene with a 110 W low pressure Hg arc lamp at room temp. under Ar for 1-4 h; identification by GC and GC-MS;A <1
B 23%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

Allyl acetate
591-87-7

Allyl acetate

A

propene
187737-37-7

propene

B

trimethylsilyl acetate
2754-27-0

trimethylsilyl acetate

C

allyl-trimethyl-silane
762-72-1

allyl-trimethyl-silane

D

(E)-trimethyl(prop-1-en-1-yl)silane
4964-03-8

(E)-trimethyl(prop-1-en-1-yl)silane

Conditions
ConditionsYield
tetrakis(triphenylphosphine) palladium(0) at 180℃; for 2h; high pressure, under nitrogen;A 2 % Chromat.
B 100%
C 48%
D 48%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

(α,α-dichlorobenzyl)trimethylsilane
25115-43-9

(α,α-dichlorobenzyl)trimethylsilane

(E)-α,β-bis(trimethylsilyl)stilbene
24894-87-9

(E)-α,β-bis(trimethylsilyl)stilbene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In 1,3,5-trimethyl-benzene at 130℃; for 18h;100%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

α,β,4-trichlorobenzyltrimethylsilane
53119-90-7

α,β,4-trichlorobenzyltrimethylsilane

(E)-α,β-bis(trimethylsilyl)-4,4'-dichlorostilbene

(E)-α,β-bis(trimethylsilyl)-4,4'-dichlorostilbene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In 1,3,5-trimethyl-benzene at 130℃; for 24h;100%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

Conditions
ConditionsYield
With hydrogenchloride; diethyl ether at 120℃; for 70h; Sealed tube;100%
With carbon monoxide; hydrogen; nickel at 200℃; under 750.06 Torr; for 2h;59%
With bromobenzene; calcium In water for 1h; Ambient temperature;5%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

1,3-diphenyl-propen-3-one
614-47-1

1,3-diphenyl-propen-3-one

(E)-1,3-diphenyl-3-trimethylsilyl-2-propene
30262-98-7

(E)-1,3-diphenyl-3-trimethylsilyl-2-propene

Conditions
ConditionsYield
With copper(I) trifluoromethanesulfonate benzene In various solvent(s) at 100℃; for 19h;100%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

3',4'-dimethoxy-1,1'-biphenyl-4-ol
17190-05-5

3',4'-dimethoxy-1,1'-biphenyl-4-ol

4-(3',4'-methoxyphenyl)phenol trimethylsilyl ether

4-(3',4'-methoxyphenyl)phenol trimethylsilyl ether

Conditions
ConditionsYield
In pyridine at 115℃; for 3h;100%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

3'-nitro-[1,1'-biphenyl]-4-ol
53059-30-6

3'-nitro-[1,1'-biphenyl]-4-ol

4-(3'-nitrophenyl)phenol trimethylsilyl ether
923294-79-5

4-(3'-nitrophenyl)phenol trimethylsilyl ether

Conditions
ConditionsYield
In pyridine at 115℃; for 3h;100%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

2-bromo-4-phenylphenol
92-03-5

2-bromo-4-phenylphenol

(2-bromo-4-phenyl)phenol trimethylsilyl ether

(2-bromo-4-phenyl)phenol trimethylsilyl ether

Conditions
ConditionsYield
In pyridine at 115℃; for 3h;100%
p-cresol
106-44-5

p-cresol

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

trimethyl(4-methylphenoxy)silane
17902-32-8

trimethyl(4-methylphenoxy)silane

Conditions
ConditionsYield
In pyridine at 115℃; for 3h;100%
With lanthanum(III) nitrate hexahydrate In acetonitrile at 20℃;90%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

4-Phenylphenol
92-69-3

4-Phenylphenol

4-phenylphenol trimethylsilyl ether
1023-13-8

4-phenylphenol trimethylsilyl ether

Conditions
ConditionsYield
In pyridine at 115℃; for 3h;100%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

2'-fluoro-[1,1'-biphenyl]-4-ol
321-62-0

2'-fluoro-[1,1'-biphenyl]-4-ol

4-(2'-fluorophenyl)phenol trimethylsilyl ether
923294-77-3

4-(2'-fluorophenyl)phenol trimethylsilyl ether

Conditions
ConditionsYield
In pyridine at 115℃; for 3h;100%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

(E)-1,3-diphenyl-2-propen-1-ol
62668-02-4

(E)-1,3-diphenyl-2-propen-1-ol

(R)-(E)-1,3-diphenyl-3-trimethylsilylpropene
106137-98-8

(R)-(E)-1,3-diphenyl-3-trimethylsilylpropene

Conditions
ConditionsYield
With tetrakis(acetonitrile)palladium(II) bis(tetrafluoroborate); allyl alcohol In methanol; dimethyl sulfoxide at 60℃; Inert atmosphere;100%
With Pd(BF4)2(MeCN)4 In methanol; dimethyl sulfoxide at 50℃; for 15h; Air; regioselective reaction;69%
iodobenzene
591-50-4

iodobenzene

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

trimethylphenylsilane
768-32-1

trimethylphenylsilane

Conditions
ConditionsYield
With sodium methylate In N,N,N,N,N,N-hexamethylphosphoric triamide99%
With sodium hydroxide; (o-hydroxyphenyl)diphenylphosphine; PdCl(ϖ-C3H5)2 In tetrahydrofuran at 100℃; for 10h; Substitution; Silylation;83%
With sodium acetate In N,N-dimethyl acetamide at 120℃; for 24h; Catalytic behavior; Solvent; Reagent/catalyst; Inert atmosphere;70%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

(1R*,2R*)-(Z)-4-chloro-2-methyl-1-phenyl-3-buten-1-ol
114716-44-8

(1R*,2R*)-(Z)-4-chloro-2-methyl-1-phenyl-3-buten-1-ol

(1R*,2R*,3Z)-4-chloro-2-methyl-1-phenyl-1-trimethylsilyloxy-3-butene

(1R*,2R*,3Z)-4-chloro-2-methyl-1-phenyl-1-trimethylsilyloxy-3-butene

Conditions
ConditionsYield
for 96h; Ambient temperature;99%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

1,1-dimethylhydrazine
57-14-7

1,1-dimethylhydrazine

N,N-dimethyl-N',N'-bis(trimethylsilyl)hydrazine
684-26-4

N,N-dimethyl-N',N'-bis(trimethylsilyl)hydrazine

Conditions
ConditionsYield
With potassium hydride In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide for 24h; Ambient temperature;99%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

(2R,3S)-3-Isopropyl-N-(2,4,6-trimethylphenylsulfonyl)-2-vinylaziridine
187532-11-2

(2R,3S)-3-Isopropyl-N-(2,4,6-trimethylphenylsulfonyl)-2-vinylaziridine

(E,4S)-5-methyl-1-trimethylsilyl-4-[N-(2,4,6-trimethylbenzene)sulfonyl]amino-2-hexene

(E,4S)-5-methyl-1-trimethylsilyl-4-[N-(2,4,6-trimethylbenzene)sulfonyl]amino-2-hexene

Conditions
ConditionsYield
Stage #1: 1,1,1,2,2,2-hexamethyldisilane With n-butyllithium In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at -78℃; for 1h; Metallation;
Stage #2: In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at -78 - -30℃; transmetallation;
Stage #3: (2R,3S)-3-Isopropyl-N-(2,4,6-trimethylphenylsulfonyl)-2-vinylaziridine In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at -78℃; Ring cleavage;
99%
pyridine
110-86-1

pyridine

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

4-trimethylsilylpryridine
18301-46-7

4-trimethylsilylpryridine

Conditions
ConditionsYield
Stage #1: pyridine; 1,1,1,2,2,2-hexamethyldisilane With sodium methylate In N,N,N,N,N,N-hexamethylphosphoric triamide for 2h;
Stage #2: With water Further stages.;
99%
pyridine
110-86-1

pyridine

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

4-trimethylsilyl-1,4-dihydropyridine

4-trimethylsilyl-1,4-dihydropyridine

Conditions
ConditionsYield
Stage #1: pyridine; 1,1,1,2,2,2-hexamethyldisilane With sodium methylate In N,N,N,N,N,N-hexamethylphosphoric triamide for 0.25h;
Stage #2: With water Further stages.;
99%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

(E)-benzalacetone
1896-62-4

(E)-benzalacetone

((Z)-1-Trimethylsilanyl-3-trimethylsilanyloxy-but-2-enyl)-benzene

((Z)-1-Trimethylsilanyl-3-trimethylsilanyloxy-but-2-enyl)-benzene

Conditions
ConditionsYield
With allyl(cyclopentadiene)palladium(II); trimethylsilyl trifluoromethanesulfonate In benzene at 20℃; for 1h;99%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

1-Iodonaphthalene
90-14-2

1-Iodonaphthalene

9-(toluene-4-sulfonyl)-1,4-dihydro-1,4-epiazano-naphthalene

9-(toluene-4-sulfonyl)-1,4-dihydro-1,4-epiazano-naphthalene

9-Tosyl-2-(trimethylsilyl)-3-(2 (trimethylsilyl)naphthalen-1-yl)-1,2,3,4-tetrahydro-1,4-epiminonaphthalene

9-Tosyl-2-(trimethylsilyl)-3-(2 (trimethylsilyl)naphthalen-1-yl)-1,2,3,4-tetrahydro-1,4-epiminonaphthalene

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; triphenylphosphine In N,N-dimethyl-formamide at 60℃; for 12h; Schlenk technique; Inert atmosphere;99%
1,3 dithiane
505-23-7

1,3 dithiane

ethyl bromide
74-96-4

ethyl bromide

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

2-ethyl-2-(trimethylsilyl)-1,3-dithiane
72658-48-1

2-ethyl-2-(trimethylsilyl)-1,3-dithiane

Conditions
ConditionsYield
Mechanism; multistep reaction; other electrophiles, influence of temperature and reaction time;98%
Yield given. Multistep reaction;
pyridine-4-carboxylic acid
55-22-1

pyridine-4-carboxylic acid

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

trimethylsilyl 4-pyridinecarboxylate
25436-39-9

trimethylsilyl 4-pyridinecarboxylate

Conditions
ConditionsYield
RT, then warmed slowly until violent gas evolution occured;98%
5-fluorouracil
51-21-8

5-fluorouracil

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

5-fluoro-2,4-bis(trimethylsilyloxy)pyrimidine
17242-85-2

5-fluoro-2,4-bis(trimethylsilyloxy)pyrimidine

Conditions
ConditionsYield
With ammonium sulfate for 14h; Heating;98%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

benzyl alcohol
100-51-6

benzyl alcohol

benzyloxy-trimethylsilane
14642-79-6

benzyloxy-trimethylsilane

Conditions
ConditionsYield
With lanthanum(III) nitrate hexahydrate In acetonitrile at 20℃;98%
With 1% Au/TiO2 In ethyl acetate at 25℃; for 1h; Inert atmosphere;96%
With natural kaolinitic clay In tetrachloromethane for 2h; Ambient temperature;90%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

(2R,3S)-3-methyl-N-(4-methylbenzenesulfonyl)-2-vinylaziridine
187531-92-6

(2R,3S)-3-methyl-N-(4-methylbenzenesulfonyl)-2-vinylaziridine

(E,4S)-1-trimethylsilyl-4-[N-(4-methylbenzene)sulfonyl]amino-2-pentene

(E,4S)-1-trimethylsilyl-4-[N-(4-methylbenzene)sulfonyl]amino-2-pentene

Conditions
ConditionsYield
Stage #1: 1,1,1,2,2,2-hexamethyldisilane With n-butyllithium In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at -78℃; for 1h; Metallation;
Stage #2: In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at -78 - -30℃; transmetallation;
Stage #3: (2R,3S)-3-methyl-N-(4-methylbenzenesulfonyl)-2-vinylaziridine In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at -78℃; for 0.5h; Ring cleavage;
98%
4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

4-nitrobenzyl trimethylsilyl ether
14856-73-6

4-nitrobenzyl trimethylsilyl ether

Conditions
ConditionsYield
With lanthanum(III) nitrate hexahydrate In acetonitrile at 20℃;98%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

octanol
111-87-5

octanol

trimethyl(oct-1-yloxy)silane
14246-16-3

trimethyl(oct-1-yloxy)silane

Conditions
ConditionsYield
With lanthanum(III) nitrate hexahydrate In acetonitrile at 20℃;98%
With 1% Au/TiO2 In ethyl acetate at 25℃; for 1.5h; Inert atmosphere;97%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

rac-octan-2-ol
4128-31-8

rac-octan-2-ol

trimethyl-(1-methyl-heptyloxy)-silane
18023-52-4

trimethyl-(1-methyl-heptyloxy)-silane

Conditions
ConditionsYield
With lanthanum(III) nitrate hexahydrate In acetonitrile at 20℃;98%
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