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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Nickel-Alumina supplier in China

Cas:7440-02-0

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Nickel

Cas:7440-02-0

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Nickel

Cas:7440-02-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

A, crushed into powder cans regeneration Flattening to clean clean can directly input to the bunker, moment can be crushed into a powder, the average particle size of 1 ~ 3 mm, basic spherical product granularity is adjustable, hemispherica

Nickel

Cas:7440-02-0

Min.Order:20 Metric Ton

Negotiable

Type:Trading Company

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Nickel

Cas:7440-02-0

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 7440-02-0 with best price

Cas:7440-02-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

NickelCAS7440-02-0

Cas:7440-02-0

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Nickel ACTIMET C C.I. 77775 CAS.7440-02-0

Cas:7440-02-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name Nickel Synonyms Nickel;Raney nickel CAS: 7440-02-0 MF: - MW: - EINECS: - Product Categories

Nickel

Cas:7440-02-0

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Nickel 7440-02-0

Cas:7440-02-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

HUBEI RISON CHEMICAL CO.,LTD.

Nickel powder CAS No: 7440-02-0(Ni) Molecular Formula: ZrNi Appearance: Greyish powder Application: used in squibs delay mixtures and initiators. Appearance:Greyish powder Storage:when store in a tightly closed container,below 30℃,the product will

Nickel powder

Cas:7440-02-0

Min.Order:1 Metric Ton

Negotiable

Type:Other

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: Nickel Synonyms: ACTIMET 8040P;ACTIMET C;Nickel wire, 0.01mm (0.0004 in.) dia., Hard, Temper: as drawn;Nickel tubing, OD: 1.59mm (0.0626 in.) ID: 0.51mm (0.02 in.);Nickel wire, 1.0mm (0.04 in.) dia., Annealed;Nickel, p.a.;Nickel,

Nickel

Cas:7440-02-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

catalyst, Nickel CAS:7440-02-0

Cas:7440-02-0

Min.Order:1 Kilogram

FOB Price: $37.0 / 42.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Nickel CAS:7440-02-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates, ster

Nickel CAS:7440-02-0

Cas:7440-02-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Nickel

Cas:7440-02-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:7440-02-0

Cas:7440-02-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

Nickel CAS: 7440-02-0 Specification Name Nickel CAS 7440-02-0 EINECS 231-111-4 Molecular Formula Ni Molar Mass 58.69 Density 8.9 g/mL at 25 °C (lit.) Melting Point

Factory supply Nickel

Cas:7440-02-0

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Changchun Artel lmport and Export trade company

Price, service, company and transport advantage: 1.place of origin china with super quality by reasonable price. 2.fast delivery by safe express way to all the country. 3.has a number of highly qualified engineers and experts to p

Best price/Nickel

Cas:7440-02-0

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Nickel

Cas:7440-02-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Raney Nickel

Cas:7440-02-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Nickel-Alumina

Cas:7440-02-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Nickel CAS.7440-02-0

Cas:7440-02-0

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:silver white, hard, malleable metal chunks or grey powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per

Nickel

Cas:7440-02-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

Nickel

Cas:7440-02-0

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our advantage:Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scient

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Nickel

Cas:7440-02-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

In Bulk SupplyNickel

Cas:7440-02-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:Nickel CAS No:7440-02-0 Synonyms:Nicke

Nickel

Cas:7440-02-0

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Nickel

Cas:7440-02-0

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

High purity Nickel powder 99%

Cas:7440-02-0

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Synthetic route

nickel(II) chloride hexahydrate

nickel(II) chloride hexahydrate

hydrazine hydrate
7803-57-8

hydrazine hydrate

sodium hydroxide
1310-73-2

sodium hydroxide

nickel
7440-02-0

nickel

Conditions
ConditionsYield
In water N2H4*H2O (80%) added to aq. soln. of NiCl2*6H2O (temp. increased to 65°C) under vigorous stirring, cooling to 50°C, aq. NaOH (50%)added (temp. increased to 54°C), 1 h; ppt. washed with water and dried at room temp. for 16 h;100%
In water; ethylene glycol byproducts: N2, H2O; other Radiation; soln. of Ni compd. in ethylene glycol treated with hydrazine hydrate andNaOH under external magnetic field (0.13-0.35 T) with vigorous stirring , react at 60°C; pptd., septd., washed (ethanol), dried (vac., 40°C, 24 h), SEM, XRD;
hydrogen
1333-74-0

hydrogen

nickel(II) hydroxide

nickel(II) hydroxide

nickel
7440-02-0

nickel

Conditions
ConditionsYield
In not given at 205°C, H2 pressure 14 atm, 45 min, form of product is powder;99.8%
In not given at 200-300°C, 10 h, form of product is powder;85%
at 270-320°C;
sodium
7440-23-5

sodium

nickel dichloride

nickel dichloride

nickel
7440-02-0

nickel

Conditions
ConditionsYield
Na-emulsion in organic solvent, at 220°C, form of product is powder;99.2%
Na-emulsion in organic solvent, at 220°C, form of product is powder;99.2%
explosive reaction;
((CO)NiNCN(CH3)2)2

((CO)NiNCN(CH3)2)2

A

nickel
7440-02-0

nickel

B

NCNMe2
1467-79-4

NCNMe2

Conditions
ConditionsYield
byproducts: CO; thermal dissociation in high vacuum;A 99%
B 99%
{(CO)NiNCN(CH2)4}2

{(CO)NiNCN(CH2)4}2

A

pyrrolidine-1-carbonitrile
1530-88-7

pyrrolidine-1-carbonitrile

B

nickel
7440-02-0

nickel

Conditions
ConditionsYield
byproducts: CO; thermal dissociation in high vacuum;A 99%
B 99%
{(CO)NiNCN(CH2)2O(CH2)2}2

{(CO)NiNCN(CH2)2O(CH2)2}2

A

N-cyanomorpholine
1530-89-8

N-cyanomorpholine

B

nickel
7440-02-0

nickel

Conditions
ConditionsYield
byproducts: CO; thermal dissociation in high vacuum;A 99%
B 99%
{(CO)NiNCN(CH2)4C(CH3)H}2

{(CO)NiNCN(CH2)4C(CH3)H}2

A

2-methylpiperidine-1-carbonitrile
5321-87-9

2-methylpiperidine-1-carbonitrile

B

nickel
7440-02-0

nickel

Conditions
ConditionsYield
byproducts: CO; thermal dissociation in high vacuum;A 99%
B 99%
{(CO)NiNCN(CH2)2C6H4(CH2)}2

{(CO)NiNCN(CH2)2C6H4(CH2)}2

A

3,4-dihydro-2(1H)-isoquinolinecarbonitrile
1705-22-2

3,4-dihydro-2(1H)-isoquinolinecarbonitrile

B

nickel
7440-02-0

nickel

Conditions
ConditionsYield
byproducts: CO; thermal dissociation in high vacuum;A 99%
B 99%
{(CO)NiNCN(CH2)6}2

{(CO)NiNCN(CH2)6}2

A

hexahydroazepin-1-yl cianide
5321-89-1

hexahydroazepin-1-yl cianide

B

nickel
7440-02-0

nickel

Conditions
ConditionsYield
byproducts: CO; thermal dissociation in high vacuum;A 99%
B 99%
[((C6H5)3P)3NiCl]2

[((C6H5)3P)3NiCl]2

A

bis(triphenylphosphine)nickel(II) chloride
14264-16-5, 53996-95-5, 62075-39-2, 39716-73-9

bis(triphenylphosphine)nickel(II) chloride

B

nickel
7440-02-0

nickel

C

nickel dichloride

nickel dichloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: triphenylphosphine; Ar-atmosphere; 140-180°C, 1 h; extn. (ether, CH2Cl2, H2O), evapn. of extract;A 97.7%
B 94.7%
C 87.5%
nickel(II) sulfate hexahydrate

nickel(II) sulfate hexahydrate

nickel
7440-02-0

nickel

Conditions
ConditionsYield
With sodium carbonate; hydrazine hydrate; sodium dodecylbenzenesulfonate In water mixt. heated at 90 °C at pH 9.6 (Na2CO3) with hydrazine:nickel 2:1 molar ratio, Ni(2+) conc. 0.25 M, sodium citrate:Ni ratio 1:4 for 18 min; metal powder filtered, washed (H2O, ethanol, acetone), dried in vac. at 40 °C; detd. by XRD;96%
With sodium carbonate; hydrazine hydrate; sodium dodecylbenzenesulfonate In water mixt. heated at 90 °C at pH 9.6 (Na2CO3) with hydrazine:nickel 2:1 molar ratio, Ni(2+) conc. 0.25 M, sodium citrate:Ni ratio 1:4 for 120 or 160 min or without citrate for 90 min; metal powder filtered, washed (H2O, ethanol, acetone), dried in vac. at 40 °C; detd. by XRD;95%
With sodium carbonate; hydrazine hydrate; sodium dodecylbenzenesulfonate In water mixt. heated at 90 °C at pH 9.6 (Na2CO3) with hydrazine:nickel 2:1 molar ratio, Ni(2+) conc. 0.25 M, sodium citrate:Ni ratio 1:4 for 140 min; metal powder filtered, washed (H2O, ethanol, acetone), dried in vac. at 40 °C; detd. by XRD;94%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

A

Cyclooctan
292-64-8

Cyclooctan

B

nickel
7440-02-0

nickel

Conditions
ConditionsYield
With hydrogen In hexane 1 atm., 20°C, vigorous reaction after induction period;A 96%
B n/a
With hydrogen In hexane 1 atm., 20°C, vigorous reaction after induction period;A 96%
B n/a
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

A

nickel
7440-02-0

nickel

B

tetracarbonyl nickel
13463-39-3, 71564-36-8

tetracarbonyl nickel

C

1,5-dicyclooctadiene
5259-72-3, 10060-40-9, 111-78-4

1,5-dicyclooctadiene

Conditions
ConditionsYield
With carbon monoxide In hexane -40°C, warming within 1 h to 0-20°C;A 0%
B 93%
C 80.6%
With carbon monoxide In hexane -40°C, warming within 1 h to 0-20°C;A 0%
B 93%
C 80.6%
ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

nickel dibromide

nickel dibromide

A

ethane
74-84-0

ethane

B

ethene
74-85-1

ethene

C

nickel
7440-02-0

nickel

D

magnesium bromide

magnesium bromide

Conditions
ConditionsYield
In tetrahydrofuran To a soln. of anhydrous salt is added C2H5MgBr at 20°C with stirring. The reaction mixture is left for 5 - 6 h at room temp.; decantation, washing with THF, water and ethanol; electron diffraction;A n/a
B n/a
C 90%
D n/a
tris[bis(pentane-2,4-dionato)nickel(II)]

tris[bis(pentane-2,4-dionato)nickel(II)]

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

nickel
7440-02-0

nickel

Conditions
ConditionsYield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; ratio B(3+) : Ni(2+) = 2 : 1; irradn. (254 nm) for 8 h gave deposition of Ni; deposit sepd., washed with acetone and water, and dried in vac. to give pure Ni;90%
trans-,trans-,trans-C12H18NiC(N2)(C6H5)2

trans-,trans-,trans-C12H18NiC(N2)(C6H5)2

B

benzophenone hydrazone
5350-57-2

benzophenone hydrazone

C

nickel
7440-02-0

nickel

Conditions
ConditionsYield
In diethyl ether byproducts: N2; heating cautiously to 20°C;A 89%
B n/a
C n/a
nickel(II) oxide
1313-99-1

nickel(II) oxide

nickel
7440-02-0

nickel

Conditions
ConditionsYield
With hydrogen In neat (no solvent) Kinetics; 1000 h, NiO calcinated at 1000°C;;85%
With H2 In neat (no solvent) Kinetics; 1000 h, NiO calcinated at 1000°C;;85%
With hydrogen In neat (no solvent) Kinetics; 180°C, 70 h, NiO prepared be H2O elimination of Ni(OH)2 in vacuum;;>99
tetracarbonyl nickel
13463-39-3, 71564-36-8

tetracarbonyl nickel

nickel
7440-02-0

nickel

Conditions
ConditionsYield
introducing of liq. Ni(CO)4 into heavy oil, vigorous mixing at 250°C, after filtration keep under petroleum ether or N2;85%
Sonication; at 240-260°C;
150-250°C. 1-2 at, high-frequency technic, diphenyl and diphenyl oxide used as germ;
trans-,trans-,trans-C12H18NiC(N2)(C6H5)2

trans-,trans-,trans-C12H18NiC(N2)(C6H5)2

A

1,5,9-cyclodecatriene

1,5,9-cyclodecatriene

B

nickel
7440-02-0

nickel

C

benzonitrile
100-47-0

benzonitrile

Conditions
ConditionsYield
byproducts: N2; -30°C;A 80.9%
B n/a
C 13.5%
nickel(II) chloride hexahydrate

nickel(II) chloride hexahydrate

nickel
7440-02-0

nickel

Conditions
ConditionsYield
With N2H4*H2O; poly(vinyl pyrrolidone) In ethylene glycol byproducts: NH3, N2, H2; ethylene glycol refluxed for 5 min, treated dropwise with hydrazine monohydrate, treated with Ni salt in ethylene glycol and poly(vinyl pyrrolidone) in ethylene glycol under vigorous stirring, refluxed for 60 min; centrifuged, washed (abs. ethanol) 6 times, evapd.(vac.) at 80°C,XRD;80%
In water Electrolysis; platinum anode and copper cathode were used; the composition of the bath: 50 g/dm3 NiCl2*6H2O, 50 g/dm3(NH4)2SO4 and 250 mol/dm3 NH4OH; the pH of the soln. was 9.5-10.2; at 25°C; the plating time was 15 min;;
With (NH2)2CSO2 In pentan-1-ol; water Kinetics; isothermal redn. of Ni-salt with thiourea dioxide, 15 mol-% alcohol, pH4.0 (Britton-Robinson buffer), 1 h, 313+/-0.5 K; gravimetric anal.;
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

nickel dibromide

nickel dibromide

nickel
7440-02-0

nickel

Conditions
ConditionsYield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratio NaBPh4 : NiBr2 = 2 : 1; irradn. (254 nm) for 8 h gave deposition of Ni; deposit sepd., washed with acetone and water, and dried in vac. to give pure Ni;80%
Conditions
ConditionsYield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : NiBr2 : CuBr2 = 8 : 3 : 1; irradn. (254 nm) for 10 h gave deposition of Ni and Cu;A 73%
B 24%
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : NiBr2 : CuBr2 = 4 : 1 : 1; irradn. (254 nm) for 10 h gave deposition of Ni and Cu;A 48%
B 49%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

3,6-dimethylene-1,7-octadiene
3382-59-0

3,6-dimethylene-1,7-octadiene

tris(1-methylethyl)phosphine
6476-36-4

tris(1-methylethyl)phosphine

A

(η(2),η(2)-3,6-dimethylene-1,7-butadiene)NiPiPr3
163976-20-3

(η(2),η(2)-3,6-dimethylene-1,7-butadiene)NiPiPr3

B

nickel
7440-02-0

nickel

Conditions
ConditionsYield
In diethyl ether stirring (-30°C, 48 h); filtering (-30°C), crystn. (-78°C), washing (pentane, -78°C); elem. anal.;A 71%
B 1%
Ni[η(1),η(2)-C5H5C2(CO2Me)2]Cp

Ni[η(1),η(2)-C5H5C2(CO2Me)2]Cp

A

nickel
7440-02-0

nickel

B

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

Conditions
ConditionsYield
With hydrogen In ethanol byproducts: C7H9(C(O)OCH3); room temp.; normal pressure;A n/a
B 70%
With H2; catalyst: Pt In ethanol byproducts: C7H9(C(O)OCH3); room temp.; normal pressure;A n/a
B 70%
With hydrogen In ethanol byproducts: C7H9(C(O)OCH3); room temp.; normal pressure;A n/a
B 70%
bis(4-acetyl-1-ethyl-3-methyl-5-pyrazolonato)nickel(II)

bis(4-acetyl-1-ethyl-3-methyl-5-pyrazolonato)nickel(II)

A

formaldehyd
50-00-0

formaldehyd

B

C3N2(CH3)(C2H5)(OH)C(O)CH3

C3N2(CH3)(C2H5)(OH)C(O)CH3

C

nickel
7440-02-0

nickel

Conditions
ConditionsYield
With methanol; benzophenone In neat (no solvent) Kinetics; Irradiation (UV/VIS); photolysis (mercury lamp, 300 nm lamps, merry-go-round unit), irradn. under N2 through a pyrex filter; centrifugation, filtration through a pipette (Celite), detd. by UV;A 56%
B 68%
C n/a
nickel(II) sulphate

nickel(II) sulphate

nickel
7440-02-0

nickel

Conditions
ConditionsYield
With Na3C6H5O7*2H2O In water Electrolysis; Ni(II):Cit=1:1, potentiostatic condditions, -1.1 V vs. SHE, Ag/AgCl immersed in 3.3 M KCl used as reference, Cu plate as working, Pt sheet as counter electrodes; soln. stirred at 500 rpm with magnet; temp. 298 K; X-ray fluorometry;65%
With Na or K or Ca or Ba hypophosphite; Na acetate or Na formate In not given 90-92°C , pH=5.0-6.5;
Electrolysis; form of product is powder;
bis(acetylacetonate)nickel(II)

bis(acetylacetonate)nickel(II)

A

nickel
7440-02-0

nickel

B

nickel(0)(1,5-cyclooctadiene)2

nickel(0)(1,5-cyclooctadiene)2

Conditions
ConditionsYield
With n-hexyllithium In toluene byproducts: n-hexane, hex-1-en, LiH; under Ar, reduction at room temp. with n-hexyllithium in presence of cyclooctadiene (Li:Ni=4); further byproduct: Ph-Ph, hex-Ph, cycloocta-1,3-diene, cycloocta-1,4-diene, cyclooctene; protolysis of liquid phase with MeOH (H2), gas chromy. of volatile compds.;A n/a
B 65%
dodecacarbonyl triosmium
15696-40-9

dodecacarbonyl triosmium

[Ni(cyclopentadienyl)(μ-CO)]2

[Ni(cyclopentadienyl)(μ-CO)]2

A

(C5H5)3Ni3Os3(CO)9

(C5H5)3Ni3Os3(CO)9

B

(η5-C5H5)NiOs3(μ-H)3(CO)9

(η5-C5H5)NiOs3(μ-H)3(CO)9

C

nickel
7440-02-0

nickel

Conditions
ConditionsYield
With hydrogen In octane Os3(CO)12 refluxed in octane with (CpNi(CO))2 for 30 min under H2 flow,cooled; filtered, evapd. in vac., purified by TLC (Kiselgel PF Merck, light petroleum-Et2O), crystd. from CHCl3/heptane at -10°C; elem. anal.;A 10%
B 60%
C n/a
magnesium-1,3-butadiene * 2 THF

magnesium-1,3-butadiene * 2 THF

((CH3)2C2N2(C6H3(CH3)2)2)NiClBr

((CH3)2C2N2(C6H3(CH3)2)2)NiClBr

A

bisacetylbis(2,6-dimethylphenylimin)(1,3-butadiene)nickel
129616-15-5

bisacetylbis(2,6-dimethylphenylimin)(1,3-butadiene)nickel

B

Ni(1,4-bis(2,6-dimethylphenyl)-2,3-dimethyl-1,4-diazabuta-1,3-diene)2
74779-91-2

Ni(1,4-bis(2,6-dimethylphenyl)-2,3-dimethyl-1,4-diazabuta-1,3-diene)2

C

nickel
7440-02-0

nickel

Conditions
ConditionsYield
In tetrahydrofuran (N2), dry solvents; addn. of Mg compd. to suspn. of Ni compd. in THF room temperature, stirring overnight;A 40%
B 60%
C n/a
2,3,5,6-tetrafluorobenzaldehyde
19842-76-3

2,3,5,6-tetrafluorobenzaldehyde

nickel
7440-02-0

nickel

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

(2,3,5,6-tetrafluorophenyl)methanol
4084-38-2

(2,3,5,6-tetrafluorophenyl)methanol

Conditions
ConditionsYield
100%
1,4-dioxane
123-91-1

1,4-dioxane

nickel
7440-02-0

nickel

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

2,3,5,6-tetrafluoroterephthalaldehyde
3217-47-8

2,3,5,6-tetrafluoroterephthalaldehyde

2,3,5,6-tetrafluoro-1,4-benzenedimethanol
92339-07-6

2,3,5,6-tetrafluoro-1,4-benzenedimethanol

Conditions
ConditionsYield
100%
nickel
7440-02-0

nickel

phthalonitrile
91-15-6

phthalonitrile

nickel(II) phthalocyanine
14055-02-8

nickel(II) phthalocyanine

Conditions
ConditionsYield
With sodium methylate In methanol pyrophoric Ni under water layer added to a methanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30% soln of CH3ONa in methanol; flask maintained at 25°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97%; elem. anal.;100%
With sodium methylate In methanol; water pyrophoric metal:phthalonitrile=1:4 and few drops of CH3ONa under water layer treated for 24 h at 25°C; septd., washed (ethanol), dried in air, elem. anal.;100%
With sodium methylate In ethanol pyrophoric Ni under water layer added to an ethanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30% soln of CH3ONa in methanol; flask maintained at 25°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97%; elem. anal.;100%
triphenylphosphine diiodide
6396-07-2

triphenylphosphine diiodide

nickel
7440-02-0

nickel

{(C6H5)3PI}(1+)*{Ni(P(C6H5)3)I3}(1-)={(C6H5)3PI}{Ni(P(C6H5)3)I3}
152442-02-9

{(C6H5)3PI}(1+)*{Ni(P(C6H5)3)I3}(1-)={(C6H5)3PI}{Ni(P(C6H5)3)I3}

Conditions
ConditionsYield
In diethyl ether under N2: dissoln. of (C6H5)3PI2 (2 equivalents) in dry diethyl ether in a rotoflow tube; addn. of coarse-grain unactivated Ni, 60°C; stirring, 7d;; isolation by standard Schlenk technique; drying in vac.; elem. anal.;100%
diiodo tri-n-butylphosphorane
21473-75-6

diiodo tri-n-butylphosphorane

nickel
7440-02-0

nickel

{(C4H9)3PI}(1+)*{Ni(P(C4H9)3)I3}(1-)={(C4H9)3PI}{Ni(P(C4H9)3)I3}
152386-23-7

{(C4H9)3PI}(1+)*{Ni(P(C4H9)3)I3}(1-)={(C4H9)3PI}{Ni(P(C4H9)3)I3}

Conditions
ConditionsYield
In diethyl ether under N2: dissoln. of (C4H9)3PI2 (2 equivalents) in dry diethyl ether in a rotoflow tube; addn. of coarse-grain unactivated Ni, 60°C; stirring, 7d;; isolation by standard Schlenk technique; drying in vac.; elem. anal.;100%
diiodotriethylphosphorane
98961-77-4

diiodotriethylphosphorane

nickel
7440-02-0

nickel

{(C2H5)3PI}(1+)*{Ni(P(C2H5)3)I3}(1-)={(C2H5)3PI}{Ni(P(C2H5)3)I3}
152386-25-9

{(C2H5)3PI}(1+)*{Ni(P(C2H5)3)I3}(1-)={(C2H5)3PI}{Ni(P(C2H5)3)I3}

Conditions
ConditionsYield
In diethyl ether under N2: dissoln. of (C2H5)3PI2 (2 equivalents) in dry diethyl ether in a rotoflow tube; addn. of coarse-grain unactivated Ni, 60°C; stirring, 7d;; isolation by standard Schlenk technique; drying in vac.; elem. anal.;100%
antimony
7440-36-0

antimony

zirconium
7440-67-7

zirconium

nickel
7440-02-0

nickel

ZrNiSb

ZrNiSb

Conditions
ConditionsYield
In neat (no solvent) Electric Arc; heating (650°C, 4 d; dynamic Ar atm., arc melting), annealing (5 h, 1050-1200°C);100%
In neat (no solvent) vac. (5E-3 mbar); stoichiometric ratio, heating (1 week, 1100°C);
In melt Electric Arc; arc melted under Ar gettered with Ti; 5 wt.-% of Sb required to compensate evaporative losses during arc-melting; ingots sealed in evacuated fused-silica tubes and annealed at 870 K for 720 h; quenched in cold water; XRD; EDX;
nickel
7440-02-0

nickel

sulfur
7704-34-9

sulfur

1,2-diaminopropan
78-90-0, 10424-38-1

1,2-diaminopropan

[Ni(1,2-diaminopropane)3]2Sn2S6*2H2O

[Ni(1,2-diaminopropane)3]2Sn2S6*2H2O

Conditions
ConditionsYield
In further solvent(s) High Pressure; prepd. under solvothermal conditions; reactants weighted in ratio of 1 Ni:1 Sn:3 S, heated in sealed Teflon-lined steel autoclave in pure 1,2-diaminopropane for 7 d at 140°C; elem. anal.;100%
P(CH2CH2C6H5)3I2
149683-89-6

P(CH2CH2C6H5)3I2

nickel
7440-02-0

nickel

{(C6H5CH2CH2)3PI}(1+)*{Ni(P(C6H5CH2CH2)3)I3}(1-)={(C6H5CH2CH2)3PI}{Ni(P(C6H5CH2CH2)3)I3}
152386-19-1

{(C6H5CH2CH2)3PI}(1+)*{Ni(P(C6H5CH2CH2)3)I3}(1-)={(C6H5CH2CH2)3PI}{Ni(P(C6H5CH2CH2)3)I3}

Conditions
ConditionsYield
In diethyl ether under N2: dissoln. of (C6H5CH2CH2)3PI2 (2 equivalents) in dry diethyl ether in a rotoflow tube; addn. of coarse-grain unactivated Ni, 60°C; stirring, 7d;; isolation by standard Schlenk technique; drying in vac.; elem. anal.;100%
(C2H5)2(CH3)PI2
147274-44-0

(C2H5)2(CH3)PI2

nickel
7440-02-0

nickel

{(C2H5)2(CH3)PI}(1+)*{Ni(P(C2H5)2(CH3))I3}(1-)={(C2H5)2(CH3)PI}{Ni(P(C2H5)2(CH3))I3}
152386-28-2

{(C2H5)2(CH3)PI}(1+)*{Ni(P(C2H5)2(CH3))I3}(1-)={(C2H5)2(CH3)PI}{Ni(P(C2H5)2(CH3))I3}

Conditions
ConditionsYield
In diethyl ether under N2: dissoln. of (C2H5)2(CH3)PI2 (2 equivalents) in dry diethyl ether in a rotoflow tube; addn. of coarse-grain unactivated Ni, 60°C; stirring, 7d;; isolation by standard Schlenk technique; drying in vac.; elem. anal.;100%
nickel
7440-02-0

nickel

tris(dimethylamino)diiodophosphorane
82859-40-3

tris(dimethylamino)diiodophosphorane

{((CH3)2N)3PI}(1+)*{Ni(P(N(CH3)2)3)I3}(1-)={((CH3)2N)3PI}{Ni(P(N(CH3)2)3)I3}
152386-30-6

{((CH3)2N)3PI}(1+)*{Ni(P(N(CH3)2)3)I3}(1-)={((CH3)2N)3PI}{Ni(P(N(CH3)2)3)I3}

Conditions
ConditionsYield
In diethyl ether under N2: dissoln. of (N(CH3)2)3PI2 (2 equivalents) in dry diethyl ether in a rotoflow tube; addn. of coarse-grain unactivated Ni, 60°C; stirring, 7d;; isolation by standard Schlenk technique; drying in vac.; elem. anal.;100%
hafnium

hafnium

antimony
7440-36-0

antimony

nickel
7440-02-0

nickel

HfNiSb

HfNiSb

Conditions
ConditionsYield
In neat (no solvent) Electric Arc; heating (650°C, 4 d; dynamic Ar atm., arc melting);100%
In neat (no solvent) Electric Arc; repeated remelting, annealing in evac. quartz tube for 250 h at 800°C, quenching (cold water);
samarium
7440-19-9

samarium

nickel
7440-02-0

nickel

Sm2NiSn4

Sm2NiSn4

Conditions
ConditionsYield
In neat (no solvent, solid phase) mixt. of Sm, Ni, Sn loaded into Ta tube, heated at 970°C for 36 h, quenched in water, annealed at 700°C for 15 d;99%
In neat (no solvent, solid phase) mixt. of Sm, Ni, Sn loaded into Nb tube, heated under dynamic vac. at 300°C for 1 d, heated at 950°C for 5 d, cooled to room temp.at 15°C/h;
thiazolidine-2-one
2682-49-7

thiazolidine-2-one

nickel
7440-02-0

nickel

Conditions
ConditionsYield
In acetonitrile byproducts: H2; Electrochem. Process; electrolyse of a soln. of the ligand in acetonitrile (NH4BF4) with a Nianode at room temp. under N2; filtered, washed with acetonitrile, dried in vac.; elem. anal.;99%
tellurium

tellurium

sulfuryl dichloride
7791-25-5

sulfuryl dichloride

nickel
7440-02-0

nickel

acetonitrile
75-05-8

acetonitrile

[Ni(NCCH3)6](2+)*[Te2Cl10](2-) = [Ni(NCCH3)6][Te2Cl10]
368867-42-9

[Ni(NCCH3)6](2+)*[Te2Cl10](2-) = [Ni(NCCH3)6][Te2Cl10]

Conditions
ConditionsYield
In acetonitrile under dry Ar; Ni and Te mixed in CH3CN; SO2Cl2 added; stirred (2 h); evapd. to dryness (vac.); recrystd. from CH3CN (room temp.); elem. anal.;99%
nickel
7440-02-0

nickel

trimethylarsine diiodide
17756-08-0

trimethylarsine diiodide

[NiI3(As(CH3)3)2]
174094-63-4

[NiI3(As(CH3)3)2]

Conditions
ConditionsYield
In diethyl ether byproducts: I2; (N2); 60°C, ca. 4 d; drying (vac.), recrystn. (Et2O); elem. anal.;99%
tellurium

tellurium

sulfur dioxide
7446-09-5

sulfur dioxide

arsenic pentafluoride
7784-36-3

arsenic pentafluoride

nickel
7440-02-0

nickel

[Ni(SO2)6](2+)*Te6(4+)*6AsF6(1-)=[Ni(SO2)6][Te6][AsF6]6

[Ni(SO2)6](2+)*Te6(4+)*6AsF6(1-)=[Ni(SO2)6][Te6][AsF6]6

Conditions
ConditionsYield
In neat (no solvent) byproducts: AsF3; all manipulations under Ar atm.; SO2 and AsF5 condensed on Ni and Te (external cooling bath of liq. N2), stirred for 5 h; SO2 distd. slowly;99%
(2S)-2-[1-(diethoxymethyl)cyclopropyl]-2-{[(1S)-1-phenylethyl]amino}acetonitrile
400709-89-9

(2S)-2-[1-(diethoxymethyl)cyclopropyl]-2-{[(1S)-1-phenylethyl]amino}acetonitrile

nickel
7440-02-0

nickel

N-{2-amino-(1S)-1-[1-(diethoxymethyl)cyclopropyl]ethyl}-N-[(1S)-1-phenylethyl]amine

N-{2-amino-(1S)-1-[1-(diethoxymethyl)cyclopropyl]ethyl}-N-[(1S)-1-phenylethyl]amine

Conditions
ConditionsYield
With sodium hydroxide In ethanol; chloroform; water; hydrogen98.4%
3,5-dimethyl-1-(carbethoxymethylene)cyclohexane
85120-26-9

3,5-dimethyl-1-(carbethoxymethylene)cyclohexane

nickel
7440-02-0

nickel

(3,5-dimethyl-cyclohexyl)-acetic acid ethyl ester
85120-28-1

(3,5-dimethyl-cyclohexyl)-acetic acid ethyl ester

Conditions
ConditionsYield
In methanol98%
Octanoic acid
124-07-2

Octanoic acid

nickel
7440-02-0

nickel

nickel(II) bis(octanoate)

nickel(II) bis(octanoate)

Conditions
ConditionsYield
In acetonitrile Electrolysis; 4 h, initial voltage 30 V; washed with acetonitrile and dried in vacuo for 3-4 h at room temp.;elem.anal;98%
With tetrabutyl-ammonium chloride In acetonitrile for 8h; Electrolysis;
nickel
7440-02-0

nickel

2-Mercaptobenzothiazole
149-30-4

2-Mercaptobenzothiazole

bis-[2-mercaptobenzothiazolatonickel(II)]
77321-77-8, 119203-46-2

bis-[2-mercaptobenzothiazolatonickel(II)]

Conditions
ConditionsYield
In acetonitrile byproducts: H2; Electrochem. Process; electrolyse of a soln. of the ligand in acetonitrile (NH4BF4) with a Nianode at room temp. under N2; filtered, washed with acetonitrile, dried in vac.; elem. anal.;98%
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