sulfur dioxide
water
iodine
A
sulfuric acid
B
hydrogen iodide
Conditions | Yield |
---|---|
0 - 25 °C; part of a Mg-S-I water splitting cycle; | A 100% B 100% |
Conditions | Yield |
---|---|
at 170-180°C; in very dilute soln. complete decompn. in 2 h, incomplete decompn. in concd. solns.; | A n/a B 100% |
byproducts: H2S4O6; | |
sodium thiosulfate In water 100°C; |
carbon oxide sulfide
dihydrogen peroxide
A
carbon dioxide
B
sulfuric acid
C
water
Conditions | Yield |
---|---|
With potassium sulfate; potassium hydrogensulfate; potassium peroxomonosulfate In water Kinetics; oxidation of OCS studied in round-bottom Pyrex bulbs, acid-water mixtures introduced into bulbs and degassed, bulb reactors filled with with a gas mixture slightly above 1 atm total pressure with a typical mixing ratio of OCS:Ar:He=40:60:700 Torr; gas chromy. and mass spectroscopy applied for determination of product content; | A 100% B n/a C n/a |
With sulfuric acid In water Kinetics; oxidation of OCS studied in round-bottom Pyrex bulbs, acid-water mixtures introduced into bulbs and degassed, bulb reactors filled with with a gas mixture slightly above 1 atm total pressure with a typical mixing ratio of OCS:Ar:He=40:60:700 Torr; gas chromy. and mass spectroscopy applied for determination of product content; | A 100% B n/a C n/a |
Conditions | Yield |
---|---|
With sulfuric acid; ammonia absorption of dild. SO2 in aq. soln. of NH3, eliberation with H2SO4, O2 from water electrolysis, 3-layer contact bed, heat exchanger, 3 H2SO4 absorbers, coke filter, tail gas recirculation, 528-682°C; | 99.5% |
With NH3; H2SO4; catalyst: V compd. absorption of dild. SO2 in aq. soln. of NH3, eliberation with H2SO4, O2 from water electrolysis, 3-layer contact bed, heat exchanger, 3 H2SO4 absorbers, coke filter, tail gas recirculation, 528-682°C; | 99.5% |
ferric hydroxide In not given 125-130°C, Fe(OH)3 on pumice or asbestos; |
Conditions | Yield |
---|---|
With air moist air introductions into four-stage contact furnace, 2-stage drum absorber, washing of tail gas in Venturi app.; 93-95 % acid concn.; | 99% |
With air moist air introductions into four-stage contact furnace, 2-stage drum absorber, washing of tail gas in Venturi app.; 93-95 % acid concn.; | 99% |
With catalyst: V compd. moist S roaster gas, absorption in concd. acid; |
hydrogenchloride
copper(II) sulfate
A
sulfuric acid
B
chlorine
C
copper
Conditions | Yield |
---|---|
In water Electrolysis; | A n/a B 90% C 99% |
In water |
Conditions | Yield |
---|---|
In hydrogenchloride room temp.; 10-15 min.; | A n/a B 99% |
In hydrogenchloride room temp.; 10-15 min.; | A n/a B 99% |
Conditions | Yield |
---|---|
With sulphurous acid byproducts: H2O; | A n/a B 99% |
With H2SO3 byproducts: H2O; | A n/a B 99% |
Conditions | Yield |
---|---|
In not given Electrolysis; Pt anode, graphite cathode, area of the electrodes 30 cm^2, 1 A, 20 min, 0.208 mg/l SO2 soln.; | A 98.16% B 70.87% |
In not given Electrolysis; Pt anode, graphite cathode, area of the electrodes 30 cm^2, 1 A, 20 min, 0.420 mg/l SO2 soln.; | A 98.52% B 74.28% |
In not given Electrolysis; Pt anode, graphite cathode, area of the electrodes 30 cm^2, 1 A, 20 min, 1.123 mg/l SO2 soln.; | A 98.86% B 74.2% |
sulfuric acid
Conditions | Yield |
---|---|
3-stage contact with heat exchangers, for pyrite roaster gas; | 98% |
With air burning at 820°C in rotating furnace, elec. filter, washing, air addn., wet elec. filter, drying, heat exchanger, two-stage inner cooling, cooler, absorption, cooling; | |
With nitric acid formation of H2SO4 by reaction of HNO3 with pyrite; faster reaction at 100 °C than at higher temperature;; | |
With air; catalyst: V2O5 - K2O - SiO2 burning at 820°C in rotating furnace, elec. filter, washing, air addn., wet elec. filter, drying, heat exchanger, two-stage inner cooling, cooler, absorption, cooling; |
Conditions | Yield |
---|---|
With (CN)2 In water byproducts: HCN; with (CN)2 excess for 4-5 days at room temp.; | 94% |
contact oven with intermediate heat exchangers, temp. regulation by fresh air addn., H2O to inlet gas, SO2 recycling; | 80% |
condensation after contact furnace at 175. degree.C; 66.3 % acid concn.; | 46.7% |
Conditions | Yield |
---|---|
In water Electrolysis; formation of PbSO4 on Pb-anode; electrolysis of PbSO4; | A 91% B 91% |
With H2O Electrolysis; | |
In water Electrolysis; |
sulphurous acid
chloric acid
A
sulfuric acid
B
chlorine dioxide
C
water
Conditions | Yield |
---|---|
With air; sulfur dioxide In sulfuric acid byproducts: HClO, HCl, Cl2; Holst-process;; | A n/a B 90% C n/a |
Conditions | Yield |
---|---|
uranyl chloride In neat (no solvent) equilibrium on thermal decompn.;; distillation;; | A 90% B n/a |
mercury In neat (no solvent) equilibrium on thermal decompn.;; distillation;; | A 90% B n/a |
bismuth(III) chloride In neat (no solvent) equilibrium on thermal decompn.;; distillation;; | A 90% B n/a |
5-Chloro-1,10-phenanthroline
bromanilic acid
(VO)2(Br2C6O4)(C12H7ClN2)2(2+)*SO4(2-)=[(VO)2(Br2C6O4)(C12H7ClN2)2](SO4)
B
sulfuric acid
Conditions | Yield |
---|---|
In methanol dropwise addn. of soln. of VOSO4 to soln of bromanilic acid, addn. of soln. of N-ligand (stirring, room temp.), refluxing (8 h; crystn.); filtration, washing (MeOH, Et2O), drying (vac., over P2O5), recrystn. (DMF/EtOH); elem. anal.; | A 88% B n/a |
Conditions | Yield |
---|---|
Stage #1: chlorosulfonic acid With Acetanilid at 26 - 45℃; for 9.2h; Stage #2: With thionyl chloride at 55℃; for 6.4h; Temperature; Further stages; | A 87% B n/a |
2.9-dimethyl-1,10-phenanthroline
bromanilic acid
(VO)2(Br2C6O4)((CH3)2C12H6N2)2(2+)*SO4(2-)=[(VO)2(Br2C6O4)((CH3)2C12H6N2)2](SO4)
B
sulfuric acid
Conditions | Yield |
---|---|
In methanol dropwise addn. of soln. of VOSO4 to soln of bromanilic acid, addn. of soln. of N-ligand (stirring, room temp.), refluxing (8 h; crystn.); filtration, washing (MeOH, Et2O), drying (vac., over P2O5), recrystn. (DMF/EtOH); elem. anal.; | A 85% B n/a |
1,10-Phenanthroline
bromanilic acid
(VO)2(Br2C6O4)(C12H8N2)2(2+)*SO4(2-)=[(VO)2(Br2C6O4)(C12H8N2)2](SO4)
B
sulfuric acid
Conditions | Yield |
---|---|
In methanol dropwise addn. of soln. of VOSO4 to soln of bromanilic acid, addn. of soln. of N-ligand (stirring, room temp.), refluxing (8 h; crystn.); filtration, washing (MeOH, Et2O), drying (vac., over P2O5), recrystn. (DMF/EtOH); elem. anal.; | A 81% B n/a |
aminosulfonic acid
A
sulfuric acid
B
nitrogen
C
sodium chloride
Conditions | Yield |
---|---|
With chlorine In water introduction of chlorine into alkaline soln.; intermediates (NaSO3NCl2/NaSO3NHCl) decompose after short time in this soln.;; | A n/a B 79.65% C n/a |
With Cl2 In water introduction of chlorine into alkaline soln.; intermediates (NaSO3NCl2/NaSO3NHCl) decompose after short time in this soln.;; | A n/a B 79.65% C n/a |
[2,2]bipyridinyl
bromanilic acid
(VO)2(Br2C6O4)(NC5H4C5H4N)2(2+)*SO4(2-)=[(VO)2(Br2C6O4)(NC5H4C5H4N)2](SO4)
B
sulfuric acid
Conditions | Yield |
---|---|
In methanol dropwise addn. of soln. of VOSO4 to soln of bromanilic acid, addn. of soln. of N-ligand (stirring, room temp.), refluxing (8 h; crystn.); filtration, washing (MeOH, Et2O), drying (vac., over P2O5), recrystn. (DMF/EtOH); elem. anal.; | A 72% B n/a |
trisulfimide
A
ammonium bisulfate
B
sulfuric acid
C
SULFAMIDE
Conditions | Yield |
---|---|
With water heat of evapn., 2 h, 2 M HCl; | A n/a B 67% C n/a |
With H2O heat of evapn., 2 h, 2 M HCl; | A n/a B 67% C n/a |
trisulfimide
A
sulfuric acid
B
aminosulfonic acid
C
SULFAMIDE
Conditions | Yield |
---|---|
With water in the cold, 48 h, 2 M HCl; | A 33% B n/a C n/a |
With H2O in the cold, 48 h, 2 M HCl; | A 33% B n/a C n/a |
In water decompn. in aq. soln.; 0 and 22°C discussed; presece of acid discussed;; |
Conditions | Yield |
---|---|
In water 0.2362 mM/g decompn. 46.8°C, 245 h.; | A 19.96% B n/a |
In water 0.2401 mM/g decompn. 25.3°C, 945.25 h.; | A 2.96% B n/a |
In water Kinetics; |
Conditions | Yield |
---|---|
condensation of humidified S burner gas; | |
absorption of moist gas to H2SO4; | |
In water in sealed tube;at 150°C;under 20 atm O2;; | 0.06% |
bismuth
sulfuric acid
pyrographite
2-butyl-5-hydroxymethyl-1H-imidazole
platinum
2-butyl-1H-imidazole-5-carboxaldehyde
Conditions | Yield |
---|---|
With sodium hydroxide In water | 100% |
With sodium hydroxide In water | 98.2% |
With sodium hydroxide In methanol; water | 94.5% |
7-Chloro-4-hydroxy-2-(4-carboxyphenyl)-1,2,5,10-tetrahydropyridazino [4,5-b]quinoline-1,10-dione
sulfuric acid
Conditions | Yield |
---|---|
In methanol | 100% |
Conditions | Yield |
---|---|
In hydrogenchloride; sulfuric acid dissolving CdS in HCl, evapn. to dryness, dissoln. in dild. H2SO4, evapn. with a drop of concd. HNO3; | 100% |
In hydrogenchloride; sulfuric acid aq. H2SO4; dissolving CdS in HCl, evapn. to dryness, dissoln. in dild. H2SO4, evapn. with a drop of concd. HNO3; | 100% |
Conditions | Yield |
---|---|
70 °C; 1-2. step of Mg-S-I water splitting cycle; | A 100% B 100% |
[Fe(μ-S2(CH2)3)(CN)(CO)4(PMe3)](1-)
sulfuric acid
hydrogen
Conditions | Yield |
---|---|
In water Electrolysis; electrolysis of soln. of Fe2(CO)4(CN)(PMe3)S2(CH2)3 with 50 equiv. H2SO4at -1.2 V for 15 min; GC analysis; | 100% |
Conditions | Yield |
---|---|
With water In sulfuric acid digesting; concn. of H2SO4 in aq. H2SO4 >93%; pptn. by adjusting H2SO4 concn. to 84.15%-93% with water; | 100% |
With H2O In sulfuric acid aq. H2SO4; digesting; concn. of H2SO4 in aq. H2SO4 >93%; pptn. by adjusting H2SO4 concn. to 84.15%-93% with water; | 100% |
With water In sulfuric acid uptake of water from the air; |
sulfuric acid
Conditions | Yield |
---|---|
In sulfuric acid aq. H2SO4; Nb-contg. compd. was treated in aq. H2SO4 for 48 h; | 100% |
sulfuric acid
1-methyl-3-(4-sulfobutyl)-1H-imidazol-3-ium hydrogensulfate
Conditions | Yield |
---|---|
In toluene at 80℃; for 24h; | 100% |
4-(pyridinium-1-yl)butane-1-sulfonate
sulfuric acid
N-(4-sulphonic acid)butylpyridinium hydrogen sulphate
Conditions | Yield |
---|---|
In toluene at 80℃; for 24h; | 100% |
Conditions | Yield |
---|---|
at 300℃; for 3h; | 100% |
strontium(II) carbonate
sulfuric acid
sulfur trioxide
boric acid
Conditions | Yield |
---|---|
at 180℃; for 24h; | 100% |
Conditions | Yield |
---|---|
In further solvent(s) H2SO4 was added to Bi in HNO3 with stirring and heating; more H2SO4 wasadded and suspn. was heated for 40 h; heated in a muffle furnace at 648K; elem. anal.; | 99.8% |
In sulfuric acid byproducts: SO2; by dissolving in boiling concd. H2SO4;; | |
In sulfuric acid byproducts: SO2; very weak reaction with diluted H2SO4.;; | |
In nitric acid Bi dissolved in HNO3 and treated with H2SO4, heated for several hours at 380 °C;; |
2-(bromomethyl)-3-methylbutanoic acid
sulfuric acid
isobutene
2-Bromomethyl-3-methyl-butyric acid tert-butyl ester
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In dichloromethane | 99% |
2,4,6-trimethyl-pyridine
N-methylcyclohexylamine
sulfuric acid
tetrabutylammomium bromide
Conditions | Yield |
---|---|
In 1,1,2,2-tetrachloroethylene | 99% |
N-nitroso-N-cyclohexylhydroxylamine potassium salt
sulfuric acid
Conditions | Yield |
---|---|
In water; toluene | 99% |
Conditions | Yield |
---|---|
In methanol byproducts: HCl; concd. H2SO4 is added to a soln. of the cluster in MeOH, HCl is evolvedand soln. is warmed up; soln. is heated to remove HCl and concd., soln. is diluted with MeOH, ppt.is sepd., washed and dried over P2O5, elem. anal.; | 99% |
Conditions | Yield |
---|---|
With acetic acid In water soln. PdEnCl2 in water was treated under heating in water bath with saturated aq. thiourea acidified with acetic acid, in 30 min 2 M H2SO4 was added; ppt. was filtered, washed with diluted H2SO4 and water, and dried; | 99% |
sulfuric acid
Conditions | Yield |
---|---|
In sulfuric acid aq. H2SO4; room temp.; | 99% |
sulfuric acid
Conditions | Yield |
---|---|
In sulfuric acid aq. H2SO4; room temp.; | 99% |
sulfuric acid
Conditions | Yield |
---|---|
In sulfuric acid aq. H2SO4; room temp.; | 99% |
sulfuric acid
Conditions | Yield |
---|---|
In sulfuric acid aq. H2SO4; room temp.; | 99% |
sulfuric acid
Conditions | Yield |
---|---|
In sulfuric acid aq. H2SO4; room temp.; | 99% |
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