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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2-Chloroanisole

Cas:766-51-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality O-Chloroanisole supplier in China

Cas:766-51-8

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Chloroanisole

Cas:766-51-8

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Chloroanisole

Cas:766-51-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

1-chloro-2-methoxybenzene

Cas:766-51-8

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--766-51-8--2-Chloroanisole factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relatio

TIANFUCHEM--766-51-8--2-Chloroanisole factory price

Cas:766-51-8

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 766-51-8 with best price

Cas:766-51-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Product name:2-Chloroanisole CAS No:766-51-8 Appearance: Pale yellow liquid Content:99% Appearance:Pale yellow liquid Storage:Preserve in well-closed, light-resistant and airtight conta

2-Chloroanisole

Cas:766-51-8

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-chloro-2-methoxy- 766-51-8

Cas:766-51-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:766-51-8

Cas:766-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

2-Chloroanisole

Cas:766-51-8

Min.Order:1 Kilogram

FOB Price: $30.0 / 50.0

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

O-Chloroanisole

Cas:766-51-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Triumph International Development Limilted

Appearance:white or yellowish white flaky crystal Storage:Keep the sun from direct sunlight ;prevention against high temperature Package:As customer request Application:Used for research and industrial manufacture. Transportatio

2-Chloroanisole

Cas:766-51-8

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Chloroanisole

Cas:766-51-8

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzene,1-chloro-2-methoxy-

Cas:766-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:clear light yellow liquid Storage:In Room Temperature Package:25kg/drum, or as per your request. Application:For medicine , pesticide intermediates Transportation:as per your request

2-Chloroanisole

Cas:766-51-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

2-Chloroanisole Chemical Properties Melting point -26.8°C Boiling point 195-196 °C (lit.) density 1.123 g/mL at 25 °C (lit.) refractive index n20/D 1.545(lit.) Fp 169 °F storage temp. 2-8°C form Liquid

2-Chloroanisole

Cas:766-51-8

Min.Order:200 Kilogram

FOB Price: $65.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Chloroanisole

Cas:766-51-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/2-Chloroanisole

Cas:766-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2-Chloroanisole

Cas:766-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

2-Chloroanisole

Cas:766-51-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2- methoxyl-5- chloroanisole cas no. 766-51-8 98%

Cas:766-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

1-Chloro-2-Methoxybenzene

Cas:766-51-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

2-Chloroanisole

Cas:766-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

O-Chloroanisole

Cas:766-51-8

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-Chloroanisole

Cas:766-51-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

O-Chloroanisole

Cas:766-51-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

2-Chloroanisole

Cas:766-51-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

2-ChloroanisoleAppearance:powder Storage:Refrigerator Package:Depended Application:766-51-8 Transportation:by air or by sea

2-Chloroanisole

Cas:766-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

2-Chloroanisole

Cas:766-51-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With N-chloro-succinimide; copper(l) chloride In acetonitrile at 80℃; for 18h;97%
With N-chloro-succinimide In acetonitrile at 80℃; for 24h;90%
2-monochlorophenol
95-57-8

2-monochlorophenol

dimethyl sulfate
77-78-1

dimethyl sulfate

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
Stage #1: 2-monochlorophenol With potassium carbonate In acetone for 0.25h;
Stage #2: dimethyl sulfate In acetone for 10h; Reflux;
96%
With sodium hydroxide In water at 90℃; for 0.5h;84.6%
With potassium hydroxide at 100℃;
With sodium hydroxide at 100℃;
With lithium hydroxide In tetrahydrofuran for 1h; Ambient temperature; Yield given;
methoxybenzene
100-66-3

methoxybenzene

A

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

B

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With lithium chloride In N,N-dimethyl acetamide at 30℃; Pt anode, graphite cathode, sintered glass diaphragm, 1.3 V vs. SCE, 965 C;A 95.8%
B 2.8%
With aluminum oxide; sodium chlorite; water; manganese(III) acetylacetonate In dichloromethane at 25℃; for 0.583333h; Product distribution; other solvents, inorganic support materials, times and temperatures, also without H2O;A 85%
B 8%
With chlorine; natural kaolinitic clay In tetrachloromethane for 2h; Heating;A 85%
B 9%
2-monochlorophenol
95-57-8

2-monochlorophenol

methyl iodide
74-88-4

methyl iodide

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With sodium carbonate In dichloromethane at 20℃;95%
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 16h;51%
With sodium hydroxide In N,N-dimethyl acetamide at 25℃; Rate constant;
With potassium carbonate at 130℃;
2-bromoanisole
578-57-4

2-bromoanisole

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With nickel dichloride In N,N-dimethyl-formamide at 170℃; for 0.0833333h; microwave irradiation;94%
With CuCl-alumina In various solvent(s) at 150℃; for 24h;54 % Chromat.
With hydrogenchloride; (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; oxygen In water; acetonitrile at 25℃; for 1.5h; Irradiation;53 %Chromat.
3-chloro-4-methoxybenzyl alcohol
14503-45-8

3-chloro-4-methoxybenzyl alcohol

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With chlorobis(cyclooctene)-iridium(I) dimer; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; lithium chloride In water; 1,3,5-trimethyl-benzene at 170℃; for 18h; Schlenk technique; Inert atmosphere;91%
2-monochlorophenol
95-57-8

2-monochlorophenol

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With layered double hydroxide - supported L-methionine at 180℃; for 6h; Autoclave; chemoselective reaction;90%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 0.0583333h; microwave irradiation;85%
With dimanganese decacarbonyl at 180℃; for 1h;2%
With leucine intercalated Mg-Al layered double hydorxide at 180℃; for 6h; Autoclave; Green chemistry; chemoselective reaction;86 %Chromat.
N-chloro-N-(4-methylphenyl)acetamide
14596-60-2

N-chloro-N-(4-methylphenyl)acetamide

methoxybenzene
100-66-3

methoxybenzene

A

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

B

2-Chloroanisole
766-51-8

2-Chloroanisole

C

N-(2-chloro-4-methylphenyl)acetamide
18931-78-7

N-(2-chloro-4-methylphenyl)acetamide

D

4-Methylacetanilide
103-89-9

4-Methylacetanilide

Conditions
ConditionsYield
at 110℃; for 12h; Mechanism; Orton Haloaniline Rearrangement; Inert atmosphere; Darkness;A 82%
B n/a
C n/a
D 87%
Methyl trichloroacetate
598-99-2

Methyl trichloroacetate

2-monochlorophenol
95-57-8

2-monochlorophenol

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With 18-crown-6 ether; potassium carbonate at 150℃; for 2h;85%
2-methoxy-benzenediazonium; tetrachloro cuprate(II)

2-methoxy-benzenediazonium; tetrachloro cuprate(II)

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
In dimethyl sulfoxide Ambient temperature;84%
carbon dioxide
124-38-9

carbon dioxide

2,3-dichloroanisole
1984-59-4

2,3-dichloroanisole

A

1-chloro-3-methoxy-benzene
2845-89-8

1-chloro-3-methoxy-benzene

B

2-Chloroanisole
766-51-8

2-Chloroanisole

C

2-chloro-6-methoxybenzoic acid
3260-89-7

2-chloro-6-methoxybenzoic acid

D

2-chloro-3-methoxybenzoic acid
33234-36-5

2-chloro-3-methoxybenzoic acid

Conditions
ConditionsYield
With tetrabutylammomium bromide In N,N-dimethyl-formamide at 5℃; electrolysis (I=0.4 A); Yields of byproduct given;A n/a
B n/a
C n/a
D 78%
With tetrabutylammomium bromide In N,N-dimethyl-formamide at 5℃; electrolysis (I=0.4 A); Yields of byproduct given;A n/a
B n/a
C 78%
D n/a
2-monochlorophenol
95-57-8

2-monochlorophenol

phosphorous acid trimethyl ester
121-45-9

phosphorous acid trimethyl ester

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With boron trifluoride In diethyl ether for 0.0416667h; microwave irradiation;76%
2-methoxy-phenol
90-05-1

2-methoxy-phenol

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With P,P-dichlorophenylphosphine oxide; phosphorus pentachloride at 160℃; for 5h;73.3%
With phosphorus pentachloride Destillation des Produktes mit Wasserdampf;
2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

A

2-Chloroanisole
766-51-8

2-Chloroanisole

B

5-chloro-2-methoxyphenyl boronic acid
89694-48-4

5-chloro-2-methoxyphenyl boronic acid

Conditions
ConditionsYield
With 1,3-dichloro-5,5-dimethylhydantoin; sodium methylate In methanol; water; acetonitrile at 60℃;A 18 % Chromat.
B 67%
With 1,3-dichloro-5,5-dimethylhydantoin In water; acetonitrile at 60℃;A 11%
B 84 % Chromat.
2-Nitroanisole
91-23-6

2-Nitroanisole

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With Dichlorophenylphosphine In various solvent(s) at 170℃; for 5h;66%
2-methoxybenzenediazonium o-benzenedisulfonamide

2-methoxybenzenediazonium o-benzenedisulfonamide

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride; copper In acetonitrile at 20℃; for 0.75h; Substitution;62%
methoxybenzene
100-66-3

methoxybenzene

A

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

B

1,3-dichloro-4-methoxybenzene
553-82-2

1,3-dichloro-4-methoxybenzene

C

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With hydrogenchloride; 3-methyl-1-(butyl-4-sulfonyl)imidazolium nitrate In water at 80℃; for 21h; Green chemistry;A 24%
B 60%
C 9%
With N-chloro-succinimide; xenon difluoride at 25℃;A 46%
B 2%
C 7%
With benzyl(trimethyl)ammonium tetrachloroiodate In acetic acid at 70℃; for 24h; Product distribution; different substrates, ratios of BTMA ICl4, solvent, reaction times and temperatures;
2-monochlorophenol
95-57-8

2-monochlorophenol

tetramethlyammonium chloride
75-57-0

tetramethlyammonium chloride

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With potassium carbonate In 1,2-dimethoxyethane at 145℃; for 1h; Microwave irradiation; Inert atmosphere; Sealed vessel;55%
3-chloro-4-methoxyphenylboronic acid
175883-60-0

3-chloro-4-methoxyphenylboronic acid

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I); water In toluene at 90℃; for 1h; Microwave irradiation; Green chemistry;47%
2-methoxy-phenylamine
90-04-0

2-methoxy-phenylamine

A

1-fluoro-2-methoxybenzene
321-28-8

1-fluoro-2-methoxybenzene

B

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With hydrogen fluoride; ammonium chloride; copper(l) chloride; sodium nitrite Product distribution; a.) 20 deg C, 1 h, 2.) irradiation, 20 deg C, 6 h;A 43%
B 20%
2-methoxy-phenylamine
90-04-0

2-methoxy-phenylamine

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With tert.-butylnitrite; N-benzyl-N,N,N-triethylammonium chloride; copper dichloride; 10-camphorsulfonic acid In acetonitrile at 20℃; for 24h; Time; Solvent;33%
1,2-dichlorotetramethylsilane
4342-61-4

1,2-dichlorotetramethylsilane

2-Methoxybenzoyl chloride
21615-34-9

2-Methoxybenzoyl chloride

A

2-Chloroanisole
766-51-8

2-Chloroanisole

B

chloro(2-methoxyphenyl)dimethylsilane
60458-00-6

chloro(2-methoxyphenyl)dimethylsilane

Conditions
ConditionsYield
bis(benzonitrile)palladium(II) dichloride; triphenylphosphine at 145℃; for 15h;A 18%
B 32%
methanol
67-56-1

methanol

sodium 4-chlorophenolate
1193-00-6

sodium 4-chlorophenolate

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With carbon monoxide at 180℃;
2-Nitroanisole
91-23-6

2-Nitroanisole

A

2-Chloroanisole
766-51-8

2-Chloroanisole

B

2,4,6-Trichlorophenol
88-06-2

2,4,6-Trichlorophenol

Conditions
ConditionsYield
With thionyl chloride at 180 - 200℃;
2-monochlorophenol
95-57-8

2-monochlorophenol

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With sodium hydroxide; methyl p-toluene sulfonate
With sodium hydroxide; dimethyl sulfate In sulfuric acid; water195 grams (91.5%)
methanol
67-56-1

methanol

1-chloro-2-fluorobenzene
348-51-6

1-chloro-2-fluorobenzene

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
<(η-C6H6)(η-C5EtMe4)Rh>(2+)*2 In nitromethane at 80℃; for 96h;19 % Chromat.
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In 2,2,2-trifluoroethanol; 1,2-dichloro-ethane at 40℃; for 48h; Irradiation;
2,6-dichloroanisole
1984-65-2

2,6-dichloroanisole

A

2-Chloroanisole
766-51-8

2-Chloroanisole

B

methoxybenzene
100-66-3

methoxybenzene

Conditions
ConditionsYield
With tetrabutylammonium perchlorate In N,N-dimethyl-formamide at 25 - 30℃; Title compound not separated from byproducts;A 7 % Chromat.
B 39 % Chromat.
2,4,6-trichloroanisole
87-40-1

2,4,6-trichloroanisole

A

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

B

1,3-dichloro-4-methoxybenzene
553-82-2

1,3-dichloro-4-methoxybenzene

C

2-Chloroanisole
766-51-8

2-Chloroanisole

D

2,6-dichloroanisole
1984-65-2

2,6-dichloroanisole

Conditions
ConditionsYield
With (C2H5)3NH2CO2; palladium on activated charcoal In acetonitrile at 80℃; Yield given. Further byproducts given. Yields of byproduct given;
2,4,6-trichloroanisole
87-40-1

2,4,6-trichloroanisole

A

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

B

1,3-dichloro-4-methoxybenzene
553-82-2

1,3-dichloro-4-methoxybenzene

C

2-Chloroanisole
766-51-8

2-Chloroanisole

D

methoxybenzene
100-66-3

methoxybenzene

Conditions
ConditionsYield
With tetrabutylammonium perchlorate In N,N-dimethyl-formamide at 25 - 30℃; Title compound not separated from byproducts;A 34 % Chromat.
B 2 % Chromat.
C n/a
D 41 % Chromat.
With tetrabutylammonium perchlorate In N,N-dimethyl-formamide at 25 - 30℃; Product distribution; other chlorinated aromatic ethers;A 34 % Chromat.
B 2 % Chromat.
C 1 % Chromat.
D 41 % Chromat.
sodium acetate
127-09-3

sodium acetate

methoxybenzene
100-66-3

methoxybenzene

A

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

B

2-methoxyphenyl acetate
613-70-7

2-methoxyphenyl acetate

C

4-methoxyphenyl acetate
1200-06-2

4-methoxyphenyl acetate

D

2-Chloroanisole
766-51-8

2-Chloroanisole

Conditions
ConditionsYield
With tungsten(VI) chloride; acetic acid In dichloromethane Ambient temperature; Title compound not separated from byproducts;A 4 % Chromat.
B 13 % Chromat.
C 25 % Chromat.
D 5 % Chromat.
2-Chloroanisole
766-51-8

2-Chloroanisole

4-bromo-2-chloro-1-methoxybenzene
50638-47-6

4-bromo-2-chloro-1-methoxybenzene

Conditions
ConditionsYield
With (CH3)4Br In liquid sulphur dioxide at -23℃; Rate constant;100%
With (CH3)4Br In liquid sulphur dioxide at -23℃;100%
With N-Bromosuccinimide; iodine In acetonitrile for 12h; Darkness;99%
2-Chloroanisole
766-51-8

2-Chloroanisole

acetyl chloride
75-36-5

acetyl chloride

4-acetyl-2-chloroanisole
37612-52-5

4-acetyl-2-chloroanisole

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane at 0℃; for 2h;100%
With nitrogen; aluminium trichloride In chloroform76%
With aluminum (III) chloride In chloroform at 0 - 20℃; for 17.42h;76%
With aluminium trichloride for 4h; heating;52%
With aluminium trichloride
2-Chloroanisole
766-51-8

2-Chloroanisole

phenylboronic acid
98-80-6

phenylboronic acid

2-methoxy-1,1'-biphenyl
86-26-0

2-methoxy-1,1'-biphenyl

Conditions
ConditionsYield
With potassium phosphate; N,N-diisopropyl 2-dicyclohexylphosphino-4-phenylbenzamide; tris(dibenzylideneacetone)dipalladium (0) In toluene at 110℃; for 1.33333h; Suzuki cross-coupling reaction;100%
With (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); triethylamine In water at 50℃; for 6h; Suzuki-Miyaura reaction; Inert atmosphere; Micellar solution;100%
With C34H41Cl2N3OPd; potassium tert-butylate In water; isopropyl alcohol at 80℃; for 15h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;99%
2-Chloroanisole
766-51-8

2-Chloroanisole

benzaldehyde
100-52-7

benzaldehyde

2-methoxyphenyl(phenyl)methanol
22788-49-4

2-methoxyphenyl(phenyl)methanol

Conditions
ConditionsYield
Stage #1: 2-Chloroanisole With iodine; magnesium In tetrahydrofuran at 150℃; for 1h; Inert atmosphere; Microwave irradiation;
Stage #2: benzaldehyde In tetrahydrofuran at 100℃; for 0.5h; Microwave irradiation;
100%
Stage #1: 2-Chloroanisole With iodine; magnesium In tetrahydrofuran at 150℃; for 1h; microwave irradiation;
Stage #2: benzaldehyde In tetrahydrofuran at 100℃; for 0.5h; Grignard reaction; microwave irradiation;
99%
2-Chloroanisole
766-51-8

2-Chloroanisole

(4bS,5R,9bS,10R)-4b,5,9b,10-Tetrahydro-indeno[2,1-a]indene-5,10-diol

(4bS,5R,9bS,10R)-4b,5,9b,10-Tetrahydro-indeno[2,1-a]indene-5,10-diol

C30H24Cl2O2

C30H24Cl2O2

Conditions
ConditionsYield
With iron(III) chloride at 50℃; for 18h; Inert atmosphere; regioselective reaction;100%
2-Chloroanisole
766-51-8

2-Chloroanisole

p-toluidine
106-49-0

p-toluidine

N-benzyl-2-methoxyaniline
50798-94-2

N-benzyl-2-methoxyaniline

Conditions
ConditionsYield
With johnphos; sodium t-butanolate; palladium diacetate In toluene at 20℃; for 14h; Arylation;99%
2-Chloroanisole
766-51-8

2-Chloroanisole

benzylamine
100-46-9

benzylamine

N-benzyl-2-methoxyaniline
50798-94-2

N-benzyl-2-methoxyaniline

Conditions
ConditionsYield
With johnphos; sodium t-butanolate; palladium diacetate In toluene at 20℃; for 14h; Substitution; Amination;99%
With [Pd(2-aminobiphenyl)(PCyp2ArXyl2)](OMs); sodium t-butanolate In 1,4-dioxane at 100℃; for 19h; Inert atmosphere; Schlenk technique;99%
With 2,6-di-tert-butyl-4-methyl-phenol; [1,3-bis(2,6-diisopentylphenyl)-4,5-dichloroimidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride; sodium hydride In toluene at 60℃; for 16h; Inert atmosphere; Schlenk technique;98%
2-Chloroanisole
766-51-8

2-Chloroanisole

2-Methylphenylboronic acid
16419-60-6

2-Methylphenylboronic acid

2-methoxy-2'-methyl-1,1'-biphenyl
19853-12-4

2-methoxy-2'-methyl-1,1'-biphenyl

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium fluoride; C58H47P In tetrahydrofuran for 13h; Suzuki-Miyaura coupling; Inert atmosphere; Reflux;99%
With potassium phosphate; C28H31ClN2Ni; triphenylphosphine In tert-Amyl alcohol; toluene at 110℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;98%
With potassium tert-butylate; C61H90Cl4N6Pd2 In ethanol at 27℃; for 0.5h; Suzuki-Miyaura Coupling; Sealed tube;98%
2-Chloroanisole
766-51-8

2-Chloroanisole

N,N-bis(2-methoxyphenyl)amine
7287-75-4

N,N-bis(2-methoxyphenyl)amine

Conditions
ConditionsYield
With lithium amide; tris(dibenzylideneacetone)dipalladium (0); johnphos; sodium t-butanolate In toluene at 80℃; for 19h;99%
2-Chloroanisole
766-51-8

2-Chloroanisole

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

pinacol 2-anisylboronate
190788-60-4

pinacol 2-anisylboronate

Conditions
ConditionsYield
With sodium acetate; bis(dibenzylideneacetone)-palladium(0); XPhos for 12h; Miyaura Borylation Reaction; Heating;99%
With potassium 2,2,2-trifluoroethoxide; dichlorobis(trimethylphosphine)nickel In tetrahydrofuran at 100℃; for 12h; Inert atmosphere; Sealed tube;76%
With potassium acetate; bis(dibenzylideneacetone)-palladium(0); tricyclohexylphosphine In 1,4-dioxane at 80℃; for 48h;70 % Chromat.
2-Chloroanisole
766-51-8

2-Chloroanisole

diphenylamine
122-39-4

diphenylamine

N-(2-methoxyphenyl)diphenylamine
20441-01-4

N-(2-methoxyphenyl)diphenylamine

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Green chemistry;99%
With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 100℃; for 5h;95%
2-Chloroanisole
766-51-8

2-Chloroanisole

acetophenone
98-86-2

acetophenone

2-(2-methoxyphenyl)-1-phenylethan-1-one
27356-33-8

2-(2-methoxyphenyl)-1-phenylethan-1-one

Conditions
ConditionsYield
With C41H50ClN3Pd; sodium t-butanolate In 1,4-dioxane at 100℃; for 4h;99%
With C41H46Cl2FeN4Pd; potassium tert-butylate In 1,4-dioxane at 100℃; for 3h; Inert atmosphere;95%
With N-heterocyclic carbene-palladacycle; sodium t-butanolate In tetrahydrofuran at 70℃; for 3h;85%
2-Chloroanisole
766-51-8

2-Chloroanisole

1-phenyl-propan-1-one
93-55-0

1-phenyl-propan-1-one

2-(2-methoxy-phenyl)-1-phenyl-propan-1-one

2-(2-methoxy-phenyl)-1-phenyl-propan-1-one

Conditions
ConditionsYield
With C40H44ClN3Pd; sodium t-butanolate In toluene at 80℃; for 3h; Inert atmosphere;99%
With N-heterocyclic carbene-palladacycle; sodium t-butanolate In tetrahydrofuran at 70℃; for 3h;98%
With sodium t-butanolate; (N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)Pd(OAc)2 In 1,4-dioxane at 60℃; for 1h;94%
morpholine
110-91-8

morpholine

2-Chloroanisole
766-51-8

2-Chloroanisole

N-(2-methoxyphenyl)morpholine
27347-13-3

N-(2-methoxyphenyl)morpholine

Conditions
ConditionsYield
With 5-(di-tert-butylphosphino)-1′, 3′, 5′-triphenyl-1′H-[1,4′]bipyrazole; potassium hydroxide; tris(dibenzylideneacetone)dipalladium (0) In tert-Amyl alcohol; water at 90℃; for 5h;99%
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry;99%
With C28H29Cl2N3OPd; potassium tert-butylate In toluene at 110℃; for 15h; Buchwald-Hartwig Coupling; Schlenk technique; Inert atmosphere;99%
2-Chloroanisole
766-51-8

2-Chloroanisole

2,6-dimethylaniline
87-62-7

2,6-dimethylaniline

N-(2,6-dimethylphenyl)-2-methoxyaniline
58656-24-9

N-(2,6-dimethylphenyl)-2-methoxyaniline

Conditions
ConditionsYield
With 5-(di-tert-butylphosphino)-1′, 3′, 5′-triphenyl-1′H-[1,4′]bipyrazole; potassium hydroxide; tris(dibenzylideneacetone)dipalladium (0) In tert-Amyl alcohol; water at 90℃; for 5h;99%
With potassium tert-butylate In 1,4-dioxane at 110℃; for 3h;99%
Stage #1: 2-Chloroanisole With PdCl(cinnamyl)(N,N′-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene); potassium 2-methylbutan-2-olate In neat (no solvent) at 25℃; for 0.0833333h; Buchwald-Hartwig Coupling;
Stage #2: 2,6-dimethylaniline In neat (no solvent) at 25℃; for 24h; Buchwald-Hartwig Coupling;
94%
2-Chloroanisole
766-51-8

2-Chloroanisole

cyclohexylamine
108-91-8

cyclohexylamine

N-(cyclohexylamino)-o-anisidine

N-(cyclohexylamino)-o-anisidine

Conditions
ConditionsYield
With (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl di-t-butylphosphine; sodium t-butanolate; palladium diacetate In 1,2-dimethoxyethane at 100℃; for 36h;99%
With C63H54Cl3N3OPd; potassium 2-methylbutan-2-olate In 1,4-dioxane at 100℃; for 2h; Buchwald-Hartwig Coupling;92%
With potassium tert-butylate In 1,4-dioxane at 110℃; for 3h;72%
2-Chloroanisole
766-51-8

2-Chloroanisole

rac-methylbenzylamine
618-36-0

rac-methylbenzylamine

N-(2-methoxy-phenyl)-1-phenyl-ethylamine

N-(2-methoxy-phenyl)-1-phenyl-ethylamine

Conditions
ConditionsYield
With 5-(di-tert-butylphosphino)-1′, 3′, 5′-triphenyl-1′H-[1,4′]bipyrazole; potassium hydroxide; tris(dibenzylideneacetone)dipalladium (0) In tert-Amyl alcohol; water at 90℃; for 5h;99%
2-Chloroanisole
766-51-8

2-Chloroanisole

aniline
62-53-3

aniline

2-methoxy-N-phenylaniline
1207-92-7

2-methoxy-N-phenylaniline

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane at 110℃; for 3h;99%
With C16H34ClPPd; sodium t-butanolate In toluene at 100℃; Buchwald-Hartwig amination; Inert atmosphere;96%
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry;95%
2-Chloroanisole
766-51-8

2-Chloroanisole

2,5-Dimethylaniline
95-78-3

2,5-Dimethylaniline

N-(2-methoxyphenyl)-2,5-dimethylaniline

N-(2-methoxyphenyl)-2,5-dimethylaniline

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane at 110℃; for 3h;99%
With (SIPr)PdCl2(TEA); potassium tert-butylate In 1,2-dimethoxyethane at 50℃; for 4.5h; Buchwald-Hartwig cross coupling; Inert atmosphere;92%
With C37H44ClN2O3PPd; potassium hydroxide; tert-butyl alcohol In water at 100℃; for 12h; Buchwald-Hartwig Coupling; Schlenk technique; Inert atmosphere;90%
2-Chloroanisole
766-51-8

2-Chloroanisole

N-methylaniline
100-61-8

N-methylaniline

(2-methoxyphenyl)methylphenylamine

(2-methoxyphenyl)methylphenylamine

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Green chemistry;99%
With C16H34ClPPd; sodium t-butanolate In toluene at 100℃; Buchwald-Hartwig amination; Inert atmosphere;97%
With C37H44ClN2O3PPd; potassium hydroxide; tert-butyl alcohol In water at 100℃; for 12h; Buchwald-Hartwig Coupling; Schlenk technique; Inert atmosphere;92%
para-bromotoluene
106-38-7

para-bromotoluene

2-Chloroanisole
766-51-8

2-Chloroanisole

2-methoxy-4'-methylbiphenyl
92495-53-9

2-methoxy-4'-methylbiphenyl

Conditions
ConditionsYield
Stage #1: para-bromotoluene With lithium
Stage #2: With zinc(II) chloride
Stage #3: 2-Chloroanisole; nickel phosphine amido pincer complex In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 70℃; for 12h; Negishi cross-coupling; Further stages.;
99%
ortho-tolylmagnesium bromide
932-31-0

ortho-tolylmagnesium bromide

2-Chloroanisole
766-51-8

2-Chloroanisole

2-methoxy-2'-methyl-1,1'-biphenyl
19853-12-4

2-methoxy-2'-methyl-1,1'-biphenyl

Conditions
ConditionsYield
With iron(II) triflate; sodium t-butanolate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In tetrahydrofuran at 60℃; for 16h; Glovebox; Sealed tube; Inert atmosphere;99%
Stage #1: 2-Chloroanisole With Ni(PPh3)(1,3-di-tert-butylimidazol-2-ylidene)Br2 In tetrahydrofuran at 0℃; for 0.0333333h; Inert atmosphere; Schlenk technique;
Stage #2: ortho-tolylmagnesium bromide In tetrahydrofuran at 60℃; for 4h; Inert atmosphere; Schlenk technique;
98%
With C46H55ClFeN3Pd; lithium chloride In tetrahydrofuran at 60℃; for 24h; Kumada coupling reaction; Inert atmosphere;95%
acetamide
60-35-5

acetamide

2-Chloroanisole
766-51-8

2-Chloroanisole

2-methoxyacetanilide
93-26-5

2-methoxyacetanilide

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In tert-butyl alcohol at 110℃; for 7h;99%
With potassium phosphate; t-BuBrettPhos; water; palladium diacetate In tert-butyl alcohol at 110℃; for 3h; Inert atmosphere;91%
2-Chloroanisole
766-51-8

2-Chloroanisole

2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

2,2'-Dimethoxybiphenyl
4877-93-4

2,2'-Dimethoxybiphenyl

Conditions
ConditionsYield
With potassium phosphate; C50H63Cl2N3Pd In ethanol at 80℃; for 4h; Suzuki-Miyaura Coupling;99%
Stage #1: 2-Methoxyphenylboronic acid With potassium phosphate; N,N-diisopropyl 2-dicyclohexylphosphino-5-(3'-nitrophenyl)benzamide; palladium diacetate In tetrahydrofuran at 23℃; for 0.0166667h; Suzuki-Miyaura cross-coupling; Inert atmosphere;
Stage #2: 2-Chloroanisole In tetrahydrofuran at 23℃; for 36h; Suzuki-Miyaura cross-coupling; Inert atmosphere;
78%
With palladium diacetate; caesium carbonate; P-phenyl-2,2,6,6-tetramethyl-phosphorinan-4-ol In toluene at 110℃; for 48h; Suzuki-Miyaura cross coupling; Inert atmosphere;70%
tert-butyl carbamate
4248-19-5

tert-butyl carbamate

2-Chloroanisole
766-51-8

2-Chloroanisole

tert-butyl 2-methoxyphenylcarbamate
154150-18-2

tert-butyl 2-methoxyphenylcarbamate

Conditions
ConditionsYield
With 4-diphenylphosphino-13-dicyclohexylphosphino-[2.2]paracyclophane; water; palladium diacetate; caesium carbonate In 1,4-dioxane at 125℃; for 24h; Buchwald-Hartwig coupling;99%
With di-tert-butyl{2′-isopropoxy-[1,1′-binaphthalen]-2-yl}phosphane; caesium carbonate; bis(dibenzylideneacetone)-palladium(0) In tert-butyl alcohol at 100℃; for 20h; Inert atmosphere;40%
With palladium diacetate; caesium carbonate; XPhos In 1,4-dioxane at 100℃; for 24h;10 %Chromat.
2-Chloroanisole
766-51-8

2-Chloroanisole

cyclopropylboronic acid
411235-57-9

cyclopropylboronic acid

1-cyclopropyl-2-methoxybenzene
10292-66-7

1-cyclopropyl-2-methoxybenzene

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); rac-3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole In toluene at 100℃; for 24h; Suzuki coupling; Inert atmosphere;99%
2-Fluoroaniline
348-54-9

2-Fluoroaniline

2-Chloroanisole
766-51-8

2-Chloroanisole

2-fluoro-N-(2-methoxyphenyl)aniline
1514859-18-7

2-fluoro-N-(2-methoxyphenyl)aniline

Conditions
ConditionsYield
With Pd-PEPPSI-(2,6-(3-pentyl)pentylphenyl-2H-imidazol-2-ylidene)Cl-o-picoline; caesium carbonate In 1,2-dimethoxyethane at 24℃; for 24h; Buchwald-Hartwig Coupling; Inert atmosphere; Glovebox;99%
With [IPr*·H][Pd(η3-cin)Cl2]; potassium tert-butylate at 60 - 80℃; for 2h; Buchwald-Hartwig Coupling; Sealed tube;80%
2-methyl-9H-fluorene
1430-97-3

2-methyl-9H-fluorene

2-Chloroanisole
766-51-8

2-Chloroanisole

C21H18O

C21H18O

Conditions
ConditionsYield
With NHC-Pd(II)-Im; potassium tert-butylate In 1,4-dioxane at 120℃; for 12h; Inert atmosphere; Schlenk technique;99%
2-Chloroanisole
766-51-8

2-Chloroanisole

phenylpropyolic acid
637-44-5

phenylpropyolic acid

2-phenylethynylanisole
41398-67-8

2-phenylethynylanisole

Conditions
ConditionsYield
With bis[dicyclohexyl(2,4,6-triisopropyl-[1,1':3',1''-terphenyl]-2-yl)phosphane]palladium(II) dichloride; caesium carbonate In tetrahydrofuran at 80℃; for 1.5h; Temperature; Solvent; Reagent/catalyst;99%
With (R)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; palladium diacetate; caesium carbonate In dimethyl sulfoxide at 130℃; for 12h;33%
2-Chloroanisole
766-51-8

2-Chloroanisole

benzoyl chloride
98-88-4

benzoyl chloride

(3-chloro-4-methoxyphenyl)(phenyl)methanone
10547-61-2

(3-chloro-4-methoxyphenyl)(phenyl)methanone

Conditions
ConditionsYield
With copper(II) ferrite In 1,2-dichloro-ethane at 35 - 38℃; for 18h; Friedel-Crafts Acylation;98%
With aluminum (III) chloride In dichloromethane at 0℃; for 3h; Inert atmosphere;82%
With aluminium trichloride81%
With aluminium trichloride; 1,1,2,2-tetrachloroethane at 120 - 130℃;
With carbon disulfide; aluminium trichloride at 0℃;

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