As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch
Cas:766-51-8
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:766-51-8
Min.Order:0 Metric Ton
Negotiable
Type:Manufacturers
inquiryColorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car
Cas:766-51-8
Min.Order:1 Metric Ton
FOB Price: $1.0 / 2.0
Type:Trading Company
inquiryTIANFUCHEM--766-51-8--2-Chloroanisole factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relatio
Cas:766-51-8
Min.Order:1 Metric Ton
FOB Price: $2000.0
Type:Lab/Research institutions
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:766-51-8
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryProduct name:2-Chloroanisole CAS No:766-51-8 Appearance: Pale yellow liquid Content:99% Appearance:Pale yellow liquid Storage:Preserve in well-closed, light-resistant and airtight conta
1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:766-51-8
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s
Cas:766-51-8
Min.Order:1 Kilogram
FOB Price: $30.0 / 50.0
Type:Lab/Research institutions
inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Appearance:white or yellowish white flaky crystal Storage:Keep the sun from direct sunlight ;prevention against high temperature Package:As customer request Application:Used for research and industrial manufacture. Transportatio
Cas:766-51-8
Min.Order:100 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:766-51-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquirySuperior quality, moderate price & quick delivery. Appearance:clear light yellow liquid Storage:In Room Temperature Package:25kg/drum, or as per your request. Application:For medicine , pesticide intermediates Transportation:as per your request
2-Chloroanisole Chemical Properties Melting point -26.8°C Boiling point 195-196 °C (lit.) density 1.123 g/mL at 25 °C (lit.) refractive index n20/D 1.545(lit.) Fp 169 °F storage temp. 2-8°C form Liquid
Cas:766-51-8
Min.Order:200 Kilogram
FOB Price: $65.0
Type:Lab/Research institutions
inquiryAppearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe
High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use
Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti
Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai
Cas:766-51-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryR & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou
high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier
Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp
2-ChloroanisoleAppearance:powder Storage:Refrigerator Package:Depended Application:766-51-8 Transportation:by air or by sea
We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate
Conditions | Yield |
---|---|
With N-chloro-succinimide; copper(l) chloride In acetonitrile at 80℃; for 18h; | 97% |
With N-chloro-succinimide In acetonitrile at 80℃; for 24h; | 90% |
Conditions | Yield |
---|---|
Stage #1: 2-monochlorophenol With potassium carbonate In acetone for 0.25h; Stage #2: dimethyl sulfate In acetone for 10h; Reflux; | 96% |
With sodium hydroxide In water at 90℃; for 0.5h; | 84.6% |
With potassium hydroxide at 100℃; | |
With sodium hydroxide at 100℃; | |
With lithium hydroxide In tetrahydrofuran for 1h; Ambient temperature; Yield given; |
Conditions | Yield |
---|---|
With lithium chloride In N,N-dimethyl acetamide at 30℃; Pt anode, graphite cathode, sintered glass diaphragm, 1.3 V vs. SCE, 965 C; | A 95.8% B 2.8% |
With aluminum oxide; sodium chlorite; water; manganese(III) acetylacetonate In dichloromethane at 25℃; for 0.583333h; Product distribution; other solvents, inorganic support materials, times and temperatures, also without H2O; | A 85% B 8% |
With chlorine; natural kaolinitic clay In tetrachloromethane for 2h; Heating; | A 85% B 9% |
Conditions | Yield |
---|---|
With sodium carbonate In dichloromethane at 20℃; | 95% |
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 16h; | 51% |
With sodium hydroxide In N,N-dimethyl acetamide at 25℃; Rate constant; | |
With potassium carbonate at 130℃; |
Conditions | Yield |
---|---|
With nickel dichloride In N,N-dimethyl-formamide at 170℃; for 0.0833333h; microwave irradiation; | 94% |
With CuCl-alumina In various solvent(s) at 150℃; for 24h; | 54 % Chromat. |
With hydrogenchloride; (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; oxygen In water; acetonitrile at 25℃; for 1.5h; Irradiation; | 53 %Chromat. |
3-chloro-4-methoxybenzyl alcohol
2-Chloroanisole
Conditions | Yield |
---|---|
With chlorobis(cyclooctene)-iridium(I) dimer; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; lithium chloride In water; 1,3,5-trimethyl-benzene at 170℃; for 18h; Schlenk technique; Inert atmosphere; | 91% |
Conditions | Yield |
---|---|
With layered double hydroxide - supported L-methionine at 180℃; for 6h; Autoclave; chemoselective reaction; | 90% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 0.0583333h; microwave irradiation; | 85% |
With dimanganese decacarbonyl at 180℃; for 1h; | 2% |
With leucine intercalated Mg-Al layered double hydorxide at 180℃; for 6h; Autoclave; Green chemistry; chemoselective reaction; | 86 %Chromat. |
N-chloro-N-(4-methylphenyl)acetamide
methoxybenzene
A
4-chloromethoxybenzene
B
2-Chloroanisole
C
N-(2-chloro-4-methylphenyl)acetamide
D
4-Methylacetanilide
Conditions | Yield |
---|---|
at 110℃; for 12h; Mechanism; Orton Haloaniline Rearrangement; Inert atmosphere; Darkness; | A 82% B n/a C n/a D 87% |
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium carbonate at 150℃; for 2h; | 85% |
2-Chloroanisole
Conditions | Yield |
---|---|
In dimethyl sulfoxide Ambient temperature; | 84% |
carbon dioxide
2,3-dichloroanisole
A
1-chloro-3-methoxy-benzene
B
2-Chloroanisole
C
2-chloro-6-methoxybenzoic acid
D
2-chloro-3-methoxybenzoic acid
Conditions | Yield |
---|---|
With tetrabutylammomium bromide In N,N-dimethyl-formamide at 5℃; electrolysis (I=0.4 A); Yields of byproduct given; | A n/a B n/a C n/a D 78% |
With tetrabutylammomium bromide In N,N-dimethyl-formamide at 5℃; electrolysis (I=0.4 A); Yields of byproduct given; | A n/a B n/a C 78% D n/a |
Conditions | Yield |
---|---|
With boron trifluoride In diethyl ether for 0.0416667h; microwave irradiation; | 76% |
Conditions | Yield |
---|---|
With P,P-dichlorophenylphosphine oxide; phosphorus pentachloride at 160℃; for 5h; | 73.3% |
With phosphorus pentachloride Destillation des Produktes mit Wasserdampf; |
2-Methoxyphenylboronic acid
A
2-Chloroanisole
B
5-chloro-2-methoxyphenyl boronic acid
Conditions | Yield |
---|---|
With 1,3-dichloro-5,5-dimethylhydantoin; sodium methylate In methanol; water; acetonitrile at 60℃; | A 18 % Chromat. B 67% |
With 1,3-dichloro-5,5-dimethylhydantoin In water; acetonitrile at 60℃; | A 11% B 84 % Chromat. |
Conditions | Yield |
---|---|
With Dichlorophenylphosphine In various solvent(s) at 170℃; for 5h; | 66% |
2-Chloroanisole
Conditions | Yield |
---|---|
With N-benzyl-N,N,N-triethylammonium chloride; copper In acetonitrile at 20℃; for 0.75h; Substitution; | 62% |
methoxybenzene
A
4-chloromethoxybenzene
B
1,3-dichloro-4-methoxybenzene
C
2-Chloroanisole
Conditions | Yield |
---|---|
With hydrogenchloride; 3-methyl-1-(butyl-4-sulfonyl)imidazolium nitrate In water at 80℃; for 21h; Green chemistry; | A 24% B 60% C 9% |
With N-chloro-succinimide; xenon difluoride at 25℃; | A 46% B 2% C 7% |
With benzyl(trimethyl)ammonium tetrachloroiodate In acetic acid at 70℃; for 24h; Product distribution; different substrates, ratios of BTMA ICl4, solvent, reaction times and temperatures; |
Conditions | Yield |
---|---|
With potassium carbonate In 1,2-dimethoxyethane at 145℃; for 1h; Microwave irradiation; Inert atmosphere; Sealed vessel; | 55% |
3-chloro-4-methoxyphenylboronic acid
2-Chloroanisole
Conditions | Yield |
---|---|
With [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I); water In toluene at 90℃; for 1h; Microwave irradiation; Green chemistry; | 47% |
Conditions | Yield |
---|---|
With hydrogen fluoride; ammonium chloride; copper(l) chloride; sodium nitrite Product distribution; a.) 20 deg C, 1 h, 2.) irradiation, 20 deg C, 6 h; | A 43% B 20% |
Conditions | Yield |
---|---|
With tert.-butylnitrite; N-benzyl-N,N,N-triethylammonium chloride; copper dichloride; 10-camphorsulfonic acid In acetonitrile at 20℃; for 24h; Time; Solvent; | 33% |
1,2-dichlorotetramethylsilane
2-Methoxybenzoyl chloride
A
2-Chloroanisole
B
chloro(2-methoxyphenyl)dimethylsilane
Conditions | Yield |
---|---|
bis(benzonitrile)palladium(II) dichloride; triphenylphosphine at 145℃; for 15h; | A 18% B 32% |
Conditions | Yield |
---|---|
With carbon monoxide at 180℃; |
Conditions | Yield |
---|---|
With thionyl chloride at 180 - 200℃; |
Conditions | Yield |
---|---|
With sodium hydroxide; methyl p-toluene sulfonate | |
With sodium hydroxide; dimethyl sulfate In sulfuric acid; water | 195 grams (91.5%) |
Conditions | Yield |
---|---|
<(η-C6H6)(η-C5EtMe4)Rh>(2+)*2 In nitromethane at 80℃; for 96h; | 19 % Chromat. |
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In 2,2,2-trifluoroethanol; 1,2-dichloro-ethane at 40℃; for 48h; Irradiation; |
Conditions | Yield |
---|---|
With tetrabutylammonium perchlorate In N,N-dimethyl-formamide at 25 - 30℃; Title compound not separated from byproducts; | A 7 % Chromat. B 39 % Chromat. |
2,4,6-trichloroanisole
A
4-chloromethoxybenzene
B
1,3-dichloro-4-methoxybenzene
C
2-Chloroanisole
D
2,6-dichloroanisole
Conditions | Yield |
---|---|
With (C2H5)3NH2CO2; palladium on activated charcoal In acetonitrile at 80℃; Yield given. Further byproducts given. Yields of byproduct given; |
2,4,6-trichloroanisole
A
4-chloromethoxybenzene
B
1,3-dichloro-4-methoxybenzene
C
2-Chloroanisole
D
methoxybenzene
Conditions | Yield |
---|---|
With tetrabutylammonium perchlorate In N,N-dimethyl-formamide at 25 - 30℃; Title compound not separated from byproducts; | A 34 % Chromat. B 2 % Chromat. C n/a D 41 % Chromat. |
With tetrabutylammonium perchlorate In N,N-dimethyl-formamide at 25 - 30℃; Product distribution; other chlorinated aromatic ethers; | A 34 % Chromat. B 2 % Chromat. C 1 % Chromat. D 41 % Chromat. |
sodium acetate
methoxybenzene
A
4-chloromethoxybenzene
B
2-methoxyphenyl acetate
C
4-methoxyphenyl acetate
D
2-Chloroanisole
Conditions | Yield |
---|---|
With tungsten(VI) chloride; acetic acid In dichloromethane Ambient temperature; Title compound not separated from byproducts; | A 4 % Chromat. B 13 % Chromat. C 25 % Chromat. D 5 % Chromat. |
2-Chloroanisole
4-bromo-2-chloro-1-methoxybenzene
Conditions | Yield |
---|---|
With (CH3)4Br In liquid sulphur dioxide at -23℃; Rate constant; | 100% |
With (CH3)4Br In liquid sulphur dioxide at -23℃; | 100% |
With N-Bromosuccinimide; iodine In acetonitrile for 12h; Darkness; | 99% |
Conditions | Yield |
---|---|
With aluminium trichloride In dichloromethane at 0℃; for 2h; | 100% |
With nitrogen; aluminium trichloride In chloroform | 76% |
With aluminum (III) chloride In chloroform at 0 - 20℃; for 17.42h; | 76% |
With aluminium trichloride for 4h; heating; | 52% |
With aluminium trichloride |
Conditions | Yield |
---|---|
With potassium phosphate; N,N-diisopropyl 2-dicyclohexylphosphino-4-phenylbenzamide; tris(dibenzylideneacetone)dipalladium (0) In toluene at 110℃; for 1.33333h; Suzuki cross-coupling reaction; | 100% |
With (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); triethylamine In water at 50℃; for 6h; Suzuki-Miyaura reaction; Inert atmosphere; Micellar solution; | 100% |
With C34H41Cl2N3OPd; potassium tert-butylate In water; isopropyl alcohol at 80℃; for 15h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
Stage #1: 2-Chloroanisole With iodine; magnesium In tetrahydrofuran at 150℃; for 1h; Inert atmosphere; Microwave irradiation; Stage #2: benzaldehyde In tetrahydrofuran at 100℃; for 0.5h; Microwave irradiation; | 100% |
Stage #1: 2-Chloroanisole With iodine; magnesium In tetrahydrofuran at 150℃; for 1h; microwave irradiation; Stage #2: benzaldehyde In tetrahydrofuran at 100℃; for 0.5h; Grignard reaction; microwave irradiation; | 99% |
2-Chloroanisole
Conditions | Yield |
---|---|
With iron(III) chloride at 50℃; for 18h; Inert atmosphere; regioselective reaction; | 100% |
Conditions | Yield |
---|---|
With johnphos; sodium t-butanolate; palladium diacetate In toluene at 20℃; for 14h; Arylation; | 99% |
Conditions | Yield |
---|---|
With johnphos; sodium t-butanolate; palladium diacetate In toluene at 20℃; for 14h; Substitution; Amination; | 99% |
With [Pd(2-aminobiphenyl)(PCyp2ArXyl2)](OMs); sodium t-butanolate In 1,4-dioxane at 100℃; for 19h; Inert atmosphere; Schlenk technique; | 99% |
With 2,6-di-tert-butyl-4-methyl-phenol; [1,3-bis(2,6-diisopentylphenyl)-4,5-dichloroimidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride; sodium hydride In toluene at 60℃; for 16h; Inert atmosphere; Schlenk technique; | 98% |
2-Chloroanisole
2-Methylphenylboronic acid
2-methoxy-2'-methyl-1,1'-biphenyl
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium fluoride; C58H47P In tetrahydrofuran for 13h; Suzuki-Miyaura coupling; Inert atmosphere; Reflux; | 99% |
With potassium phosphate; C28H31ClN2Ni; triphenylphosphine In tert-Amyl alcohol; toluene at 110℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube; | 98% |
With potassium tert-butylate; C61H90Cl4N6Pd2 In ethanol at 27℃; for 0.5h; Suzuki-Miyaura Coupling; Sealed tube; | 98% |
Conditions | Yield |
---|---|
With lithium amide; tris(dibenzylideneacetone)dipalladium (0); johnphos; sodium t-butanolate In toluene at 80℃; for 19h; | 99% |
Conditions | Yield |
---|---|
With sodium acetate; bis(dibenzylideneacetone)-palladium(0); XPhos for 12h; Miyaura Borylation Reaction; Heating; | 99% |
With potassium 2,2,2-trifluoroethoxide; dichlorobis(trimethylphosphine)nickel In tetrahydrofuran at 100℃; for 12h; Inert atmosphere; Sealed tube; | 76% |
With potassium acetate; bis(dibenzylideneacetone)-palladium(0); tricyclohexylphosphine In 1,4-dioxane at 80℃; for 48h; | 70 % Chromat. |
Conditions | Yield |
---|---|
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Green chemistry; | 99% |
With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 100℃; for 5h; | 95% |
Conditions | Yield |
---|---|
With C41H50ClN3Pd; sodium t-butanolate In 1,4-dioxane at 100℃; for 4h; | 99% |
With C41H46Cl2FeN4Pd; potassium tert-butylate In 1,4-dioxane at 100℃; for 3h; Inert atmosphere; | 95% |
With N-heterocyclic carbene-palladacycle; sodium t-butanolate In tetrahydrofuran at 70℃; for 3h; | 85% |
Conditions | Yield |
---|---|
With C40H44ClN3Pd; sodium t-butanolate In toluene at 80℃; for 3h; Inert atmosphere; | 99% |
With N-heterocyclic carbene-palladacycle; sodium t-butanolate In tetrahydrofuran at 70℃; for 3h; | 98% |
With sodium t-butanolate; (N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)Pd(OAc)2 In 1,4-dioxane at 60℃; for 1h; | 94% |
Conditions | Yield |
---|---|
With 5-(di-tert-butylphosphino)-1′, 3′, 5′-triphenyl-1′H-[1,4′]bipyrazole; potassium hydroxide; tris(dibenzylideneacetone)dipalladium (0) In tert-Amyl alcohol; water at 90℃; for 5h; | 99% |
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry; | 99% |
With C28H29Cl2N3OPd; potassium tert-butylate In toluene at 110℃; for 15h; Buchwald-Hartwig Coupling; Schlenk technique; Inert atmosphere; | 99% |
2-Chloroanisole
2,6-dimethylaniline
N-(2,6-dimethylphenyl)-2-methoxyaniline
Conditions | Yield |
---|---|
With 5-(di-tert-butylphosphino)-1′, 3′, 5′-triphenyl-1′H-[1,4′]bipyrazole; potassium hydroxide; tris(dibenzylideneacetone)dipalladium (0) In tert-Amyl alcohol; water at 90℃; for 5h; | 99% |
With potassium tert-butylate In 1,4-dioxane at 110℃; for 3h; | 99% |
Stage #1: 2-Chloroanisole With PdCl(cinnamyl)(N,N′-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene); potassium 2-methylbutan-2-olate In neat (no solvent) at 25℃; for 0.0833333h; Buchwald-Hartwig Coupling; Stage #2: 2,6-dimethylaniline In neat (no solvent) at 25℃; for 24h; Buchwald-Hartwig Coupling; | 94% |
Conditions | Yield |
---|---|
With (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl di-t-butylphosphine; sodium t-butanolate; palladium diacetate In 1,2-dimethoxyethane at 100℃; for 36h; | 99% |
With C63H54Cl3N3OPd; potassium 2-methylbutan-2-olate In 1,4-dioxane at 100℃; for 2h; Buchwald-Hartwig Coupling; | 92% |
With potassium tert-butylate In 1,4-dioxane at 110℃; for 3h; | 72% |
Conditions | Yield |
---|---|
With 5-(di-tert-butylphosphino)-1′, 3′, 5′-triphenyl-1′H-[1,4′]bipyrazole; potassium hydroxide; tris(dibenzylideneacetone)dipalladium (0) In tert-Amyl alcohol; water at 90℃; for 5h; | 99% |
Conditions | Yield |
---|---|
With potassium tert-butylate In 1,4-dioxane at 110℃; for 3h; | 99% |
With C16H34ClPPd; sodium t-butanolate In toluene at 100℃; Buchwald-Hartwig amination; Inert atmosphere; | 96% |
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry; | 95% |
Conditions | Yield |
---|---|
With potassium tert-butylate In 1,4-dioxane at 110℃; for 3h; | 99% |
With (SIPr)PdCl2(TEA); potassium tert-butylate In 1,2-dimethoxyethane at 50℃; for 4.5h; Buchwald-Hartwig cross coupling; Inert atmosphere; | 92% |
With C37H44ClN2O3PPd; potassium hydroxide; tert-butyl alcohol In water at 100℃; for 12h; Buchwald-Hartwig Coupling; Schlenk technique; Inert atmosphere; | 90% |
Conditions | Yield |
---|---|
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Green chemistry; | 99% |
With C16H34ClPPd; sodium t-butanolate In toluene at 100℃; Buchwald-Hartwig amination; Inert atmosphere; | 97% |
With C37H44ClN2O3PPd; potassium hydroxide; tert-butyl alcohol In water at 100℃; for 12h; Buchwald-Hartwig Coupling; Schlenk technique; Inert atmosphere; | 92% |
Conditions | Yield |
---|---|
Stage #1: para-bromotoluene With lithium Stage #2: With zinc(II) chloride Stage #3: 2-Chloroanisole; nickel phosphine amido pincer complex In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 70℃; for 12h; Negishi cross-coupling; Further stages.; | 99% |
ortho-tolylmagnesium bromide
2-Chloroanisole
2-methoxy-2'-methyl-1,1'-biphenyl
Conditions | Yield |
---|---|
With iron(II) triflate; sodium t-butanolate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In tetrahydrofuran at 60℃; for 16h; Glovebox; Sealed tube; Inert atmosphere; | 99% |
Stage #1: 2-Chloroanisole With Ni(PPh3)(1,3-di-tert-butylimidazol-2-ylidene)Br2 In tetrahydrofuran at 0℃; for 0.0333333h; Inert atmosphere; Schlenk technique; Stage #2: ortho-tolylmagnesium bromide In tetrahydrofuran at 60℃; for 4h; Inert atmosphere; Schlenk technique; | 98% |
With C46H55ClFeN3Pd; lithium chloride In tetrahydrofuran at 60℃; for 24h; Kumada coupling reaction; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0) In tert-butyl alcohol at 110℃; for 7h; | 99% |
With potassium phosphate; t-BuBrettPhos; water; palladium diacetate In tert-butyl alcohol at 110℃; for 3h; Inert atmosphere; | 91% |
Conditions | Yield |
---|---|
With potassium phosphate; C50H63Cl2N3Pd In ethanol at 80℃; for 4h; Suzuki-Miyaura Coupling; | 99% |
Stage #1: 2-Methoxyphenylboronic acid With potassium phosphate; N,N-diisopropyl 2-dicyclohexylphosphino-5-(3'-nitrophenyl)benzamide; palladium diacetate In tetrahydrofuran at 23℃; for 0.0166667h; Suzuki-Miyaura cross-coupling; Inert atmosphere; Stage #2: 2-Chloroanisole In tetrahydrofuran at 23℃; for 36h; Suzuki-Miyaura cross-coupling; Inert atmosphere; | 78% |
With palladium diacetate; caesium carbonate; P-phenyl-2,2,6,6-tetramethyl-phosphorinan-4-ol In toluene at 110℃; for 48h; Suzuki-Miyaura cross coupling; Inert atmosphere; | 70% |
tert-butyl carbamate
2-Chloroanisole
tert-butyl 2-methoxyphenylcarbamate
Conditions | Yield |
---|---|
With 4-diphenylphosphino-13-dicyclohexylphosphino-[2.2]paracyclophane; water; palladium diacetate; caesium carbonate In 1,4-dioxane at 125℃; for 24h; Buchwald-Hartwig coupling; | 99% |
With di-tert-butyl{2′-isopropoxy-[1,1′-binaphthalen]-2-yl}phosphane; caesium carbonate; bis(dibenzylideneacetone)-palladium(0) In tert-butyl alcohol at 100℃; for 20h; Inert atmosphere; | 40% |
With palladium diacetate; caesium carbonate; XPhos In 1,4-dioxane at 100℃; for 24h; | 10 %Chromat. |
2-Chloroanisole
cyclopropylboronic acid
1-cyclopropyl-2-methoxybenzene
Conditions | Yield |
---|---|
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); rac-3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole In toluene at 100℃; for 24h; Suzuki coupling; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With Pd-PEPPSI-(2,6-(3-pentyl)pentylphenyl-2H-imidazol-2-ylidene)Cl-o-picoline; caesium carbonate In 1,2-dimethoxyethane at 24℃; for 24h; Buchwald-Hartwig Coupling; Inert atmosphere; Glovebox; | 99% |
With [IPr*·H][Pd(η3-cin)Cl2]; potassium tert-butylate at 60 - 80℃; for 2h; Buchwald-Hartwig Coupling; Sealed tube; | 80% |
Conditions | Yield |
---|---|
With NHC-Pd(II)-Im; potassium tert-butylate In 1,4-dioxane at 120℃; for 12h; Inert atmosphere; Schlenk technique; | 99% |
Conditions | Yield |
---|---|
With bis[dicyclohexyl(2,4,6-triisopropyl-[1,1':3',1''-terphenyl]-2-yl)phosphane]palladium(II) dichloride; caesium carbonate In tetrahydrofuran at 80℃; for 1.5h; Temperature; Solvent; Reagent/catalyst; | 99% |
With (R)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; palladium diacetate; caesium carbonate In dimethyl sulfoxide at 130℃; for 12h; | 33% |
2-Chloroanisole
benzoyl chloride
(3-chloro-4-methoxyphenyl)(phenyl)methanone
Conditions | Yield |
---|---|
With copper(II) ferrite In 1,2-dichloro-ethane at 35 - 38℃; for 18h; Friedel-Crafts Acylation; | 98% |
With aluminum (III) chloride In dichloromethane at 0℃; for 3h; Inert atmosphere; | 82% |
With aluminium trichloride | 81% |
With aluminium trichloride; 1,1,2,2-tetrachloroethane at 120 - 130℃; | |
With carbon disulfide; aluminium trichloride at 0℃; |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View