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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Bromoanisole Manufacturer/High quality/Best price/In stock

Cas:578-57-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality O-Bromoanisole supplier in China

Cas:578-57-4

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Chemwill Asia co.,Ltd is one of the leading manufacturer in CHINA. Product quality, process, price and service 2-Bromoanisole CAS 578-57-4 1-Bromo-2-methoxy-benzene IN STOCK o-bromoanisole CAS 578-57-4 578-57-4 CAS 578-57-4 highly quality

2-Bromoanisole CAS 578-57-4 1-Bromo-2-methoxy-benzene IN STOCK o-bromoanisole CAS 578-57-4

Cas:578-57-4

Min.Order:5 Kiloliter

FOB Price: $3.5 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

1-bromo-2-methoxybenzene

Cas:578-57-4

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Jinan Finer Chemical Co., Ltd

Product Description Name 2-Bromoanisole CAS 578-57-4 Assay 99% Appearance C

2-Bromoanisole

Cas:578-57-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU-CHEM 578-57-4 2-Bromoanisole

Cas:578-57-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

2-Bromoanisole 578-57-4

Cas:578-57-4

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 578-57-4 with fast shipping

Cas:578-57-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

TIANFUCHEM--High purity 2-Bromoanisole factory price

Cas:578-57-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Product name: 2-Bromoanisole CAS : 578-57-4 Appearance: Light yellow liquid Content: 99% Appearance:Light yellow liquid Storage:Preserve in well-closed, light-resistant and airtight containers. Package:25kg/drum Application: Flavours & Fragrances Int

2-Bromoanisole

Cas:578-57-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-bromo-2-methoxy- 578-57-4

Cas:578-57-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality 2-Bromoanisole Basic information Product Name: 2-Bromoanisole Synonyms: 1-bromo-2-methoxy-benzen;2-Bromo-1-methoxybenzene;2-Methoxybromobenzene;2-Met

2-Bromoanisole

Cas:578-57-4

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-bromo-2-methoxy-

Cas:578-57-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

2-Bromoanisole CAS 578-57-4

Cas:578-57-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

High quality o-bromoanisole CAS NO.578-57-4

Cas:578-57-4

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

2-Bromoanisole

Cas:578-57-4

Min.Order:1 Kilogram

FOB Price: $30.0 / 50.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,1-bromo-2-methoxy-

Cas:578-57-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

O-Bromoanisole

Cas:578-57-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2-BROMOANISOLE

Cas:578-57-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Bromoanisole

Cas:578-57-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply o-bromoanisole

Cas:578-57-4

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality O-Bromoanisole

Cas:578-57-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

o-bromoanisoleAppearance:Colorless transparent liquid Storage:Keep away of light, cool place Package:according to customers' requirements Application:pharmaceutical intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB

o-bromoanisole

Cas:578-57-4

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Best Offer2-Bromoanisole

Cas:578-57-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:2-Bromoanisole CAS No:578-57-4 Synonym

2-Bromoanisole

Cas:578-57-4

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-Bromoanisole

Cas:578-57-4

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

2-Bromoanisole Chemical Properties Melting point 2 °C (lit.) Boiling point 223 °C (lit.) density 1.502 g/mL at 25 °C (lit.) refractive index n20/D 1.573(lit.) Fp 206 °F storage temp. Store below +30°C. solu

2-Bromoanisole

Cas:578-57-4

Min.Order:200 Kilogram

FOB Price: $65.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

TIANFUCHEM--High purity 2-Bromoanisole factory price

Cas:578-57-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and

2-Bromoanisole; 1-Bromo-2-methoxybenzene

Cas:578-57-4

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

TIANFUCHEM--High purity 2-Bromoanisole factory price

Cas:578-57-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methoxybenzene
100-66-3

methoxybenzene

A

1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

B

2-bromoanisole
578-57-4

2-bromoanisole

C

2,4-dibromoanisole
21702-84-1

2,4-dibromoanisole

Conditions
ConditionsYield
With bromine; tetramethylammonium bromide In liquid sulphur dioxide at -23℃; Rate constant; Product distribution; Thermodynamic data; in H2O at 25 deg C, NaBr, HClO4; ΔH (excit), -ΔS (excit);A 98.99%
B 0.56%
C 0.43%
With (CH3)4Br In liquid sulphur dioxide at -23℃; Kinetics; Thermodynamic data; Product distribution; ΔH(excit.); ΔS(excit.);A 98.99%
B 0.56%
C 0.43%
With (CH3)4Br In liquid sulphur dioxide at -23℃;A 98.99%
B 0.56%
C 0.43%
2-methoxy-phenylamine
90-04-0

2-methoxy-phenylamine

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With tert.-butylnitrite; tetrabutylammomium bromide; copper(I) bromide; 10-camphorsulfonic acid In acetonitrile at 20℃; for 24h; Reagent/catalyst; Time; Solvent;98%
Stage #1: 2-methoxy-phenylamine With tert.-butylnitrite In dichloromethane; water at 0℃; for 0.166667h;
Stage #2: With carbon tetrabromide; dimethylglyoxal In dichloromethane; water at 15 - 35℃; for 16h;
78%
With tert.-butylnitrite; tetrabutylammomium bromide; toluene-4-sulfonic acid; copper(ll) bromide In acetonitrile at 20℃; for 23h;74%
methoxybenzene
100-66-3

methoxybenzene

A

1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

B

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With Oxone; potassium bromide In methanol at 20℃; for 1h;A 97%
B 2%
With Oxone; potassium bromide In acetonitrile at 20℃; for 24h;A 84%
B 15%
With PyHBrCl2 In methanol at 20℃; for 0.0833333h;A 78%
B 18%
2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With N-Bromosuccinimide In acetonitrile at 80℃; for 12h;97%
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; for 8h; Sealed tube;82%
With 1,10-Phenanthroline; oxygen; potassium bromide; copper(ll) bromide In N,N-dimethyl-formamide at 130℃; for 20h;67%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; sodium methylate In methanol; water; acetonitrile at 23℃;94 % Chromat.
2-hydroxybromobenzene
95-56-7

2-hydroxybromobenzene

methyl iodide
74-88-4

methyl iodide

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
Stage #1: 2-hydroxybromobenzene With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 1.16667h; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran; mineral oil at 20℃; for 19h; Inert atmosphere; Reflux;
97%
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 2.5h; Inert atmosphere;96%
With potassium hydroxide In CD2Cl2; hexane; acetonitrile89%
2-hydroxybromobenzene
95-56-7

2-hydroxybromobenzene

dimethyl sulfate
77-78-1

dimethyl sulfate

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With potassium carbonate at 60℃; for 0.3h; Williamson synthesis;94%
With sodium hydroxide
With potassium hydroxide
With sodium hydroxide for 3h; Heating;
With potassium carbonate In acetone Inert atmosphere;
2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With potassium phosphate; tetrabuthylammonium tribromide In acetonitrile at 100℃; for 16h; Reagent/catalyst;90%
bromobenzene
108-86-1

bromobenzene

potassium ferrocyanide

potassium ferrocyanide

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With sodium carbonate In N,N-dimethyl-formamide at 120℃; for 4h;90%
2-hydroxybromobenzene
95-56-7

2-hydroxybromobenzene

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 0.0583333h; microwave irradiation;84%
With leucine intercalated Mg-Al layered double hydorxide at 180℃; for 6h; Autoclave; Green chemistry; chemoselective reaction;87 %Chromat.
2-bromophenyltrimethylammonium trifluoromethanesulfonate

2-bromophenyltrimethylammonium trifluoromethanesulfonate

potassium methanolate
865-33-8

potassium methanolate

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 25℃; for 3h; Inert atmosphere; Schlenk technique;84%
triethyl(2-methoxyphenyl)germane

triethyl(2-methoxyphenyl)germane

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With N-Bromosuccinimide In N,N-dimethyl-formamide at 20℃; for 4h;75%
2-hydroxybromobenzene
95-56-7

2-hydroxybromobenzene

phosphorous acid trimethyl ester
121-45-9

phosphorous acid trimethyl ester

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With boron trifluoride In diethyl ether for 0.0416667h; microwave irradiation;74%
2,4-dibromoanisole
21702-84-1

2,4-dibromoanisole

A

1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

B

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With butyl magnesium bromide; zirconocene dichloride In tetrahydrofuran for 3h; Ambient temperature;A 72%
B 22%
2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

A

2-bromoanisole
578-57-4

2-bromoanisole

B

methoxybenzene
100-66-3

methoxybenzene

Conditions
ConditionsYield
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; for 8h; Sealed tube;A 64%
B 20%
With tetrabutylammomium bromide; copper(ll) bromide In water at 100℃; for 8h; Sealed tube;A 12%
B 26%
2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

A

2-bromoanisole
578-57-4

2-bromoanisole

B

5-bromo-2-methoxybenzoic acid
2476-35-9

5-bromo-2-methoxybenzoic acid

Conditions
ConditionsYield
With potassium phosphate; bromine In acetonitrile at 100℃; for 4h; Reagent/catalyst;A 26%
B 56%
2-methoxybenzenediazonium o-benzenedisulfonamide

2-methoxybenzenediazonium o-benzenedisulfonamide

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With tetrabutylammomium bromide; copper In acetonitrile at 20℃; for 0.75h; Substitution;55%
With tetrabutylammomium bromide In acetonitrile at 60℃; for 0.75h; Substitution;53%
(2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate
1232133-61-7

(2,4,6-trimethylphenyl)(2’-methoxyphenyl)iodonium triflate

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With copper(I) bromide In acetonitrile at 80℃; for 2h;47%
2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

A

2-bromoanisole
578-57-4

2-bromoanisole

B

2,4-dibromoanisole
21702-84-1

2,4-dibromoanisole

C

5-bromo-2-methoxybenzoic acid
2476-35-9

5-bromo-2-methoxybenzoic acid

Conditions
ConditionsYield
With potassium phosphate; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In acetonitrile at 100℃; for 4h;A 40%
B 7%
C 32%
2-Chloroanisole
766-51-8

2-Chloroanisole

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With dibromodifluoromethane; ISOPROPYLAMIDE; copper at 150℃; for 8h; Further byproducts given;11%
phosgene

phosgene

diethyl ether
60-29-7

diethyl ether

2,4-dibromoanisole
21702-84-1

2,4-dibromoanisole

phenylmagnesium bromide

phenylmagnesium bromide

A

1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

B

2-bromoanisole
578-57-4

2-bromoanisole

C

methoxybenzene
100-66-3

methoxybenzene

2-hydroxybromobenzene
95-56-7

2-hydroxybromobenzene

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With potassium hydroxide; methyl iodide
With diazomethane; diethyl ether
(methylation);
2-hydroxybromobenzene
95-56-7

2-hydroxybromobenzene

methyl p-toluene sulfonate
80-48-8

methyl p-toluene sulfonate

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With potassium hydroxide
2,6-dibromoanisole
38603-09-7

2,6-dibromoanisole

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With water; isopropylmagnesium chloride 1) THF, 40 deg C, 3 h; 2) 0 deg C; Yield given. Multistep reaction;
(2-methoxy-phenyl)-trimethyl-silane
704-43-8

(2-methoxy-phenyl)-trimethyl-silane

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With N-chloro-succinimide; sodium bromide In methanol for 0.0833333h; Ambient temperature; Yield given;
With N-chloro-succinimide; sodium bromide In methanol for 0.0833333h; Ambient temperature;
methanol
67-56-1

methanol

sodium-<2-bromo-phenolate>

sodium-<2-bromo-phenolate>

2-bromoanisole
578-57-4

2-bromoanisole

Conditions
ConditionsYield
With carbon monoxide at 180℃;
ethyl bromide
74-96-4

ethyl bromide

diethyl ether
60-29-7

diethyl ether

2,4-dibromoanisole
21702-84-1

2,4-dibromoanisole

magnesium

magnesium

A

1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

B

2-bromoanisole
578-57-4

2-bromoanisole

C

methoxybenzene
100-66-3

methoxybenzene

hydrogenchloride
7647-01-0

hydrogenchloride

2,6-dibromoanisole
38603-09-7

2,6-dibromoanisole

2-bromoanisole
578-57-4

2-bromoanisole

O-allyl-2-bromophenol
60333-75-7

O-allyl-2-bromophenol

methyl iodide
74-88-4

methyl iodide

A

2-bromoanisole
578-57-4

2-bromoanisole

B

methoxybenzene
100-66-3

methoxybenzene

Conditions
ConditionsYield
Stage #1: O-allyl-2-bromophenol With [2,2]bipyridinyl; tetrabutylammonium tetrafluoroborate; palladium dichloride In N,N-dimethyl-formamide at 20℃; Reduction; Electrochemical reaction;
Stage #2: methyl iodide With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 12h; Methylation;
2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

A

2-bromoanisole
578-57-4

2-bromoanisole

B

2,4-dibromoanisole
21702-84-1

2,4-dibromoanisole

C

5-bromo-2-methoxyphenylboronic acid
89694-45-1

5-bromo-2-methoxyphenylboronic acid

Conditions
ConditionsYield
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In water; acetonitrile at 40℃; for 4h;A 45 % Chromat.
B 18 % Chromat.
C 34 % Chromat.
2-bromoanisole
578-57-4

2-bromoanisole

2,4-dibromoanisole
21702-84-1

2,4-dibromoanisole

Conditions
ConditionsYield
With (CH3)4Br In liquid sulphur dioxide at -23℃; Rate constant;100%
With (CH3)4Br In liquid sulphur dioxide at -23℃;100%
With N-Bromosuccinimide; iodine In acetonitrile for 12h; Darkness;99%
With dihydrogen peroxide; ammonium bromide; acetic acid at 20℃; for 12h;54%
With bromine; tetramethylammonium bromide In liquid sulphur dioxide at -23℃; Product distribution; Rate constant;
2-bromoanisole
578-57-4

2-bromoanisole

phenylboronic acid
98-80-6

phenylboronic acid

2-methoxy-1,1'-biphenyl
86-26-0

2-methoxy-1,1'-biphenyl

Conditions
ConditionsYield
With di-tert-butyl(4-sulfonatobenzyl)phosphonium; palladium diacetate; sodium carbonate In water at 50℃; for 24h; Solvent; Temperature; Reagent/catalyst; Suzuki Coupling; Inert atmosphere; Glovebox;100%
With di-tert-butyl(4-sulfonatobenzyl)phosphonium; palladium diacetate; sodium carbonate In water at 50℃; Reagent/catalyst; Solvent; Temperature; Suzuki Coupling; Inert atmosphere; Glovebox;100%
With sodium carbonate In water at 100℃; Suzuki-Miyaura reaction;99.1%
2-bromoanisole
578-57-4

2-bromoanisole

p-toluidine
106-49-0

p-toluidine

2-methoxy-N-(4-methylphenyl)aniline
107455-62-9

2-methoxy-N-(4-methylphenyl)aniline

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene for 24h; Buchwald-Hartwig Coupling; Inert atmosphere; Reflux;100%
With bis[2-(diphenylphosphino)phenyl] ether; sodium t-butanolate; palladium dichloride In toluene at 80℃; for 3h;97%
With palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether; sodium t-butanolate In toluene at 80℃; for 3h;94%
2-bromoanisole
578-57-4

2-bromoanisole

benzaldehyde
100-52-7

benzaldehyde

2-methoxyphenyl(phenyl)methanol
22788-49-4

2-methoxyphenyl(phenyl)methanol

Conditions
ConditionsYield
Stage #1: 2-bromoanisole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere;
Stage #2: benzaldehyde In tetrahydrofuran; hexane at -78 - 22℃; for 20h; Inert atmosphere;
100%
Stage #1: 2-bromoanisole With magnesium; lithium chloride In tetrahydrofuran at 50℃; for 0.125h; Flow reactor;
Stage #2: benzaldehyde In tetrahydrofuran at 20℃; for 0.333333h; Flow reactor;
95%
Stage #1: 2-bromoanisole With n-butyllithium In tetrahydrofuran; hexane at -78℃; Inert atmosphere;
Stage #2: benzaldehyde In tetrahydrofuran; hexane at -78 - 20℃; for 17h; Inert atmosphere;
90%
2-bromoanisole
578-57-4

2-bromoanisole

2-tert-Butylphenol
88-18-6

2-tert-Butylphenol

3-tert-butyl-2'-methoxybiphenyl-2-ol

3-tert-butyl-2'-methoxybiphenyl-2-ol

Conditions
ConditionsYield
With caesium carbonate; diisopropyl(2-tert-butyl)phenoxyphosphine; RhCl(PPh3)3 In toluene for 18h; Heating;100%
2-bromoanisole
578-57-4

2-bromoanisole

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

2-methoxy-4'-methylbiphenyl
92495-53-9

2-methoxy-4'-methylbiphenyl

Conditions
ConditionsYield
With potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 0.25h; Suzuki-Miyaura reaction;100%
With Pd/C; potassium carbonate In ethanol; water at 100℃; for 3h; Suzuki-Miyaura Coupling;95%
With cetyltrimethylammonim bromide; sodium hydroxide In water at 25℃; for 1h; Catalytic behavior; Suzuki Coupling; Microwave irradiation;94%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

2-bromoanisole
578-57-4

2-bromoanisole

tert-butyl (E)-3-(2-methoxyphenyl)prop-2-enoate
474097-69-3

tert-butyl (E)-3-(2-methoxyphenyl)prop-2-enoate

Conditions
ConditionsYield
With IMes-Pd(dmba)Cl; potassium carbonate In 1-methyl-pyrrolidin-2-one at 140℃; for 18h; Heck-Mizoroki reaction; Inert atmosphere;100%
With dichlorobis(1,4-dimesityl-1H-1,2,3-triazol-5-ylidene)palladium(II); sodium acetate In N,N-dimethyl acetamide at 150℃; for 8h; Mizoroki-Heck reaction; Inert atmosphere; optical yield given as %de;51%
With C4H7Cl2Pd(1-)*C27H39N2(1+); potassium carbonate In N,N-dimethyl-formamide at 100℃; for 40h; Heck Reaction; Sealed tube;51%
2-bromoanisole
578-57-4

2-bromoanisole

2-Cyanophenylboronic acid
138642-62-3

2-Cyanophenylboronic acid

2'-methoxy-[1,1'-biphenyl]-2-carbonitrile

2'-methoxy-[1,1'-biphenyl]-2-carbonitrile

Conditions
ConditionsYield
With sodium tetrachloropalladate(II); 2-(1-(1-phenylethylamino)methyl)pyridine In water; N,N-dimethyl-formamide at 110℃; for 16h; Suzuki-Miyaura coupling;100%
2-bromoanisole
578-57-4

2-bromoanisole

(S,S)-1,2-diphenyl-1,2-diaminoethane
29841-69-8

(S,S)-1,2-diphenyl-1,2-diaminoethane

(1R,2R)-N1,N2-bis(2-methoxyphenyl)-1,2-diphenylethane-1,2-diamine

(1R,2R)-N1,N2-bis(2-methoxyphenyl)-1,2-diphenylethane-1,2-diamine

Conditions
ConditionsYield
Stage #1: (S,S)-1,2-diphenyl-1,2-diaminoethane With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 20℃; for 1.5h; Inert atmosphere; Schlenk technique; Glovebox;
Stage #2: 2-bromoanisole In toluene at 120℃; for 9h; Inert atmosphere; Schlenk technique; Glovebox;
100%
2-bromoanisole
578-57-4

2-bromoanisole

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

cyclohexyl (2-methoxyphenyl)methanol
92300-73-7

cyclohexyl (2-methoxyphenyl)methanol

Conditions
ConditionsYield
Stage #1: 2-bromoanisole With iodine; magnesium In tetrahydrofuran for 6.16667h; Sealed tube; Inert atmosphere; Reflux;
Stage #2: cyclohexanecarbaldehyde In tetrahydrofuran at 20℃; Sealed tube; Inert atmosphere;
100%
3,7-dimethyl-oct-6-enal
106-23-0, 26489-02-1

3,7-dimethyl-oct-6-enal

2-bromoanisole
578-57-4

2-bromoanisole

1-(2-methoxyphenyl)-3,7-dimethyloct-6-en-1-ol

1-(2-methoxyphenyl)-3,7-dimethyloct-6-en-1-ol

Conditions
ConditionsYield
Stage #1: 2-bromoanisole With iodine; magnesium In tetrahydrofuran at 20℃; for 1h; Inert atmosphere;
Stage #2: 3,7-dimethyl-oct-6-enal In tetrahydrofuran at 20℃; for 1.25h; Inert atmosphere;
100%
2-bromoanisole
578-57-4

2-bromoanisole

methoxybenzene
100-66-3

methoxybenzene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); formaldehyd; caesium carbonate In dimethyl sulfoxide at 80℃; for 12h;99%
With butyl magnesium bromide; zirconocene dichloride for 12h; Ambient temperature;98%
With lithium aluminium tetrahydride In 1,2-dimethoxyethane at 35℃; for 4h; ultrasonic acceleration of reduction;98%
2-bromoanisole
578-57-4

2-bromoanisole

2-methoxyphenyllithium
31600-86-9

2-methoxyphenyllithium

Conditions
ConditionsYield
With n-butyllithium In hexane; pentane at 0 - 20℃; for 1h; Inert atmosphere;99%
With n-butyllithium In hexane; pentane at 0 - 20℃;97%
With n-butyllithium In hexane; pentane at 20℃; in evacuated, closed vessel;
2-bromoanisole
578-57-4

2-bromoanisole

acetic anhydride
108-24-7

acetic anhydride

3-bromo-4-methoxyacetophenone
35310-75-9

3-bromo-4-methoxyacetophenone

Conditions
ConditionsYield
With lithium perchlorate at 100℃; for 5h;99%
With aluminum (III) chloride In dichloromethane at 20 - 40℃; Friedel-Crafts acylation; Inert atmosphere;96%
With aluminium trichloride In dichloromethane68%
2-bromoanisole
578-57-4

2-bromoanisole

thiophenol
108-98-5

thiophenol

1-methoxy-2-(phenylthio)benzene
14065-22-6

1-methoxy-2-(phenylthio)benzene

Conditions
ConditionsYield
With (R)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; palladium diacetate; sodium t-butanolate In 1,2-dimethoxyethane at 110℃; for 2h; Inert atmosphere;99%
With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine In toluene for 3h; Inert atmosphere; Reflux;97%
With copper(l) iodide; N,N'-dihexyloxalamide; potassium tert-butylate In 1,4-dioxane at 110℃; for 24h; Sealed tube; Inert atmosphere;95%
2-bromoanisole
578-57-4

2-bromoanisole

N-methylaniline
100-61-8

N-methylaniline

(2-methoxyphenyl)methylphenylamine

(2-methoxyphenyl)methylphenylamine

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Green chemistry;99%
With dicyclohexyl(2-methoxy-6-methylbiphenyl-2,-yl)phosphine; potassium tert-butylate; palladium diacetate In 1,4-dioxane at 160℃; for 0.25h; Microwave irradiation; Inert atmosphere;80%
With tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate at 80℃; for 29h; Arylation;77%
styrene
292638-84-7

styrene

2-bromoanisole
578-57-4

2-bromoanisole

(E)-2-methoxystilbene
52805-92-2

(E)-2-methoxystilbene

Conditions
ConditionsYield
With (1-adamantyl)di(tert-butyl) phosphine; triethylamine; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl-formamide at 20℃; for 20h; Heck reaction;99%
With C27H21F3N6OPd; tetrabutylammomium bromide; sodium acetate at 140℃; for 12h; Heck reaction; Inert atmosphere;89%
With potassium phosphate In N,N-dimethyl-formamide at 130℃; for 15h; Heck Reaction;84%
2-bromoanisole
578-57-4

2-bromoanisole

2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

2,2'-Dimethoxybiphenyl
4877-93-4

2,2'-Dimethoxybiphenyl

Conditions
ConditionsYield
With potassium carbonate; palladium dichloride In water; N,N-dimethyl-formamide at 20℃; for 0.166667h; Suzuki cross-coupling reaction;99%
With Ph2P(CH2CH2O)22CH3; triethylamine; palladium dichloride In water at 100℃; for 1h; Suzuki coupling; Inert atmosphere;98%
With potassium carbonate; Co0.38Fe0.57LaO3Pd0.05 In isopropyl alcohol at 80℃; for 1h; Suzuki reaction;89%
2-bromoanisole
578-57-4

2-bromoanisole

o-cyanophenylboronic acid-1,3-propylene glycol ester
172732-52-4

o-cyanophenylboronic acid-1,3-propylene glycol ester

2'-methoxy-[1,1'-biphenyl]-2-carbonitrile

2'-methoxy-[1,1'-biphenyl]-2-carbonitrile

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium phosphate In toluene for 1h; Heating;99%
morpholine
110-91-8

morpholine

2-bromoanisole
578-57-4

2-bromoanisole

N-(2-methoxyphenyl)morpholine
27347-13-3

N-(2-methoxyphenyl)morpholine

Conditions
ConditionsYield
With (1,3-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]imidazole-2-ylidene)PdCl2(triethylamine); potassium tert-butylate In 1,2-dimethoxyethane at 20℃; for 6h; Buchwald-Hartwig Coupling; Sealed tube;99%
With potassium tert-butylate In 1,2-dimethoxyethane at 20℃; for 6h; Buchwald-Hartwig Coupling;99%
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry;99%
methanol
67-56-1

methanol

2-bromoanisole
578-57-4

2-bromoanisole

carbon monoxide
201230-82-2

carbon monoxide

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With dichloro[2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II); triethylamine at 100℃; under 2585.74 Torr; for 16h;99%
1-phenylmethyl-4-piperidone
3612-20-2

1-phenylmethyl-4-piperidone

2-bromoanisole
578-57-4

2-bromoanisole

1-benzyl-4-(2-methoxyphenyl)piperidin-4-ol
130305-58-7

1-benzyl-4-(2-methoxyphenyl)piperidin-4-ol

Conditions
ConditionsYield
Stage #1: 2-bromoanisole With iodine; magnesium In tetrahydrofuran Grignard reaction; Inert atmosphere; Reflux;
Stage #2: 1-phenylmethyl-4-piperidone In tetrahydrofuran at 20℃; for 3h; Grignard reaction; Inert atmosphere; Cooling with ice;
99%
Stage #1: 2-bromoanisole With n-butyllithium In tetrahydrofuran; hexane at -70 - 1℃;
Stage #2: 1-phenylmethyl-4-piperidone In tetrahydrofuran at 20℃;
23.1%
2-bromoanisole
578-57-4

2-bromoanisole

triisopropylsilanethiol
156275-96-6

triisopropylsilanethiol

triisopropyl-(2-methoxyphenylsulfanyl)-silane

triisopropyl-(2-methoxyphenylsulfanyl)-silane

Conditions
ConditionsYield
With (R)-(-)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; palladium diacetate; lithium hexamethyldisilazane In toluene at 110℃; Inert atmosphere;99%
With caesium carbonate; triphenylphosphine; palladium diacetate In toluene at 100℃; for 16h;33%
2-bromoanisole
578-57-4

2-bromoanisole

aniline
62-53-3

aniline

2-methoxy-N-phenylaniline
1207-92-7

2-methoxy-N-phenylaniline

Conditions
ConditionsYield
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry;99%
With potassium tert-butylate; (ϖ-allyl)(diphosphinecyclobutene)palladium at 20℃; for 12h;97%
With potassium phosphate; copper(l) iodide In diethylene glycol at 70℃; for 14h; Sealed tube;93%
2-bromoanisole
578-57-4

2-bromoanisole

Pentafluorobenzene
363-72-4

Pentafluorobenzene

2,3,4,5,6-pentafluoro-2′-methoxy-1,1′-biphenyl
15945-35-4

2,3,4,5,6-pentafluoro-2′-methoxy-1,1′-biphenyl

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; potassium carbonate In Isopropyl acetate at 80℃; for 12h;99%
With potassium phosphate; chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium (II); Trimethylacetic acid In N,N-dimethyl acetamide at 100℃; Glovebox;96%
With potassium phosphate; chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II); Trimethylacetic acid In N,N-dimethyl acetamide at 80℃; for 2 - 4h;96%
2-bromoanisole
578-57-4

2-bromoanisole

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

Conditions
ConditionsYield
With sodium methylate; nickel diacetate In 1,4-dioxane at 110℃;99%
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; trichlorophosphate at 165℃; for 24h; Inert atmosphere;67%

Conditions
ConditionsYield
With caesium carbonate; copper(I) oxide In N,N-dimethyl-formamide at 110℃; for 18h;99%
With copper diacetate; sodium hydroxide; 3-(diphenylphosphino)propionic acid In 1,4-dioxane at 120℃; for 36h; Sealed tube;51%
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