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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Methyl 2-methoxybenzoate Manufacturer/High quality/Best price/In stock

Cas:606-45-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Methyl 2-Methoxybenzoate supplier in China

Cas:606-45-1

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name Methyl 2-methoxybenzoate CAS number 606-45-1 Assay ≥99% Appearance Colorless liquid Capacity 200mt/year Application Pharmaceutical intermedi

Methyl 2-methoxybenzoate

Cas:606-45-1

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Methyl 2-Methoxy Benzoate

Cas:606-45-1

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Methoxybenzoic acid methyl ester

Cas:606-45-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--606-45-1--Methyl 2-methoxybenzoate in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business rel

TIANFUCHEM--606-45-1--Methyl 2-methoxybenzoate in stock

Cas:606-45-1

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 606-45-1 with best price

Cas:606-45-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name 2-Methoxybenzoic acid ethyl ester CAS 7335-26-4 Synonyms ETHYL O-ANISATE Molecular formula C10H12O3 Molecular weight 1

Methyl 2-methoxybenzoate

Cas:606-45-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoic acid,2-methoxy-, methyl ester 606-45-1

Cas:606-45-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: Methyl 2-methoxybenzoate CAS: 606-45-1 MF: C9H10O3 MW: 166.17 EINECS: 210-118-6 Mol File: 606-45-1.mol Methyl 2-methoxybenzoate Structure Methyl 2-methoxybenzoate Chemical Properties Boiling point 248 °C (lit

606-45-1

Cas:606-45-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methyl 2-Methoxybenzoate

Cas:606-45-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Methyl 2-methoxybenzoate

Cas:606-45-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

METHYL 2-METHOXYBENZOATE

Cas:606-45-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl 2-methoxybenzoate

Cas:606-45-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply methyl o-anisate

Cas:606-45-1

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

Methyl 2-methoxybenzoateCAS NO.: 606-45-1

Cas:606-45-1

Min.Order:1 Gram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Methyl2-methoxybenzoate

Cas:606-45-1

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Methyl 2-methoxybenzoate

Cas:606-45-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Changzhou Anchor Biological Technology Co., Ltd.

Our company is engaged in customizing the benzene ring and pyridine derivative organic intermediates, and the quantity is flexible according to customer's needs. It mainly provides high-quality intermediates for domestic and foreign pharmaceutical an

Methyl 2-methoxybenzoate Manufacturer/High quality/Best price/In stock CAS NO.606-45-1

Cas:606-45-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Methyl 2-methoxybenzoate

Cas:606-45-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

stable supply&competitive price Storage:Available Package:26KG Or as client requirement Application:Important pharm intermediate Transportation:By air or By sea

Methyl 2-Methoxyacetate

Cas:606-45-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Methyl 2-methoxybenzoate 100g

Cas:606-45-1

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Methyl 2-methoxybenzoate

Cas:606-45-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Methyl 2-Methoxybenzoate

Cas:606-45-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

High quality Methyl 2-methoxybenzoate cas NO.: 606-45-1

Cas:606-45-1

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

Methyl 2-methoxybenzoate

Cas:606-45-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Fred Technology Co.,Ltd.

Fredchem focus on CRO/CMO business and its own R&D of API/Intermediates Package:Grams, Kilograms Application:Pharmaceutical field Transportation:According to customer request Port:Shanghai

Methyl 2-methoxybenzoate

Cas:606-45-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Methyl o-Anisate

Cas:606-45-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:off-white powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as prima

Methyl 2-methoxybenzoate

Cas:606-45-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Methyl 2-methoxybenzoate cas 606-45-1Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Methyl 2-methoxybenzoate cas 606-45-1

Cas:606-45-1

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

dimethyl sulfate
77-78-1

dimethyl sulfate

salicylic acid
69-72-7

salicylic acid

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With potassium carbonate In acetone at 50 - 60℃; for 27h; Time; Large scale;99%
With potassium carbonate In acetone at 0 - 10℃; for 4h; Reflux; Inert atmosphere;91.1%
With potassium carbonate In acetone at 20℃; for 3.16667h; Heating / reflux;80%
methanol
67-56-1

methanol

2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With thionyl chloride at 20℃; for 18h; Cooling with ice; Inert atmosphere;99%
With Oxone In toluene at 60℃; for 48h; Green chemistry;97%
With 2-(dimethoxymethylidene)propanedinitrile at 60℃; for 48h;95%
methanol
67-56-1

methanol

2-bromoanisole
578-57-4

2-bromoanisole

carbon monoxide
201230-82-2

carbon monoxide

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With dichloro[2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II); triethylamine at 100℃; under 2585.74 Torr; for 16h;99%
2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With 5 wt percent zeolite NaY-Bf at 200℃; for 5h; Autoclave; Green chemistry;98%
With potassium carbonate In dimethyl sulfoxide at 90℃; for 16h; Inert atmosphere; Green chemistry;96%
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

salicylic acid
69-72-7

salicylic acid

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With diiron nonacarbonyl at 180℃; for 1h; Sealed tube;97%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 0.0208333h; microwave irradiation;92%
With potassium carbonate at 150℃; for 10h;
methanol
67-56-1

methanol

ortho-anisaldehyde
135-02-4

ortho-anisaldehyde

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With perchloric acid; sodium percarbonate; vanadia for 1.3h; Cooling;96%
With dihydrogen peroxide at 20℃; for 20h;95%
With aluminium(III) chloride hexahydrate; urea hydrogen peroxide adduct at 60℃; Green chemistry;90%
methanol
67-56-1

methanol

4-iodoanisol
529-28-2

4-iodoanisol

carbon monoxide
201230-82-2

carbon monoxide

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With triethylamine at 100℃; under 3750.38 Torr; for 1.5h; Inert atmosphere;96%
With triethylamine; palladium on activated charcoal at 130℃; under 3750.38 Torr; for 2h; Sonogashira coupling;77%
With triethylamine; G1-C2 PAMAM dendrimer*PPh2*PdCl2 at 105℃; under 5171.62 Torr; for 19h;100 % Chromat.
methanol
67-56-1

methanol

(2-methoxyphenyl)methanol
612-16-8

(2-methoxyphenyl)methanol

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With bismuth(III) chloride; palladium diacetate; potassium carbonate at 20℃; for 2h; chemoselective reaction;95%
With sodium methylate; potassium iodide at 15℃; Electrochemical reaction;85%
With oxygen; potassium carbonate at 70℃; under 750.075 Torr; for 48h;53%
methyl bromide
74-83-9

methyl bromide

salicylic acid
69-72-7

salicylic acid

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With potassium hydroxide In water at 15 - 20℃; Concentration; Temperature;94%
With sodium hydroxide In water at 20 - 25℃; Temperature;94%
With sodium hydroxide In water at 11 - 20℃; Temperature; Cooling;94%
methyl 2-hydroxy-5-nitrobenzoate
17302-46-4

methyl 2-hydroxy-5-nitrobenzoate

2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

A

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

B

5-nitrosalicylic acid
96-97-9

5-nitrosalicylic acid

Conditions
ConditionsYield
Stage #1: 2-Methoxybenzoic acid With potassium carbonate In N,N-dimethyl acetamide at 110℃; for 0.5h;
Stage #2: methyl 2-hydroxy-5-nitrobenzoate at 110℃; for 24h;
A 93%
B n/a
2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

methyl salicylate
119-36-8

methyl salicylate

A

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

B

salicylic acid
69-72-7

salicylic acid

Conditions
ConditionsYield
Stage #1: 2-Methoxybenzoic acid With potassium carbonate In N,N-dimethyl acetamide at 110℃; for 0.5h;
Stage #2: methyl salicylate at 110℃; for 24h; Solvent; Reagent/catalyst; Temperature;
A 92%
B n/a
salicylic acid
69-72-7

salicylic acid

methyl iodide
74-88-4

methyl iodide

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With potassium carbonate In acetone Heating;91%
With silver(l) oxide; benzene
With potassium hydroxide; Aliquat 336 1.) 60 deg C, 0.1 Torr, 6 h, 2.) room temp., 24 h; Yield given. Multistep reaction;
With potassium carbonate In N,N-dimethyl-formamide at 90℃;
With potassium carbonate In acetone at 20℃; Reflux; Darkness;
methanol
67-56-1

methanol

N-(2-methoxybenzoyl)-N-phenylhydroxylamine
34661-16-0

N-(2-methoxybenzoyl)-N-phenylhydroxylamine

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With sodium perchlorate In acetonitrile electrolysis;87%
Methyltrimethoxysilan
1185-55-3

Methyltrimethoxysilan

o-iodo-methyl-benzoic acid
610-97-9

o-iodo-methyl-benzoic acid

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With oxygen; copper diacetate; caesium carbonate In N,N-dimethyl-formamide at 145℃; under 760.051 Torr; for 18h;86%
Methoxytrimethylsilane
1825-61-2

Methoxytrimethylsilane

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With oxygen; copper diacetate; caesium carbonate In N,N-dimethyl-formamide at 145℃; under 760.051 Torr; for 18h;86%
methanol
67-56-1

methanol

2-Methoxybenzoyl chloride
21615-34-9

2-Methoxybenzoyl chloride

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
In dichloromethane for 2h; Heating;85%
With pyridine for 2h; Yield given;
With triethylamine In dichloromethane at 0℃;
With triethylamine In dichloromethane at 0℃; Inert atmosphere;1.56 g
methanol
67-56-1

methanol

2-bromoanisole
578-57-4

2-bromoanisole

carbon monoxide
201230-82-2

carbon monoxide

A

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

B

2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

Conditions
ConditionsYield
With tert-Amyl alcohol; sodium hydride; cobalt(II) acetate In tetrahydrofuran at 40℃; under 760 Torr; for 20h; Irradiation;A 84.5%
B 8%
2-bromoanisole
578-57-4

2-bromoanisole

carbon monoxide
201230-82-2

carbon monoxide

A

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

B

2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

Conditions
ConditionsYield
With methanol; tert-Amyl alcohol; sodium hydride; cobalt(II) acetate In tetrahydrofuran at 40℃; under 760 Torr; for 20h; Irradiation;A 84.5%
B 8%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

2-Chloroanisole
766-51-8

2-Chloroanisole

lithium methanolate
865-34-9

lithium methanolate

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; 5 mol% Pd/C; sodium fluoride In 1,4-dioxane at 150℃; Inert atmosphere;83%
methyl iodide
74-88-4

methyl iodide

methyl salicylate
119-36-8

methyl salicylate

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
Stage #1: methyl salicylate With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.333333h;
Stage #2: methyl iodide In N,N-dimethyl-formamide at 20℃; for 15h;
81%
With potassium carbonate In N,N-dimethyl-formamide at 70℃; for 4h;74%
With potassium hydroxide In methanol for 3h; Reflux;53%
With methanol; sodium methylate
With potassium carbonate; potassium iodide In acetone Reflux;
diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

methyl salicylate
119-36-8

methyl salicylate

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In methanol; hexane; acetonitrile for 15h; Ambient temperature;78%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With pyridine; copper (II) carbonate hydroxide at 90℃; for 24h; Chan-Lam Coupling;78%
methanol
67-56-1

methanol

2-Chloroanisole
766-51-8

2-Chloroanisole

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With 1,3-bis(dicyclohexylphosphino)propane bis(tetrafluoroborate) salt; palladium diacetate; potassium carbonate In dimethyl sulfoxide at 120℃; for 20h; Molecular sieve;74%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

2-methoxybenzylamine
6850-57-3

2-methoxybenzylamine

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
Stage #1: tert.-butylhydroperoxide; 2-methoxybenzylamine In water; dimethyl sulfoxide
Stage #2: In water; dimethyl sulfoxide at 100℃; for 20h; Sealed tube;
74%
dimethyl sulfate
77-78-1

dimethyl sulfate

methyl salicylate
119-36-8

methyl salicylate

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With lithium hydroxide In tetrahydrofuran at 70℃; for 0.5h;72%
O-methyl S-p-methylphenyl thiocarbonate
3186-53-6

O-methyl S-p-methylphenyl thiocarbonate

2-Methoxyphenylboronic acid
5720-06-9

2-Methoxyphenylboronic acid

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); copper(I) thiophene-2-carboxylate; trifuran-2-yl-phosphane In 1,4-dioxane at 60℃; for 16h; Sealed tube; Inert atmosphere;70%
methyl 2,6-dimethoxybenzoate
2065-27-2

methyl 2,6-dimethoxybenzoate

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); 1,1,3,3-Tetramethyldisiloxane; tricyclohexylphosphine In toluene at 110℃; for 12h; Glovebox; Inert atmosphere; Sealed tube;68%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

ortho-anisaldehyde
135-02-4

ortho-anisaldehyde

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With copper (II)-fluoride In water; dimethyl sulfoxide at 120℃; for 12h; Schlenk technique; Inert atmosphere; Green chemistry;67%
methanol
67-56-1

methanol

1-(2-methoxyphenyl)ethanol
13513-82-1

1-(2-methoxyphenyl)ethanol

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

Conditions
ConditionsYield
With N-iodo-succinimide; 1,10-Phenanthroline; oxygen; potassium carbonate; copper dichloride In dimethyl sulfoxide at 140℃; under 3750.38 Torr; for 24h; Molecular sieve;60%
With oxygen; potassium carbonate at 150℃; under 4500.45 Torr; for 24h; Autoclave;84 %Chromat.
methanol
67-56-1

methanol

methoxybenzene
100-66-3

methoxybenzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

A

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

B

ortho-anisaldehyde
135-02-4

ortho-anisaldehyde

Conditions
ConditionsYield
Stage #1: methoxybenzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran; hexane at -78 - 20℃; for 2h;
Stage #3: methanol Further stages;
A 53%
B 6%
pyrrolidine
123-75-1

pyrrolidine

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

(2-methoxyphenyl)(pyrrolidin-1-yl)methanone
120173-04-8

(2-methoxyphenyl)(pyrrolidin-1-yl)methanone

Conditions
ConditionsYield
In acetonitrile at 35℃; under 6000480 Torr; for 96h;100%
2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

methyl 2-methoxy-5-iodobenzoate
40757-09-3

methyl 2-methoxy-5-iodobenzoate

Conditions
ConditionsYield
With iodine; silver sulfate In methanol at 20℃; for 0.5h; Inert atmosphere;99%
With gold(III) chloride; N-iodo-succinimide In dichloromethane at 20℃; for 24h; Inert atmosphere;96%
With N-iodo-succinimide; [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) In dichloromethane; toluene at 20℃; for 14h; regioselective reaction;91%
2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

methyl 5-bromo-2-methoxybenzoate
7120-41-4

methyl 5-bromo-2-methoxybenzoate

Conditions
ConditionsYield
With N-Bromosuccinimide; silver hexafluoroantimonate; 1-methylthiotriptycene In 1,2-dichloro-ethane at 20℃; for 1h; Inert atmosphere; Schlenk technique;99%
With gold(III) chloride; N-Bromosuccinimide In dichloromethane at 80℃; for 23h; Inert atmosphere;96%
With iodine pentoxide; potassium bromide In water at 20℃; for 20h; regioselective reaction;92%
acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

tert-butyl 2-methoxybenzoate
16537-20-5

tert-butyl 2-methoxybenzoate

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran Ambient temperature;98%
2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

dimethyl methane phosphonate
756-79-6

dimethyl methane phosphonate

dimethyl [2-(2-methoxyphenyl)-2-oxoethyl]phosphonate
918874-30-3

dimethyl [2-(2-methoxyphenyl)-2-oxoethyl]phosphonate

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran Barbier reaction; Cooling with ice; Inert atmosphere;97%
With n-butyllithium In tetrahydrofuran at -78 - 0℃; Inert atmosphere;
ethanol
64-17-5

ethanol

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

ethyl 2-methoxybenzoate
7335-26-4

ethyl 2-methoxybenzoate

Conditions
ConditionsYield
With platinum(IV) oxide; hydrogen at 60℃; under 750.075 - 1500.15 Torr; for 16h; Autoclave; Green chemistry; chemoselective reaction;97%
2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

methyl salicylate
119-36-8

methyl salicylate

Conditions
ConditionsYield
With aluminium trichloride; sodium iodide at 70 - 80℃; for 2h;95%
With aluminum (III) chloride In dichloromethane at -5 - 25℃;94%
With aluminium(III) iodide In carbon disulfide for 0.9h; Heating;76%
With cerium(III) chloride; sodium iodide In acetonitrile for 20h; dealkylation; Heating;67%
With niobium pentachloride In 1,2-dichloro-ethane for 6h; Heating;
2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-methoxy-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic acid methyl ester
1146214-77-8

2-methoxy-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic acid methyl ester

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; 2-(dimethyl(phenyl)silyl)-1-(6-methoxypyridin-2-yl)-2,3-dihydro-1H-naphtho[1,8-de]-[1,3,2]diazaborinine In hexane at 80℃; for 20h; Time; Schlenk technique; Inert atmosphere;95%
With silica-SMAP-Ir(OCH3)(C8H12) In hexane ligand reacted with B-compound in hexane in presence of Ir-complex as catalyst at 25°C for 2 h;85%
With Silica-SMAP-Ir(OMe)(cod) In hexane at 25℃; for 2h; Autoclave; regioselective reaction;85%
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; (2-(diisopropylsilyl)phenyl)di-p-tolylphosphane In tetrahydrofuran at 80℃; for 16h; Inert atmosphere; Glovebox; Sealed tube;82%
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; (2-(diisopropylsilyl)phenyl)di-p-tolylphosphane In tetrahydrofuran at 80℃; Inert atmosphere;
2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

2-Methoxybenzoic acid
579-75-9

2-Methoxybenzoic acid

Conditions
ConditionsYield
Stage #1: 2-methoxybenzoic acid methyl ester With sodium hydroxide In methanol; water for 2h; Reflux;
Stage #2: With hydrogenchloride In methanol; water pH=1;
94%
With sodium hydroxide In methanol at 40℃; for 2.5h;94.3%
With potassium hydroxide In methanol at 35℃; for 1h;93%
2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

2-methoxybenzoylhydrazine
7466-54-8

2-methoxybenzoylhydrazine

Conditions
ConditionsYield
With hydrazine hydrate In ethanol for 4h; Reflux;94%
With hydrazine hydrate In ethanol at 80℃; for 1h; Inert atmosphere;92%
With hydrazine hydrate for 5h; Heating;90%
[hydroxy(tosyloxy)iodo]benzene
27126-76-7

[hydroxy(tosyloxy)iodo]benzene

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

phenyl(4-methoxy-3-methoxycarbonylphenyl)iodonium tosylate

phenyl(4-methoxy-3-methoxycarbonylphenyl)iodonium tosylate

Conditions
ConditionsYield
In 2,2,2-trifluoroethanol at 20℃; for 17h;94%
Diphenylmethane
101-81-5

Diphenylmethane

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

A

benzophenone
119-61-9

benzophenone

B

methyl 5-benzhydryl-2-methoxybenzoate
1169764-31-1

methyl 5-benzhydryl-2-methoxybenzoate

C

1,1,2,2-tetraphenylethane
632-50-8

1,1,2,2-tetraphenylethane

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone; iron(II) chloride In 1,2-dichloro-ethane at 100℃; for 36h; Inert atmosphere; regioselective reaction;A 0.14 mmol
B 94%
C 0.07 mmol
1-methyl-4-(phenylmethyl)benzene
620-83-7

1-methyl-4-(phenylmethyl)benzene

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

methyl 2-methoxy-5-(phenyl(p-tolyl)methyl)benzoate
1169764-40-2

methyl 2-methoxy-5-(phenyl(p-tolyl)methyl)benzoate

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone; iron(II) chloride In 1,2-dichloro-ethane at 100℃; for 36h; Inert atmosphere; regioselective reaction;94%
methanesulfonic acid
75-75-2

methanesulfonic acid

hexamethylenetetramine
100-97-0

hexamethylenetetramine

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

methyl 5-formyl-2-methoxybenzoate
78515-16-9

methyl 5-formyl-2-methoxybenzoate

Conditions
ConditionsYield
at 0 - 90℃; for 16h; Temperature; Large scale;94%
2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

salicylic acid
69-72-7

salicylic acid

Conditions
ConditionsYield
With AlBrCl3(1-)*C5H5N*H(1+) at 140℃; for 3h;93%
With lithium chloride In N,N-dimethyl-formamide for 22h; Heating;90%
With iodine; aluminium In cyclohexane at 80℃; for 18h; Solvent; Reagent/catalyst;86%
2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

(p-fluorophenyl)trimethylsilane
455-17-4

(p-fluorophenyl)trimethylsilane

4'-fluoro-4-methoxy-biphenyl-3-carboxylic acid methyl ester
64465-74-3

4'-fluoro-4-methoxy-biphenyl-3-carboxylic acid methyl ester

Conditions
ConditionsYield
With (Ph3P)Au(I)(OTs); [bis(acetoxy)iodo]benzene; camphor-10-sulfonic acid In methanol; chloroform at 20℃;92%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

C18H18IO6(1+)*CF3O3S(1-)

C18H18IO6(1+)*CF3O3S(1-)

Conditions
ConditionsYield
With iodine; 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 6h; Sealed tube;92%
With iodine; 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 6h;92%
With iodine; 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; for 6h;92%
2-methoxybenzoic acid methyl ester
606-45-1

2-methoxybenzoic acid methyl ester

1-methoxy-2-methoxymethylbenzene
21998-86-7

1-methoxy-2-methoxymethylbenzene

Conditions
ConditionsYield
With aluminium(III) triflate; tris(2,4-pentanedionato)ruthenium(III); hydrogen; [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In deuteromethanol; toluene at 130℃; under 30402 Torr; for 12h; Autoclave;91%
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