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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

tert-Butyl hydroperoxide Manufacturer/High quality/Best price/In stock

Cas:75-91-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hefei TNJ chemical industry co.,ltd

1,ISO Certificate 2,Factory price 3,Free sample and Fast delivery Appearance:Colorless transparent liquid Storage:All products should be stored at a dry and ventilated location away from fire and other dangerous goods, and should avoid direct sunl

Tert-Butyl hydroperoxide,CAS 75-91-2

Cas:75-91-2

Min.Order:1 Metric Ton

FOB Price: $1.0

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply tert-butyl hydroperoxide

Cas:75-91-2

Min.Order:1

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Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

tert-Butyl hydroperoxide

Cas:75-91-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production Cyromazine、lead diacetate trihydrate /Lead acetate trihydrateC、 2-phenylacetamide 、 4-Aminophenyl-1-phenethylpiperidine 、Citric acid monohydrate 、 Citric acid/c

Tert-butyl hydroperoxide 75-91-2

Cas:75-91-2

Min.Order:1 Kilogram

FOB Price: $2.0

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Henan Tianfu Chemical Co., Ltd.

tert-Butyl hydroperoxide Basic information Product Name: tert-Butyl hydroperoxide Synonyms: Butylhydroperoxid;1,1-Dimethylethyl hydroperoxide;1,1-dimethylethyl-hydroperoxid;1,1-dimethyle

75-91-2

Cas:75-91-2

Min.Order:1 Kilogram

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Henan Sinotech Import&Export Corporation

Product Name tert-Butyl hydroperoxide Synonyms tert-Butyl hydroperoxide;TBHP CAS: 75-91-2 MF: C4H10O2 MW: - EINECS:

Tert-Butyl Hydroperoxide CAS NO. 75-91-2

Cas:75-91-2

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:75-91-2

Cas:75-91-2

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Triumph International Development Limilted

Appearance:white or yellowish white flaky crystal Storage:Keep the sun from direct sunlight ;prevention against high temperature Package:As customer request Application:Used for research and industrial manufacture. Transportatio

tert-Butyl hydroperoxide

Cas:75-91-2

Min.Order:100 Metric Ton

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

tert-Butyl hydroperoxide

Cas:75-91-2

Min.Order:0 Metric Ton

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

tert-Butyl hydroperoxide

Cas:75-91-2

Min.Order:0

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Tert-Butyl Hydroperoxide

Cas:75-91-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

tert-Butyl hydroperoxide

Cas:75-91-2

Min.Order:1 Kilogram

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

tert-Butyl hydroperoxide

Cas:75-91-2

Min.Order:0

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Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

Jinlan Pharm-Drugs Technology Co.,Limited (with its export company Hangzhou Royall Import & Export Co.,Ltd.)is located in Hangzhou, Zhejiang Province. Neighboring Ningbo port, Shanghai port, Hangzhou Xiaoshan Int’l Airport and Shanghai Pudong Int’l A

(1s-trans)-2-[(phenylmethoxy)methyl]-3-cyclopenten-1-ol

Cas:75-91-2

Min.Order:0

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Type:Other

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Colorless to light yellow transparent liquid Storage:Store in a cool, low-temperature, well-ventilated non-combustible warehouse Package:170kg/plastic pail (Grade one peroxid, can no

tert-Butyl hydroperoxide(TBHP)

Cas:75-91-2

Min.Order:1 Kilogram

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

tert-Butyl hydroperoxide

Cas:75-91-2

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Hangzhou Dingyan Chem Co., Ltd

C-1513 TBHP,Tert Butyl Hydroperoxide Colour:60HazenMax. Fe:0.0003%Max.Appearance:Colorless to light yellow transparent liquid

tert-Butyl hydroperoxide

Cas:75-91-2

Min.Order:0

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Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers406.Safe and fa

Tert-Butyl hydroperoxide

Cas:75-91-2

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

tert-butyl hydroperoxide

Cas:75-91-2

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

tert-Butyl hydroperoxide

Cas:75-91-2

Min.Order:0

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 75-91-2 with best price

Cas:75-91-2

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

tert-Butyl hydroperoxide

Cas:75-91-2

Min.Order:0

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

tert-Butyl hydroperoxide 75-91-2

Cas:75-91-2

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Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Tert-butyl hydroperoxide 70%

Cas:75-91-2

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Hubei Langyou International Trading Co., Ltd

Tert-Butyl hydroperoxide,CAS 75-91-2 Application:Tert-Butyl hydroperoxide,CAS 75-91-2

Tert-Butyl hydroperoxide,CAS 75-91-2

Cas:75-91-2

Min.Order:0

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Type:Other

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Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl

tert-Butyl hydroperoxide

Cas:75-91-2

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Hunan Longxianng Runhui Trading Co.,Ltd

Tert-Butyl hydroperoxide,CAS 75-91-2Appearance:Clear liquid Storage:keep in dry place Package:Aluminum Foil Bag or as your requirement Application:75-91-2 Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airp

Tert-Butyl hydroperoxide,CAS 75-91-2

Cas:75-91-2

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Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

tert-Butyl hydroperoxide

Cas:75-91-2

Min.Order:0

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Beantown Chemical

in stock Application:75-91-2

tert-Butyl hydroperoxide solution, 70 wt. % in water

Cas:75-91-2

Min.Order:0

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Synthetic route

1-tert-butylperoxy-5-methyl-3,3-bistrifluoromethyl-1H-1,2-benziodoxole

1-tert-butylperoxy-5-methyl-3,3-bistrifluoromethyl-1H-1,2-benziodoxole

A

1,1,1,3,3,3-hexafluoro-2-(2-iodo-5-methylphenyl)-propan-2-ol
65653-64-7

1,1,1,3,3,3-hexafluoro-2-(2-iodo-5-methylphenyl)-propan-2-ol

B

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

Conditions
ConditionsYield
With 2,2,6,6-tetramethyl-piperidine-N-oxyl In cyclohexane at 81℃; for 30h; Decomposition;A 100%
B 30%
9-tert-butyl-10-methyl-9,10-dihydroacridine
123525-58-6

9-tert-butyl-10-methyl-9,10-dihydroacridine

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

10-methylacridanium

10-methylacridanium

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With 9,10-Dicyanoanthracene; oxygen; trifluoroacetic acid; scandium tris(trifluoromethanesulfonate) In [D3]acetonitrile at 24.85℃; for 1h; Irradiation;A n/a
B 100%
C n/a
tert-butylamine
75-64-9

tert-butylamine

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

Conditions
ConditionsYield
Stage #1: tert-butylamine With sodium hydrogen sulfate; 1,2-dibutoxyethane; lead(IV) tetraacetate; oxalic acid at 26℃; for 2.33333h;
Stage #2: With cobalt(II) nitrate at 45℃; for 4h; Temperature;
98.8%
tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

Conditions
ConditionsYield
With dihydrogen peroxide; trifluoroacetic acid In water at 5 - 90℃; for 0.0583333h; Reagent/catalyst; Temperature; Flow reactor;94.3%
With sulfuric acid; dihydrogen peroxide at 0 - 20℃; for 12h;59%
With ferrocenedicarboxylate; water; oxygen; dinitrogen monoxide at 20℃; Rate constant; Irradiation; pH 8; pulse radiolysis; var. ferrocenes;
cyclohexane
110-82-7

cyclohexane

1-tert-butylperoxy-5-methyl-3,3-bistrifluoromethyl-1H-1,2-benziodoxole
187939-68-0

1-tert-butylperoxy-5-methyl-3,3-bistrifluoromethyl-1H-1,2-benziodoxole

A

1,1,1,3,3,3-hexafluoro-2-(2-iodo-5-methylphenyl)-propan-2-ol
65653-64-7

1,1,1,3,3,3-hexafluoro-2-(2-iodo-5-methylphenyl)-propan-2-ol

B

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

C

1-iodocyclohexane
626-62-0

1-iodocyclohexane

D

1,1,1,3,3,3-hexafluoro-2-m-tolylpropan-2-ol

1,1,1,3,3,3-hexafluoro-2-m-tolylpropan-2-ol

Conditions
ConditionsYield
at 81℃; for 30h; Decomposition; Further byproducts given;A 3%
B 1%
C 94%
D 94%
methanol
67-56-1

methanol

t-butyl heptafluoroperoxybutyrate
91481-65-1

t-butyl heptafluoroperoxybutyrate

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

methyl heptafluorobutyrate
356-24-1

methyl heptafluorobutyrate

C

2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

Conditions
ConditionsYield
at 40℃; for 3h; Yield given. Yields of byproduct given;
In methanol at 10 - 40℃; for 3h; Rate constant; Kinetics; Thermodynamic data; ΔH(act.), ΔS(act.), various temperature;
Isopropylbenzene
98-82-8

Isopropylbenzene

acetone di-tert-butylperoxyketal
4262-61-7

acetone di-tert-butylperoxyketal

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

tert-butyl peroxyacetate
107-71-1

tert-butyl peroxyacetate

C

dicumene
1889-67-4

dicumene

D

tert-butyl cumyl peroxide
3457-61-2

tert-butyl cumyl peroxide

E

acetone
67-64-1

acetone

F

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
at 120℃; for 2h; Product distribution; Kinetics; Mechanism; rate constants, ΔH(excit.), ΔS(excit.);A 16 % Chromat.
B 14 % Chromat.
C 33 % Chromat.
D 52 % Chromat.
E 88 % Chromat.
F 110 % Chromat.
at 110℃; for 4h; Mechanism;
tert-Butyl peroxybenzoate
614-45-9

tert-Butyl peroxybenzoate

aluminum ethoxide
555-75-9

aluminum ethoxide

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

ethanol
64-17-5

ethanol

C

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
With sulfuric acid Product distribution; Mechanism; multistep reaction;
tert-Butyl peroxybenzoate
614-45-9

tert-Butyl peroxybenzoate

aluminum isopropoxide
555-31-7

aluminum isopropoxide

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

isopropyl alcohol
67-63-0

isopropyl alcohol

Conditions
ConditionsYield
With sulfuric acid Product distribution; Mechanism; multistep reaction;
tert-Butyl peroxybenzoate
614-45-9

tert-Butyl peroxybenzoate

aluminium propanolate
4073-85-2

aluminium propanolate

A

propan-1-ol
71-23-8

propan-1-ol

B

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

C

propionic acid
802294-64-0

propionic acid

Conditions
ConditionsYield
With sulfuric acid Product distribution; Mechanism; multistep reaction;
tert-Butyl peroxybenzoate
614-45-9

tert-Butyl peroxybenzoate

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

sodium benzoate
532-32-1

sodium benzoate

Conditions
ConditionsYield
With sodium hydroxide; cetyltrimethylammonium chloride at 25℃; Rate constant; basic hydrolysis with different cationic micelles with or without NaOH;
2,3-Dimethyl-2-butene
563-79-1

2,3-Dimethyl-2-butene

azo-t-butane
15464-01-4

azo-t-butane

A

2,3-dimethyl-2,3-epoxybutane
5076-20-0

2,3-dimethyl-2,3-epoxybutane

B

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

C

formaldehyd
50-00-0

formaldehyd

D

acetone
67-64-1

acetone

E

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With oxygen In gas at 69.9℃; under 200 Torr; for 1.33333h; Product distribution; Irradiation; different time, temperature and oxygen pressure;
tert-butylperoxytrimethylsilane
3965-63-7

tert-butylperoxytrimethylsilane

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

tertiary butyl chloride
507-20-0

tertiary butyl chloride

C

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

D

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

E

isobutene
115-11-7

isobutene

F

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With phosphorus trichloride In nonane Kinetics; Mechanism; other solvent : butyl methacrylate;A 0.56 (unit not given)
B 0.04 (unit not given)
C 0.11 (unit not given)
D 0.46 (unit not given)
E 0.09 (unit not given)
F 0.04 (unit not given)
tert-butyl peroxyacetate
107-71-1

tert-butyl peroxyacetate

aluminum ethoxide
555-75-9

aluminum ethoxide

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

ethanol
64-17-5

ethanol

C

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
With sulfuric acid Product distribution; multistep reaction;
tert-butyl peroxyacetate
107-71-1

tert-butyl peroxyacetate

aluminum isopropoxide
555-31-7

aluminum isopropoxide

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

acetic acid
64-19-7

acetic acid

C

isopropyl alcohol
67-63-0

isopropyl alcohol

Conditions
ConditionsYield
With sulfuric acid Product distribution; Mechanism; multistep reaction;
tert-butyl peroxyacetate
107-71-1

tert-butyl peroxyacetate

aluminium propanolate
4073-85-2

aluminium propanolate

A

propan-1-ol
71-23-8

propan-1-ol

B

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

C

propionic acid
802294-64-0

propionic acid

Conditions
ConditionsYield
With sulfuric acid Product distribution; Mechanism; multistep reaction;
acetone di-tert-butylperoxyketal
4262-61-7

acetone di-tert-butylperoxyketal

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With sulfuric acid; water In 1,4-dioxane at 25℃; Kinetics; Mechanism; other aliphatic ketone di-tert-butylperoxyketals, induction and steric parameters of substituents at the carbonyl group of the ketones;
With sulfuric acid; water In 1,4-dioxane at 25℃; Equilibrium constant;
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

cyclohexene
110-83-8

cyclohexene

1-(tert-butylperoxy)-2-cyclohexene
51437-25-3

1-(tert-butylperoxy)-2-cyclohexene

Conditions
ConditionsYield
In decane; toluene at 30℃;100%
With [Cu(4-methyl-1,3-bis(2-pyridylimino)isoindole)(OAc)] In water86%
With pyrazolate-based cobalt(II)-containing MFU-1 metal-organic framework at 70℃; for 2h;11.9%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

2,6-di-tert-butyl-4-methyl-phenol
128-37-0

2,6-di-tert-butyl-4-methyl-phenol

2,6-di-tert-butyl-4-(tert-butylperoxy)-4-methylcyclohexa-2,5-dien-1-one
13154-57-9

2,6-di-tert-butyl-4-(tert-butylperoxy)-4-methylcyclohexa-2,5-dien-1-one

Conditions
ConditionsYield
With dirhodium(II) tetrakis(caprolactam) In water; 1,2-dichloro-ethane at 40℃; for 0.75h; chemoselective reaction;99%
With tetra-(n-butyl)ammonium iodide In nonane; 1,2-dichloro-ethane at 20℃; for 24h;99%
With cobalt naphthenate
(electrochemical oxidation);
With sodium chloride; sodium hydroxide; benzyl alcohol In water at 70℃; for 12h; Sealed tube; Green chemistry;
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

phenyl isocyanate
103-71-9

phenyl isocyanate

phenyl-peroxycarbamic acid tert-butyl ester
20666-88-0

phenyl-peroxycarbamic acid tert-butyl ester

Conditions
ConditionsYield
With copper acetylacetonate In tetrachloromethane at 20℃; for 1h; Product distribution; Mechanism;99%
With copper acetylacetonate In benzene at 30℃; for 0.25h;29%
With copper acetylacetonate In tetrachloromethane at 20℃; for 1h; Product distribution; Mechanism; other solvent (benzene), other temperature (30 deg C);6%
With triethylamine In Petroleum ether
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

3,5-di-tert-butyl-2-hydroxybenzonitrile
95091-86-4

3,5-di-tert-butyl-2-hydroxybenzonitrile

2,4-di-tert-butyl-4-tert-butylperoxy-6-cyano-2,5-cyclohexadienone

2,4-di-tert-butyl-4-tert-butylperoxy-6-cyano-2,5-cyclohexadienone

Conditions
ConditionsYield
With salcomine In dichloromethane for 0.333333h; Ambient temperature;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

oct-1-ene
111-66-0

oct-1-ene

1,2-Epoxyoctane
2984-50-1

1,2-Epoxyoctane

Conditions
ConditionsYield
[Ti(NMe2){c-C6H11)7Si7O12}] at 79.85℃; Kinetics; Further Variations:; Catalysts; Epoxidation;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

Cbz-(L)-Glu-OBn
3705-42-8

Cbz-(L)-Glu-OBn

2-benzyloxycarbonylamino-4-tert-butylperoxycarbonyl-butyric acid benzyl ester

2-benzyloxycarbonylamino-4-tert-butylperoxycarbonyl-butyric acid benzyl ester

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In decane; acetonitrile at -20 - 20℃; for 4h;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

{(C6H4CH2N(CH3)2)(C6H4(O)CH2N(CH3)2)Pd}

{(C6H4CH2N(CH3)2)(C6H4(O)CH2N(CH3)2)Pd}

{(C6H4(O)(CH2N(CH3)2))2Pd}
63232-39-3

{(C6H4(O)(CH2N(CH3)2))2Pd}

Conditions
ConditionsYield
bis(acetylacetonate)oxovanadium In chloroform-d1 react. with 2.0 equiv. Me3COOH and 2mol% VO(acac)2 at 20°C;99%
In chloroform-d1; dichloromethane addn. of CH2Cl2 and the peroxide to the Pd-complex in CDCl3, react. for 5 d;60%
bis(acetylacetonate)oxidovanadium(IV) In chloroform-d1; dichloromethane addn. of CH2Cl2 and the peroxide to the Pd-complex and catalyst in CDCl3, react. for 1.5 h;>99
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

1-benzyl N-carbobenzoxy-L-glutamate
65706-99-2

1-benzyl N-carbobenzoxy-L-glutamate

(2R)-benzyl 2-(benzyloxycarbonylamino)-5-(tert-butylperoxy)-5-oxopentanoate
592532-30-4

(2R)-benzyl 2-(benzyloxycarbonylamino)-5-(tert-butylperoxy)-5-oxopentanoate

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In decane; dichloromethane; acetonitrile at -20 - 20℃; for 4h;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

N-(4-chloro-6-(1,4-dioxa-8-azaspiro[4.5]decan-8-yl)-1,3,5-triazin-2-yl)-N-(prop-2-ynyl)-methanesulfonamide
1258621-51-0

N-(4-chloro-6-(1,4-dioxa-8-azaspiro[4.5]decan-8-yl)-1,3,5-triazin-2-yl)-N-(prop-2-ynyl)-methanesulfonamide

N-(4-(tert-butylperoxy)-6-(1,4-dioxa-8-azaspiro[4.5]decan-8-yl)-1,3,5-triazin-2-yl)-N-(prop-2-ynyl)methanesulfonamide
1258621-53-2

N-(4-(tert-butylperoxy)-6-(1,4-dioxa-8-azaspiro[4.5]decan-8-yl)-1,3,5-triazin-2-yl)-N-(prop-2-ynyl)methanesulfonamide

Conditions
ConditionsYield
With potassium hydroxide In water; acetonitrile at 0 - 50℃; Inert atmosphere;99%
styrene
292638-84-7

styrene

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

pivalaldehyde
630-19-3

pivalaldehyde

(1-(tert-butylperoxy)-3,3-dimethylbutyl)benzene
1312775-15-7

(1-(tert-butylperoxy)-3,3-dimethylbutyl)benzene

Conditions
ConditionsYield
With iron(II) chloride In decane; acetonitrile at 85℃; for 1h; Inert atmosphere;99%
With iron(II) chloride In decane; ethyl acetate at 80℃; for 12h; Inert atmosphere; Sealed tube; Green chemistry;79%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

2-(4-chlorophenyl)-1,3-dioxolane
2403-54-5

2-(4-chlorophenyl)-1,3-dioxolane

2-(tert-butylperoxy)-2-(4-chlorophenyl)-1,3-dioxolane
1449315-81-4

2-(tert-butylperoxy)-2-(4-chlorophenyl)-1,3-dioxolane

Conditions
ConditionsYield
With iron(III)-acetylacetonate In decane; acetonitrile at 20 - 80℃; for 3h; Molecular sieve; Inert atmosphere;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

tert-butyl (2-methoxyphenyl)methyl ether
143741-85-9

tert-butyl (2-methoxyphenyl)methyl ether

tert-butyl (tert-butylperoxy)(2-methoxyphenyl)methyl ether
1449315-76-7

tert-butyl (tert-butylperoxy)(2-methoxyphenyl)methyl ether

Conditions
ConditionsYield
With iron(III)-acetylacetonate In decane; acetonitrile at 20 - 80℃; for 3h; Molecular sieve; Inert atmosphere;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

benzyl methacrylate
2495-37-6

benzyl methacrylate

pivalaldehyde
630-19-3

pivalaldehyde

C19H30O4
1415690-07-1

C19H30O4

Conditions
ConditionsYield
With iron(II) chloride In decane; acetonitrile at 85℃; for 1h; Inert atmosphere;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

4-methoxybenzoic acid
100-09-4

4-methoxybenzoic acid

methyl 4-methoxybenzoate
121-98-2

methyl 4-methoxybenzoate

Conditions
ConditionsYield
With copper quinolate In water; dimethyl sulfoxide at 120℃; for 24h; Solvent;99%
With copper doped mesoporous polymelamine-formaldehyde In water; dimethyl sulfoxide at 100℃; for 16h; Catalytic behavior;97%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

benzaldehyde
100-52-7

benzaldehyde

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

Conditions
ConditionsYield
Stage #1: tert.-butylhydroperoxide; benzaldehyde In water; dimethyl sulfoxide
Stage #2: In water; dimethyl sulfoxide at 100℃; for 20h; Sealed tube;
99%
With copper (II)-fluoride In water; dimethyl sulfoxide at 120℃; for 12h; Schlenk technique; Inert atmosphere; Green chemistry;65%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

3-Methylindole
83-34-1

3-Methylindole

isovaleraldehyde
590-86-3

isovaleraldehyde

1-(1-(tert-butylperoxy)-3-methylbutyl)-3-methyl-indole

1-(1-(tert-butylperoxy)-3-methylbutyl)-3-methyl-indole

Conditions
ConditionsYield
With toluene-4-sulfonic acid In dichloromethane at 20℃; for 0.5h; chemoselective reaction;99%
With toluene-4-sulfonic acid In dichloromethane at 20℃; for 0.5h;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

2-(2-(5-methoxy-1H-indol-3-yl)ethyl)isoindoline-1,3-dione
55747-66-5

2-(2-(5-methoxy-1H-indol-3-yl)ethyl)isoindoline-1,3-dione

isovaleraldehyde
590-86-3

isovaleraldehyde

C28H34N2O5

C28H34N2O5

Conditions
ConditionsYield
With toluene-4-sulfonic acid In dichloromethane at 20℃; for 0.5h; chemoselective reaction;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}

bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}

2-(phenylthio)ethanol
699-12-7

2-(phenylthio)ethanol

Rh2(α,α,α′,α′-tetramethyl-1,3-benzenedipropanoate)2-bis-2-(phenylsulfinyl)ethanol

Rh2(α,α,α′,α′-tetramethyl-1,3-benzenedipropanoate)2-bis-2-(phenylsulfinyl)ethanol

Conditions
ConditionsYield
In dichloromethane at 20℃; for 9h;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

tri(p-tolyl)antimony
5395-43-7

tri(p-tolyl)antimony

2,4,6-tribromophenol
118-79-6

2,4,6-tribromophenol

benzene
71-43-2

benzene

μ2-oxobis[(2,4,6-tribromophenoxo)tris(para-tolyl)antimony] benzene monosolvate

μ2-oxobis[(2,4,6-tribromophenoxo)tris(para-tolyl)antimony] benzene monosolvate

Conditions
ConditionsYield
Stage #1: tert.-butylhydroperoxide; tri(p-tolyl)antimony; 2,4,6-tribromophenol In diethyl ether at 20℃; for 24h;
Stage #2: benzene In n-heptane
99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

tris(3-fluorophenyl)antimony

tris(3-fluorophenyl)antimony

Pentafluorobenzoic acid
602-94-8

Pentafluorobenzoic acid

μ2-oxobis[pentafluorobenzoatetri(3-fluorophenyl)-antimony]

μ2-oxobis[pentafluorobenzoatetri(3-fluorophenyl)-antimony]

Conditions
ConditionsYield
In diethyl ether at 20℃; for 24h;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

pentafluoropropionic acid
422-64-0

pentafluoropropionic acid

tri(p-tolyl)antimony
5395-43-7

tri(p-tolyl)antimony

μ2-oxobis[tri(4-methylphenyl)pentafluoropropanoateantimony]

μ2-oxobis[tri(4-methylphenyl)pentafluoropropanoateantimony]

Conditions
ConditionsYield
In diethyl ether at 20℃; for 24h;99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

2-chloro-benzaldehyde
89-98-5

2-chloro-benzaldehyde

methyl chlorobenzoate
610-96-8

methyl chlorobenzoate

Conditions
ConditionsYield
Stage #1: tert.-butylhydroperoxide; 2-chloro-benzaldehyde In water; dimethyl sulfoxide
Stage #2: In water; dimethyl sulfoxide at 100℃; for 20h; Sealed tube;
99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

2-fluoro-6-(trifluoromethyl)benzoic acid
32890-94-1

2-fluoro-6-(trifluoromethyl)benzoic acid

methyl 2-fluoro-6-(trifluoromethyl)benzoate
153556-50-4

methyl 2-fluoro-6-(trifluoromethyl)benzoate

Conditions
ConditionsYield
Stage #1: tert.-butylhydroperoxide; 2-fluoro-6-(trifluoromethyl)benzoic acid In water; dimethyl sulfoxide
Stage #2: In water; dimethyl sulfoxide at 100℃; for 20h; Sealed tube;
99%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

2-ethylhexanoic acid chloride
760-67-8

2-ethylhexanoic acid chloride

tertiary butyl per-2-ethylhexanoate
3006-82-4

tertiary butyl per-2-ethylhexanoate

Conditions
ConditionsYield
With potassium hydroxide In water at 27 - 35℃;98.5%
With potassium hydroxide In water at 27 - 35℃; Product distribution / selectivity; Industry scale;98.5%
In water at 40 - 45℃; Product distribution / selectivity;90%
With 1-methyl-1H-imidazole at 25 - 35℃; Product distribution / selectivity;88%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

isononanoyl chloride
36727-29-4

isononanoyl chloride

tert-butyl peroxy-3,5,5-trimethylhexanoate

tert-butyl peroxy-3,5,5-trimethylhexanoate

Conditions
ConditionsYield
With potassium hydroxide In water at 25℃;98.2%
With potassium hydroxide In water at 25℃; Product distribution / selectivity; Industry scale;98.2%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

2-Iodobenzoyl chloride
609-67-6

2-Iodobenzoyl chloride

tert-butyl 2-iodobenzoperoxoate
10568-20-4

tert-butyl 2-iodobenzoperoxoate

Conditions
ConditionsYield
With pyridine; dichloromethane In dichloromethane at -20℃; for 4.5h; Inert atmosphere;98%
With pyridine In dichloromethane at -20 - 20℃; Oxidation;90%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

4-nitro-benzoyl chloride
122-04-3

4-nitro-benzoyl chloride

tert-butyl 4-nitrobenzoperoxoate
16166-61-3

tert-butyl 4-nitrobenzoperoxoate

Conditions
ConditionsYield
With pyridine In dichloromethane at -20 - 20℃; Oxidation;98%
Stage #1: 4-nitro-benzoyl chloride With pyridine In dichloromethane at -20℃; for 0.166667h;
Stage #2: tert.-butylhydroperoxide In dichloromethane at -20℃; for 4h; Further stages.;
98%
With pyridine In dichloromethane at -20℃; for 4h; Inert atmosphere;98%
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