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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Di-tert-butyl peroxide Manufacturer/High quality/Best price/In stock

Cas:110-05-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Di-Tert-Butyl Peroxide supplier in China

Cas:110-05-4

Min.Order:1 Kilogram

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Type:Manufacturers

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Hefei TNJ chemical industry co.,ltd

1,ISO Certificate 2,Factory price 3,Free sample and Fast delivery Appearance:Colorless transparent liquid Storage:All products should be stored at a dry and ventilated location away from fire and other dangerous goods, and should avoid direct sunl

Di-tert-butyl peroxide,CAS 110-05-4

Cas:110-05-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production Cyromazine、lead diacetate trihydrate /Lead acetate trihydrateC、 2-phenylacetamide 、 4-Aminophenyl-1-phenethylpiperidine 、Citric acid monohydrate 、 Citric acid/c

Di-tert-butyl peroxide 110-05-4

Cas:110-05-4

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Trading Company

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Ality Chemical Corporation

We are manufacturer of this product. If you are looking for the material's manufacturer or supplier in China, Ality Group is your best choice. Specifications of our Di-tert-butyl peroxide CAS 110-05-4: Items

Factory Supply Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:1 Gram

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Type:Other

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Henan Tianfu Chemical Co., Ltd.

High quality,low price Di-tert-butyl peroxide Basic information Product Name: Di-tert-butyl peroxide Synonyms: T-BUTYL PEROXIDE;TERT-BUTYL PEROXIDE;(tert-C4H9O)2;(tributyl)peroxide;2-(

Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:1 Metric Ton

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Henan Sinotech Import&Export Corporation

Chemical Name: Di-Tert Butyl Peroxide Alias: DTBP CAS No.: 110-05-4 Molecular formula: C8H18O2 Molecular weight: 146.2 Brief Introduction: SF-A is a light yellow transparent liquid, is a dialkyl organic peroxides. Mainly used as a cross-l

Di-Tert Butyl Peroxide

Cas:110-05-4

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shandong Hanjiang Chemical Co., Ltd.

Company profile Shandong Hanjiang Chemical Co., Ltd. is located in Qilu Petrochemical Industrial Park, Zibo City, Shandong Province. The best-selling products include DMF, dichloromethane, acetonitrile, glacial acetic acid, cyclohexanone, cyclohexan

Di-tert-butyl peroxide Manufacturer/High quality/Best price/In stock CAS NO.110-05-4

Cas:110-05-4

Min.Order:1 Kilogram

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Di-tert-butyl peroxide with CAS:110-05-4

Cas:110-05-4

Min.Order:1 Metric Ton

FOB Price: $3145.0 / 3788.0

Type:Trading Company

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Di-tert-butyl peroxide CAS NO.110-05-4 CAS NO.110-05-4

Cas:110-05-4

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Lonwin Chemical Group Limited

Di-tert-butyl peroxide CAS: 110-05-4 Specification items specification results appearance clear liquid clear liquid hema content (%, min) 98 98.2 color (apha, max) 30 16 residual

Factory supply Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:0 Metric Ton

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:0

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Type:Lab/Research institutions

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Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

DI TERT BUTYL PEROXIDE

Cas:110-05-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Di-Tert-Butyl Peroxide

Cas:110-05-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediat

Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

Di-tert-butyl peroxideCAS NO.: 110-05-4

Cas:110-05-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Senova Technology Company Limited

Good price, high purity, mature production technology, accept custom synthesis per customer's requirements Package:As per Customer‘ requirements Application:Pharmaceutical intermediate

Tet Butyl Peroxide

Cas:110-05-4

Min.Order:0

Negotiable

Type:Other

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:0

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Type:Other

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Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers625.Safe and fa

Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:0

Negotiable

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Di-tert-butyl Peroxide

Cas:110-05-4

Min.Order:0

Negotiable

Type:Manufacturers

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:0

Negotiable

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 110-05-4 with competitive price

Cas:110-05-4

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Di-tert-butyl peroxide

Cas:110-05-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Di-Tert-Butyl Peroxide

Cas:110-05-4

Min.Order:0

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Type:Other

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Hubei Langyou International Trading Co., Ltd

Di-tert-butyl peroxide,CAS 110-05-4 Application:Di-tert-butyl peroxide,CAS 110-05-4

Di-tert-butyl peroxide,CAS 110-05-4

Cas:110-05-4

Min.Order:0

Negotiable

Type:Other

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Koning Pharmchem Co., Ltd.

Di-tert-butyl peroxide CAS NO.110-05-4Appearance:colourless liquid Storage:Dry and ventilated Package:Standard or as customer's require Application:intermediates Transportation:Delivery by EMS, DHL, FEDEX, UPS, TNT

Di-tert-butyl peroxide CAS NO.110-05-4

Cas:110-05-4

Min.Order:0

Negotiable

Type:Trading Company

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Hunan Longxianng Runhui Trading Co.,Ltd

Di-tert-butyl peroxide,CAS 110-05-4Appearance:Clear liquid Storage:keep in dry place Package:Aluminum Foil Bag or as your requirement Application:110-05-4 Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airp

Di-tert-butyl peroxide,CAS 110-05-4

Cas:110-05-4

Min.Order:0

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Synthetic route

tert-butylamine
75-64-9

tert-butylamine

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

Conditions
ConditionsYield
Stage #1: tert-butylamine With potassium sulfate; aluminum isopropoxide at 10℃; for 2h;
Stage #2: With nickel(II) fluoride for 4h; Temperature; Concentration;
98.2%
tert-butyl alcohol
75-65-0

tert-butyl alcohol

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

Conditions
ConditionsYield
With sulfuric acid; dihydrogen peroxide at 35 - 45℃; for 2h;96%
With dihydrogen peroxide In Petroleum ether at 70 - 80℃; for 4h; Reagent/catalyst; Temperature;95.3%
With sulfuric acid; dihydrogen peroxide at 29 - 39℃; for 2h; Cooling;
With dihydrogen peroxide at 60℃; Temperature; Large scale;
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

Martins sulfurane
32133-82-7

Martins sulfurane

A

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

B

diphenyl sulfide
139-66-2

diphenyl sulfide

C

1,1'-sulfinylbisbenzene
945-51-7

1,1'-sulfinylbisbenzene

D

diphenyl sulphone
127-63-9

diphenyl sulphone

E

1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol
718-64-9

1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol

F

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
With 2,2-diphenyl-1-picrylhydrazine In chloroform-d1 at -78℃; Product distribution; chemiluminescence, other peroxides;A n/a
B 2%
C 94%
D 2%
E n/a
F n/a
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

tert-Butyl 2,2,2-trichloroacetimidate
98946-18-0

tert-Butyl 2,2,2-trichloroacetimidate

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In pentane 1.) -5 deg C, 15 min, 2.) up to r.t.;63%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

tert-butyl hydrogen sulfate
17011-26-6

tert-butyl hydrogen sulfate

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

Conditions
ConditionsYield
With sulfuric acid
tert-butyl hydrogen sulfate
17011-26-6

tert-butyl hydrogen sulfate

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

Conditions
ConditionsYield
With dihydrogen peroxide at 0℃;
With dihydrogen peroxide In water at 25℃; for 7.91667h; Temperature;A 65.94 %Chromat.
B 23.92 %Chromat.
tert-butyl hydrogen sulfate
17011-26-6

tert-butyl hydrogen sulfate

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

Conditions
ConditionsYield
With sulfuric acid; dihydrogen peroxide
Isobutane
75-28-5

Isobutane

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

Conditions
ConditionsYield
With hydrogen bromide; oxygen at 158℃;
With hydrogen bromide; oxygen at 158℃;
tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

Conditions
ConditionsYield
With dihydrogen peroxide; acid
With sulfuric acid; water; dihydrogen peroxide
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

A

methanol
67-56-1

methanol

B

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

C

acetone
67-64-1

acetone

D

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
With antimonypentachloride In acetonitrile at 52℃; Product distribution; Thermodynamic data; other time, other reagents, activation energy of total decomposition and of homolysis;
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

A

methane
34557-54-5

methane

B

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

C

acetone
67-64-1

acetone

D

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
With perchloric acid; cyclohexanone In acetonitrile at 302℃; Rate constant; Mechanism; kinetic curves of decomposition; in presence of methyl ethyl ketone instead of cyclohexanone;
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

A

2,2'-oxybis(2-methyl-propane)
6163-66-2

2,2'-oxybis(2-methyl-propane)

B

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

C

acetone
67-64-1

acetone

D

isobutene
115-11-7

isobutene

E

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With vanadia; silica gel In benzene at 60℃; for 2h; Rate constant; Mechanism; other metal catalysts;
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

A

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

B

acetone
67-64-1

acetone

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With dicobalt octacarbonyl In benzene at 6 - 8℃; for 0.5h; Product distribution; various amounts of Co2(CO)8, Fe(CO)5; various amounts of educt;A 1 % Chromat.
B 2 % Chromat.
C 88 % Chromat.
With 3,5-di-tert-butyl-1,2-benzoquinone In toluene at 70℃; Reduction; addition;
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

A

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

B

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
cobalt(II) phthalocyanine In various solvent(s) at 40℃; Rate constant; Product distribution; use of iron phthalocyanine, 20 deg C, effects of added various solvents;
With water; oxygen In chlorobenzene at 70℃; for 2h; Product distribution; Further Variations:; Reagents; Decomposition;
tert-butylperoxytrimethylsilane
3965-63-7

tert-butylperoxytrimethylsilane

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

tertiary butyl chloride
507-20-0

tertiary butyl chloride

C

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

D

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

E

isobutene
115-11-7

isobutene

F

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With phosphorus trichloride In nonane Kinetics; Mechanism; other solvent : butyl methacrylate;A 0.56 (unit not given)
B 0.04 (unit not given)
C 0.11 (unit not given)
D 0.46 (unit not given)
E 0.09 (unit not given)
F 0.04 (unit not given)
di-t-butyldiazene
927-83-3

di-t-butyldiazene

A

methanol
67-56-1

methanol

B

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

C

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

D

acetone
67-64-1

acetone

E

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With oxygen at 59.9℃; Quantum yield; Mechanism; Irradiation; Other temperatures (298, 373 K), the effect of added t-butyl hydroperoxide.;
tert-butylperoxyl
3395-62-8

tert-butylperoxyl

A

methanol
67-56-1

methanol

B

formaldehyd
50-00-0

formaldehyd

C

methyl tert-butyl peroxide
51392-67-7

methyl tert-butyl peroxide

D

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

E

acetone
67-64-1

acetone

F

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In water at 19.9℃; Rate constant; Product distribution; Mechanism;A 0.01 mmol
B 0.37 mmol
C 0.08 mmol
D 0.08 mmol
E 0.98 mmol
F 0.56 mmol
di-tert-butoxydiazene
14976-54-6, 82554-97-0

di-tert-butoxydiazene

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

Conditions
ConditionsYield
In tert-butyl alcohol at 70℃; var solv.: c-C6D12 at 62.2 degC; cage effect determined;
di-tert-butyl hyponitrite
14976-54-6, 82554-97-0

di-tert-butyl hyponitrite

A

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

B

acetone
67-64-1

acetone

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With oxygen; sodium chloride; egg lecithin at 30℃; under 760 Torr; for 600h; Product distribution; other solvent, reagent, concentrations;
tert-Butyl-(tert-butylphenoxy)peracetat
52946-63-1

tert-Butyl-(tert-butylphenoxy)peracetat

A

formaldehyd
50-00-0

formaldehyd

B

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In various solvent(s) at 40 - 60℃; Rate constant; Thermodynamic data; E(activ.) and preexponential factor;
2-tert-butylperoxy-2-methyl-propyl
54156-75-1

2-tert-butylperoxy-2-methyl-propyl

A

2-methyl-1,2-epoxypropane
558-30-5

2-methyl-1,2-epoxypropane

B

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

Conditions
ConditionsYield
With tri-n-butyl-tin hydride In benzene at 24.9℃; Rate constant; Irradiation;
2,6-Di-tert-butyl-(N-tert-butylnitrono)phenoxyl
54749-42-7

2,6-Di-tert-butyl-(N-tert-butylnitrono)phenoxyl

A

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

B

acetone
67-64-1

acetone

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With tert.-butylhydroperoxide In benzene for 4h; Product distribution; Ambient temperature; other solvents: chlorbenzene, freone-1,1,3; other temperatures: 70 deg C for 30 min;
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

A

methanol
67-56-1

methanol

B

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

C

acetone
67-64-1

acetone

D

isobutene
115-11-7

isobutene

E

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With aluminium trichloride In ethyl acetate at 69.9℃; Product distribution; Kinetics; Thermodynamic data; variation of temperature, further chlorides of elements of group III or IV;
Di-t-butyl ketone
815-24-7

Di-t-butyl ketone

A

tetramethyl-2,2,3,3 butane
594-82-1

tetramethyl-2,2,3,3 butane

B

Isobutane
75-28-5

Isobutane

C

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

D

isobutene
115-11-7

isobutene

E

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With oxygen In decane at 323℃; Product distribution; Mechanism; Kinetics; Irradiation; other temperatures: 348, 373, 398 K;
azo-t-butane
15464-01-4

azo-t-butane

A

tetramethyl-2,2,3,3 butane
594-82-1

tetramethyl-2,2,3,3 butane

B

Isobutane
75-28-5

Isobutane

C

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

D

isobutene
115-11-7

isobutene

E

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With oxygen In decane at 323℃; Product distribution; Mechanism; Kinetics; Irradiation; other temperatures: 298, 348 K;
Isobutane
75-28-5

Isobutane

A

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

B

acetone
67-64-1

acetone

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With [5,10,15,20-tetrakis(heptafluoropropyl)porphinato]iron(II)-(3-fluoropyridine)2; oxygen In benzene at 80℃; under 6464.3 Torr; for 91h; Product distribution; Mechanism; other reagent: (5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(II) bis(3-fluoropyridine) complex;A 7.8 % Turnov.
B 8.1 % Turnov.
C 84 % Turnov.
With oxygen; [5,10,15,20-tetrakis(pentafluorophenyl)porphinato]iron(II)-(3-fluoropyridine)2 In benzene at 80℃; under 6464.3 Torr; for 20h; other catalyst: (5,10,15,20-tetrakis(heptafluoropropyl)porphyrinato)iron(II) bis(3-fluoropyridine) complex;A 10.3 % Turnov.
B 3.6 % Turnov.
C 86 % Turnov.
di-tert-butylhydroperoxide
4444-61-5

di-tert-butylhydroperoxide

A

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

B

acetone
67-64-1

acetone

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In dichloromethane at -20.5 - 17℃; Kinetics; Mechanism; Rate constant;
tert-butoxy radical
3141-58-0

tert-butoxy radical

A

methyl radical
2229-07-4

methyl radical

B

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

C

acetone
67-64-1

acetone

Conditions
ConditionsYield
In tetrachloromethane at 295℃; Rate constant; other solvents, other temperature;
sulfuric acid
7664-93-9

sulfuric acid

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

tert-butyl alcohol
75-65-0

tert-butyl alcohol

A

tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

B

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

2C17H13Cl4N2(1-)*2Cu(1+)*C6H6

2C17H13Cl4N2(1-)*2Cu(1+)*C6H6

[Cl2NN]Cu-OtBu
1215209-38-3

[Cl2NN]Cu-OtBu

Conditions
ConditionsYield
With pyridine In fluorobenzene at 10℃; Kinetics; Temperature; Concentration;100%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

copper hydroxide
20427-59-2

copper hydroxide

copper(II) oxide

copper(II) oxide

Conditions
ConditionsYield
Stage #1: di-tert-butyl peroxide; copper hydroxide In water at 60℃; for 0.5h; Inert atmosphere;
Stage #2: In water for 5h; Sonication; Inert atmosphere;
100%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

4,4-dimethyl-cyclohexanol
932-01-4

4,4-dimethyl-cyclohexanol

ethyl acrylate
140-88-5

ethyl acrylate

8,8-dimethyl-1-oxa-spiro[4.5]decan-2-one
96517-19-0

8,8-dimethyl-1-oxa-spiro[4.5]decan-2-one

Conditions
ConditionsYield
Stage #1: di-tert-butyl peroxide; 4,4-dimethyl-cyclohexanol; ethyl acrylate at 50 - 160℃; for 4.16667h;
Stage #2: With sodium hydroxide; water In tert-butyl methyl ether at 40℃;
Stage #3: With sulfuric acid In tert-butyl methyl ether; water pH=1;
96.3%
titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

aqueous 3N-K2 CO3

aqueous 3N-K2 CO3

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

water
7732-18-5

water

phytol
150-86-7

phytol

(2S,3S)-epoxy-(3S,7R,11R)-3,7,11,15-tetramethylhexadecane-1-ol

(2S,3S)-epoxy-(3S,7R,11R)-3,7,11,15-tetramethylhexadecane-1-ol

Conditions
ConditionsYield
silica gel In diethyl ether; dichloromethane95%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

methyl chlorobenzoate
610-96-8

methyl chlorobenzoate

Conditions
ConditionsYield
With copper(l) chloride In chlorobenzene at 130℃; for 12h; Schlenk technique; Inert atmosphere;95%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

t-butyl 4-methoxybenzoate
833-79-4

t-butyl 4-methoxybenzoate

Conditions
ConditionsYield
With copper(I) bromide In hexane at 50℃; for 5h; Inert atmosphere;95%
tetrahydrofuran
109-99-9

tetrahydrofuran

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

p-ethoxycarbonylphenyl isocyanate
30806-83-8

p-ethoxycarbonylphenyl isocyanate

ethyl 4-((tert-butoxycarbonyl)(tetrahydrofuran-2-yl)amino)benzoate

ethyl 4-((tert-butoxycarbonyl)(tetrahydrofuran-2-yl)amino)benzoate

Conditions
ConditionsYield
With copper(l) chloride at 130℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;95%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

N-methoxy-2-methylbenzamide
57139-25-0

N-methoxy-2-methylbenzamide

C13H17NO2

C13H17NO2

Conditions
ConditionsYield
With palladium diacetate; trifluoroacetic acid In cyclohexane at 100℃; for 0.5h;94%
tetrahydrofuran
109-99-9

tetrahydrofuran

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

p-trifluoromethyl-phenylisocyanate
1548-13-6

p-trifluoromethyl-phenylisocyanate

tert-butyl (tetrahydrofuran-2-yl)(4-(trifluoromethyl)phenyl)carbamate

tert-butyl (tetrahydrofuran-2-yl)(4-(trifluoromethyl)phenyl)carbamate

Conditions
ConditionsYield
With copper(l) chloride at 130℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;94%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

4-ethoxybenzaldehyde
10031-82-0

4-ethoxybenzaldehyde

C13H18O3
1409654-77-8

C13H18O3

Conditions
ConditionsYield
With copper(I) bromide In hexane at 50℃; for 5h; Inert atmosphere;93%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

Methyl phenyl sulfone
3112-85-4

Methyl phenyl sulfone

Conditions
ConditionsYield
In water at 100℃; for 12h; Sealed tube;93%
With water at 110℃; for 12h; Temperature; Sealed tube; Green chemistry;93%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

[(C5HiPr4)Sm(μ-I)(THF)2]2
372521-42-1

[(C5HiPr4)Sm(μ-I)(THF)2]2

(C5HiPr4)SmIOtBu(THF)
372521-43-2

(C5HiPr4)SmIOtBu(THF)

Conditions
ConditionsYield
In toluene Sm-complex and ligand were loaded in flask, toluene was condensed at -20°C, stirred for 10 min at room temp.; toluene was removed;92%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

3,4-dimethoxy-benzaldehyde
120-14-9

3,4-dimethoxy-benzaldehyde

3,4-dimethoxybenzoic acid t-butyl ester

3,4-dimethoxybenzoic acid t-butyl ester

Conditions
ConditionsYield
With copper(I) bromide In hexane at 50℃; for 5h; Inert atmosphere;92%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

sodium 4-methoxybenzenesulfinate
6462-50-6

sodium 4-methoxybenzenesulfinate

p-anisyl methyl sulfone
3517-90-6

p-anisyl methyl sulfone

Conditions
ConditionsYield
In water at 80℃; for 12h; Sealed tube;92%
With water at 110℃; for 12h; Sealed tube; Green chemistry;92%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

sodium 4-bromobenzenesulfinate
34176-08-4

sodium 4-bromobenzenesulfinate

4-bromoohenyl methyl sulfone
3466-32-8

4-bromoohenyl methyl sulfone

Conditions
ConditionsYield
With water at 110℃; for 12h; Sealed tube; Green chemistry;92%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

sodium 4-iodobenzenesulfinate

sodium 4-iodobenzenesulfinate

1-iodo-4-(methylsulfonyl)benzene
64984-08-3

1-iodo-4-(methylsulfonyl)benzene

Conditions
ConditionsYield
With water at 110℃; for 12h; Sealed tube; Green chemistry;92%
tetrahydrofuran
109-99-9

tetrahydrofuran

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

4-acetylphenyl isocyanate
49647-20-3

4-acetylphenyl isocyanate

tert-butyl (4-acetylphenyl)(tetrahydrofuran-2-yl)carbamate

tert-butyl (4-acetylphenyl)(tetrahydrofuran-2-yl)carbamate

Conditions
ConditionsYield
With copper(l) chloride at 130℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;92%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

β-naphthaldehyde
66-99-9

β-naphthaldehyde

tert-butyl naphthalene-2-carboperoxoate
34304-74-0

tert-butyl naphthalene-2-carboperoxoate

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide In water for 2h; Irradiation; Green chemistry;92%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

3-Phenoxybenzaldehyde
39515-51-0

3-Phenoxybenzaldehyde

C17H18O3
98992-33-7

C17H18O3

Conditions
ConditionsYield
With copper(I) bromide In hexane at 50℃; for 5h; Inert atmosphere;91%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

3,4,5-trimethoxy-benzaldehyde
86-81-7

3,4,5-trimethoxy-benzaldehyde

tert-butyl 3,4,5-trimethoxybenzoperoxoate

tert-butyl 3,4,5-trimethoxybenzoperoxoate

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide In water for 2h; Irradiation; Green chemistry;91%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

6-methoxynaphthalene-2-carbaldehyde
3453-33-6

6-methoxynaphthalene-2-carbaldehyde

tert-butyl 6-methoxy-naphthalene-2-carboparoxoate

tert-butyl 6-methoxy-naphthalene-2-carboparoxoate

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide In water for 2h; Irradiation; Green chemistry;91%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

tert-butyl 4-methylbenzoate
13756-42-8

tert-butyl 4-methylbenzoate

Conditions
ConditionsYield
With copper(I) bromide In hexane at 50℃; for 5h; Inert atmosphere;90%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

N-phenyl-N-tosylmethacrylamide
1356668-56-8

N-phenyl-N-tosylmethacrylamide

2-methyl-N-phenyl-2-(p-tolyl)butanamide

2-methyl-N-phenyl-2-(p-tolyl)butanamide

Conditions
ConditionsYield
With iron(III) sulfate In fluorobenzene at 115℃; for 8h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere; Sealed tube;90%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

sodium p-chlorobenzenesulphinate
14752-66-0

sodium p-chlorobenzenesulphinate

4-chlorophenyl methyl sulfone
98-57-7

4-chlorophenyl methyl sulfone

Conditions
ConditionsYield
In water at 100℃; for 12h; Sealed tube;90%
With water at 110℃; for 12h; Sealed tube; Green chemistry;90%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

sodium 3-methylbenzenesulfinate
15898-38-1

sodium 3-methylbenzenesulfinate

methyl 3-methylphenyl sulfone
10355-06-3

methyl 3-methylphenyl sulfone

Conditions
ConditionsYield
With water at 110℃; for 12h; Sealed tube; Green chemistry;90%
tetrahydrofuran
109-99-9

tetrahydrofuran

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

3,4-dichlorophenyl isocyanate
34893-92-0

3,4-dichlorophenyl isocyanate

tert-butyl (3,5-dichlorophenyl)(tetrahydrofuran-2-yl)carbamate

tert-butyl (3,5-dichlorophenyl)(tetrahydrofuran-2-yl)carbamate

Conditions
ConditionsYield
With copper(l) chloride at 130℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;90%
tetrahydrofuran
109-99-9

tetrahydrofuran

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

3-tolyl isocyanate
621-29-4

3-tolyl isocyanate

tert-butyl (tetrahydrofuran-2-yl)(m-tolyl)carbamate

tert-butyl (tetrahydrofuran-2-yl)(m-tolyl)carbamate

Conditions
ConditionsYield
With copper(l) chloride at 130℃; for 12h; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere; Schlenk technique; Glovebox;90%
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