Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:100-84-5
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:100-84-5
Min.Order:0 Metric Ton
Negotiable
Type:Manufacturers
inquiry3-Methylanisole CAS No.: 100-84-5 Molecular Formula: C8H10O Molecular Weight: 122.16 Structural formula: A. Physical & Chemical Properties 1.Density:0.96 2.Boiling point:175-176℃ 3.Refractive lndex: 1.512-1.514 4.Solubility: not dis
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so
Cas:100-84-5
Min.Order:1 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryOur Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con
Cas:100-84-5
Min.Order:1 Kilogram
FOB Price: $1.0 / 10.0
Type:Trading Company
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:100-84-5
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryProduct Name 3-Methylanisole Synonyms 1-Methoxy-3-methylbenzene CAS: 100-84-5 MF: - MW: - EINECS: - Prod
Cas:100-84-5
Min.Order:5 Metric Ton
FOB Price: $1.0 / 2.0
Type:Other
inquiryStorage:room temperature Package:200kg/drum Application: 3-Methylanisole, is widely used in chemical reaction as intermediates to obtain target materials such as dyes, pharmaceuticals, perfumes, photo initiators and agrochemicals. It is also used
Cas:100-84-5
Min.Order:1 Kilogram
FOB Price: $1.0
Type:Lab/Research institutions
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:100-84-5
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiry3-Methylanisole CAS:100-84-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia
Cas:100-84-5
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:100-84-5
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:100-84-5
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:100-84-5
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:100-84-5
Min.Order:0 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be
Cas:100-84-5
Min.Order:1 Gram
Negotiable
Type:Other
inquiryMassive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Cas:100-84-5
Min.Order:1 Gram
FOB Price: $1.0
Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:100-84-5
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryWe are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov
Cas:100-84-5
Min.Order:100 Gram
FOB Price: $100.0 / 2000.0
Type:Lab/Research institutions
inquiryProduct name: M-Methylanisole CAS No.:100-84-5 Molecule Formula:C8H10O Molecule Weight:122.16 Purity: 99.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard TESTING ITEMS
Cas:100-84-5
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
3-Methylanisole Basic information Product Name: 3-Methylanisole Synonyms: 1-METHOXY-3-METHYLBENZENE;AMBROL;M-METHOXYTOLUENE;M-METHYLANISOLE;M-METHYL TOLYL ETHER;1-methoxy-3-methyl-benzen;1-Methyl-3-methoxybenzene;3-Methylmethoxybenzene CAS:
Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:100-84-5
Min.Order:1 Metric Ton
FOB Price: $1.0
Type:Trading Company
inquiryWe produce carbomer by our own factory,carbomer 940 is our best seller.It is used for cosmetic and medical.And we also become agent for lubrizol.Our carbomer 940 get high viscosity and good transparency.The price will depond on the market,surely supp
Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai
Cas:100-84-5
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryConditions | Yield |
---|---|
With palladium dichloride In methanol at 40℃; for 18h; Inert atmosphere; Green chemistry; chemoselective reaction; | 99% |
With [IrCl(CO)(PPh3)2]; hydrazine hydrate; potassium hydroxide In methanol at 160℃; for 3h; Wolff-Kishner Reduction; Sealed tube; | 86% |
With [IrCl(CO)(PPh3)2]; hydrazine hydrate; potassium hydroxide In methanol at 160℃; for 3h; Sealed tube; | 86% |
With carbon monoxide; hydrogen; benzene unter Zusatz von Octacarbonyldikobalt und CoCO3 auf 190grad/238 at; | |
Multi-step reaction with 3 steps 1: 78 percent / sodium iodide; sodium hydride / tetrahydrofuran / 0 - 20 °C 2: sulfuryl chloride / CH2Cl2 / -78 °C 3: lithium; 4,4'-di-tert-butylbiphenyl / tetrahydrofuran / 1 h / 0 °C View Scheme |
4-bromo-3-methylanisole
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With potassium carbonate; butan-1-ol; palladium diacetate; triphenylphosphine at 100℃; for 14h; | 98% |
3-methoxyphenylacetonitrile
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
Stage #1: 3-methoxyphenylacetonitrile With 15-crown-5; sodium In tetrahydrofuran; hexane at 0℃; for 0.333333h; Birch Reduction; Inert atmosphere; Stage #2: With water In tetrahydrofuran; hexane at 0℃; for 1h; Birch Reduction; Inert atmosphere; chemoselective reaction; | 98% |
Stage #1: 3-methoxyphenylacetonitrile With dibenzo-18-crown-6; sodium In tetrahydrofuran; toluene at 0℃; for 0.333333h; Inert atmosphere; Stage #2: With propan-1-ol In tetrahydrofuran; toluene at 0℃; for 1h; | 78% |
Conditions | Yield |
---|---|
Stage #1: 3-methoxy-benzaldehyde With iron(III) chloride In methanol at 20℃; for 0.05h; Stage #2: In methanol at 20℃; for 0.166667h; chemoselective reaction; | 95% |
With borohydride exchange resin; nickel diacetate In methanol for 3h; Ambient temperature; | 93% |
With triethylsilane; palladium dichloride In ethanol for 0.5h; Inert atmosphere; | 86.0 %Chromat. |
With triethylsilane; palladium dichloride In ethanol at 20℃; for 0.5h; Inert atmosphere; | 86 %Chromat. |
1-iodo-4-methoxy-2-methylbenzene
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With potassium carbonate; butan-1-ol; palladium diacetate; triphenylphosphine at 100℃; for 1h; | 93% |
Conditions | Yield |
---|---|
With benzyltrimethylammonium chloride; sodium hydroxide In water at 70℃; Concentration; Temperature; Autoclave; | 92.2% |
1-Methoxy-3-methyl-2-(2-methyl-propane-2-sulfonyl)-benzene
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With bis(acetylacetonate)nickel(II); isopropylmagnesium chloride In tetrahydrofuran at 20℃; for 20h; | 92% |
Conditions | Yield |
---|---|
In methanol for 1.6h; Methylation; | 92% |
Conditions | Yield |
---|---|
With sodium hydroxide at 50℃; for 5h; | 91.8% |
With sodium hydroxide |
Conditions | Yield |
---|---|
With ethene; 5%-palladium/activated carbon at 130℃; under 760.051 Torr; | 88% |
Conditions | Yield |
---|---|
With 20 % Pd(OH)2/C; hydrogen In methanol at 20℃; under 760.051 Torr; for 3h; | 86% |
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 72℃; for 24h; Inert atmosphere; | 85% |
With sodium hydroxide In N,N-dimethyl acetamide at 25℃; Rate constant; | |
With potassium hydroxide |
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium carbonate at 150℃; for 2h; | 85% |
Conditions | Yield |
---|---|
With N,N'-dimethylimidazolium-2-carboxylate In acetonitrile at 160℃; for 1.33333h; Microwave irradiation; Green chemistry; | 84% |
With dimanganese decacarbonyl at 180℃; for 1h; Reagent/catalyst; | 81% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 90℃; Inert atmosphere; |
(2R,3S)-2,3-dihydroxy-1-methylcyclohexa-4,6-diene
methyl iodide
A
2-methylmethoxybenzene
C
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With potassium hydroxide In dimethyl sulfoxide at 0℃; for 1.5h; | A n/a B 80% C n/a |
2-tert-butylsulfinyl-3-methoxytoluene
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With nickel In ethanol for 8h; Reflux; | 80% |
m-methoxybenzyl chloride
A
1,2-bis(3-methoxyphenyl)ethane
B
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With nickel In 1,2-dimethoxyethane for 6h; Ambient temperature; | A 69% B n/a |
Conditions | Yield |
---|---|
Stage #1: 3-methoxyphenyl bromide With bis(tri-t-butylphosphine)palladium(0); oxygen In toluene at 20℃; for 0.0166667h; Schlenk technique; Stage #2: methyllithium In toluene at 20℃; for 0.0333333h; Schlenk technique; | 69% |
pentanal
m-methoxyphenylacetic acid
A
1-(3-methoxyphenyl)hexan-2-ol
B
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; caesium carbonate In N,N-dimethyl acetamide at 20℃; for 16h; Irradiation; Inert atmosphere; | A 63% B 20 %Chromat. |
methanol
3-methyl-phenol
A
2,5-Dimethylphenol
B
2,3-Dimethylphenol
C
2,3,6-trimethylphenol
D
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
silica gel at 350℃; under 61504.9 Torr; Product distribution; Further Variations:; Catalysts; Pressures; Temperatures; | A 46% B 9% C 38% D n/a |
2-methoxy-6-methylphenyl trifluoromethanesulfonate
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With formic acid; tributyl-amine; 1,3-bis-(diphenylphosphino)propane; bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 80℃; for 8h; | 46% |
vanillin triflate
A
3-methoxybenzyl alcohol
B
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With palladium 10% on activated carbon; hydrogen In ethyl acetate at 20℃; under 760.051 Torr; for 40h; | A 30% B 42% |
methanol
phenol
A
4-Methylanisole
B
2-methylmethoxybenzene
C
2-methoxy-1,3-dimethylbenzene
D
2,4-dimethylanisole
E
methoxybenzene
F
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
APTi-II-770 at 349.9℃; Product distribution; alkylation; other catalysts, other temperatures; also cresols, further products; | A n/a B 1.8% C n/a D n/a E 19% F n/a |
4,4',4''-((1,3,5-triazine-2,4,6-triyl)tris(oxy))tris(3-methoxybenzaldehyde)
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With palladium 10% on activated carbon; hydrogen In ethyl acetate at 20℃; for 24h; | 14% |
Conditions | Yield |
---|---|
With water; tris-(dibenzylideneacetone)dipalladium(0); trifuran-2-yl-phosphane In tetrahydrofuran Heating; | 3% |
Conditions | Yield |
---|---|
With diethyl ether; magnesium anschliessend Behandeln mit Dimethylsulfat, zuletzt auf dem Dampfbad; |
diethyl ether
2-bromo-3-methylanisole
lithium dimethylamide
B
1-methoxy-3-methyl-benzene
2,4-dibromo-5-methylanisole
A
4-bromo-3-methylanisole
B
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With diethyl ether; magnesium anschliessende Hydrolyse; |
Conditions | Yield |
---|---|
at 400 - 420℃; durch Ueberleiten ueber ThO2; |
1-methoxy-3-methyl-benzene
4-bromo-3-methylanisole
Conditions | Yield |
---|---|
With hydrogenchloride; N-Bromosuccinimide; water In acetone at 20℃; for 0.0833333h; Inert atmosphere; | 100% |
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; methyl 2-n-pentyl-1H-indole-3-carboxylate In n-heptane at 23℃; for 16h; Darkness; Green chemistry; regioselective reaction; | 99% |
With N-Bromosuccinimide; 2,4,6-trimethylaniline In dichloromethane at -40℃; for 2h; Inert atmosphere; regioselective reaction; | 98% |
1-methoxy-3-methyl-benzene
1-iodo-4-methoxy-2-methylbenzene
Conditions | Yield |
---|---|
With iodine; n-butyltriphenylphosphonium peroxodisulfate In acetonitrile for 0.5h; Heating; | 100% |
With N,N,N-trimethylbenzenemethanaminium dichloroiodate; zinc(II) chloride In acetic acid for 0.5h; Ambient temperature; | 94% |
With N-iodo-succinimide; 2,4,6-trifluoroaniline In dichloromethane at 20℃; for 24h; Inert atmosphere; regioselective reaction; | 94% |
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
Stage #1: 1-methoxy-3-methyl-benzene With potassium tert-butylate at -35℃; for 0.333333h; Stage #2: With n-butyllithium In hexane at -35 - 20℃; for 12h; | 100% |
1-methoxy-3-methyl-benzene
2-bromo-5-methoxybenzyl bromide
Conditions | Yield |
---|---|
With N-Bromosuccinimide In dichloromethane for 4h; Heating; IR lamp; | 99% |
With N-Bromosuccinimide In dichloromethane for 4h; Bromination; Heating; irradiation; | 88% |
With N-Bromosuccinimide Photolysis; | 88% |
4-methyl-1,2,4-triazoline-3,5-dione
1-methoxy-3-methyl-benzene
1-(4-methoxy-2-methylbenzene)-4-methyl-1,2,4-triazoline-3,5-dione
Conditions | Yield |
---|---|
With trifluoroacetic acid In chloroform at 62℃; for 0.166667h; regioselective reaction; | 99% |
Conditions | Yield |
---|---|
With tetrabutylammonium acetate for 4.5h; Electrolysis; Inert atmosphere; Sealed tube; regioselective reaction; | 99% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; | 98% |
1-methoxy-3-methyl-benzene
A
3-methylcyclohexen-2-one
B
3-Methylcyclohexanone
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium In tetrahydrofuran; ethanol at -30℃; for 2h; | A 97% B 3% |
1-methoxy-3-methyl-benzene
1-chloro-4-methoxy-2-methylbenzene
Conditions | Yield |
---|---|
With N-chloro-succinimide; 2,4,6-trimethylaniline In dichloromethane at 20℃; Inert atmosphere; regioselective reaction; | 96% |
With aluminum oxide; sodium chlorite; (salen)Mn(III) In dichloromethane at 20℃; for 0.5h; | 87% |
With Oxone; potassium chloride In water; acetonitrile at 20℃; | 76% |
1-methoxy-3-methyl-benzene
2,4-diiodo-5-methyl-methoxybenzene
Conditions | Yield |
---|---|
With N,N,N-trimethylbenzenemethanaminium dichloroiodate; zinc(II) chloride In acetic acid for 24h; Ambient temperature; | 96% |
With iodine; mercury(II) oxide In dichloromethane for 20h; Ambient temperature; | 80% |
With sulfuric acid; iodine; periodic acid In water; acetic acid |
1-methoxy-3-methyl-benzene
1-deuteriomethyl-3-methoxybenzene
Conditions | Yield |
---|---|
Stage #1: 1-methoxy-3-methyl-benzene With 2,2,6,6-tetramethyl-piperidine; n-butyllithium; potassium tert-butylate In tetrahydrofuran; hexane at -78℃; Inert atmosphere; Stage #2: With d(4)-methanol In tetrahydrofuran; hexane Inert atmosphere; regioselective reaction; | 96% |
1-methoxy-3-methyl-benzene
3-methoxybenzyl 3-methoxybenzoate
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; tetra-(n-butyl)ammonium iodide In water at 80℃; for 6h; | 96% |
Conditions | Yield |
---|---|
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride; N-methylaniline In diethyl ether; xylene at 120℃; for 6.5h; | 95% |
With trimethylsilyl iodide at 105 - 114℃; for 0.25h; Microwave irradiation; Inert atmosphere; | 92% |
With 1,3-dimethyl-2-imidazolidinone; sodium hexamethyldisilazane In tetrahydrofuran at 185℃; for 12h; further reagent: LDA; | 87% |
Conditions | Yield |
---|---|
In methanol; water at 20℃; for 2h; | 95% |
With trifluoroacetic acid |
1-methoxy-3-methyl-benzene
[(2,6-bis(diphenylphosphinomethyl)pyridine)Pt(C2H4C6H3(OMe)Me)]SbF6
[(2,6-bis(diphenylphosphinomethyl)pyridine)Pt(C2H4C6H3(OMe)Me)]SbF6
Conditions | Yield |
---|---|
In dichloromethane; water aryl compd. (1.5 equiv.) and H2O were added to soln. of Pt complex in CH2Cl2; mixt. was stirred for 2 h; dried (Na2SO4); filtered; concd. (vac.); Et2O added dropwise; filtered; dried (vac.); elem. anal.; | A 95% B n/a |
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
With iron(III) chloride; silver hexafluoroantimonate In 1,2-dichloro-ethane at 100℃; for 16h; Inert atmosphere; Sealed tube; | 95% |
tertiary butyl chloride
1-methoxy-3-methyl-benzene
2-tert-butyl-5-methylanisole
Conditions | Yield |
---|---|
rhenium(I) pentacarbonyl bromide In 1,2-dichloro-ethane at 84℃; for 5h; Product distribution; | 93% |
Stage #1: 1-methoxy-3-methyl-benzene With aluminum (III) chloride In dichloromethane at 0 - 5℃; for 1h; Stage #2: tertiary butyl chloride In dichloromethane at 0 - 5℃; for 5h; Temperature; | 87.46% |
With phosphoric acid at 55 - 60℃; | |
With aluminium trichloride | |
With aluminium trichloride |
Conditions | Yield |
---|---|
With [2,2]bipyridinyl; ammonia; dihydrogen peroxide; oxygen In N,N-dimethyl-formamide at 80℃; under 1500.15 - 3000.3 Torr; for 6h; Autoclave; | 93% |
With tert.-butylnitrite; N-hydroxyphthalimide; palladium diacetate In acetonitrile at 70℃; for 24h; Inert atmosphere; Sealed tube; | 81% |
With air; ammonia; vanadium-titanium oxide at 383.9℃; for 0.000333333h; | 16.1 |
Conditions | Yield |
---|---|
Stage #1: dicyanozinc; 1-methoxy-3-methyl-benzene With hydrogenchloride In 1,1,2,2-tetrachloroethane at 17℃; Stage #2: With aluminium trichloride In 1,1,2,2-tetrachloroethane at 55℃; for 3h; | 93% |
(E)-3-phenylacrylic acid
1-methoxy-3-methyl-benzene
A
3-(4-hydroxy-2-methyl-phenyl)-3-phenyl-propionic acid
B
3-(4-methoxy-2-methyl-phenyl)-3-phenyl-propionic acid
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid at 125℃; for 3h; | A 5% B 93% |
1-diacetoxy-2-methoxyphenyl-λ3-iodane
trifluoroacetic acid
1-methoxy-3-methyl-benzene
Conditions | Yield |
---|---|
In dichloromethane at -30 - 20℃; | 93% |
1-methoxy-3-methyl-benzene
4-hydroxy-3-methyl-cyclohex-2-en-1-one
Conditions | Yield |
---|---|
Stage #1: 1-methoxy-3-methyl-benzene With ammonia; lithium; tert-butyl alcohol In diethyl ether at -78℃; Birch reduction; Inert atmosphere; Stage #2: With oxalic acid In methanol; water at 20℃; for 1h; Stage #3: With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; for 3h; Inert atmosphere; | 93% |
para-methylphenylmagnesium bromide
1-methoxy-3-methyl-benzene
3,4'-dimethylbiphenyl
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)nickel (0); C23H28N4 In tetrahydrofuran; m-xylene at 60℃; for 4h; Kumada Cross-Coupling; Inert atmosphere; Sealed tube; | 93% |
With (IPr)Ni(π-allyl)Cl In tetrahydrofuran at 60℃; for 12h; Kumada Cross-Coupling; Inert atmosphere; | 81% |
1-methoxy-3-methyl-benzene
1-methoxy-5-methyl-cyclohexa-1,4-diene
Conditions | Yield |
---|---|
With lithium In ethanol; ammonia at -78℃; for 0.5h; | 92% |
With ammonia; sodium In diethyl ether at -78 - -35℃; for 2h; | 82% |
With ammonia; sodium In diethyl ether; tert-butyl alcohol at -78 - -35℃; for 2h; | 82% |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View