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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1,4-Benzenedimethanol Manufacturer/High quality/Best price/In stock

Cas:589-29-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality p-xylylene glycol supplier in China

Cas:589-29-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hefei TNJ chemical industry co.,ltd

ISO Certificaiton Technology: Technology innovation is our eternal pursuit,or we will be left behind.Our technology experts,all from famous universities and institutes,has rich experience and high achievements in chemical research.This makes sure

p-phenylenedimethanol

Cas:589-29-7

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 1,4-Benzenedimethanol 589-29-7 ISO Producer

Cas:589-29-7

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Leader Biochemical Group

About Product Details 1,4-Benzenedimethanol Chemical Properties

China Biggest factory Manufacturer Supply High Quality 1,4-Benzenedimethanol CAS 589-29-7

Cas:589-29-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 5.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

1,4-Benzenedimethanol Basic information Product Name: 1,4-Benzenedimethanol Synonyms: BENZENE-1,4-DIMETHANOL;1,4-PHENYLENEDIMETHANOL;1,4-PHENYLENE DICARBINOL;1,4-BIS(HYDROXYMETHYL)BENZEN

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

1, 4-Benzenedimethanol CAS 589-29-7

Cas:589-29-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 589-29-7 with best price

Cas:589-29-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Product name 1,4-Benzenedimethanol Cas number 589-29-7 Molecular formula C8H10O2 Molecular weight 138.16 Appearance White to off-

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

1,4-PHENYLENEDIMETHANOLCAS NO.:589-29-7

Cas:589-29-7

Min.Order:1 Gram

FOB Price: $4.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,4-Benzenedimethanol 589-29-7

Cas:589-29-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen

589-29-71,4-terephthalol

Cas:589-29-7

Min.Order:25 Gram

FOB Price: $53.03 / 106.06

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

1,4-Benzenedimethanol CAS:589-29-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inter

1,4-Benzenedimethanol CAS:589-29-7

Cas:589-29-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

1,4-Benzenedimethanol CAS: 589-29-7 Specification melting point 116-119℃ boiling point 309.1°c at 760 mmhg flash point 147°c vapour pressur 0.000282mmhg at 25°c Welcome to c

Factory supply 1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

1,4-Benzenedimethanol CAS 589-29-7

Cas:589-29-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,4-Benzenedimethanol Manufacturer

Cas:589-29-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 1,4-Benzenedimethanol CAS No.: 589-29-7 Molecule Formula:C10H16O2 Molecule Weight:168.23 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard TESTING ITEMS

Lower Price 1,4-Benzenedimethanol on stock

Cas:589-29-7

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Top Purity 1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

1,4-Benzenedimethanol Chemical Properties Melting point 114-118 °C(lit.) Boiling point 138-143 °C1 mm Hg(lit.) density 1.0742 (rough estimate) refractive index 1.5090 (estimate) Fp 138-143°C/1mm storage temp. Store

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

1,4-Benzenedimethanol

Cas:589-29-7

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Synthetic route

1,4-benzenedicarboxylic acid dimethyl ester
120-61-6

1,4-benzenedicarboxylic acid dimethyl ester

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With hydrogen; sodium ethanolate In 1,4-dioxane at 80℃; under 38002.6 Torr; for 16h;99%
With C13H34BFeNOP2; hydrogen In tetrahydrofuran at 100℃; under 22502.3 Torr; for 18h; Autoclave; Inert atmosphere;96%
With C15H29MnNO3P2(1+)*Br(1-); potassium tert-butylate; hydrogen In 1,4-dioxane at 110℃; under 22502.3 Torr; for 24h; Inert atmosphere; Autoclave;95%
terephthalaldehyde,
623-27-8

terephthalaldehyde,

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With C48H43ClN2P2Ru; ammonium formate In water; toluene at 90℃; for 10h; Catalytic behavior; Schlenk technique;99%
Stage #1: terephthalaldehyde, With [HC{(Me)CN(2,6-iPr2C6H3)}2MgnBu]; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In toluene at 20℃; for 8h; Inert atmosphere;
Stage #2: With hydrogenchloride; water In methanol; toluene for 1h; Inert atmosphere; Reflux;
97%
With hydrogen In methanol at 130℃; under 11251.1 Torr; for 2h; Catalytic behavior; Autoclave;96.3%
1,4-di(t-butyldimethylsiloxymethyl)benzene
139140-15-1

1,4-di(t-butyldimethylsiloxymethyl)benzene

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With low-loading and alkylated polystyrene-supported-SO3H In water at 40℃; for 12h;99%
methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With [Ru(2-(methylthio)-N-[(pyridin-2-yl)methyl]ethan-1-amine)(triphenylphosphine)Cl2]; potassium tert-butylate; hydrogen In toluene at 80℃; under 30003 Torr; for 3h;99%
With sodium tetrahydroborate In ethanol UV-irradiation;
1-(tert-butyldimethylsilyloxymethyl)-4-triethylsilyloxymethylbenzene

1-(tert-butyldimethylsilyloxymethyl)-4-triethylsilyloxymethylbenzene

A

p-xylylene glycol
589-29-7

p-xylylene glycol

B

[4-({[tert-butyl(dimethyl)silyl]oxy}methyl)phenyl]methanol
118992-89-5

[4-({[tert-butyl(dimethyl)silyl]oxy}methyl)phenyl]methanol

Conditions
ConditionsYield
With MCM-41 In methanol for 8h; Ambient temperature; Yields of byproduct given;A n/a
B 97%
With mesoporous silica MCM-41 In methanol at 20℃; for 8h;A n/a
B 97%
diethyl terephthalate
636-09-9

diethyl terephthalate

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With C30H34Cl2N2P2Ru; potassium methanolate; hydrogen In tetrahydrofuran at 100℃; under 38002.6 - 76005.1 Torr; for 10h; Glovebox; Autoclave;97%
With potassium borohydride; lithium chloride for 0.0833333h; microwave irradiation;85 % Chromat.
terephthalic acid
100-21-0

terephthalic acid

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With [Zn(BH4)2(py)] In tetrahydrofuran for 7h; Heating;95%
With zirconium(IV) borohydride In tetrahydrofuran at 25℃; for 1h; Reduction;91%
Stage #1: terephthalic acid With sodium aminodiboranate In tetrahydrofuran at 20℃;
Stage #2: With water
90%
With zinc(II) tetrahydroborate In tetrahydrofuran for 5h; Heating;70%
Multi-step reaction with 2 steps
1: sulfuric acid / 3 h / 70 °C
2: lithium aluminium tetrahydride / tetrahydrofuran / 15 h / 20 °C / Inert atmosphere
View Scheme
1,4-bis(pinacolborane ester)benzene

1,4-bis(pinacolborane ester)benzene

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With sodium hydroxide In water Inert atmosphere;95%
4-(hydroxylmethyl)benzaldehyde
52010-97-6

4-(hydroxylmethyl)benzaldehyde

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With formic acid; C20H29ClIrN4(1+)*Cl(1-) In water at 80℃; for 0.0833333h;95%
With HNa*CHO2(1-); C63H72ClN3O5PRuS(1+)*Br(1-) In dimethylsulfoxide-d6; water-d2 at 37℃; for 12h;
1,4-bis((methoxymethoxy)methyl)benzene
1058648-83-1

1,4-bis((methoxymethoxy)methyl)benzene

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
phosphotungstic acid In ethanol for 3h; Heating;93%
1,4-bis[(ethoxymethoxy)methyl]benzene
1058648-85-3

1,4-bis[(ethoxymethoxy)methyl]benzene

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
phosphotungstic acid In ethanol for 2.5h; Heating;90%
4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
Stage #1: 4-Carboxybenzaldehyde With sodium aminodiboranate In tetrahydrofuran at 20℃;
Stage #2: With water
90%
With tributylphosphine; diphenylsilane; C45H25F12N7Ni2O9 In 1,4-dioxane at 100℃; for 16h;75%
1,4-di(t-butyldimethylsiloxymethyl)benzene
139140-15-1

1,4-di(t-butyldimethylsiloxymethyl)benzene

A

p-xylylene glycol
589-29-7

p-xylylene glycol

B

[4-({[tert-butyl(dimethyl)silyl]oxy}methyl)phenyl]methanol
118992-89-5

[4-({[tert-butyl(dimethyl)silyl]oxy}methyl)phenyl]methanol

Conditions
ConditionsYield
With sodium tetrachloroaurate(III) dihydrate In methanol at 20℃; for 0.5h;A n/a
B 86%
terephthaloyl chloride
100-20-9

terephthaloyl chloride

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran; diethyl ether for 4.5h; Heating;84%
With zinc(II) tetrahydroborate; N,N,N,N,-tetramethylethylenediamine In diethyl ether at 40℃; for 24h;75%
terephthalaldehyde,
623-27-8

terephthalaldehyde,

A

p-xylylene glycol
589-29-7

p-xylylene glycol

B

4-(hydroxylmethyl)benzaldehyde
52010-97-6

4-(hydroxylmethyl)benzaldehyde

Conditions
ConditionsYield
With C48H43ClN2P2Ru; ammonium formate In water; toluene at 90℃; for 9h; Catalytic behavior; Schlenk technique;A 17%
B 83%
With hydrogen; palladium on activated charcoal In ethanol Ambient temperature;A 3%
B 74%
With Grubbs catalyst first generation; potassium hydroxide In 1,4-dioxane at 80℃; for 20h; Cannizzaro reaction;A 36%
B 40%
1,4-bis(bromomethyl)benzene
623-24-5

1,4-bis(bromomethyl)benzene

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With water; sodium carbonate In 1,4-dioxane at 80℃; for 3h; Solvent; Reagent/catalyst; Temperature;80%
With water; sodium carbonate In 1,4-dioxane at 80℃; for 3h; Solvent; Temperature; Reagent/catalyst;80%
With potassium carbonate
With water for 5h; Reflux;
With water; sodium formate at 140℃; under 3040.2 Torr; for 1h; Reagent/catalyst; Pressure;
4-(methoxycarbonyl)benzyl alcohol
6908-41-4

4-(methoxycarbonyl)benzyl alcohol

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With dichloro(benzene)ruthenium(II) dimer; 2-((di-p-tolylphosphino)methyl)-1-methyl-1H-imidazole; potassium tert-butylate; hydrogen In tetrahydrofuran at 100℃; under 37503.8 Torr; for 4.5h;80%
Stage #1: 4-(methoxycarbonyl)benzyl alcohol With diethoxymethylane; sodium triethylborohydride In diethyl ether; toluene at 20℃; for 8h; Inert atmosphere;
Stage #2: With sodium hydroxide In methanol; diethyl ether; toluene at 20℃; for 2h; Reagent/catalyst;
76%
With [RuCl2(N-heterocyclic carbene)(bis[2-(diphenylphosphino)ethyl]amine)]; potassium tert-butylate; hydrogen In tetrahydrofuran; 2-methyltetrahydrofuran at 45℃; under 3750.38 Torr; for 2.5h; Autoclave;63%
Multi-step reaction with 4 steps
1: 100 percent
2: 88 percent / LiAlH4 / diethyl ether; diethyl ether / 1 h / Heating
3: 87 percent
4: 17 percent / 31percent aq. H2SiF6, Et3N / acetonitrile / 1 h / 0 °C
View Scheme
terephthalaldehyde,
623-27-8

terephthalaldehyde,

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
In methanol at 20℃; for 4h; Inert atmosphere; Glovebox;75%
terephthalic acid monoethyl ester
713-57-5

terephthalic acid monoethyl ester

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
Stage #1: terephthalic acid monoethyl ester With tetrabutylammonium borohydride; ethyl iodide In dichloromethane at 25℃; for 2h;
Stage #2: With dihydrogen peroxide; sodium hydroxide In water at 0 - 25℃; for 0.333333h;
75%
potassium (acetoxymethyl)trifluoroborate

potassium (acetoxymethyl)trifluoroborate

4-chlorophenyl trifluoromethanesulfonate
29540-84-9

4-chlorophenyl trifluoromethanesulfonate

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With sodium carbonate; bis(dibenzylideneacetone)-palladium(0); ruphos In 1,4-dioxane; water for 48h; Suzuki-Miyaura cross-coupling; Inert atmosphere; Reflux;73.1%
4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

A

p-xylylene glycol
589-29-7

p-xylylene glycol

B

4-(hydroxylmethyl)benzaldehyde
52010-97-6

4-(hydroxylmethyl)benzaldehyde

Conditions
ConditionsYield
With phenylsilane; C34H30CoO6; potassium In tetrahydrofuran at 20℃; for 20h; Inert atmosphere; Schlenk technique; Glovebox;A n/a
B 73%
1,4-C6H3(Mn(CO)5)2
17477-07-5

1,4-C6H3(Mn(CO)5)2

A

dimanganese decacarbonyl
10170-69-1

dimanganese decacarbonyl

B

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With carbon monoxide; hydrogen In tetrahydrofuran (N2), CO/H2 (1:1), in an autoclave, mixture heated at 70°C for 3.5 h, cooled, gases vented; filtered, solvent removed (reduced pressure), hexane added, filtered, solvent removed, IR, NMR, mass spectra;A 71%
B 69%
O,O'-(ethane-1,2-diyl)dimethyl diterephthalate
2225-04-9

O,O'-(ethane-1,2-diyl)dimethyl diterephthalate

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With C23H29Cl2N2OPRuS; potassium tert-butylate; hydrogen In tetrahydrofuran at 110℃; under 37503.8 Torr; for 18h; Reagent/catalyst; Temperature; Inert atmosphere; Schlenk technique; Autoclave;71%
4-<(tert-butyldimethylsiloxy)methyl><(triisopropylsiloxy)methyl>benzene
139706-46-0

4-<(tert-butyldimethylsiloxy)methyl><(triisopropylsiloxy)methyl>benzene

A

p-xylylene glycol
589-29-7

p-xylylene glycol

B

[4-({[tert-butyl(dimethyl)silyl]oxy}methyl)phenyl]methanol
118992-89-5

[4-({[tert-butyl(dimethyl)silyl]oxy}methyl)phenyl]methanol

C

(4-(((triisopropylsilyl)oxy)methyl)phenyl)methanol
139706-47-1

(4-(((triisopropylsilyl)oxy)methyl)phenyl)methanol

Conditions
ConditionsYield
With fluorosilicic acid; triethylamine In acetonitrile at 0℃; for 1h;A 17%
B 7%
C 70%
para-xylene
106-42-3

para-xylene

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With hydrogen bromide; dihydrogen peroxide In 1,2-dichloro-ethane at 5℃; for 12h; Irradiation;70%
3-hydroxymethyl-benzoic acid
3006-96-0

3-hydroxymethyl-benzoic acid

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
In sulfuric acid at 40℃; for 14h; electroreduction;68%
1,4-benzenedicarboxylic acid dimethyl ester
120-61-6

1,4-benzenedicarboxylic acid dimethyl ester

A

p-xylylene glycol
589-29-7

p-xylylene glycol

B

4-(methoxycarbonyl)benzyl alcohol
6908-41-4

4-(methoxycarbonyl)benzyl alcohol

Conditions
ConditionsYield
With dichloro(benzene)ruthenium(II) dimer; 2-((di-p-tolylphosphino)methyl)-1-methyl-1H-imidazole; potassium tert-butylate; hydrogen In tetrahydrofuran at 100℃; under 37503.8 Torr; for 4.5h;A 67%
B 13%
With dichlorido-bis[(2-diphenylphosphino)ethyl]amine-cobalt(II); hydrogen; sodium methylate In 1,4-dioxane at 120℃; under 37503.8 Torr; for 48h; Autoclave;
With tris((2-(diphenylphosphino)ethyl)amino)ruthenium monocarbonyl; hydrogen; phenol In toluene under 45004.5 Torr; for 18h; Glovebox; Inert atmosphere; Heating; Autoclave;A 9 %Spectr.
B 88 %Spectr.
ethyl 4-(aminocarbonyl)benzoate
67052-28-2

ethyl 4-(aminocarbonyl)benzoate

p-xylylene glycol
589-29-7

p-xylylene glycol

Conditions
ConditionsYield
With C24H20ClN2OPRu; potassium tert-butylate; hydrogen In tetrahydrofuran at 110℃; under 10640.7 Torr; for 36h; Inert atmosphere; Schlenk technique;63%
(C7H7(CH3)2CHOHC2CH2O)2C6H4
883555-96-2

(C7H7(CH3)2CHOHC2CH2O)2C6H4

p-xylylene glycol
589-29-7

p-xylylene glycol

C104H88Co8O32

C104H88Co8O32

Conditions
ConditionsYield
Stage #1: (C7H7(CH3)2CHOHC2CH2O)2C6H4; dicobalt octacarbonyl In dichloromethane at 20℃; Nicholas Reaction; Inert atmosphere;
Stage #2: p-xylylene glycol With boron trifluoride diethyl etherate In dichloromethane at -78 - 20℃; Nicholas Reaction; Inert atmosphere;
100%
p-xylylene glycol
589-29-7

p-xylylene glycol

terephthalaldehyde,
623-27-8

terephthalaldehyde,

Conditions
ConditionsYield
With manganese(IV) oxide; molecular sieve In hexane for 3h; Heating;99%
With dihydrogen peroxide In water at 100℃; for 5.5h; chemoselective reaction;99%
With 1-methyl-1H-imidazole; copper(I) oxide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical In acetonitrile at 25℃; for 24h;99%
p-xylylene glycol
589-29-7

p-xylylene glycol

terephthalonitrile
623-26-7

terephthalonitrile

Conditions
ConditionsYield
With ammonium hydroxide; iodine at 60℃; for 2h;99%
With ammonium hydroxide; iodine at 60℃; for 2h;99%
Stage #1: p-xylylene glycol With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; tert-butylhypochlorite In dichloromethane at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With ammonia; iodine In dichloromethane; water at 20℃; for 2h; Inert atmosphere;
99%
oxirane
75-21-8

oxirane

p-xylylene glycol
589-29-7

p-xylylene glycol

poly(ethylene oxide)-functionalized 1,4-dihydroxymethylbenzene, Mn 1.1E3 by GPC, Mw/Mn 1.13; monomer(s): ethylene oxide; 1,4-dihydroxymethylbenzene

poly(ethylene oxide)-functionalized 1,4-dihydroxymethylbenzene, Mn 1.1E3 by GPC, Mw/Mn 1.13; monomer(s): ethylene oxide; 1,4-dihydroxymethylbenzene

Conditions
ConditionsYield
Stage #1: p-xylylene glycol With monopotassium naphthalene In tetrahydrofuran at 22℃; for 2h;
Stage #2: oxirane In tetrahydrofuran at 40℃; for 20h;
Stage #3: With acetic acid In tetrahydrofuran
99%
(C7H7(CH3)2CHOHC2CH2O)2C6H4
883555-96-2

(C7H7(CH3)2CHOHC2CH2O)2C6H4

p-xylylene glycol
589-29-7

p-xylylene glycol

((OCH2)2C6H4)2((C7H7(CH3)2CHC2Co2(CO)6CH2O)2C6H4)2

((OCH2)2C6H4)2((C7H7(CH3)2CHC2Co2(CO)6CH2O)2C6H4)2

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In 1,4-dioxane; dichloromethane ligand reacted with Co complex in CH2Cl2, treated with 1,4-benzenedimethanol in dioxane at room temp.;99%
2-(2-methacryloyloxyethyloxy)ethyl isocyanate
107023-60-9

2-(2-methacryloyloxyethyloxy)ethyl isocyanate

p-xylylene glycol
589-29-7

p-xylylene glycol

C26H36N2O10

C26H36N2O10

Conditions
ConditionsYield
With dibutyltin dilaurate In N,N-dimethyl-formamide at 20℃; for 3h;99%
oxirane
75-21-8

oxirane

p-xylylene glycol
589-29-7

p-xylylene glycol

poly(ethylene oxide)-functionalized 1,4-dihydroxymethylbenzene, Mn 4.8E3 by GPC, Mw/Mn 1.27; monomer(s): ethylene oxide; 1,4-dihydroxymethylbenzene

poly(ethylene oxide)-functionalized 1,4-dihydroxymethylbenzene, Mn 4.8E3 by GPC, Mw/Mn 1.27; monomer(s): ethylene oxide; 1,4-dihydroxymethylbenzene

Conditions
ConditionsYield
Stage #1: p-xylylene glycol With monopotassium naphthalene In tetrahydrofuran at 22℃; for 2h;
Stage #2: oxirane In tetrahydrofuran at 40℃; for 24h;
Stage #3: With acetic acid In tetrahydrofuran
98%
p-xylylene glycol
589-29-7

p-xylylene glycol

chromium(0) hexacarbonyl
199620-14-9, 13007-92-6

chromium(0) hexacarbonyl

tricarbonyl[C6H4(CH2OH)2]chromium(0)
69439-58-3

tricarbonyl[C6H4(CH2OH)2]chromium(0)

Conditions
ConditionsYield
In tetrahydrofuran; dibutyl ether the mixt. of Cr(CO)6 and the alcohol in dibutyl ether and THF was heated under reflux with stirring at between 180 and 240°C for 20-48 hunder N2; filtered, washed with THF, concd., filtered, dried in vac., dissolved in THF, filtered, concd. in vac. (N2 atm.); elem. anal.;98%
In tetrahydrofuran; dibutyl ether N2 atmosphere; refluxing (26 h); crystn. on cooling (ice bath), filtration off, chromy., recrystn. (CH2Cl2/hexane); elem. anal.;90%
p-xylylene glycol
589-29-7

p-xylylene glycol

1,4-bis(bromomethyl)benzene
623-24-5

1,4-bis(bromomethyl)benzene

Conditions
ConditionsYield
With Silphos; bromine In acetonitrile for 0.166667h; Heating;97%
With hydrogen bromide bei der Destillation;
p-xylylene glycol
589-29-7

p-xylylene glycol

terephthalic acid
100-21-0

terephthalic acid

Conditions
ConditionsYield
With diethylene glycol dimethyl ether at 70℃; for 0.583333h; Sonication;97%
With C24H33IrN4O3; water; sodium hydroxide for 18h; Reflux;96%
With sodium hypochlorite; water at 25℃; for 0.5h;94%
p-xylylene glycol
589-29-7

p-xylylene glycol

4-Methylbenzyl alcohol
589-18-4

4-Methylbenzyl alcohol

Conditions
ConditionsYield
With hydrogen; nickel In sodium hydroxide at 20℃;96%
Multi-step reaction with 2 steps
1: pyridine
2: 76 percent / H2 / Pd/C(ethylenediamine) / methanol / 1 h / 20 °C
View Scheme
With hydrogen In ethanol; water at 170℃; under 15001.5 Torr; for 12h; Autoclave; Sealed tube; Green chemistry;97.8 %Chromat.
oxirane
75-21-8

oxirane

p-xylylene glycol
589-29-7

p-xylylene glycol

poly(ethylene oxide)-functionalized 1,4-dihydroxymethylbenzene, Mn 1.9E4 by GPC, Mw/Mn 1.07; monomer(s): ethylene oxide; 1,4-dihydroxymethylbenzene

poly(ethylene oxide)-functionalized 1,4-dihydroxymethylbenzene, Mn 1.9E4 by GPC, Mw/Mn 1.07; monomer(s): ethylene oxide; 1,4-dihydroxymethylbenzene

Conditions
ConditionsYield
Stage #1: p-xylylene glycol With monopotassium naphthalene In tetrahydrofuran at 22℃; for 2h;
Stage #2: oxirane In tetrahydrofuran at 40℃; for 64h;
Stage #3: With acetic acid In tetrahydrofuran
96%
Dimethoxymethane
109-87-5

Dimethoxymethane

p-xylylene glycol
589-29-7

p-xylylene glycol

{4-[(methoxymethoxy)methyl]phenyl}methanol
207223-84-5

{4-[(methoxymethoxy)methyl]phenyl}methanol

Conditions
ConditionsYield
With 12-tungstophosphoric acid immobilized on [bmim][FeCl4] at 75 - 82℃; for 0.00972222h; Microwave irradiation;96%
1-methyl-pyrrolidin-2-one
872-50-4

1-methyl-pyrrolidin-2-one

3,3',4,4'-tetraaminobiphenyl
91-95-2

3,3',4,4'-tetraaminobiphenyl

p-xylylene glycol
589-29-7

p-xylylene glycol

C68H46N12O2

C68H46N12O2

Conditions
ConditionsYield
With ruthenium(II) bis(triphenylphosphine) dichloride at 190℃; for 14h; Inert atmosphere; Schlenk technique;96%
p-xylylene glycol
589-29-7

p-xylylene glycol

sodium acetate
127-09-3

sodium acetate

1,4-bis(hydroxymethyl)benzene diacetate
14720-70-8

1,4-bis(hydroxymethyl)benzene diacetate

Conditions
ConditionsYield
In water at 100℃; for 8h;96%
p-xylylene glycol
589-29-7

p-xylylene glycol

cyanoacetic acid
372-09-8

cyanoacetic acid

1,4-bis(cyanoacetoxymethyl)benzene
51821-19-3

1,4-bis(cyanoacetoxymethyl)benzene

Conditions
ConditionsYield
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In dichloromethane for 12h; Heating;95.3%
With dicyclohexyl-carbodiimide
p-xylylene glycol
589-29-7

p-xylylene glycol

p-bis(iodomethyl)benzene
30362-89-1

p-bis(iodomethyl)benzene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; cesium iodide In acetonitrile at 20℃; for 0.416667h;95%
With Silphos; iodine In acetonitrile for 0.0833333h; Heating;95%
With tetrachlorosilane; sodium iodide In chloroform; acetonitrile at 20℃; for 5h;88%
With hydrogen iodide
p-xylylene glycol
589-29-7

p-xylylene glycol

trityl chloride
76-83-5

trityl chloride

(4-(trityloxymethyl)phenyl)methanol
679412-25-0

(4-(trityloxymethyl)phenyl)methanol

Conditions
ConditionsYield
With pyridine95%
p-xylylene glycol
589-29-7

p-xylylene glycol

chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

1,4-bis((methoxymethoxy)methyl)benzene
1058648-83-1

1,4-bis((methoxymethoxy)methyl)benzene

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In dichloromethane at -20 - 20℃;95%
formaldehyde diethyl acetal
462-95-3

formaldehyde diethyl acetal

p-xylylene glycol
589-29-7

p-xylylene glycol

C11H16O3

C11H16O3

Conditions
ConditionsYield
With 12-tungstophosphoric acid immobilized on [bmim][FeCl4] at 75 - 82℃; for 0.00972222h; Microwave irradiation;95%
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