CAS No.7646-78-8,Tin tetrachloride Suppliers,MSDS download

Dayang Chem (Hangzhou) Co.,Ltd.

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Items Standard Result Clarity conform conform Hydrochloric acid insoluble nothing

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Simagchem Corporation

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Hefei TNJ chemical industry co.,ltd

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Henan Tianfu Chemical Co., Ltd.

Product Name: Tin tetrachloride Synonyms: STANNIC TETRACHLORIDE;STANNIC CHLORIDE;STANNIC CHLORIDE HYDRATE;TIN CHLORIDE;TIN(+4)CHLORIDE;TIN(+4)CHLORIDE HYDRATE;TIN TETRACHLORIDE;TIN(IV) CHLORIDE CAS: 7646-78-8 MF: Cl4Sn

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Tin tetrachloride CAS NO.7646-78-8

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Hangzhou Fandachem Co.,Ltd

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Kono Chem Co.,Ltd

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

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Antimex Chemical Limied

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Beantown Chemical

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Tin(IV) chloride, anhydrous, 98% trace metals basis

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QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

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Synthetic route

: 13445-49-3
Marshall's acid

: tin(ll) chloride

A: 7664-93-9
sulfuric acid

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In hydrogenchloride room temp.; 10-15 min.;	A n/a B 99%
In hydrogenchloride room temp.; 10-15 min.;	A n/a B 99%

...Expand

: tin(IV) oxide

: iron(II) chloride

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 98.97 % SnCl4 at 800°C in presence of C;;	98.97%
In neat (no solvent) byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 76.10 % SnCl4 at 800°C;;	76.1%
In neat (no solvent) byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 27.20 % SnCl4 at 700°C; equilibrium reaction discussed;;	27.2%

: tin(IV) oxide

: 7786-30-3
magnesium chloride

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 98.3 % SnCl4 at 800°C in presence of C;;	98.3%
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 74.60 % SnCl4 at 800°C;;	74.6%
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 58.79 % SnCl4 at 700°C; equilibrium reaction examinated;;	58.79%

: tin(IV) oxide

: 7646-85-7
zinc(II) chloride

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 97.87 % SnCl4 at 800°C in presence of C;;	97.87%
In neat (no solvent) byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 5.2 % SnCl4 at 800°C;;	5.2%
In neat (no solvent) byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 4.3 % SnCl4 at 600°C;;	4.3%

: 117440-15-0
tetrakis-biphenyl-(2)-tin(IV)

A: 10271-66-6
biphenyl-(2)-mercury(II) chloride

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With mercury dichloride In ethanol 20h heating in sealed tube to 120°C; absol. ethanol;;	A 90.5% B n/a
With HgCl2 In ethanol 20h heating in sealed tube to 120°C; absol. ethanol;;	A 90.5% B n/a

: 625-58-1
ethyl nitrate

: tin(ll) chloride

A: 5470-11-1
hydroxylamine hydrochloride

B: 7664-41-7
ammonia

C: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With hydrogenchloride In hydrogenchloride byproducts: C2H5OH, H2O; in concd. HCl soln.; evapn. of the alcohol,diluting with water,pptg. of the Sn with H2S,evapn. and crystn. from alcohol;	A 90% B <1 C n/a

...Expand

: 56-23-5
tetrachloromethane

: 595-90-4
tetraphenyltin(IV)

: 94-36-0
dibenzoyl peroxide

A: 67-72-1
hexachloroethane

B: 7646-78-8
tin(IV) chloride

C: 108-90-7
chlorobenzene

D: 88-99-3
benzene-1,2-dicarboxylic acid

E: 65-85-0
benzoic acid

Conditions

Conditions	Yield
50h boiling;	A n/a B 84.1% C n/a D n/a E n/a

...Expand

: Tc(dimethylglyoxime)3(μ-OH)SnCl3*H2O

A: TcCl(dimethylglyoxime)3

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With HCl In acetonitrile room temp., 30 min. (crystn.); cooling (-20°C), decantation, washing (cold MeCN, cold 1 M HCl), drying (vac., 6 h), recrystn. (EtOH/HCl); elem. anal.;	A 82% B n/a

: (R,R,S,S)-2,2',6,6'-tetra-tert-butyl-4,4'-spirobis(8-sila-4-stannatetrahydro-s-indacene)

: 10026-11-6
zirconium(IV) chloride

: rac-dimethylsilanediylbis(t-butylcyclopentadienyl) zirconium dichloride

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In toluene stirring (16 h); solvent removal (vac.), addn. pentane, filtration, volatiles rremoval (vac.);	A 80% B n/a

...Expand

: Tc(cyclohexanedione dioxime)3(μ-OH)SnCl3*3H2O

A: TcCl(cyclohexanedione dioxime)3

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With HCl In acetonitrile stirring (30 min., pptn.); addn. of excess 1 M HCl, collection (after 15 min.), washing (1 M HCl, H2O), drying (vac.), recrystn. (MeCN/1 M HCl); elem. anal.;	A 75% B n/a

: 10170-69-1
dimanganese decacarbonyl

: tin(ll) chloride

A: {Mn(CO)4SnCl((CH3)2NCHO)}3

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In N,N-dimethyl-formamide byproducts: CO; Ar atmosphere, 150°C, 24 h; pptn. on addn. of H2O, washing (dild. HCl and cyclohexane), drying (vac.); elem. anal.;	A 73% B n/a

...Expand

: 625-01-4
ethyl chlorosulfate

: 7553-56-2
iodine

tin: tin

A: 7647-01-0
hydrogenchloride

B: 74-85-1
ethene

C: 7646-78-8
tin(IV) chloride

D SO2: SO2

Conditions

Conditions	Yield
at 130℃;

...Expand

: (4-ethoxycarbonyl-3,5-dimethyl-pyrrol-2-yl)-(4-ethoxycarbonyl-3,5-dimethyl-pyrrol-2-ylidene)-methane; compound with tin tetrachloride

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
beim Erhitzen;

: tin(IV) chloride * 2 ether

A: 60-29-7
diethyl ether

B: 7646-78-8
tin(IV) chloride

: tin(IV) chloride * 2 ether

A: 60-29-7
diethyl ether

B: 75-00-3
chloroethane

C: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
bei hoeherer Temperatur;

...Expand

: 64-17-5
ethanol

: 595-90-4
tetraphenyltin(IV)

mercury (II)-chloride: mercury (II)-chloride

A: 7646-78-8
tin(IV) chloride

B: 100-56-1
phenylmercury(II) chloride

...Expand

: diisopentyl ether ; compound with tin tetrachloride

A: 7646-78-8
tin(IV) chloride

B di-g-pentyl ether: di-g-pentyl ether

Conditions

Conditions	Yield
bei der Destillation;

: 625836-84-2
4-benzylmercapto-3-nitro-1,8-naphthalic anhydride

A: 625836-85-3
4-benzylmercapto-3-amino-1,8-naphthalic anhydride

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With hydrogenchloride; tin(ll) chloride In water at 90℃; for 2h;

: 69080-31-5
tin tetrachloride pyridine adduct

A: 110-86-1
pyridine

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
thermal dissociation, 280 to 340°C; reaction monitoring by pressure measurement;

: ammonium chloride

: tin(IV) oxide

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent) calcination of SnO2 and NH4Cl;;

: 10028-15-6
ozone

: tin(ll) chloride

A: 7732-18-5
water

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With hydrogenchloride; oxygen In not given redn. of O3 by SnCl2 in a HCl-containing soln. by shaking in a O2-O3 mixture for a period of 90 min.;;

...Expand

: iron(III) oxide

: 7782-50-5
chlorine

: tin(IV) oxide

A: 7705-08-0
iron(III) chloride

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
Kinetics; chlorination of mechanical SnO2/Fe2O3 mixt. at const. temp. in range 700-850°C; monitoring by gravimetric and chem. anal.; X-ray diffraction;
Kinetics; chlorination of SnO2/Fe2O3 mixt. (obtained by copptn. from hydrochloric SnCl4/FeCl3 soln. with concd. ammonia and ppt. calcination in air at 600°C for 24 h) at const. temp. in range 700-850°C; monitoring by gravimetric and chem. anal.; X-ray diffraction;

...Expand

: indium(III) oxide

: 7782-50-5
chlorine

: tin(IV) oxide

A: 27693-84-1, 21563-01-9
In2Cl6

B: 10025-82-8
indium(III) chloride

C: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; byproducts: O2; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2 flow 100 ml/min); chem. anal.;
With sulfur dioxide In neat (no solvent) Kinetics; byproducts: O2, SO3, In2(SO4)3; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2/SO2 flow 100 ml/min); chem. anal.;

...Expand

: tin (IV) chloride pentahydrate

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With SOCl2 or COCl2 In neat (no solvent)
With COCl2 In neat (no solvent) complete draining with COCl2 at 100°C in 24 h;;
With thionyl chloride In neat (no solvent) complete draining with boiling SOCl2 in some hours;;

: 165071-88-5
4-[N-ethyl,N-(2-chloroethyl)amino]nitrobenzene

: 7646-78-8
tin(IV) chloride

: 32868-99-8
4-[N-ethyl,N-(2-chloroethyl)amino]aniline hydrochloride

Conditions

Conditions	Yield
With ammonium hydroxide In 1,4-dioxane; hydrogenchloride	100%

: 7646-78-8
tin(IV) chloride

: Dimethylaluminium-acetylacetonat

: 594-27-4
tetramethylstannane

Conditions

Conditions	Yield
In benzene molar ratio 2 : 1, room temp.;	100%
In benzene molar ratio 2 : 1, room temp.;	100%

: 110-91-8
morpholine

: 7646-78-8
tin(IV) chloride

: [SnCl4(morpholine)2]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 110-89-4
piperidine

: 7646-78-8
tin(IV) chloride

: [SnCl4(piperidine)2]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 110-86-1
pyridine

: 7646-78-8
tin(IV) chloride

: [SnCl4(pyridine)2]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with pyridine (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 108-89-4
picoline

: 7646-78-8
tin(IV) chloride

: [SnCl4(γ-picoline)2]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 91-22-5
quinoline

: 7646-78-8
tin(IV) chloride

: [SnCl4(quinoline)1.5]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 366-18-7
[2,2]bipyridinyl

: 7646-78-8
tin(IV) chloride

: [SnCl4(2,2'-bipyridine)]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 7646-78-8
tin(IV) chloride

: 55147-78-9
bis(bis(trimethylsilyl)amido)tin(II)

: 145298-59-5
bis{bis(trimethylsilyl)amino}tin dichloride

Conditions

Conditions	Yield
In hexane byproducts: SnCl2; (N2); SnCl4 added dropwise (vigorous stirring, -78°C); kept for 12 h at room temp.; filtered; hexane removed (vac.);	100%

: 232946-68-8
4-(2-(trimethylgermyl)ethyl)phenol

: 7646-78-8
tin(IV) chloride

: 232946-69-9
HOC6H4(CH2)2Ge(CH3)2Cl

Conditions

Conditions	Yield
In nitromethane heating at 50°C for 6 h;	100%

: 110-85-0
piperazine

: 7646-78-8
tin(IV) chloride

: [SnCl4(piperazine)1.5]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: tin tetraacetate

: 7646-78-8
tin(IV) chloride

: tin dichloride diacetate

Conditions

Conditions	Yield
In chloroform absence of moisture; equimolar amts., refluxing (3-4 h); solvent removal (reduced pressure); elem. anal.;	100%

: 7646-78-8
tin(IV) chloride

: 107-19-7
propargyl alcohol

: 1322728-88-0
1-trichlorostannyl-2-chloro-2-hydroxymethyl-ethene

Conditions

Conditions	Yield
In dichloromethane N2; DCM soln. of ligand and SnCl4 (1:1 molar ratio) stirred at room temp. for 24 h; evapd. (vac., room temp.), NMR;	100%
In chloroform-d1 N2; 1:1 mixt. at 25°C; NMR;

: 7646-78-8
tin(IV) chloride

: 693-02-7
hex-1-yne

: 1322728-87-9
1-trichlorostannyl-2-chloro-2-n-butyl-ethene

Conditions

Conditions	Yield
In dichloromethane N2; DCM soln. of ligand and SnCl4 (1:1 molar ratio) stirred at room temp. for 24 h; evapd. (vac., room temp.), NMR;	100%
In chloroform-d1 N2; 1:1 mixt. at 25°C; NMR;

: 917-92-0
2,2-dimethyl-3-butyne

: 7646-78-8
tin(IV) chloride

: 1322728-83-5
1-trichlorostannyl-2-chloro-2-tert-butyl-ethene

Conditions

Conditions	Yield
In dichloromethane N2; DCM soln. of ligand and SnCl4 (1:1 molar ratio) stirred at room temp. for 24 h; evapd. (vac., room temp.), NMR;	100%
In chloroform-d1 N2; 1:1 mixt. at 25°C; NMR;

: 7646-78-8
tin(IV) chloride

: 536-74-3
phenylacetylene

: 1322728-81-3
1-trichlorostannyl-2-chloro-2-phenyl-ethene

Conditions

Conditions	Yield
In dichloromethane N2; DCM soln. of ligand and SnCl4 (1:1 molar ratio) stirred at room temp. for 24 h; evapd. (vac., room temp.), NMR;	100%
In chloroform-d1 N2; 1:1 mixt. at 25°C; NMR;

: ammonium sulfate

: 7646-78-8
tin(IV) chloride

: 7783-05-3
disulfuric acid

: O21S6Sn(2-)*2H4N(1+)

Conditions

Conditions	Yield
at 250℃; for 24h;	100%

...Expand

: 7646-78-8
tin(IV) chloride

: 7783-05-3
disulfuric acid

: silver sulfate

: O21S6Sn(2-)*2Ag(1+)

Conditions

Conditions	Yield
at 250℃; for 24h;	100%

...Expand

: C38H40Sn

: 7646-78-8
tin(IV) chloride

: C36H34Cl2Sn

Conditions

Conditions	Yield
In neat (no solvent) at 130℃; for 14h; Schlenk technique;	100%

: 4885-02-3
Dichloromethyl methyl ether

: C24H28S3

: 7646-78-8
tin(IV) chloride

: C25H27S3(1+)*0.5Cl6Sn(2-)

Conditions

Conditions	Yield
In 1,2-dichloro-ethane for 24h; Reflux; Inert atmosphere;	100%

...Expand

: 7647-01-0
hydrogenchloride

: 7732-18-5
water

: 4-methyl-7-(pyrazin-2-yl)-2H-[1,2,4]triazolo[3,2-c][1,2,4]triazole

: 7646-78-8
tin(IV) chloride

: C8H7N7*Cl6Sn(2-)*2H2O*2H(1+)

Conditions

Conditions	Yield
In ethanol	100%

...Expand

: 75-00-3
chloroethane

: 7646-78-8
tin(IV) chloride

: 597-64-8
tetraethyltin

Conditions

Conditions	Yield
With magnesium In diethyl ether; toluene at 50℃; Inert atmosphere; Flow reactor;	99.4%

: 304-88-1
N-phenylbenzohydroxamic acid

: 7646-78-8
tin(IV) chloride

: dichlorotin bis-N-benzoyl-N-phenylhydroxylamine

Conditions

Conditions	Yield
With Li In methanol (Ar); Li was dissolved in dry MeOH, soln. of hydroxylaminederiv. was added and then SnCl4 was dropped into the stirred mixt.; formed ppt. was filtered off, washed with MeOH and ether, and dried in vac.; recrystn. from MeOH/CHCl3; elem. anal.;	99.3%

: N-[2-Hydroxy-3-nitrophenyl]-N'-[2-bromophenyl] urea

: 7646-78-8
tin(IV) chloride

: 182500-25-0
N-(2-hydroxy-3-aminophenyl)-N'-(2-bromophenyl)urea

Conditions

Conditions	Yield
In ethanol	99%
In ethanol	99%
In ethanol	99%

: 597580-25-1
3-mercaptothietane

: 7646-78-8
tin(IV) chloride

: C16H28S4Sn

Conditions

Conditions	Yield
Stage #1: 3-mercaptothietane With sodium hydroxide In water at 20℃; for 0.666667h; Stage #2: tin(IV) chloride In water at 30℃; for 6h; Product distribution / selectivity;	99%
With pyridine In dichloromethane at -30 - -20℃; for 6.08h; Product distribution / selectivity;	75%

: 594-27-4
tetramethylstannane

: 7646-78-8
tin(IV) chloride

: 1066-45-1
trimethyltin(IV)chloride

Conditions

Conditions	Yield
stirring overnight at 60°F, N2-atmosphere; distd. at 15 Torr;	99%
molar ratio of (CH3)4Sn:SnCl4=3:1; distn.;
In neat (no solvent) react. Me4Sn with SnCl4 (3:1) at 130°C for 2 h; recrystn. from hexane;

: 7646-78-8
tin(IV) chloride

: tin(ll) chloride

Conditions

Conditions	Yield
With triphenyl phosphine In dichloromethane Ar atmosphere; 20°C, 7 d;	99%
In gas byproducts: SnCl; formation with SnCl at flash-light photolysis of gasous SnCl4 with intermediate formation of SnCl3;;
With methane In neat (no solvent) redn. to SnCl2 by use of CH4 in a closed quartz tube above ca. 500°C;;

: 92-66-0
4-bromo-1,1'-biphenyl

: 7646-78-8
tin(IV) chloride

: 39767-03-8
tetra(p-biphenylyl)tin

Conditions

Conditions	Yield
Stage #1: 4-bromo-1,1'-biphenyl With magnesium In tetrahydrofuran; ethylene dibromide for 2h; Reflux; Stage #2: tin(IV) chloride In tetrahydrofuran; ethylene dibromide at 20℃; Reflux;	99%
With Na In benzene addn. of a small portion of p-bromobiphenyl and SnCl4 to sodium in benzene, warmed, dropwise addn. of the remaining portion with stirring over 30 min, refluxed for 5 h; filtered hot, cooled; elem. anal.;	90%
With Na In benzene Wurtz react.;

: 60-35-5
acetamide

: 7646-78-8
tin(IV) chloride

: SnCl4(acetamide)2

Conditions

Conditions	Yield
In Petroleum ether SnCl4 was mixed with soln. of ligand in petroleum ether under N2, stirred for several h; filtered, washed with petroleum ether, recrystd. from dichloroethane, dried in vac.; elem. anal.;	99%