Items Standard Result Appearance White powder Conforms Assay 99.0% min 9
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inquiryMagnesium chloride Basic information Product Name: Magnesium chloride Synonyms: dus-top;Lys, TMS;magnesiumchloride(mgcl2);magnesiumchloride[mg2cl4];magnesiumchloride[mgcl2];magnesiumchlo
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Cas:7786-30-3
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inquiryProduct Name Magnesium chloride CAS 7786-30-3 Molecular Formula Cl2Mg Molecular Weight
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inquiry1.Prompt Goods; 2.Flexible payment terms; 3.Documents & Certificate support. Name: Magnesium chloride Structure: Formula: Cl2Mg Molecular Weight : 95.21 Synonyms: magnesiumdichloride;MAGNESIUMCHLORIDE,98%ANHYDROUS;Slow-Mag;MAGNESIUMCHLORI
Chemical name: magnesium chloride English Name: magnesium chloride Molecular formula: MgCl2 · 6H2O Molecular weight: 203.30 CAS No: 7786-30-3 Performance: white or gray flake, soluble in water, in humid air, eas
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Magnesium chloride CAS: 7786-30-3 Specification Item Standard Identification A.H-NMR:Comply with the structure B.LC-MS:Comply with the structure C.The IR spectrum
Appearance:white powder without visible impurities Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By
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inquiryB
magnesium chloride
Conditions | Yield |
---|---|
In tetrahydrofuran Ar atm.; hot THF; | A 100% B 100% |
Conditions | Yield |
---|---|
In melt melting the starting materials in an evacuated silica ampoule at 900°C for 48 h, cracking the ampoule under Ar; | 95% |
In neat (no solvent) reduction of molten ZnCl2 with Mg forming MgCl2;; | |
In neat (no solvent) reduction of molten ZnCl2 with Mg forming MgCl2;; |
zirconium(IV) chloride
magnesium
A
zirconium
B
magnesium chloride
Conditions | Yield |
---|---|
In melt heating at 800°C under inert gas in a closed vessel, Kroll-process; apparatus described;; separation of Mg and MgCl2 by vacuum destillation;; | A 93% B n/a |
In melt heating at 800°C under inert gas in a closed vessel, Kroll-process; apparatus described;; separation of Mg and MgCl2 by vacuum destillation;; | A 93% B n/a |
Conditions | Yield |
---|---|
In neat (no solvent) High Pressure; mixed, sealed in autoclave under Ar, heated at 450, 500, 550, and 600 °C for 10 h; washed with water, dried in vac. at 70 °C for 12 h; powder XRD; | A 93% B n/a C n/a D n/a |
dichlorobis(3,5-di-tert-butylpyrazolylato)titanium(IV)
methylmagnesium chloride
A
dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)
B
magnesium chloride
Conditions | Yield |
---|---|
In tetrahydrofuran; hexane Ar-atmosphere; MeMgCl soln. (THF) addn. (0°C), stirring (room temp., 20 h), evapn. (reduced pressure); extg. (hexane), filtering, evapn. (reduced pressure); elem. anal.; | A 93% B n/a |
(trimethylsilyl)methylmagnesium chloride
tantalum pentachloride
trimethylphosphane
B
magnesium chloride
Conditions | Yield |
---|---|
In diethyl ether; hexane under N2 atm. slurry TaCl5 in hexane at -20°C was treated dropwise with Me3SiCH2MgCl in Et2O, solvent was removed in vacuo, residue was taken up in hexane at 0°C and filtered, PMe3 was added and heated to 50°C for 1 h; soln. was filtered, concd. and cooled to -20°C; | A 92% B n/a |
rac-ethanediyl-bis(1-indenyl)zirconium dichloride
methylmagnesium bromide
B
magnesium chloride
Conditions | Yield |
---|---|
In 1,4-dioxane; diethyl ether; hexane (N2); dioxane was added to 3 M soln. MeMgBr in hexane and Et2O, stirred for 1 h, filtered, filtrate was added to soln. of zirconium complex in Et2O at -78°C, warmed to room temp. overnight; evapd., dissolved in benzene, filtered, evapd. in vac., crystd. from toluene/hexanes; | A 91% B n/a |
ethylmagnesium bromide
A
ethane
B
ethene
C
palladium
E
magnesium chloride
Conditions | Yield |
---|---|
In tetrahydrofuran To a soln. of anhydrous salt is added C2H5MgBr at 20°C with stirring. The reaction mixture is left for 5 - 6 h at room temp.; decantation, washing with THF, water and ethanol; electron diffraction; | A n/a B n/a C 90% D n/a E n/a |
bis(η5-tetramethyl(trimethylsilyl)cyclopentadienyl)titanium dichloride
magnesium
Bis(trimethylsilyl)ethyne
A
(η2-bis(trimethylsilyl)ethyne)bis(η5-tetramethyl(trimethylsilyl)cyclopentadienyl)titanium(II)
B
magnesium chloride
Conditions | Yield |
---|---|
In tetrahydrofuran -18°C (40 h), filtering, evapn. (vac.); extg. (hexane), MgCl2 pptn. (-5°C, overnight), concg., crystn. (-18°C, overnight); elem. anal.; | A 80% B n/a |
gallium
magnesium
methyl iodide
A
magnesium chloride
B
trimethyl gallium
Conditions | Yield |
---|---|
In neat (no solvent) inert gas atmosphere; mixing, heating in autoclave (100 - 160°C, stirring, 12 h); distillation; | A n/a B 65% |
gallium
magnesium
ethyl iodide
A
triethyl gallium
B
magnesium chloride
Conditions | Yield |
---|---|
In hexane inert condition; addn. of hexane to mixt. of Mg and Ga (vac.), addn. of hexane, dropwise addn. of EtI (boiling hexane); distillation; | A 65% B n/a |
gallium
iodine
magnesium
ethyl iodide
A
triethyl gallium
B
magnesium chloride
Conditions | Yield |
---|---|
In neat (no solvent) inert condition; addn. of I2 to mixt. of Mg and Ga, heating in vac. (150°C), chilling, addn. of EtI (50 - 70°C, 1 h), heating (90 °C, 4 h); distillation; | A 61% B n/a |
[ZrCl2(C32H38N4)]
dibenzylmagnesium
A
C39H45N4Zr(C4H8O)(CH2C6H5)
B
magnesium chloride
Conditions | Yield |
---|---|
In tetrahydrofuran; toluene stirring (room temp., 1 h); evapn., toluene addn., filtering, evapn., n-pentane addn., filtering, drying (vac.); elem. anal.; | A 61% B n/a |
Conditions | Yield |
---|---|
In neat (no solvent) inert condition; addn. of I2 to alloy Mg-Ga, heating in vac. (150 °C), chilling, addn. of EtI), heating (85°C, 4 h); distillation; | A 57% B n/a |
dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)
tert-butylamine
A
chlorotris(3,5-di-tert-butylpyrazolato)titanium(IV)
B
(tert-butylimido(chloro)(3,5-di-tert-butylpyrazolato)titanium)2
C
magnesium chloride
Conditions | Yield |
---|---|
In hexane byproducts: tert-butylammonium chloride; Ar-atmosphere; stirring (room temp., 16 h); filtering, evapn. (reduced pressure), crystn. (hexane, -15°C, -20°C); elem. anal.; | A 56% B 10% C n/a |
chlorotris(3,5-di-tert-butylpyrazolato)titanium(IV)
methylmagnesium chloride
A
methyltris(3,5-di-tert-butylpyrazolylato)titanium(IV)
B
magnesium chloride
Conditions | Yield |
---|---|
In tetrahydrofuran Ar-atmosphere; MeMgCl soln. (THF) addn. (0°C), stirring (room temp., 20 h), evapn. (reduced pressure); extg. (hexane), filtering, evapn. (reduced pressure); elem. anal.; | A 52% B n/a |
Conditions | Yield |
---|---|
With water In neat (no solvent) reduction of dry CaCl2 in H2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;; | A 50% B n/a C n/a |
With water In neat (no solvent) reduction of dry CaCl2 in H2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;; | A 50% B n/a C n/a |
With water In neat (no solvent) reduction of dry CaCl2 in CO2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;; | A 30% B n/a C n/a |
With water In neat (no solvent) reduction of dry CaCl2 in CO2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;; | A 30% B n/a C n/a |
Conditions | Yield |
---|---|
In diethyl ether under Ar, -80°C, molar ratio arsacarbollyl:(CH3)2CHMgCl=4.50:4.44, 1h stirring at room temp.; colorless ppt. is filtered off, solvent removed, extd. with hot hexane, evapd. to dryness, subl. in high vac. at 50°C, elem. anal.; | A 50% B n/a |
Vanadium (III) chloride-(tris-tetrahydrofuran)
pentafluorophenylmagnesium chloride
B
Tetrakis(pyridin)-dichlorovanadin(II)
C
magnesium chloride
Conditions | Yield |
---|---|
In tetrahydrofuran 1 mol of complex was slowly added to an THF soln. of 2 mol RMgCl at -15°C, after 1 h the temp. was raised to room temp. (Ar atm.);; dioxane in Et2O was added, evapd., ppt. was washed with Et2O;; | A 43% B 47% C n/a |
Vanadium (III) chloride-(tris-tetrahydrofuran)
(trimethylsilyl)methylmagnesium chloride
A
Tetrakis(pyridin)-dichlorovanadin(II)
B
tetrakis(trimethylsilylmethyl)vanadium
C
magnesium chloride
Conditions | Yield |
---|---|
In diethyl ether 1 mol of complex was slowly added to an ether soln. of 2 mol RMgCl at -15°C, after 1 h the temp. was raised to room temp. (Ar atm.);; dioxane was added, ppt. was extd. with pentane; elem. anal.;; | A 43% B 45% C n/a |
dichlorobis(3,5-di-tert-butylpyrazolylato)titanium(IV)
benzylmagnesium chloride
A
dibenzylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)
B
magnesium chloride
Conditions | Yield |
---|---|
In diethyl ether; toluene Ar-atmosphere; BnMgCl soln. (Et2O) addn. (0°C), stirring (room temp., 16 h), evapn. (reduced pressure); extg. (hexane), filtering, concg. (reduced pressure), crystn. (-20°C, 2 d); elem. anal.; | A 43% B n/a |
trichloro-(3,5-di-tert-butylpyrazolylato)titanium(IV)
methylmagnesium chloride
A
dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)
B
magnesium chloride
Conditions | Yield |
---|---|
In tetrahydrofuran; hexane Ar-atmosphere; pptn. on mixing reagents (-78°C, 0.25 h), stirring(room temp., 3 h), evapn. (reduced pressure); extg. (hexane), filtering, evapn. (reduced pressure); | A 35% B n/a |
boron trifluoride
boron trichloride
B
boron nitride
C
magnesium chloride
Conditions | Yield |
---|---|
700-1000°C; diluterd with N2; washing with HCl at 1000°C; | A n/a B 34% C n/a |
Conditions | Yield |
---|---|
In diethyl ether under Ar, -80°C, molar ratio ClP((CH3)2C2B9H9):(CH3)2CHMgCl=1:1, warmed to -20°C; colorless ppt. is filtered off, solvent removed, extd. with hot hexane, evapd. to dryness, subl. in high vac. at room temp., elem. anal.; | A 33% B n/a |
magnesium chloride
Conditions | Yield |
---|---|
With hydrogenchloride In neat (no solvent) heating of brucite at 383-412 °C in a stream of dry HCl with formation of MgCl2; | 10.33% |
With HCl In neat (no solvent) heating of brucite at 383-412 °C in a stream of dry HCl with formation of MgCl2; | 10.33% |
Conditions | Yield |
---|---|
In butyldiglyme; ethyldiglym at 40℃; for 3h; |
isopropylmagnesium chloride
methyltrichlorogermane
B
magnesium chloride
Conditions | Yield |
---|---|
In butyldiglyme; ethyldiglym at 40℃; for 3h; |
isopropylmagnesium chloride
methyltrichlorogermane
B
magnesium chloride
Conditions | Yield |
---|---|
In butyldiglyme; ethyldiglym at 40℃; for 3h; |
Conditions | Yield |
---|---|
In butyldiglyme; ethyldiglym for 1h; |
triethylaluminum
n-butyl-ethylmagnesium
A
hydridomagnesium chloride
C
butyl magnesium bromide
D
ethylmagnesium chloride
E
magnesium chloride
Conditions | Yield |
---|---|
In 2-Methylpentane for 4383h; Reactivity; |
Conditions | Yield |
---|---|
With copper In glycerol byproducts: CuCl; Electrolysis; electrolysis of MgCl2 in anhydrous glycerin, copper electrodes, formation of CuCl at the anode and of C3H6O3Mg at the cathode;; | 100% |
With Cu In glycerol byproducts: CuCl; Electrolysis; electrolysis of MgCl2 in anhydrous glycerin, copper electrodes, formation of CuCl at the anode and of C3H6O3Mg at the cathode;; | 100% |
Conditions | Yield |
---|---|
In tetrachloromethane stirred vigorously for 3 d under N2; filtd. or evapn. of solvent under reduced pressure; | 99% |
magnesium chloride
MgCl(Zr2(OC3H7)9)
Conditions | Yield |
---|---|
In isopropyl alcohol; benzene byproducts: KCl; reflux (2 h), volatiles removal, stirring (70°C, 10 h), KCl pptn.; filtration, volatiles removal (27°C, red. pressure), pptn., recrystn. (n-hexane/toluene) or volatilization (210°C, 0.01 mmHg); elem. anal.; | 99% |
magnesium chloride
Mg(Zr2(OC3H7)9)2
Conditions | Yield |
---|---|
In isopropyl alcohol; benzene byproducts: KCl; reflux (2 h), volatiles removal, stirring (70°C, 10 h), KCl pptn., filtration, volatiles removal, (27°C, red. pressure), pptn.; volatilization (175°C, 0.1 mmHg) (70%); elem. anal.; | 99% |
aluminum isopropoxide
magnesium chloride
Mg(2+)*Cl(1-)*Al(OC3H7)4(1-)=MgCl(Al(OC3H7)4)
Conditions | Yield |
---|---|
In isopropyl alcohol; benzene byproducts: KCl; stirring (27°C, 12 h), pptn. (KCl), filtration; volatiles removal (reduced pressure, 27°C), recrystn. (hexane/toluene, -10°C); elem. anal.; | 99% |
Conditions | Yield |
---|---|
In diethyl ether under Ar atm. soln. Mg(BH4)2 in Et2O was prepared by react. MgCl2 and NaBH4 (V.N.Konoplev, Zh.Neorg.Khim., 1980, 25 (7), 1737-1740), anhydrous ammonia was passed through soln. at -10°C; react. mixt. was allowed to warm to room temp., volatiles were removed in vacuo; elem. anal.; | 99% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 1h; Reagent/catalyst; Inert atmosphere; Schlenk technique; | 99% |
Conditions | Yield |
---|---|
With pyrographite In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 98.3 % SnCl4 at 800°C in presence of C;; | 98.3% |
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 74.60 % SnCl4 at 800°C;; | 74.6% |
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 58.79 % SnCl4 at 700°C; equilibrium reaction examinated;; | 58.79% |
Conditions | Yield |
---|---|
With pyrographite In neat (no solvent) byproducts: MgO, CO; formation at reaction of SnO2, MgCl2 and C under exclusion of air for 2 h at 800°C;; collecting of formed SnCl2 at 300-330°C in a condensator at exclusion of air;; | 98.3% |
With C In neat (no solvent) byproducts: MgO, CO; formation at reaction of SnO2, MgCl2 and C under exclusion of air for 2 h at 800°C;; collecting of formed SnCl2 at 300-330°C in a condensator at exclusion of air;; | 98.3% |
With pyrographite In neat (no solvent) byproducts: MgO, CO; heating of a mixture of SnO2 with double excess of MgCl2 in presence of C in 2 h at 523, 548 and 573°C forms liquid SnCl2; examination of the equilibrium reaction;; |
Conditions | Yield |
---|---|
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 40-60 bar, 0°C, 18 h); centrifugation; not isolated; | 96% |
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 0°C, 8 h); centrifugation; not isolated; | 59% |
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 25°C, 40 h); centrifugation; not isolated; | 41% |
With catalyst: TiCl4*2THF/ Mg-anthracene In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 0°C, 40 h); centrifugation; not isolated; | 22% |
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 60°C, 48 h); centrifugation; not isolated; | 15% |
magnesium chloride
Mg[Al(ONC(CH3)2)4]2
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: NaCl; (moisture free); reflux (4 h), NaCl pptn.; filtration, excess solvent removal (red. pressure), crystn., recrystn. (toluene, -20°C); elem anal.; | 96% |
Conditions | Yield |
---|---|
Stage #1: levodopa With potassium tert-butylate In tetrahydrofuran; N,N-dimethyl acetamide for 0.25h; Stage #2: magnesium chloride In tetrahydrofuran; N,N-dimethyl acetamide | 96% |
trifluoroacetic acid
magnesium chloride
magnesium(II) 2,2,2-trifluoroacetate
Conditions | Yield |
---|---|
at 20 - 100℃; for 1h; | 95% |
Conditions | Yield |
---|---|
In water byproducts: NaCl; Trofimenko, S., J. Am. Chem. Soc., 89 (1967), 3170; crystd. (toluene/CH2Cl2), sublimed (vac.); elem. anal., TGA; | 94% |
Conditions | Yield |
---|---|
Stage #1: [Rh(1,10-phenanthroline)(NH3)4](CF3SO3)3; 5,6-chrysenedione; sodium hydroxide In water; acetonitrile Stage #2: magnesium chloride With sephadex QAE anionexchange column | 94% |
tetrahydrofuran
tert-butyl acetoacetate sodium salt
magnesium chloride
Conditions | Yield |
---|---|
at 20℃; for 72h; Inert atmosphere; Schlenk technique; Glovebox; | 94% |
Conditions | Yield |
---|---|
In 1,2-dimethoxyethane mixt. of MgCl2, NaBH4 in DME was stirred for 10 h under inert atm; filtered, washed with DME, solvent was vac. distilled, extd. with CH2Cl2, CH2Cl2 was distilled in vacuo; elem. anal.; | 93% |
for 7 - 22h; Inert atmosphere; Glovebox; Schlenk technique; | 85% |
2,5‐dihydroxyterephthalate
magnesium chloride
Conditions | Yield |
---|---|
Stage #1: 2,5‐dihydroxyterephthalate; magnesium chloride; iron(II) chloride In methanol; N,N-dimethyl-formamide at 120℃; for 16h; Stage #2: In N,N-dimethyl-formamide at 120℃; for 9h; Stage #3: In methanol at 60℃; | 93% |
Conditions | Yield |
---|---|
In methanol; N,N-dimethyl-formamide at 120℃; for 16h; | 93% |
Conditions | Yield |
---|---|
In benzene soln. of Ti(OPr-i)4 (6.37 mol) in benzene added to slurry of MgCl2 (3.15mol) in benzene; stirred at room temp. until dissolution of MgCl2 (24 h ); reflux for 1 h; evapd. (vac. 0.5 mm, room temp.); crystd. at -20°C (hexane/CH2Cl2= 2:1); elem. anal.; | 91% |
Conditions | Yield |
---|---|
In diethyl ether ball milled and refluxed in Et2O; | 90% |
In neat (no solvent) (Ar); mechanical action (3 h, room temp.); extn. (Et2O); | 76% |
In not given |
Conditions | Yield |
---|---|
750 °C for 1 h in inert gas, molar ratio of K2TaF4:chloride = 1:2; | 90% |
700-1000 °C in inert gas, molar ratio of K2TaF7:chloride = 1:2; |
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