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Nanjing Freehoo Chemical Co., Ltd.

1.professional factory direct sales 2.High quality magnesium Grignard reagents is our advantage products 3.complete documents and export capabilities 4.Low price 5. Quick production and shipping Appearance:Dark purple liquid Storage:15-20°C is suitab

Benzylmagnesium chloride 1M/manufacturer/export

Cas:6921-34-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Benzylmagnesium chloride

Cas:6921-34-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Benzylmagnesium Chloride supplier in China

Cas:6921-34-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

benzylmagnesium chloride

Cas:6921-34-2

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Benzylmagnesium chloride

Cas:6921-34-2

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Benzylmagnesium chloride

Cas:6921-34-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Benzylmagnesium chloride Basic information Product Name: Benzylmagnesium chloride Synonyms: chloro(phenylmethyl)-magnesiu;BENZYLMAGNESIUM CHLORIDE;Benzylmagnesium chloride solution;BENZY

Benzylmagnesium Chloride (ca. 16% in Tetrahydrofuran, ca. 1mol/L)

Cas:6921-34-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 6921-34-2 with best quality

Cas:6921-34-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Magnesium,chloro(phenylmethyl)- 6921-34-2

Cas:6921-34-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:6921-34-2

Cas:6921-34-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Benzylmagnesium chloride

Cas:6921-34-2

Min.Order:1 Kilogram

FOB Price: $10.0 / 100.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Benzylmagnesium chloride

Cas:6921-34-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Benzyl magnesium chloride

Cas:6921-34-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Benzyl magnesium chloride

Cas:6921-34-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

CHLORO(PHENYLMETHYL)-MAGNESIUM

Cas:6921-34-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Magnesium,chloro(phenylmethyl)-

Cas:6921-34-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Benzyl magnesium chloride

Cas:6921-34-2

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: Benzylmagnesium Chloride CAS No.:6921-34-2 Molecule Formula:C7H7ClMg Molecule Weight:150.88 Purity: 1.0M Package: 180kg/drum Description:Dark purple liquid Manufacture Standards:Enterprise Standard TESTING ITEMS

High Quality Benzylmagnesium Chloride in stock

Cas:6921-34-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:Benzylmagnesium chloride CAS No:6921-3

Benzylmagnesium chloride

Cas:6921-34-2

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Benzylmagnesium chloride Basic information Product Name: Benzylmagnesium chloride Synonyms: chloro(phenylmethyl)-magnesiu;BENZYLMAGNESIUM CHLORIDE, 1.0M SOLUTION IN DIETHYL ETHER;BENZYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN;BENZY

Benzylmagnesium chloride

Cas:6921-34-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Benzyl magnesium chloride

Cas:6921-34-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Benzyl magnesium chloride

Cas:6921-34-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Benzyl magnesium chloride

Cas:6921-34-2

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Benzylmagnesium chloride

Cas:6921-34-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Benzyl magnesium chloride

Cas:6921-34-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Benzylmagnesium chloride

Cas:6921-34-2

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Benzyl magnesium chloride

Cas:6921-34-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

benzylmagnesium chloride

Cas:6921-34-2

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Benzylmagnesium chloride 500ml

Cas:6921-34-2

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Benzylmagnesium chloride

Cas:6921-34-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

benzyl chloride
100-44-7

benzyl chloride

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
With bromine; magnesium In tetrahydrofuran; tert-butyl methyl ether at 20 - 35℃; Product distribution / selectivity; Inert atmosphere;99%
With magnesium In tetrahydrofuran at 20 - 23℃;95%
With polymer supported 'magnesium(anthracene)'90%
benzyl chloride
100-44-7

benzyl chloride

A

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

B

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
With magnesium In tetrahydrofuran; 2-methyltetrahydrofuran at 60℃; under 5171.62 Torr; Solvent; Temperature; Inert atmosphere; Flow reactor;A n/a
B 83%
{C5H5FeC5H4CH2N(CH3)2CH2CHCH2}(1+)*Br(1-)={C5H5FeC5H4CH2N(CH3)2CH2CHCH2}Br

{C5H5FeC5H4CH2N(CH3)2CH2CHCH2}(1+)*Br(1-)={C5H5FeC5H4CH2N(CH3)2CH2CHCH2}Br

1-propylmagnesium chloride
2234-82-4

1-propylmagnesium chloride

A

N,N'-dimethylbenzylamine
103-83-3

N,N'-dimethylbenzylamine

B

N,N-dimethylaminomethylferrocene
1271-86-9

N,N-dimethylaminomethylferrocene

C

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

D

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
With CoCl2A n/a
B 70%
C 10%
D 61%
With CoCl2A n/a
B 70%
C 10%
D 61%
(3-Methyl-2-phenyl-3,6-dihydro-2H-selenopyran-2-yl)-phenyl-methanone
114272-48-9, 114272-57-0

(3-Methyl-2-phenyl-3,6-dihydro-2H-selenopyran-2-yl)-phenyl-methanone

A

(±)2-methyl-1-phenylpentan-1-one
31366-05-9

(±)2-methyl-1-phenylpentan-1-one

B

1,2-diphenyl-3-methylhexane
114272-51-4

1,2-diphenyl-3-methylhexane

C

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
With nickel In ethanol Heating;A n/a
B 57%
C n/a
9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium
86901-19-1

9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium

benzyl chloride
100-44-7

benzyl chloride

A

9,10-dibenzyl-9,10-dihydroanthracene
3613-43-2

9,10-dibenzyl-9,10-dihydroanthracene

B

9-benzyl-9,10-dihydroanthracene
2294-89-5

9-benzyl-9,10-dihydroanthracene

C

2-Benzyl-1,2-dihydro-anthracene
126695-08-7

2-Benzyl-1,2-dihydro-anthracene

D

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran for 3h; Ambient temperature; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium
86901-19-1

9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium

benzyl chloride
100-44-7

benzyl chloride

A

9-benzyl-9,10-dihydroanthracene
2294-89-5

9-benzyl-9,10-dihydroanthracene

B

2-Benzyl-1,2-dihydro-anthracene
126695-08-7

2-Benzyl-1,2-dihydro-anthracene

C

1,2-Dibenzyl-1,2-dihydro-anthracene

1,2-Dibenzyl-1,2-dihydro-anthracene

D

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran for 3h; Ambient temperature; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium
86901-19-1

9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium

benzyl chloride
100-44-7

benzyl chloride

A

9-benzyl-9,10-dihydroanthracene
2294-89-5

9-benzyl-9,10-dihydroanthracene

B

2-Benzyl-1,2-dihydro-anthracene
126695-08-7

2-Benzyl-1,2-dihydro-anthracene

C

1,4-Dibenzyl-1,4-dihydro-anthracene

1,4-Dibenzyl-1,4-dihydro-anthracene

D

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran for 3h; Ambient temperature; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
benzyl chloride
100-44-7

benzyl chloride

A

2-methylanthracene
613-12-7

2-methylanthracene

B

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

C

toluene
108-88-3

toluene

D

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
With magnesium 9,10-dimethylanthracene * 3 THF In tetrahydrofuran for 3h; Yield given. Yields of byproduct given;
benzyl chloride
100-44-7

benzyl chloride

A

9,10-dibenzyl-9,10-dihydroanthracene
3613-43-2

9,10-dibenzyl-9,10-dihydroanthracene

B

9-benzyl-9,10-dihydroanthracene
2294-89-5

9-benzyl-9,10-dihydroanthracene

C

2-Benzyl-1,2-dihydro-anthracene
126695-08-7

2-Benzyl-1,2-dihydro-anthracene

D

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
With magnesium anthracene * 3 THF In diethyl ether for 1h; Ambient temperature; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
diethyl ether
60-29-7

diethyl ether

benzyl chloride
100-44-7

benzyl chloride

magnesium

magnesium

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

2-(Dimethyl-λ4-sulfanylidene)-1,2-diphenyl-ethanone
60014-28-0

2-(Dimethyl-λ4-sulfanylidene)-1,2-diphenyl-ethanone

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Se / toluene / 1.5 h / Heating
2: Raney nickel / ethanol / Heating
View Scheme
4-(chloroacetyl)biphenyl
635-84-7

4-(chloroacetyl)biphenyl

A

2-(4-biphenylyl)-3-chloro-1-phenylpropan-2-ol
75450-68-9

2-(4-biphenylyl)-3-chloro-1-phenylpropan-2-ol

B

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

benzyl bromide
100-39-0

benzyl bromide

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
With iodine; magnesium In tetrahydrofuran at 20 - 50℃; for 0.5h; Inert atmosphere;
benzyl chloride
100-44-7

benzyl chloride

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

Conditions
ConditionsYield
With diethyl ether; magnesium
acetophenone
98-86-2

acetophenone

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

1,2-diphenylpropane-2-ol
5342-87-0

1,2-diphenylpropane-2-ol

Conditions
ConditionsYield
In dichloromethane at 0 - 20℃;100%
truxenone
4430-15-3

truxenone

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

5,10,15-triol-5,10,15-tribenzyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene

5,10,15-triol-5,10,15-tribenzyl-10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene

Conditions
ConditionsYield
In tetrahydrofuran for 8h; Ambient temperature;100%
(3aR,5S,6aR)-2,2-dimethyl-5-[(2R)-oxiran-2-yl]-3a,5,6,6a-tetrahydrofuro[2,3-d] [1,3]dioxole
2457-93-4

(3aR,5S,6aR)-2,2-dimethyl-5-[(2R)-oxiran-2-yl]-3a,5,6,6a-tetrahydrofuro[2,3-d] [1,3]dioxole

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

6-benzyl-3,6-dideoxy-1,2-O-isopropylidene-D-glucose
125218-34-0

6-benzyl-3,6-dideoxy-1,2-O-isopropylidene-D-glucose

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃;100%
2-(2-bromoethyl)isoindoline-1,3-dione
574-98-1

2-(2-bromoethyl)isoindoline-1,3-dione

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

9b-benzyl-2,3-dihydrooxazolo[2,3-a]isoindol-5-(9bH)-one
876065-74-6

9b-benzyl-2,3-dihydrooxazolo[2,3-a]isoindol-5-(9bH)-one

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃; for 48h;100%
((CH3)5C5)Co((C2H5)2C2B3H3)Ta(Cl)2(C5H5)

((CH3)5C5)Co((C2H5)2C2B3H3)Ta(Cl)2(C5H5)

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

((CH3)5C5)Co((C2H5)2C2B3H3)Ta(CH2C6H5)2(C5H5)

((CH3)5C5)Co((C2H5)2C2B3H3)Ta(CH2C6H5)2(C5H5)

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether stirring (2 h); evapn., CH2Cl2 addn., filtering, evapn., washing (petroleum ether); elem. anal.;100%
(1RS,4SR)-4-(tert-butyldimethylsilyloxy)cyclopent-2-enyl picolinate

(1RS,4SR)-4-(tert-butyldimethylsilyloxy)cyclopent-2-enyl picolinate

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

C18H28OSi

C18H28OSi

Conditions
ConditionsYield
With copper(I) bromide dimethylsulfide complex; zinc dibromide In tetrahydrofuran; diethyl ether at 0℃; for 1h; regioselective reaction;100%
benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

4-(cyano-ethoxycarbonyl-methylene)-piperidine-1-carboxylic acid benzyl ester
475095-03-5

4-(cyano-ethoxycarbonyl-methylene)-piperidine-1-carboxylic acid benzyl ester

4-benzyl-4-(cyano-ethoxycarbonyl-methylene)-piperidine-1-carboxylic acid benzyl ester
911228-42-7

4-benzyl-4-(cyano-ethoxycarbonyl-methylene)-piperidine-1-carboxylic acid benzyl ester

Conditions
ConditionsYield
Stage #1: benzylmagnesium chloride With copper(l) cyanide In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
Stage #2: 4-(cyano-ethoxycarbonyl-methylene)-piperidine-1-carboxylic acid benzyl ester In tetrahydrofuran at -10 - 20℃;
100%
α-methoxy-N-methoxycarbonylazocane
1227635-41-7

α-methoxy-N-methoxycarbonylazocane

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

α-benzyl-N-methoxycarbonylazocane
1227635-47-3

α-benzyl-N-methoxycarbonylazocane

Conditions
ConditionsYield
Stage #1: α-methoxy-N-methoxycarbonylazocane; benzylmagnesium chloride In dichloromethane at -78℃; for 1h; Inert atmosphere;
Stage #2: With boron trifluoride diethyl etherate In dichloromethane at -78℃; Inert atmosphere;
100%
benzyl 2-methoxyazepane-1-carboxylate
1227635-42-8

benzyl 2-methoxyazepane-1-carboxylate

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

α-benzyl-N-benzyloxycarbonylazepane
1227635-50-8

α-benzyl-N-benzyloxycarbonylazepane

Conditions
ConditionsYield
Stage #1: benzyl 2-methoxyazepane-1-carboxylate; benzylmagnesium chloride In dichloromethane at -78℃; for 1h; Inert atmosphere;
Stage #2: With boron trifluoride diethyl etherate In dichloromethane at -78℃; Inert atmosphere;
100%
α-methoxy-N-benzyloxycarbonylazocane
1227635-43-9

α-methoxy-N-benzyloxycarbonylazocane

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

α-benzyl-N-benzyloxycarbonylazocane
1227635-51-9

α-benzyl-N-benzyloxycarbonylazocane

Conditions
ConditionsYield
Stage #1: α-methoxy-N-benzyloxycarbonylazocane; benzylmagnesium chloride In dichloromethane at -78℃; for 1h; Inert atmosphere;
Stage #2: With boron trifluoride diethyl etherate In dichloromethane at -78℃; Inert atmosphere;
100%
benzyl 2-methoxypyrrolidine-1-carboxylate
88001-42-7

benzyl 2-methoxypyrrolidine-1-carboxylate

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

α-benzyl-N-benzyloxycarbonylpyrrolidine
1227635-48-4

α-benzyl-N-benzyloxycarbonylpyrrolidine

Conditions
ConditionsYield
Stage #1: benzyl 2-methoxypyrrolidine-1-carboxylate; benzylmagnesium chloride In dichloromethane at -78℃; for 1h; Inert atmosphere;
Stage #2: With boron trifluoride diethyl etherate In dichloromethane at -78℃; Inert atmosphere;
100%
2-methoxypiperidine-1-carboxylic acid benzyl ester
66893-75-2

2-methoxypiperidine-1-carboxylic acid benzyl ester

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

α-benzyl-N-benzyloxycarbonylpiperidine
1227635-49-5

α-benzyl-N-benzyloxycarbonylpiperidine

Conditions
ConditionsYield
Stage #1: 2-methoxypiperidine-1-carboxylic acid benzyl ester; benzylmagnesium chloride In dichloromethane at -78℃; for 1h; Inert atmosphere;
Stage #2: With boron trifluoride diethyl etherate In dichloromethane at -78℃; Inert atmosphere;
100%
2-methoxy-piperidine-1-carboxylic acid methyl ester
56475-86-6

2-methoxy-piperidine-1-carboxylic acid methyl ester

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

α-benzyl-N-methoxycarbonylpiperidine
144688-84-6

α-benzyl-N-methoxycarbonylpiperidine

Conditions
ConditionsYield
Stage #1: 2-methoxy-piperidine-1-carboxylic acid methyl ester; benzylmagnesium chloride In dichloromethane at -78℃; for 1h; Inert atmosphere;
Stage #2: With boron trifluoride diethyl etherate In dichloromethane at -78℃; Inert atmosphere;
100%
1-Carbomethoxy-2-methoxy-hexamethylenimine
84839-66-7

1-Carbomethoxy-2-methoxy-hexamethylenimine

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

α-benzyl-N-methoxycarbonylazepane
1227635-46-2

α-benzyl-N-methoxycarbonylazepane

Conditions
ConditionsYield
Stage #1: 1-Carbomethoxy-2-methoxy-hexamethylenimine; benzylmagnesium chloride In dichloromethane at -78℃; for 1h; Inert atmosphere;
Stage #2: With boron trifluoride diethyl etherate In dichloromethane at -78℃; Inert atmosphere;
100%
methyl 2-methoxypyrrolidine-1-carboxylate
56475-88-8

methyl 2-methoxypyrrolidine-1-carboxylate

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

α-benzyl-N-methoxycarbonylpyrrolidine
144688-80-2

α-benzyl-N-methoxycarbonylpyrrolidine

Conditions
ConditionsYield
Stage #1: methyl 2-methoxypyrrolidine-1-carboxylate; benzylmagnesium chloride In dichloromethane at -78℃; for 1h; Inert atmosphere;
Stage #2: With boron trifluoride diethyl etherate In dichloromethane at -78℃; Inert atmosphere;
100%
acetylacetone
123-54-6

acetylacetone

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

spiro[adamantane-2,3'-diazirine]
41736-95-2

spiro[adamantane-2,3'-diazirine]

A

2-Adamantanone
700-58-3

2-Adamantanone

B

1-benzyl-3,5-dimethyl-1H-pyrazole
1134-81-2

1-benzyl-3,5-dimethyl-1H-pyrazole

Conditions
ConditionsYield
Stage #1: benzylmagnesium chloride; spiro[adamantane-2,3'-diazirine] In diethyl ether at 0℃; for 2h; Inert atmosphere;
Stage #2: acetylacetone With toluene-4-sulfonic acid In ethanol at 80℃; for 24h; Inert atmosphere;
A 84%
B 100%
2,2,6,6-tetramethyl-piperidine
768-66-1

2,2,6,6-tetramethyl-piperidine

zinc trimethylacetate

zinc trimethylacetate

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

TMPZnCl*Mg(OPiv)2, TMP - 2,2,6,6-tetramethylpiperidyl, OPiv -pivalate

TMPZnCl*Mg(OPiv)2, TMP - 2,2,6,6-tetramethylpiperidyl, OPiv -pivalate

Conditions
ConditionsYield
Stage #1: 2,2,6,6-tetramethyl-piperidine; benzylmagnesium chloride In tetrahydrofuran at 40℃; Inert atmosphere; Schlenk technique;
Stage #2: zinc trimethylacetate In tetrahydrofuran at 20℃; for 0.333333h; Inert atmosphere; Schlenk technique;
100%
Stage #1: 2,2,6,6-tetramethyl-piperidine; benzylmagnesium chloride In tetrahydrofuran at 20 - 40℃; for 12h; Inert atmosphere; Schlenk technique;
Stage #2: zinc trimethylacetate In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Schlenk technique;
C20H32N3O2P

C20H32N3O2P

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

(3aR,7aR)-1,3-diisopropyl-2-(((S)-1-(3-methoxyphenyl)-2-phenylethyl)amino)octahydrobenzo[d][1,3,2]diazaphosphole 2-oxide

(3aR,7aR)-1,3-diisopropyl-2-(((S)-1-(3-methoxyphenyl)-2-phenylethyl)amino)octahydrobenzo[d][1,3,2]diazaphosphole 2-oxide

Conditions
ConditionsYield
In dichloromethane at -48℃; for 6h; Inert atmosphere;100%
benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

Conditions
ConditionsYield
With ethylene dibromide; silver(I) 4-methylbenzenesulfonate In tetrahydrofuran at 20℃; for 0.5h;99%
With dilithium tetrachlorocuprate; N,N'-di-tert-butyldiaziridinone In tetrahydrofuran at 20℃; for 3h; Inert atmosphere;98%
With trifluoromethanesulfonic acid anhydride In diethyl ether for 0.333333h; Heating;95%
(S)-3-(1H-indol-3-yl)-N-methoxy-N-methyl-2-(triethylsilyloxy)-propanamide
1155864-28-0

(S)-3-(1H-indol-3-yl)-N-methoxy-N-methyl-2-(triethylsilyloxy)-propanamide

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

(S)-4-(1H-indol-3-yl)-1-phenyl-3-(triethylsilyloxy)butan-2-one
1155864-29-1

(S)-4-(1H-indol-3-yl)-1-phenyl-3-(triethylsilyloxy)butan-2-one

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃; Inert atmosphere;99%
(Z)-5<(tert-butyldimethylsilyl)oxy>3,4-epoxy-3-methyl-1-pentyne

(Z)-5<(tert-butyldimethylsilyl)oxy>3,4-epoxy-3-methyl-1-pentyne

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

1-(t-butyldimethylsilyloxy)-3-methyl-6-phenylhexa-3,4-dien-2-ol

1-(t-butyldimethylsilyloxy)-3-methyl-6-phenylhexa-3,4-dien-2-ol

Conditions
ConditionsYield
Stage #1: benzylmagnesium chloride With copper(I) bromide dimethylsulfide complex; lithium bromide In tetrahydrofuran at -20℃; for 0.5h; Inert atmosphere;
Stage #2: (Z)-5<(tert-butyldimethylsilyl)oxy>3,4-epoxy-3-methyl-1-pentyne In tetrahydrofuran at -80 - -50℃; for 4h; Inert atmosphere; optical yield given as %de;
99%
tert-butyl N-[(1R)-2-[methoxy(methyl)amino]-1-methyl-2-oxo-ethyl]carbamate
146553-06-2

tert-butyl N-[(1R)-2-[methoxy(methyl)amino]-1-methyl-2-oxo-ethyl]carbamate

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

((R)-1-methyl-2-oxo-3-phenyl-propyl)-carbamic acid tert-butyl ester
1426421-61-5

((R)-1-methyl-2-oxo-3-phenyl-propyl)-carbamic acid tert-butyl ester

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at -16 - 20℃;99%
(1RS,2SR,7SR)-4-[2-(1H-indol-3-yl)ethyl]-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione

(1RS,2SR,7SR)-4-[2-(1H-indol-3-yl)ethyl]-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

(1RS,2SR,7SR)-5-benzyl-5-hydroxy-4-[2-(1H-indol-3-yl)ethyl]-4-azatricyclo[5.2.1.02,6]dec-8-ene-3-one

(1RS,2SR,7SR)-5-benzyl-5-hydroxy-4-[2-(1H-indol-3-yl)ethyl]-4-azatricyclo[5.2.1.02,6]dec-8-ene-3-one

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at -78 - 20℃; diastereoselective reaction;99%
C25H31NO3

C25H31NO3

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

(1R,2S,5R)-5-methyl-2-(2-phenylpropan-2-yl)cyclohexyl (4-methoxyphenyl)-L-phenylalaninate

(1R,2S,5R)-5-methyl-2-(2-phenylpropan-2-yl)cyclohexyl (4-methoxyphenyl)-L-phenylalaninate

Conditions
ConditionsYield
Stage #1: benzylmagnesium chloride With zinc(II) chloride In tetrahydrofuran at 20℃; for 1h; Schlenk technique;
Stage #2: C25H31NO3 In tetrahydrofuran at -78℃; for 2h; Schlenk technique; diastereoselective reaction;
99%
(5S,2E)-ethyl 4,4-dichloro-5-(1,1-dimethylethylsulfonamido)-6-methylhept-2-enoate

(5S,2E)-ethyl 4,4-dichloro-5-(1,1-dimethylethylsulfonamido)-6-methylhept-2-enoate

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

(2S,5S,3Z)-ethyl 2-benzyl-4-chloro-5-(1,1-dimethylethylsulfonamido)-6-methylhept-3-enoate

(2S,5S,3Z)-ethyl 2-benzyl-4-chloro-5-(1,1-dimethylethylsulfonamido)-6-methylhept-3-enoate

Conditions
ConditionsYield
Stage #1: benzylmagnesium chloride With copper(l) cyanide; lithium chloride In tetrahydrofuran at -78 - 0℃; for 0.166667h; Inert atmosphere;
Stage #2: (5S,2E)-ethyl 4,4-dichloro-5-(1,1-dimethylethylsulfonamido)-6-methylhept-2-enoate In tetrahydrofuran at -78℃; for 0.5h; Inert atmosphere; diastereoselective reaction;
99%
5,7-di-tert-butyl-1,2,3,3a-tetrahydrobenzo[d]pyrrolo[2,1-b]oxazole

5,7-di-tert-butyl-1,2,3,3a-tetrahydrobenzo[d]pyrrolo[2,1-b]oxazole

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

2-(2-benzylpyrrolidin-1-yl)-4,6-di-tert-butylphenol

2-(2-benzylpyrrolidin-1-yl)-4,6-di-tert-butylphenol

Conditions
ConditionsYield
In diethyl ether; 1,2-dichloro-ethane at 0℃; Solvent; Inert atmosphere;99%
3-(4’-methoxy-1,1’-biphenyl-4-yl)-2-(methylsulfanyl)benzofuran

3-(4’-methoxy-1,1’-biphenyl-4-yl)-2-(methylsulfanyl)benzofuran

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

2-benzyl-3-(4’-methoxy-1,1’-biphenyl-4-yl)benzofuran

2-benzyl-3-(4’-methoxy-1,1’-biphenyl-4-yl)benzofuran

Conditions
ConditionsYield
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](triphenylphosphine)nickel(II) dichloride In toluene at 50℃; for 4h; Schlenk technique; Inert atmosphere;99%
1,3-chlorobromopropane
109-70-6

1,3-chlorobromopropane

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

1-Chloro-4-phenylbutane
4830-93-7

1-Chloro-4-phenylbutane

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 5℃; for 6h;98.6%
In tetrahydrofuran at 0 - 5℃; for 6h;94.1%
2-[(1-phenylmethyl)sulfinyl]pyridine
87577-90-0

2-[(1-phenylmethyl)sulfinyl]pyridine

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

2-Benzylpyridine
101-82-6

2-Benzylpyridine

Conditions
ConditionsYield
With phenylmagnesium bromide In tetrahydrofuran for 0.25h; Ambient temperature;98%

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