CAS No.16940-66-2,Sodium tetrahydroborate Suppliers,MSDS download

: 121-43-7
Trimethyl borate

: 7646-69-7
sodium hydride

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
Heating;	99.5%
In neat (no solvent) 1mol B(OCH3)3, 4mol NaH, 225-275°C;; 90-96% NaBH4;;	94%
In neat (no solvent) 1mol B(OCH3)3, 4mol NaH, 225-275°C;; 90-96% NaBH4;;	94%

: boric acid trimethylester tetrahydrofuranate

: Tetrahydro-furan; compound with trifluoroborane

: 7646-69-7
sodium hydride

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: NaF; addn. of B(OCH3)3THF to NaH at 60-65°C (stirring, N2-atmosphere), NaH dissolves, boiling, cooling to ambient temp., addn. of BF3THF, distn. of THF and B(OCH3), extractn. of residue with isopropyl amine;; pure product;;	99%
In tetrahydrofuran byproducts: NaF; addn. of B(OCH3)3THF to NaH at 60-65°C (stirring, N2-atmosphere), NaH dissolves, boiling, cooling to ambient temp., addn. of BF3THF, distn. of THF and B(OCH3), extractn. of residue with isopropyl amine;; pure product;;	99%

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: neodymium borohydride * 3 tetrahydrofuran

: disodium 5,6-dihydro-1,4-dithiine-2,3-dithiolate

A: 16940-66-2
sodium tetrahydroborate

B: [Na3(tetrahydrofuran)1.5Nd(5,6-dihydro-1,4-dithiine-2,3-dithiolate)3]

Conditions

Conditions	Yield
In tetrahydrofuran (Ar); a flask charged with Nd complex, THF condensed, C4H4S2(SNa)2 added, stirred for 3 d at 20°C; filtered, evapd., extd. (THF), filtered; obtained impure;	A n/a B 99%

...Expand

: 7646-69-7
sodium hydride

: 19287-45-7
diborane

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In further solvent(s) react. of NaH with B2H6 in alkylene glycol dialkylether at 35-75°C;;	98%
In tetrahydrofuran in abs. tetrahydrofurane; 4 h, under shaking; good yield; Na(BH4) suspension distilled, filtered and dried in oil pump vacuum at 130°C; purity = 97.5 %;	93%
In tetrahydrofuran in abs. tetrahydrofurane; 4 h, under shaking; good yield; Na(BH4) suspension distilled, filtered and dried in oil pump vacuum at 130°C; purity = 97.5 %;	93%

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: NaZn(BH4)3*3DME

A: 16940-66-2
sodium tetrahydroborate

B: N,N,N',N'-tetramethylethylenediaminebis(tetrahydroborate)zinc(II)

Conditions

Conditions	Yield
In benzene org. compd. soln. addn. dropwise (magnetic stirring) to Zn-complex soln., NaBH4 ppt. filtration off after 1 h, solvent evapn. from filtrate (vac.); residue washing (pentane), drying (vac.); elem. anal; thermal anal.;	A 77% B 97%

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: 109-63-7
trifluoroborane diethyl ether

: 7646-69-7
sodium hydride

A: 16940-66-2
sodium tetrahydroborate

B: 19287-45-7
diborane

Conditions

Conditions	Yield
In diethylene glycol method for preparation of diborane, addn. of BF3-etherate (frehly distd.) to NaH in diglyme;;	A n/a B 92%
In diethylene glycol method for preparation of diborane, addn. of BF3-etherate (frehly distd.) to NaH in diglyme;;	A n/a B 92%
In diethyl ether at 110°C, method for preparation of diborane;;
In diethyl ether at 110°C, method for preparation of diborane;;

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: borax

: 1333-74-0
hydrogen

: 1310-73-2
sodium hydroxide

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
magnesium In water byproducts: MgO; process starts from borax and NaOH by exothermal steam process (H2O); dread at 270°C; H2 at surface of Mg particles generated protide to form NaBH4; process dependent on of rate temp. change, size of Mg particles; XRD;	90%

...Expand

: 7637-07-2
boron trifluoride

: 7646-69-7
sodium hydride

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
With catalyst: Na-alcoholate In neat (no solvent) passing BF3 over NaH in presence of a Na-alcoholate, 250-300°C;;	90%
In neat (no solvent) byproducts: B2H6; on passing a mixture of BF3 and H2 (ratio=1:2) over powdered NaH at about 180°C;;
In diethyl ether react. of NaH with a soln. of BF3 in ether in an autoclave (about 10 at), 24h, about 120°C;;
In mineral oil at 250-265°C;; washing with petroleum ether, extractn. of NaBH4 from the residue with liquid NH3 at -33°C;;
In neat (no solvent) byproducts: B2H6; on passing a mixture of BF3 and H2 (ratio=1:2) over powdered NaH at about 180°C;;

: NaSm(BH4)4 * 4 dimethoxyethane

A: 16940-66-2
sodium tetrahydroborate

B: [Sm(BH4)3(tetrahydrofuran)3]

Conditions

Conditions	Yield
With tetrahydrofuran In neat (no solvent) byproducts: DME; 140-160°C, vac., 2 h; extn. (THF), filtration off of NaBH4, distn. off of solvent; elem. anal.;	A n/a B 89%

: 121-43-7
Trimethyl borate

: 7646-69-7
sodium hydride

A: 16940-66-2
sodium tetrahydroborate

B: 18024-69-6
sodium tetramethoxyborate

Conditions

Conditions	Yield
In tetrahydrofuran with excess NaH; at 65°C;	A 83% B n/a
In tetrahydrofuran on boiling in THF, pptn. of NaBH4;;
In tetrahydrofuran on boiling in THF, pptn. of NaBH4;;

...Expand

: 18024-69-6
sodium tetramethoxyborate

: 7646-69-7
sodium hydride

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In neat (no solvent) heating to 250-270°C, excess NaH;;	78%
In neat (no solvent) heating to 250-270°C, excess NaH;;	78%
In neat (no solvent) molar ratio NaH:NaB(OCH3)4=4:1, 250.C;; 91% NaBH4;;	66%
In neat (no solvent) molar ratio NaH:NaB(OCH3)4=4:1, 250.C;; 91% NaBH4;;	66%

: sodium trimethoxyborohydride

: 7646-69-7
sodium hydride

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In neat (no solvent) molar ratio NaH:NaBH(OCH3)3=3:1, 250-270°C;;	78%
In neat (no solvent) heating to 250-270°C, excess NaH;;	78%
In neat (no solvent) molar ratio NaH:NaBH(OCH3)3=3:1, 250-270°C;;	78%

: Sodium borate

: magnesium hydride

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
With sodium carbonate In neat (no solvent) byproducts: MgO, CO2; ball milled at room temp. for 60 min; extn. by anhyd. ethylendiamine under Ar; filtered soln. evapd. in vac. at room temp.; detn. by XRD;	78%
With sodium peroxide In neat (no solvent) byproducts: MgO, H2; ball milled at room temp. for 60 min; extn. by anhyd. ethylendiamine under Ar, soln. evapd. in vac. at room temp.; detn. by XRD;	67%
With sodium hydroxide In neat (no solvent) byproducts: MgO, H2; ball milled at room temp. for 60 min; extn. by anhyd. ethylendiamine under Ar; filtered soln. evapd. in vac. at room temp.; detn. by XRD;	64%
In neat (no solvent) byproducts: MgO, B2O3; ball milled at room temp. for 60 min; extn. by anhyd. ethylendiamine under Ar; filtered soln. evapd. in vac. at room temp.; detn. by XRD;	43%

: NaNd(BH4)4 * 4 dimethoxyethane

A: 16940-66-2
sodium tetrahydroborate

B: neodymium borohydride * 3 tetrahydrofuran

Conditions

Conditions	Yield
With tetrahydrofuran In neat (no solvent) byproducts: DME; 140-160°C, vac., 2 h; extn. (THF), filtration off of NaBH4, distn. off of solvent, drying (vac., 1 h); elem. anal.;	A n/a B 78%

: 148977-74-6
sodium amidotrihydridoborate

: 13292-87-0
dimethylsulfide borane complex

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In tetrahydrofuran for 5h; Inert atmosphere;	78%

: magnesium hydride

: BO2(1-)*(x)H2O*Na(1+)

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
for 6h; Milling;	76%

: sodium borate

: 1333-74-0
hydrogen

: 7440-23-5
sodium

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In neat (no solvent) react. of Na-borate with Na and H2 at 400-500°C, H2-pressure: several atm, addn. of SiO2 to separate excess Na in form of Na2SiO3;; purity up to 96%;;	75%

...Expand

: sodium triborate

: 1333-74-0
hydrogen

: 7440-23-5
sodium

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In neat (no solvent) react. of Na-borate with Na and H2 at 400-500°C, H2-pressure: several atm, addn. of SiO2 to separate excess Na in form of Na2SiO3;; purity up to 96%;;	75%

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: disodium octaborate

: 1333-74-0
hydrogen

: 7440-23-5
sodium

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In neat (no solvent) react. of Na-borate with Na and H2 at 400-500°C, H2-pressure: several atm, addn. of SiO2 to separate excess Na in form of Na2SiO3;; purity up to 96%;;	75%

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: 13755-29-8
sodium tetrafluoroborate

: 1333-74-0
hydrogen

: 7440-23-5
sodium

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In further solvent(s) introduction of dry H2 under pressure in a dispersion of Na in an inert solvent at 275°C, simultanuous addn. of NaBF4;;	75%
In further solvent(s) introduction of dry H2 under pressure in a dispersion of Na in an inert solvent at 250-350°C, simultanuous addn. of NaBF4;;

...Expand

: Sodium borate

: 1333-74-0
hydrogen

: 7440-23-5
sodium

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In neat (no solvent) react. of Na-borate with Na and H2 at 400-500°C, H2-pressure: several atm, addn. of SiO2 to separate excess Na in form of Na2SiO3;; purity up to 96%;;	75%

...Expand

: 14044-65-6
borane-THF

: 148977-74-6
sodium amidotrihydridoborate

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 5h; Inert atmosphere;	75%

: sodium tetrahydroxyborate

: Mg17Al12

A: 1333-84-2, 1344-28-1
aluminum oxide

B: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
for 20h; Milling; Inert atmosphere;	A n/a B 72%

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: sodium yttrium hydroborate*4 1,2-dimethoxyethane

: 597-49-9
3-ethylpentan-3-ol

A: 16940-66-2
sodium tetrahydroborate

B: 72033-96-6
ytrrium tetrahydridoborate

C: 144782-40-1
bis(3-ethyl-3-pentoxy)borane

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: H2; under inert atm.; excess of alcohol in THF added dropwise at room temp. to stirred soln. of tetrahydroborate complex in THF (accompanied by vigorous gas evolution); stirring was continued for 1 h; mixt. allowed to stand for the reaction to be completed; within 5 ds ppt. sepd. by filtration (identified as NaBH4 by X-ray diffraction and IR spectroscopy); filtrate was distd. (vac., 0.1 mmHg) at room temp. to remove solvent and at 50°C; residue pumped out at 100-115°C; volatile collected ...;	A 70% B n/a C 69%

Yield

In tetrahydrofuran byproducts: H2; under inert atm.; excess of alcohol in THF added dropwise at room temp. to stirred soln. of tetrahydroborate complex in THF (accompanied by vigorous gas evolution); stirring was continued for 1 h; mixt. allowed to stand for the reaction to be completed; within 5 ds ppt. sepd. by filtration (identified as NaBH4 by X-ray diffraction and IR spectroscopy); filtrate was distd. (vac., 0.1 mmHg) at room temp. to remove solvent and at 50°C; residue pumped out at 100-115°C; volatile collected ...;

A 70%
B n/a
C 69%

...Expand

: 37080-36-7
tetraphenylphosphonium tetrahydroborate

: NaLu(BH4)4*(1,2-dimethoxyethane)4

A: 16940-66-2
sodium tetrahydroborate

B: (Ph4P)[Lu(BH4)4]

Conditions

Conditions	Yield
In dichloromethane CH2Cl2 was added to mixt. NaLu(BH4)4*4DME andPh4PBH4 and stirred for several minutes; NaBH4 was filtered off, soln. was concd., Et2O was added, ppt. was separated, washed with Et2O and dried in vac.; elem. anal.;	A n/a B 68.5%

...Expand

: NaZr(BH4)5*3(1,2-dimethoxyethane)

: 597-49-9
3-ethylpentan-3-ol

A: 16940-66-2
sodium tetrahydroborate

B: zirconium(IV) borohydride

C: 144782-40-1
bis(3-ethyl-3-pentoxy)borane

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: H2; under inert atm.; excess of alcohol in THF added dropwise at room temp. to stirred soln. of tetrahydroborate complex in THF (accompanied by vigorous gas evolution); stirring was continued for 1 h; mixt. allowed to stand for the reaction to be completed; within 5 ds ppt. sepd. by filtration (identified as NaBH4 by X-ray diffraction and IR spectroscopy); filtrate was distd. (vac., 0.1 mmHg) at room temp. to remove solvent and at 50°C; residue pumped out at 100-115°C; volatile collected ...;	A 66% B n/a C 65%

Yield

In tetrahydrofuran byproducts: H2; under inert atm.; excess of alcohol in THF added dropwise at room temp. to stirred soln. of tetrahydroborate complex in THF (accompanied by vigorous gas evolution); stirring was continued for 1 h; mixt. allowed to stand for the reaction to be completed; within 5 ds ppt. sepd. by filtration (identified as NaBH4 by X-ray diffraction and IR spectroscopy); filtrate was distd. (vac., 0.1 mmHg) at room temp. to remove solvent and at 50°C; residue pumped out at 100-115°C; volatile collected ...;

A 66%
B n/a
C 65%

...Expand

: BO2(1-)*(x)H2O*Na(1+)

: 1333-74-0
hydrogen

: 1310-73-2
sodium hydroxide

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
With aluminium at 579.84℃; under 17251.7 Torr;	65%

...Expand

: boron trioxide

: 7646-69-7
sodium hydride

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In neat (no solvent) heating to >330°C for 20-48h;;	60%
In neat (no solvent) heating to >330°C for 20-48h;;	60%
With catalyst: Na-alcoholate In neat (no solvent) at about 350°C;;

: boron trioxide

: 7646-69-7
sodium hydride

A: sodium metaborate

B: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
In neat (no solvent) on trituration at 330-350°C for 20-48h;;	A n/a B 60%
In neat (no solvent) on trituration at 330-350°C for 20-48h;;	A n/a B 60%
heating at 330 - 350°C;
heating at 330 - 350°C;

...Expand

: sodium metaborate

: 7646-69-7
sodium hydride

: 16940-66-2
sodium tetrahydroborate

Conditions

Conditions	Yield
With silica gel In solid powders ball milled for 4 h at 400 rpm, SiO2 added, ball-milled for 2 h more, pressed into pellet under 10, 20 or 30 MPa in Ar-filled box, calcined under 0.1 MPa Ar at 480°C for 5 h; extd. by isopropyl amine in modified Soxlet apparatus for 3 h; filtered,evapd. at 50°C;	32%

: 16940-66-2
sodium tetrahydroborate

: calcium chloride

: calcium borohydride

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: sodium chloride; under N2, soln. of CaCl2 and NaBH4 (molar ratio 1:1) in THF stirred with glass beads at 67°C (refluxed) for 1 h;	100%
In tetrahydrofuran byproducts: sodium chloride; under N2, soln. of CaCl2 and NaBH4 (molar ratio 1:1) in THF stirred with glass beads at 25°C for 8 h;	99%
In tetrahydrofuran byproducts: sodium chloride; under N2, soln. of CaCl2 and NaBH4 (molar ratio 1:1) in THF stirred with magnetic stirrer at 67°C (refluxed) for 8i h;	96%

: 16940-66-2
sodium tetrahydroborate

: 7553-56-2
iodine

: 14452-61-0
diborane

Conditions

Conditions	Yield
byproducts: H2, NaI; Interaction of initial cryst. materials in molar ratio NaBH4:I2 = 1.35 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.;	100%
byproducts: H2, NaI; Interaction of initial cryst. materials in molar ratio NaBH4:I2 = 1.5 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.;	97.7%
Kinetics; byproducts: H2, NaI; Interaction of initial cryst. materials in molar ratio NaBH4:I2 = 2.5 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.;	94%
Kinetics; byproducts: H2, NaI; Interaction of initial cryst. materials in molar ratio NaBH4:I2 = 2.0 under mechanical activation with a vibration ball mill (dry N2, atm. pressure, 25°C).; Detn. of gas phase formed by infrared and mass spectroscopy, and gas volumetric anal.;	88.7%
byproducts: H2, HI; Grinding of initial materials (molar ratio = 1) while being cooled withliq. N2, thorough mixing, transferring of mixt. to a thermographic ampoule and heating in vac. or N2.; Sepn. of gas mixt. by fractional condensation. Detn. of composition after the thermography by gas volumetric anal.;

: 16940-66-2
sodium tetrahydroborate

: 7550-35-8
lithium bromide

: lithium borohydride

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: sodium bromide; under N2, soln. of LiBr and NaBH4 (molar ratio 1:1) in THF stirred withglass beads at 67°C (refluxed) for 8 h;	100%
In tetrahydrofuran byproducts: sodium bromide; under N2, soln. of LiBr and NaBH4 (molar ratio 1:1) in THF stirred withmagnetic stirrer at 67°C (refluxed) for 16 h;	99%
In diethyl ether byproducts: sodium bromide; under N2, soln. of LiBr in Et2O stirred with magnetic stirrer for 2 min, 1 equiv of NaBH4 introduced, maintained at 35°C with stirring for 32 h;	99%

: 16940-66-2
sodium tetrahydroborate

: lithium chloride

: lithium borohydride

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: sodium chloride; under N2, soln. of LiCl and NaBH4 (molar ratio 1:1) in THF stirred withglass beads at 25°C for 24 h or at 67°C (refluxed) for 10h;	100%
extraction with ether; purity: 97-98 %;	75%
In tetrahydrofuran byproducts: sodium chloride; under N2, soln. of LiCl and NaBH4 (molar ratio 1:1) in THF stirred withmagnetic stirrer at 67°C (refluxed) for 48 h;	65%

: 16940-66-2
sodium tetrahydroborate

: 91159-98-7
benzo-2-chloro-1,3,2-diazaborolane

: 89799-28-0
2,3-dihydro-1H-1,3,2-benzodiazaborole

Conditions

Conditions	Yield
In benzene recrystn. from benzene;	100%

: 10544-50-0
sulfur

: 16940-66-2
sodium tetrahydroborate

: 7664-41-7
ammonia

: 10043-11-5
ammonia borane complex

Conditions

Conditions	Yield
In ammonia to NaBH4 in a flask at -40°C NH3 is condensed, then slowly S8 isadded (5 h), to the mixt. (after 3 h) CH2Cl2 is added, then the mixt. is warmed to room temp.; residue is extd. with CH2Cl2, the soln. is evapd., elem. anal.;	100%

...Expand

: 16940-66-2
sodium tetrahydroborate

: [(μ-η(2)-η(3)-HC*C-CH2)CoMo(Cp)(CO)5](BF4)

: 126979-16-6
(μ-η(2)-η(2)-HC*CCH3)CoMo(Cp)(CO)5

Conditions

Conditions	Yield
In dichloromethane Ar-atmosphere; addn. of excess of NaBH4 to soln. of complex at 0°C; extn. (ether), washing org. layer by H2O, drying (MgSO4), evapn.; elem. anal.;	100%

: 16940-66-2
sodium tetrahydroborate

: 103746-20-9, 103833-40-5
IrH2(CH3CN)(C6H5P(CH2CH2CH2P(C6H11)2)2)(1+)*BF4(1-)={IrH2(CH3CN)(C6H5P((CH2)3P(C6H11)2)2)}{BF4}

: 145036-85-7
IrH3(C6H5P(CH2CH2CH2P(C6H11)2)2)*C2H5OH

Conditions

Conditions	Yield
In tetrahydrofuran nitrogen atmosphere; NaBH4 added to the Ir complex in THF; mixt. stirred for 20 min; addn. of ethanol, stirring (1 h); removal of the solvent (red. pressure); residue dissolved in THF, filtration; elem. anal.;	100%

: 16940-66-2
sodium tetrahydroborate

: 105404-21-5
1,3-diferrocenyl-2-propen-1-one

: 72971-83-6
rac-1,3-diferrocenylprop-2-en-1-ol

Conditions

Conditions	Yield
In 1,4-dioxane; methanol NaBH4 added to soln. of Fe complex (stirring); stirred (14 h); H2O added; cooled (7-8°C); ppt. filtered; washed (H2O); dried (room temp.); recrystd. (hexane); elem.anal.;	100%

: 16940-66-2
sodium tetrahydroborate

: 441072-64-6
Pt2Me2(μ-Cl)(μ-N,N'-bis[(2-diphenylphosphino)phenyl]formamidinate)

: 441072-56-6
Pt2(methyl)2(μ-H)(μ-N,N'-bis[2-(diphenylphosphino)phenyl]formamidinate)

Conditions

Conditions	Yield
In methanol; dichloromethane under N2 atm. to soln. Pt2Me2(μ-Cl)(μ-dpfam) in CH2Cl2 was addedNaBH4 and MeOH at 0°C and mixt. was stirred for 1 h; solvents were removed under reduced pressure, residue was extd. with CH2Cl2 and filtered, soln. was evapd.; elem. anal.;	100%

: 16940-66-2
sodium tetrahydroborate

: 196520-48-6
(η(5)-cyclopentadienyl)OsCl(triisopropylphosphine)2

: 196520-49-7
OsH(η(5)-C5H5)(PiPr3)2

Conditions

Conditions	Yield
With MeOH In toluene air-free atmosphere; stirring (room temp., 15 min); filtering, evapn., pentane addn., filtering, evapn.;	100%

: 16940-66-2
sodium tetrahydroborate

: 14044-65-6
borane-THF

: 186336-54-9
diphosphane-borane

: 186336-57-2
sodium 1,1,2-tris(borane)-1,2,2-trihydrogendiphosphide

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: H2, Na2[P2H2(BH3)4]; N2 atm.; molar ratio P2H4BH3:NaBH4 1:1, cooling (-78 to -196°C), stirring (4 h), heating (-78°C, 3 h), stirring (room temp., 6 h); crystn. (-78°C, several d);	100%

...Expand

: 16940-66-2
sodium tetrahydroborate

: [(5,7-dimethyl-6-anthracyl-1,4,8,11-tetraazacyclotetradeca-4,7-diene)nickel(II)] nitrate iodide

: sodium perchlorate

: 7732-18-5
water

: [(5,7-dimethyl-6-anthracyl-1,4,8,11-tetraazacyclotetradecane)nickel(II)] perchlorate dihydrate

Conditions

Conditions	Yield
In methanol a 15 equiv of NaBH4 was added to a soln. of complex in methanol, the mixt. was allowed to stir at room temp. for 2 h, ppt. was filtered off, dissolved in H2O, aq. satd. NaClO4 was added dropwise, cooled; ppt. was filtered, washed with ice-cold water and then ether; elem. anal.;	100%

...Expand

: 16940-66-2
sodium tetrahydroborate

: [(5,7-dimethyl-6-(p-hydroxymethylbenzyl)-1,4,8,11-tetraazacyclotetradeca-4,7-diene)nickel(II)] nitrate iodide

: sodium perchlorate

: [(5,7-dimethyl-6-(p-hydroxymethylbenzyl)-1,4,8,11-tetraazacyclotetradecane)nickel(II)] perchlorate

Conditions

Conditions	Yield
In methanol a 15 equiv of NaBH4 was added to a soln. of complex in methanol, the mixt. was allowed to stir at room temp. for 2 h, ppt. was filtered off, dissolved in H2O, aq. satd. NaClO4 was added dropwise, cooled; ppt. was filtered, washed with ice-cold water and then ether;	100%

...Expand

: 16940-66-2
sodium tetrahydroborate

: 60426-33-7
(2,6-bis[(di-t-butylphosphino)methyl]phenyl)chloronickel

: 60399-53-3
(2,6-bis[(di-t-butylphosphino)methyl]phenyl)hydridonickel

Conditions

Conditions	Yield
In ethanol; benzene excess of NaBH4, stirring in C6H6/EtOH=1:1 for 20 h at 20°C, addn. of further NaBH4. stirring for 3 h; addn. of water and C6H6, evapn. of C6H6-layer;	100%

: 16940-66-2
sodium tetrahydroborate

: 39007-30-2, 52019-98-4
[2,6-bis(2-(2-mercaptophenyl)1-methyl-2-azaethenyl)pyridine]zinc(II)

: 354115-72-3
[2,6-bis(1-(2-mercaptoanilino)ethyl)pyridine]zinc(II)

Conditions

Conditions	Yield
In ethanol; N,N-dimethyl-formamide all manipulations under Ar atm.; soln. of NaBH4 in EtOH/DMF (1/4) added dropwise to soln. of complex in DMF at 0°C, stirred at room temp for 2 h; DMF/EtOH removed in vac., residue dissolved in MeOH, pptd. by addn. of water; elem. anal.;	100%

: 16940-66-2
sodium tetrahydroborate

: 203380-20-5
(1S,2R,3S,4R)-3-methoxymethyl-2-triphenylstannylbicyclo[2.2.1]heptane(-)

: 7553-56-2
iodine

: 203380-22-7
diphenyl[(1S,2R,3S,4R)-3-(1-methoxymethyl)bicyclo[2.2.1]heptan-2-yl]tin hydride

Conditions

Conditions	Yield
In dichloromethane I2 addn. to Sn-compd. soln. (DCM), stirring 1 h at room temp., concn. (reduced pressure), B-compd. soln. (EtOH), after 1 h mixt. partitioning between satd. aq. NH4Cl and Et2O, aq. phase extn. (Et2O), extract drying (MgSO4), concn. (reduced pressure);	100%

...Expand

: 16940-66-2
sodium tetrahydroborate

: 852290-93-8
[(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradeca-4,7-diene)nickel(II)] nitrate iodide

: sodium perchlorate

: 7732-18-5
water

: [(5,7-dimethyl-6-benzyl-1,4,8,11-tetraazacyclotetradecane)nickel(II)] perchlorate monohydrate

Conditions

Conditions	Yield
In methanol a large excess of NaBH4 was added to a soln. of complex in methanol, themixt. was allowed to stir at room temp. for 2 h, ppt. was filtered off, dissolved in H2O, aq. satd. NaClO4 was added dropwise, cooled; ppt. was filtered, washed with ice-cold water and then ether; elem. anal.;	100%

...Expand

: 16940-66-2
sodium tetrahydroborate

: diphenyl[(1S,2R,3S,4R)-3-hydroxymethylbicyclo[2.2.1]heptan-2-yl]tin iodide

: 203380-24-9
diphenyl[(1S,2R,3S,4R)-3-hydroxymethylbicyclo[2.2.1]heptan-2-yl]tin hydride

Conditions

Conditions	Yield
In ethanol B-compd. soln. addn. to Sn-compd. soln. at ambient temp., mixt. concn. (reduced pressure) after 30 min, residue partitionation between satd. aq.NH4Cl and Et2O, aq. phase extn. (Et2O), org. extract drying (MgSO4), co ncn. (reduced pressure);	100%

: 16940-66-2
sodium tetrahydroborate

: 920-66-1
1,1,1,3',3',3'-hexafluoro-propanol

: Sodium Tris(1,1,1,3,3,3-hexafluoroisopropoxy)borohydride

Conditions

Conditions	Yield
In tetrahydrofuran at 0℃;	100%

: 16940-66-2
sodium tetrahydroborate

: 1101230-25-4
carbonylchlorohydrido(4,5-bis((diisopropylphosphino)methyl)acridine)ruthenium(II)

: C28H43BClNOP2Ru

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;	100%

: 16940-66-2
sodium tetrahydroborate

: 110-71-4
1,2-dimethoxyethane

: 55011-46-6
5-nitro-2H-tetrazole

A: [Na(1,,2-dimethoxyethane)3][bis(5-nitro-2H-tetrazolyl)dihydroborate]

B: 1333-74-0
hydrogen

Conditions

Conditions	Yield
at 20℃; for 4h; Inert atmosphere;	A 100% B 3.9 mmol

...Expand

: 16940-66-2
sodium tetrahydroborate

: 110-71-4
1,2-dimethoxyethane

: 75393-84-9
5-(trinitromethyl)-2H-tetrazole

A: [Na(1,,2-dimethoxyethane)3][bis(5-(trinitromethyl)-2H-tetrazolyl)dihydroborate]

B: 1333-74-0
hydrogen

Conditions

Conditions	Yield
at 20℃; for 4h; Inert atmosphere;	A 100% B 3.8 mmol

...Expand

: 16940-66-2
sodium tetrahydroborate

: 110-71-4
1,2-dimethoxyethane

: 75393-85-0
5-(fluorodinitromethyl)tetrazole

A: [Na(1,,2-dimethoxyethane)3][bis(5-(fluorodinitromethyl)-2H-tetrazolyl)dihydroborate]

B: 1333-74-0
hydrogen

Conditions

Conditions	Yield
at 20℃; for 4h; Inert atmosphere;	A 100% B 3.7 mmol

...Expand

: 16940-66-2
sodium tetrahydroborate

: 110-71-4
1,2-dimethoxyethane

: 26621-32-9
3,5-dinitro-1H-1,2,4-triazole

A: [Na(1,,2-dimethoxyethane)3][bis(3,5-dinitro-1H-1,2,4-triazolyl)dihydroborate]

B: 1333-74-0
hydrogen

Conditions

Conditions	Yield
at 20℃; for 4h; Inert atmosphere;	A 100% B 4.1 mmol

...Expand

: 16940-66-2
sodium tetrahydroborate

: 517-25-9
trinitromethane

: sodium (trinitromethyl)borate

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Schlenk technique; Inert atmosphere;	100%
In tetrahydrofuran at 20℃; for 0.75h;

: 16940-66-2
sodium tetrahydroborate

: 7677-24-9
trimethylsilyl cyanide

: 88503-36-0
sodium dicyanodihydridoborate

Conditions

Conditions	Yield
for 48h; Inert atmosphere; Reflux;	100%

: 16940-66-2
sodium tetrahydroborate

: cis-α-dichloro {N,N′-[1,2-phenylenebis(methylene)]bis[2-(diphenylphosphino)ethylamine]}ruthenium(II)

: hydrideborohydride {N,N′-[1,2-phenylenebis(methylene)]bis[2-(diphenylphosphino)ethylamine]}ruthenium(II)

Conditions

Conditions	Yield
With ethanol for 1h; Inert atmosphere; Reflux;	100%

: 16940-66-2
sodium tetrahydroborate

: [bis(2-diphenylphosphinophenyl)amide]PdCl

: C36H29NP2Pd

Conditions

Conditions	Yield
In tetrahydrofuran; benzene-d6 at 20℃; for 1h; Inert atmosphere;	100%

: 16940-66-2
sodium tetrahydroborate

: (S)-(+)-β-phenyl-β-alanine methyl ester hydrochloride

: C9H12BNO2

Conditions

Conditions	Yield
With zinc(II) chloride In tetrahydrofuran for 4h; Reagent/catalyst; Reflux;	99.6%

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