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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Trimethylgallium Manufacturer/High quality/Best price/In stock

Cas:1445-79-0

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Henan Allgreen Chemical Co.,Ltd

TRIMETHYLGALLIUM Basic information Product Name: TRIMETHYLGALLIUM Synonyms: GALLIUM TRIMETHYL;TRIMETHYLGALLIUM;(CH3)3Ga;trimethyl-galliu;TMGa;Trimethylgallium,99+%;

TRIMETHYLGALLIUM

Cas:1445-79-0

Min.Order:1 Kilogram

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Trimethylgallium

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Trimethylgallium

Cas:1445-79-0

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

TRIMETHYLGALLIUM

Cas:1445-79-0

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 1445-79-0 with best quality

Cas:1445-79-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

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Shanghai Minstar Chemical Co., Ltd

Product Name: TRIMETHYLGALLIUM CAS: 1445-79-0 MF: C3H9Ga MW: 114.83 EINECS: 215-897-6 Mol File: 1445-79-0.mol TRIMETHYLGALLIUM Structure TRIMETHYLGALLIUM Chemical Properties Melting point -15,8°C Boiling point 55,7&deg

TRIMETHYLGALLIUM

Cas:1445-79-0

Min.Order:1 Gram

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Gallium, trimethyl-

Cas:1445-79-0

Min.Order:1 Gram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Gallium, trimethyl-

Cas:1445-79-0

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Gallium,trimethyl-

Cas:1445-79-0

Min.Order:1 Milligram

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

TRIMETHYLGALLIUM

Cas:1445-79-0

Min.Order:1 Kilogram

FOB Price: $2.0

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Hangzhou Ocean Chemical Co., Ltd.

Ocean inorganic department is a professional supplier and exporter engaging in inorganic chemical materials and metal organic compounds. Over the past years, our company is committed to improving the product quality and developing new products, in

Trimethylgallium

Cas:1445-79-0

Min.Order:0 Metric Ton

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

TRIMETHYLGALLIUM

Cas:1445-79-0

Min.Order:1 Gram

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Trimethylgallium, elec. gr., 99.9998%

Cas:1445-79-0

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Trimethyl gallium

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Trimethylgallium

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

TRIMETHYLGALLIUM

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Henan Tianfu Chemical Co., Ltd.

High quality,low price Application:Usd for medical intermediate Transportation:by sea/by air

TRIMETHYLGALLIUM

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Hunan Russell Chemicals Technology Co.,Ltd

low price and high purity Application:ALD related industries,medicine and electronic materials

Trimethylgallium

Cas:1445-79-0

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Antimex Chemical Limied

Trimethylgallium

Trimethylgallium

Cas:1445-79-0

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Hangzhou Fandachem Co.,Ltd

Trimethylgallium cas 1445-79-0Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Trimethylgallium cas 1445-79-0

Cas:1445-79-0

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

TRIMETHYLGALLIUM

Cas:1445-79-0

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Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

Trimethylindium manufature

Cas:1445-79-0

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Asure Biochem CO.,LTD.

*stable and better quality products*efficient and meticulous servicesAppearance:Powder Storage:Store in dry, cool and ventilated place Package:1kg/tin 5kg/tin 25kg/drum 180kg/drum Application:1. Chemical raw materials 2. Catalysts, additives, etc. Tr

Trimethylgallium

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Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

trimethylgallane

Cas:1445-79-0

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

TRIMETHYLGALLIUM

Cas:1445-79-0

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#1445-79-0;CAT#A808237

Cas:1445-79-0

Min.Order:10 Milligram

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HENAN SUNLAKE ENTERPRISE CORPORATION

Henan Sunlake Enterprise Corporation Our Advantages 1, Any inquiry about ch

TRIMETHYLGALLIUM

Cas:1445-79-0

Min.Order:1 Kilogram

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SuZhou LaiTeou

CAS no. : 1445-79-0 English name: TRIMETHYLGALLIUM English synonyms: TMGa; Me3Ga; (CH3) 3 ga; Trimethylgallane; Trimethyl - galliu; TRIMETHYLGALLIUM; GALLIUM TRIMETHYL; Trimethylgallium, 99 + %; TRIMETHYLGALLIUM (III); Trimethylgallium, elec. G

Trimethylgallium Manufacturer/High quality/Best price/In stock

Cas:1445-79-0

Min.Order:1 Kilogram

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Hangzhou Yierdechem Co. Ltd

With about ten years experiences in the field of pharmaceutical chemicals, Yierdechem has established solid business cooperation relationships with many large companys worldwide.As a leading supplier of API and pharmaceutical intermediates, holds its

Trimethylgallium

Cas:1445-79-0

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Synthetic route

(Me3Ga)3*triphos

(Me3Ga)3*triphos

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In neat (no solvent) heated slowly under 1E-2 mmHg in a trap-to-trap distillation apparatus (receiver flask at -196 °C), liberation of Me3Ga started at 50 °C, temp. was raised to 120 °C;; distillate contained benzene;;100%
gallium(III) trichloride

gallium(III) trichloride

trimethylaluminum
75-24-1

trimethylaluminum

sodium chloride
7647-14-5

sodium chloride

A

Na(1+)*CH3AlCl3(1-)

Na(1+)*CH3AlCl3(1-)

B

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
at 120 - 145℃; Solvent; Temperature;A n/a
B 98%
gallium
7440-55-3

gallium

methyl aluminium sesquichloride

methyl aluminium sesquichloride

A

trimethylaluminum
75-24-1

trimethylaluminum

B

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
With methylene chloride; sodium at 40 - 50℃; under 375.038 Torr; Inert atmosphere; Flow reactor;A 93.7%
B 96.8%
gallium(III) trichloride

gallium(III) trichloride

trimethylaluminum
75-24-1

trimethylaluminum

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
With tridodecylamine In 5,5-dimethyl-1,3-cyclohexadiene at 100℃; for 1h;93.3%
Stage #1: gallium(III) trichloride With triethylaluminum Heating;
Stage #2: trimethylaluminum at 160℃;
85%
Stage #1: trimethylaluminum With triethylamine In toluene at 25 - 100℃; for 1h;
Stage #2: gallium(III) trichloride In toluene Product distribution / selectivity;
81%
(Me3Ga)4*tetraphos

(Me3Ga)4*tetraphos

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In neat (no solvent) heated slowly under 1E-2 mmHg in a trap-to-trap distillation apparatus (receiver flask at -196 °C), liberation of Me3Ga started at 65 °C, proceeded rapidly at 120-130 °C;; contained traces of benzene;;93%
gallium
7440-55-3

gallium

methyl iodide
74-88-4

methyl iodide

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
Stage #1: gallium With magnesium at 60℃; for 1h; Inert atmosphere;
Stage #2: methyl iodide In 1,3,5-trimethyl-benzene at 60 - 190℃; for 3.66h;
92%
With magnesium In neat (no solvent) byproducts: MgI2; inert atm.; heating (autoclave, 120-160°C, 12 h); distn.;65%
gallium
7440-55-3

gallium

methyl magnesium iodide
917-64-6

methyl magnesium iodide

iodine
7553-56-2

iodine

methyl iodide
74-88-4

methyl iodide

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
Stage #1: gallium; iodine; methyl iodide In toluene at 40 - 50℃; for 6h; Inert atmosphere; Sonication;
Stage #2: methyl magnesium iodide In toluene at 100 - 110℃; for 5h; Inert atmosphere;
92%
trimethylaluminum
75-24-1

trimethylaluminum

triethyl gallium
1115-99-7

triethyl gallium

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
at 20 - 140℃; Glovebox; Inert atmosphere;92%
(Me3Ga)2*diphos

(Me3Ga)2*diphos

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In neat (no solvent) heated slowly under 1E-2 mmHg in a trap-to-trap distillation apparatus (receiver flask at -196 °C), liberation of Me3Ga started at 85 °C, the rate was more satisfactory at 110-130 °C;;91%
trimethylaluminum
75-24-1

trimethylaluminum

Gallium trichloride
13450-90-3

Gallium trichloride

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
Reflux;90%
In neat (no solvent) warming the mixt. of GaCl3 and trimethylaluminum from 233 K to room temp., stirring for 90 min; vaporization of volatiles in vac., fractional condensation at 178 K; IR;
Stage #1: trimethylaluminum at 80 - 85℃; under 187.519 Torr; for 0.5h;
Stage #2: Gallium trichloride at 80 - 90℃; for 0.5h;
(CH2)3(P(C6H5)2Ga(CH3)3)2*2C6H6

(CH2)3(P(C6H5)2Ga(CH3)3)2*2C6H6

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In neat (no solvent) metal complex decomposed at 110-120°C for 2-3 h;90%
(triphenylphosphine)trimethylgallium

(triphenylphosphine)trimethylgallium

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In neat (no solvent) metal complex decomposed at 100-110°C for 2-3 h;88%
In neat (no solvent) heated slowly under 1E-2 mmHg in a trap-to-trap distillation apparatus (receiver flask at -196 °C), liberation of Me3Ga started at 80 °C, the rate was more satisfactory at 90 °C;;71%
(CH2)5(P(C6H5)2Ga(CH3)3)2*2C6H6

(CH2)5(P(C6H5)2Ga(CH3)3)2*2C6H6

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In neat (no solvent) metal complex decomposed at 110-120°C for 2-3 h;88%
gallium(III) trichloride

gallium(III) trichloride

dimethylaluminum chloride
1184-58-3

dimethylaluminum chloride

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
Stage #1: gallium(III) trichloride; dimethylaluminum chloride In toluene
Stage #2: With triethylamine In toluene at 100℃; for 1h; Product distribution / selectivity;
82%
gallium(III) trichloride

gallium(III) trichloride

methyllithium
917-54-4

methyllithium

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In diethyl ether at -10 - -5℃; for 10h; Large scale;80%
gallium(III) trichloride

gallium(III) trichloride

trimethylaluminum
75-24-1

trimethylaluminum

A

dimethylchlorogallane
6917-81-3

dimethylchlorogallane

B

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
With potassium chloride; sodium chloride at 120℃; Inert atmosphere;A 25.6%
B 71.3%
With potassium chloride; sodium chloride at 120℃; Inert atmosphere;A 25.6%
B 69.6%
gallium(III) trichloride

gallium(III) trichloride

methylaluminium sesquichloride

methylaluminium sesquichloride

A

dimethylchlorogallane
6917-81-3

dimethylchlorogallane

B

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
With potassium chloride; sodium chloride at 120 - 155℃; Concentration; Temperature; Inert atmosphere;A 24.7%
B 69.6%
With potassium chloride; sodium chloride at 70 - 180℃; Concentration; Temperature; Inert atmosphere;A 27.4%
B 68%
gallium
7440-55-3

gallium

magnesium
7439-95-4

magnesium

methyl iodide
74-88-4

methyl iodide

A

magnesium chloride
7786-30-3

magnesium chloride

B

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In neat (no solvent) inert gas atmosphere; mixing, heating in autoclave (100 - 160°C, stirring, 12 h); distillation;A n/a
B 65%
lithium hydride

lithium hydride

dimethylchlorogallane
6917-81-3

dimethylchlorogallane

A

tris(dimethylgallium hydride)

tris(dimethylgallium hydride)

B

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In diethyl ether; pentane byproducts: LiCl; under Ar, excess of LiH in Et2O suspn. was added to Et2O soln. of Me2GaCl, reflux for 20 h, filtn., evapn. in vac. at room temp., drying at 45 °C (1E-3 Torr), solid was suspended in n-pentane, Me2GaCl was added in n-pentane, reflux for 16 h; soln. was filtered, residue was twice washed with n-pentane, combined filtrate was evapd., oily residue was distd. in vac. at room temp. (1E-3 Torr) with a cooled (-40 °C) collector, Me3Ga was collected at liq. N2 temp.;A 49%
B n/a
1,1'-bis(dimethylgallyl)ferrocene
348089-02-1

1,1'-bis(dimethylgallyl)ferrocene

A

[(Fe(η5-C5H4)2)2(GaMe)2]
561301-67-5

[(Fe(η5-C5H4)2)2(GaMe)2]

B

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In diethyl ether; toluene under Ar atm. Fe(C5H4GaMe2)2 was treated with Et2O and toluene at room temp. and cooled to +6°C; ppt. was washed with n-hexane and dried in vacuo;A 46%
B n/a
In chloroform under Ar atm. Fe(C5H4GaMe2)2 was dissolved in CHCl3 and cooled to +6°C; elem. anal.;
dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
With gallium(III) trichloride at 80 - 120℃;
dimethylmercury
593-74-8

dimethylmercury

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
With gallium at 110 - 130℃;
1,1,1,2-tetramethyl-digallane

1,1,1,2-tetramethyl-digallane

A

trimethyl gallium
1445-79-0

trimethyl gallium

B

gallium

gallium

C

hydrogen

hydrogen

gallium
7440-55-3

gallium

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
With methyl magnesium iodide; methyl iodide In 1,4-dioxane byproducts: MgI2; excess of CH3MgI and CH3I, heated at 101°C;
With methyl magnesium iodide; methyl iodide In tetrahydrofuran byproducts: MgI2; excess of CH3MgI and CH3I, heated at 65°C;
With methyl magnesium iodide; methyl iodide In di-isopropyl ether byproducts: MgI2; excess of CH3MgI and CH3I, heated at 69°C;
gallium
7440-55-3

gallium

dimethylmercury
593-74-8

dimethylmercury

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
according to A. Storr, B. S. Thomas, Can. J. Chem. 48 (1970) 3667;
dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

Gallium trichloride
13450-90-3

Gallium trichloride

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In neat (no solvent) vigorously starting reaction, completed at 80 - 120 °C;;
dimethylzinc

dimethylzinc

Gallium trichloride
13450-90-3

Gallium trichloride

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
In not given reaction of excess GaCl3 with Zn(CH3)2;;
Mg5Ga2

Mg5Ga2

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
With methyl iodide In further solvent(s) under N2, MeI added slowly to stirred suspn. of Mg5Ga2 in di-isopentyl ether, react. initiated with I2, stirred for 18 h, refluxed for 24 h, cooled to ambient temp.; distn. at bath temp. of 190°C;30-50
gallium(III) chloride

gallium(III) chloride

trimethyl gallium
1445-79-0

trimethyl gallium

Conditions
ConditionsYield
With methylmagnesium bromide GaCl3 is treated with a three-fold excess of MeMgBr; elem. anal.;
tert-butylamine
75-64-9

tert-butylamine

trimethyl gallium
1445-79-0

trimethyl gallium

trimethylgallium-tert-butyl amine

trimethylgallium-tert-butyl amine

Conditions
ConditionsYield
In not given inert atm., PhMe or hexane as solvent, equimolar ratio;100%
In toluene (under dry nitrogen); t-butyl amine added to stirred soln. of trimethylgallium at -78°C; warmed to 25°C; stirred for 24 h; evapd. (vac.); sublimed (65-67°C; E-3 Torr);
trimethyl gallium
1445-79-0

trimethyl gallium

dimethyl(methylperoxy)gallium
66622-03-5

dimethyl(methylperoxy)gallium

Conditions
ConditionsYield
With oxygen In n-heptane100%
With oxygen In not given according to: Yu. A. Aleksandrov, G. I. Makin et al., Zh. Obshch. Khim.48 (1978) 467; oxidn. of Ge-compd. with molecular oxygen in hydrocarbonmedium at -78°C;100%
With O2 In neat (no solvent) heated from -120°C -70°C;
3-Methylpyrazole
1453-58-3

3-Methylpyrazole

trimethyl gallium
1445-79-0

trimethyl gallium

dimethyl-(3-methyl-pyrazol-1-yl)-gallium
79422-26-7

dimethyl-(3-methyl-pyrazol-1-yl)-gallium

Conditions
ConditionsYield
In benzene byproducts: CH4; under argon atm., reflux, 1 h; evapn. of solvent;100%
tris(trimethylsilyl)antimony
7029-27-8

tris(trimethylsilyl)antimony

trimethyl gallium
1445-79-0

trimethyl gallium

(CH3)3GaSb(Si(CH3)3)3

(CH3)3GaSb(Si(CH3)3)3

Conditions
ConditionsYield
In not given N2-atmosphere; equimolar amts.; can be recrystallized (pentane, low temp.) or sublimated (55°C, 1E-2 mbar);100%
tris(trimethylsilyl)bismuthane
81183-20-2

tris(trimethylsilyl)bismuthane

trimethyl gallium
1445-79-0

trimethyl gallium

(CH3)3GaBi(Si(CH3)3)3

(CH3)3GaBi(Si(CH3)3)3

Conditions
ConditionsYield
In neat (no solvent) all manipulations under N2 atm.; mixed equimolar amts. of Ga and Bi compds. at ambient temp.; elem. anal.;100%
triisopropylbismuthine
85824-61-9

triisopropylbismuthine

trimethyl gallium
1445-79-0

trimethyl gallium

((CH3)2CH)3BiGa(CH3)3

((CH3)2CH)3BiGa(CH3)3

Conditions
ConditionsYield
In neat (no solvent) all manipulations under N2 atm.; mixed equimolar amts. of Ga and Bi compds. at ambient temp.; elem. anal.;100%
tetraethyldistibine
4669-92-5

tetraethyldistibine

trimethyl gallium
1445-79-0

trimethyl gallium

[Et4Sb2][GaMe3]2

[Et4Sb2][GaMe3]2

Conditions
ConditionsYield
In neat (no solvent) under N2 atm. react. Me3Ga and Et4Sb2; elem. anal.;100%
N,N',N'-Trimethyl-hexamethylcyclotristannazan
1080-40-6

N,N',N'-Trimethyl-hexamethylcyclotristannazan

trimethyl gallium
1445-79-0

trimethyl gallium

[(CH3)2GaN(Sn(CH3)3)(CH3)]2

[(CH3)2GaN(Sn(CH3)3)(CH3)]2

Conditions
ConditionsYield
In toluene molar ratio 3:1;100%
In benzene dry Ar atm.; 3 equiv. of AlMe3, cooling (-15°C), heating (room temp., stirring), refluxing (1,5 h, 70-80°C); concn., standing (5 to -5 degree.C, several days), washing (toluene), drying (vac.); elem. anal.;64%
tris(diethylamino)difluorophosphorane
32318-29-9

tris(diethylamino)difluorophosphorane

trimethyl gallium
1445-79-0

trimethyl gallium

[FP(N(C2H5)2)3](1+)*[(CH3)3GaF](1-)=[FP(N(C2H5)2)3][(CH3)3GaF]
222190-85-4

[FP(N(C2H5)2)3](1+)*[(CH3)3GaF](1-)=[FP(N(C2H5)2)3][(CH3)3GaF]

Conditions
ConditionsYield
In tetrahydrofuran Ar atm.; equimolar amts., stirring (20°C, 24 h); evapn. (vac.); elem. anal.;100%
N.N'.N''-Triethyl-hexamethyl-hexahydro-symm.-triazatristannin
1778-12-7

N.N'.N''-Triethyl-hexamethyl-hexahydro-symm.-triazatristannin

trimethyl gallium
1445-79-0

trimethyl gallium

[(CH3)2GaN(Sn(CH3)3)(CH2CH3)]2

[(CH3)2GaN(Sn(CH3)3)(CH2CH3)]2

Conditions
ConditionsYield
In toluene molar ratio 3:1;100%
[(CH3)2SnN(CH(CH3)2)]3
234443-32-4

[(CH3)2SnN(CH(CH3)2)]3

trimethyl gallium
1445-79-0

trimethyl gallium

[(CH3)2GaN(Sn(CH3)3)(CH(CH3)2)]2

[(CH3)2GaN(Sn(CH3)3)(CH(CH3)2)]2

Conditions
ConditionsYield
In toluene molar ratio 3:1;100%
In benzene dry Ar atm.; 3 equiv. of AlMe3, cooling (-15°C), heating (room temp., stirring), refluxing (1,5 h, 70-80°C); concn., standing (5 to -5 degree.C, several days), washing (toluene), drying (vac.); elem. anal.;73%
[(CH3)2SnN(CH2CH2CH3)]3
234443-31-3

[(CH3)2SnN(CH2CH2CH3)]3

trimethyl gallium
1445-79-0

trimethyl gallium

[(CH3)2GaN(Sn(CH3)3)(CH2CH2CH3)]2

[(CH3)2GaN(Sn(CH3)3)(CH2CH2CH3)]2

Conditions
ConditionsYield
In toluene molar ratio 3:1;100%
In benzene dry Ar atm.; 3 equiv. of AlMe3, cooling (-15°C), heating (room temp., stirring), refluxing (1,5 h, 70-80°C); concn., standing (5 to -5 degree.C, several days), washing (toluene), drying (vac.); elem. anal.;67%
[(CH3)2SnN(CH2CH(CH3)2)]3
234443-33-5

[(CH3)2SnN(CH2CH(CH3)2)]3

trimethyl gallium
1445-79-0

trimethyl gallium

[(CH3)2GaN(Sn(CH3)3)(CH2CH(CH3)2)]2

[(CH3)2GaN(Sn(CH3)3)(CH2CH(CH3)2)]2

Conditions
ConditionsYield
In toluene molar ratio 3:1;100%
In benzene dry Ar atm.; 3 equiv. of AlMe3, cooling (-15°C), heating (room temp., stirring), refluxing (1,5 h, 70-80°C); concn., standing (5 to -5 degree.C, several days), washing (toluene), drying (vac.); elem. anal.;76%
[(CH3)2SnNCH(CH3)(CH2CH3)]3

[(CH3)2SnNCH(CH3)(CH2CH3)]3

trimethyl gallium
1445-79-0

trimethyl gallium

[(CH3)2GaN(Sn(CH3)3)((CH3)CH(CH2CH3))]2

[(CH3)2GaN(Sn(CH3)3)((CH3)CH(CH2CH3))]2

Conditions
ConditionsYield
In toluene molar ratio 3:1;100%
isopropylamine
75-31-0

isopropylamine

trimethyl gallium
1445-79-0

trimethyl gallium

[(CH3)3GaNH2(CH(CH3)2)]

[(CH3)3GaNH2(CH(CH3)2)]

Conditions
ConditionsYield
In not given inert atm., PhMe or hexane as solvent, equimolar ratio;100%
(2,6-iPr2C6H3)N(SiMe3)Si(OH)3
163631-37-6

(2,6-iPr2C6H3)N(SiMe3)Si(OH)3

trimethyl gallium
1445-79-0

trimethyl gallium

[(2,6-Me2C6H3)N(SiMe3)SiO(OGaMe2)(OGaMe)]2

[(2,6-Me2C6H3)N(SiMe3)SiO(OGaMe2)(OGaMe)]2

Conditions
ConditionsYield
In 1,4-dioxane; hexane byproducts: CH4; molar ratio Ga:ligand 2:1, ratio n-hexane/1,4-dioxane 10/1, addn. (room temp.), refluxing (1 h), pptn.; crystn. (12 h), concn.; elem. anal.;100%
(2,6-iPr2C6H3)N(SiMe3)Si(OH)3
163631-37-6

(2,6-iPr2C6H3)N(SiMe3)Si(OH)3

trimethyl gallium
1445-79-0

trimethyl gallium

[Ga4(OC4H8O)4(O3SiC6H3((CH3)2CH)2N(Si(CH3)3))4]

[Ga4(OC4H8O)4(O3SiC6H3((CH3)2CH)2N(Si(CH3)3))4]

Conditions
ConditionsYield
In 1,4-dioxane; hexane byproducts: CH4; equimolar ratio, ratio n-hexane/1,4-dioxane 10/1, stirring (10 min, roomtemp.), refluxing (1 h); evapn. (vac.); elem. anal.;100%
(2,4,6-Me3C6H2)N(SiMe3)(Si(OH)3)

(2,4,6-Me3C6H2)N(SiMe3)(Si(OH)3)

trimethyl gallium
1445-79-0

trimethyl gallium

[(2,4,6-Me3C6H2)N(SiMe3)SiO(OGaMe2)(OGaMe)]2

[(2,4,6-Me3C6H2)N(SiMe3)SiO(OGaMe2)(OGaMe)]2

Conditions
ConditionsYield
In 1,4-dioxane; hexane byproducts: CH4; molar ratio Ga:ligand 2:1, ratio n-hexane/1,4-dioxane 10/1, addn. (room temp.), refluxing (1 h), pptn.; crystn. (12 h), concn.; elem. anal.;100%
(2,4,6-Me3C6H2)N(SiMe3)(Si(OH)3)

(2,4,6-Me3C6H2)N(SiMe3)(Si(OH)3)

trimethyl gallium
1445-79-0

trimethyl gallium

[(2,4,6-Me3C6H2)N(SiMe3)SiO3Ga*dioxane]4

[(2,4,6-Me3C6H2)N(SiMe3)SiO3Ga*dioxane]4

Conditions
ConditionsYield
In 1,4-dioxane; hexane byproducts: CH4; equimolar ratio, ratio n-hexane/1,4-dioxane 10/1, stirring (10 min, roomtemp.), refluxing (1 h); evapn. (vac.); elem. anal.;100%
NH-pyrazole
288-13-1

NH-pyrazole

trimethyl gallium
1445-79-0

trimethyl gallium

1-dimethylgallylpyrazole
79422-25-6

1-dimethylgallylpyrazole

Conditions
ConditionsYield
In benzene byproducts: CH4; under argon atm., reflux, 1 h; evapn. of solvent;100%
N,N'-di-tert-butyloxamide
37486-48-9

N,N'-di-tert-butyloxamide

trimethyl gallium
1445-79-0

trimethyl gallium

(N,N-di-tert-butyloxamidate)Ga2Me4

(N,N-di-tert-butyloxamidate)Ga2Me4

Conditions
ConditionsYield
In dichloromethane (inert atm.), Me3Ga injected to a stirred suspn. of ligand in CH2Cl2 at -76°C, slowly warmed to room temp.; evapd.(vac.), elem. anal.;100%
N,N'-di-tert-butyloxamide
37486-48-9

N,N'-di-tert-butyloxamide

trimethyl gallium
1445-79-0

trimethyl gallium

(N,N-di-tert-butyloxamidate)Ga2Me4
1309357-34-3, 1309357-37-6

(N,N-di-tert-butyloxamidate)Ga2Me4

Conditions
ConditionsYield
In tetrahydrofuran (inert atm.), Me3Ga injected to a stirred suspn. of ligand in THF at room temp., refluxed for 1 h; evapd.(vac.), elem. anal.;100%
C19H23N2O(1+)*Cl(1-)
1510833-98-3

C19H23N2O(1+)*Cl(1-)

trimethyl gallium
1445-79-0

trimethyl gallium

C21H28GaN2O(1+)*Cl(1-)
1510834-04-4

C21H28GaN2O(1+)*Cl(1-)

Conditions
ConditionsYield
In dichloromethane at -50℃; for 1h; Inert atmosphere; Schlenk technique;100%
C22H29N2O(1+)*Cl(1-)
1510833-99-4

C22H29N2O(1+)*Cl(1-)

trimethyl gallium
1445-79-0

trimethyl gallium

C24H34GaN2O(1+)*Cl(1-)

C24H34GaN2O(1+)*Cl(1-)

Conditions
ConditionsYield
In dichloromethane at -70 - 20℃; for 1h; Inert atmosphere; Schlenk technique;100%
1-(2,6-diisopropylphenyl)-3-(2-hydroxyphenyl)-4,5-dihydro-imidazolyl chloride
724794-67-6

1-(2,6-diisopropylphenyl)-3-(2-hydroxyphenyl)-4,5-dihydro-imidazolyl chloride

trimethyl gallium
1445-79-0

trimethyl gallium

C23H32GaN2O(1+)*Cl(1-)

C23H32GaN2O(1+)*Cl(1-)

Conditions
ConditionsYield
In dichloromethane at -70 - 20℃; for 1h; Inert atmosphere; Schlenk technique;100%
C24H33GaN2O

C24H33GaN2O

trimethyl gallium
1445-79-0

trimethyl gallium

C27H42Ga2N2O

C27H42Ga2N2O

Conditions
ConditionsYield
In toluene at 20℃; for 0.166667h; Inert atmosphere; Schlenk technique;100%
all-cis-1,3,5-triethynyl-1,3,5-trimethyl-1,3,5-trisilacyclohexane

all-cis-1,3,5-triethynyl-1,3,5-trimethyl-1,3,5-trisilacyclohexane

trimethyl gallium
1445-79-0

trimethyl gallium

1,3,5-tris(dimethylgallanylethynyl)-1,3,5-trimethyl-1,3,5-trisilacyclohexane

1,3,5-tris(dimethylgallanylethynyl)-1,3,5-trimethyl-1,3,5-trisilacyclohexane

Conditions
ConditionsYield
In neat (no solvent) at 42℃; for 24h; Temperature; Schlenk technique; Inert atmosphere;100%
tris[(ethynyl)dimethylsilyl](trimethylsilyl)methane

tris[(ethynyl)dimethylsilyl](trimethylsilyl)methane

trimethyl gallium
1445-79-0

trimethyl gallium

tris[(dimethylgallanylethynyl)dimethylsilyl](trimethylsilyl)methane

tris[(dimethylgallanylethynyl)dimethylsilyl](trimethylsilyl)methane

Conditions
ConditionsYield
In neat (no solvent) at 20℃; for 72h;100%
C27H39ClN2O

C27H39ClN2O

trimethyl gallium
1445-79-0

trimethyl gallium

C29H44ClGaN2O

C29H44ClGaN2O

Conditions
ConditionsYield
In dichloromethane at -50 - 20℃; Inert atmosphere; Schlenk technique;100%
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