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Shanghai Longjin Metallic Material Co., Ltd.

Size can be customized according to customer requirements 1) Quick response and timely delivery 2) Quality assurance: provide product analysis sheet 3) Reasonable and competitive price Appearance:Gray-black powder/silvery white granules S

Factory Supply Bismuth powder/Bismuth particle CAS NO.7440-69-9

Cas:7440-69-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Bismuth

Cas:7440-69-9

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Bismuth

Cas:7440-69-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Competitive Price High Quality Fast Delivery custom-made Welcome to Henan Tianfu Chemical Co., Ltd. website. Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; development of noble me

7440-69-9,Bismuth

Cas:7440-69-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 7440-69-9 with best quality

Cas:7440-69-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Alias: Nano-copper powder;Nanometer copper powder;Nano Copper;Copper Nano powder;Nano cu powder;Cu nanoparticle;Cu nanopowder Molecular formula: Cu Appearance: Black brown or Black pow

Copper Nanoparticle

Cas:7440-69-9

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Bismuth 7440-69-9

Cas:7440-69-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Bismuth CAS:7440-69-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates, ste

Bismuth CAS:7440-69-9

Cas:7440-69-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Bismuth

Cas:7440-69-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Bismuth

Cas:7440-69-9

Min.Order:1 Kilogram

FOB Price: $8.0 / 10.0

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

Bismuth CAS: 7440-69-9 Specification Test Item Standard: USP Identification IR spectrum similar to that of RS HPLC retention time similar to that of RS Related substance

Factory supply Bismuth

Cas:7440-69-9

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Bismuth

Cas:7440-69-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Price, service, company and transport advantage: 1.place of origin china with super quality by reasonable price. 2. it's customers' right to choose the package (ems, dhl, fedex, ups); 3. it's custo

BEST PRICE/Bismuth

Cas:7440-69-9

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Bismuth

Cas:7440-69-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Bismuth

Cas:7440-69-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Bismuth

Cas:7440-69-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Colloidal Bismuth Pectin

Cas:7440-69-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Bismuth Basic information Product Name: Bismuth Synonyms: Bismuth pieces;Bismuth rod;Bismuth shot;Bismuth sticks;BismuthgranulesNmm;Bismuthingot;BismuthpiecesNhemispherescagpiece;BismuthpowderNmesh CAS: 7440-69-9 MF: Bi MW: 208.98 EIN

Bismuth

Cas:7440-69-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

bismuth atom/bismuth powder/Nano-grade bismuth atom 7440-69-9

Cas:7440-69-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

bismuth atom/bismuth powder/Nano-grade bismuth atom 7440-69-9

Cas:7440-69-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Leshan Kairuida Photoelectric Technology Co., Ltd.

Overview 1、Bismuth(Bi) 2、Technology docking: Electrolysis-zone melting 3、Inspection:ICP-MS;Laser particle size analyzer, scanning electron microscope。 Services: provide practical protective measures, provide material application solutions。 4、Pur

Bismuth

Cas:7440-69-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

bismuth atom/bismuth powder/Nano-grade bismuth atom 7440-69-9

Cas:7440-69-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Bismuth Cas.no 7440-69-9 98%

Cas:7440-69-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

bismuth atom/bismuth powder/Nano-grade bismuth atom 7440-69-9

Cas:7440-69-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Bismuth

Cas:7440-69-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Bismuth

Cas:7440-69-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Bismuth

Cas:7440-69-9

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Bismuth

Cas:7440-69-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Bismuth 100g

Cas:7440-69-9

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Bismuth

Cas:7440-69-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

bismuth
7440-69-9

bismuth

Conditions
ConditionsYield
With zinc In neat (no solvent) byproducts: ZnO; complete reduction at 500°C;;100%
With Zn In neat (no solvent) byproducts: ZnO; complete reduction at 500°C;;100%
With urea byproducts: H2O, CO2, N2; react. in a crucible over a low Meker flame, heating gently for 10 min; metal was extd. manually with a spatula;71%
bismuth(III) sulfide

bismuth(III) sulfide

bismuth
7440-69-9

bismuth

Conditions
ConditionsYield
In neat (no solvent) decomposition on heating above boiling temperature;; re-sulphuration on cooling down under exclusion of air; formation of Bi oxide in presence of air;;100%
With sodium hydroxide In neat (no solvent) heating of Bi2S3 with NaOH at 400-500°C; thermodynamic calculations;;
With iron In neat (no solvent) byproducts: FeS; heating of the sulfide with Fe; formation of Bi and Bi containing dross;; addition of alkaline or earth alkaline sulfides to the reaction mixture; separation from As and Sb containing speiss;;
bismuth(III) bromide
7787-58-8

bismuth(III) bromide

bismuth
7440-69-9

bismuth

Conditions
ConditionsYield
With calcium reduction with Ca at 220°C;;100%
With magnesium In diethyl ether reduction in presence of ether at 25°C;;100%
With Mg In diethyl ether reduction in presence of ether at 25°C;;100%
bismuth(III) acetate oxide

bismuth(III) acetate oxide

bismuth
7440-69-9

bismuth

Conditions
ConditionsYield
With hydrogen In acetic acid reduction at 150°C, 100 atm., 24 hours, 1,25n solution (acetic acid), 0.1n acetate;;100%
vanadocene

vanadocene

(C6F5)3GeBi(C2H5)2
69162-04-5

(C6F5)3GeBi(C2H5)2

A

bismuth
7440-69-9

bismuth

B

(C5H5)2VC2H5

(C5H5)2VC2H5

C

(C5H5)2VGe(C6F5)3

(C5H5)2VGe(C6F5)3

Conditions
ConditionsYield
In toluene mixt. held for 5 h at 20°C; org. layer decanted; solvent evapd. (vac.); extd. (hexane); recrystd. (toluene/hexane=8/1); ESR;A 100%
B 86%
C 90%
triphenylbismuthane
603-33-8

triphenylbismuthane

bismuth
7440-69-9

bismuth

Conditions
ConditionsYield
With hydrogen In xylene byproducts: C6H6; 60 atm, 124 h, 225°C;99.4%
With hydrogen In xylene reduction of triphenyl Bi with H2 under a pressure of 60 at on heating at 250°C;;99.4%
With hydrogen In xylene byproducts: C6H6; 60 atm, 124 h, 150°C;6.9%
sodium octahydrotriborate tridioxanate

sodium octahydrotriborate tridioxanate

bismuth(III)

bismuth(III)

bismuth
7440-69-9

bismuth

Conditions
ConditionsYield
In water room temp.; X-ray diffraction, gravimetric anal.;99%
vanadocene

vanadocene

{(C6F5)3Ge}2BiC2H5
69202-61-5

{(C6F5)3Ge}2BiC2H5

A

bismuth
7440-69-9

bismuth

B

(C5H5)2VC2H5

(C5H5)2VC2H5

C

(C5H5)2VGe(C6F5)3

(C5H5)2VGe(C6F5)3

Conditions
ConditionsYield
In toluene mixt. held for 5 h at 20°C; org. layer decanted; solvent evapd. (vac.); extd. (hexane); recrystd. (toluene/hexane=8/1); ESR;A 90%
B 97%
C 74%
benzene-d6
1076-43-3

benzene-d6

triphenylbismuthane
603-33-8

triphenylbismuthane

A

bismuth
7440-69-9

bismuth

B

biphenyl
92-52-4

biphenyl

C

biphenyl-d10
1486-01-7

biphenyl-d10

D

2,3,4,5,6-pentadeuterio-biphenyl
20637-23-4

2,3,4,5,6-pentadeuterio-biphenyl

Conditions
ConditionsYield
In benzene-d6 Irradiation (UV/VIS); 40-50°C, 150 h;A n/a
B 2.5%
C 2.3%
D 95.2%
(4-bromobenzoylseleno)bis(4-methylphenyl)bismuth

(4-bromobenzoylseleno)bis(4-methylphenyl)bismuth

A

bismuth
7440-69-9

bismuth

B

tri(p-tolyl)bismuth
5142-75-6

tri(p-tolyl)bismuth

Conditions
ConditionsYield
In neat (no solvent) byproducts: Se-(4-CH3C6H4) 4-bromobenzenecarboselenoate; Bi-compound under N2 in an ampoule was heated at 150°C for 2 h; ppt. was filtered (Bi), washed with diethyl ether and CH2Cl2, evapd., column chromy. on silica gel (hexane-diethyl ether);A 1%
B 95%
bismuth(III) chloride
7787-60-2

bismuth(III) chloride

triethylstannane
997-50-2

triethylstannane

A

bismuth
7440-69-9

bismuth

B

chlorotriethylstannane
994-31-0

chlorotriethylstannane

Conditions
ConditionsYield
byproducts: H2; heating dry powdered BiCl3 with (C2H5)3SnH under reflux;;A n/a
B 93%
byproducts: H2; heating dry powdered BiCl3 with (C2H5)3SnH under reflux;;A n/a
B 93%
(4-methylbenzoylseleno)bis(4-methylphenyl)bismuth

(4-methylbenzoylseleno)bis(4-methylphenyl)bismuth

A

bismuth
7440-69-9

bismuth

B

tri(p-tolyl)bismuth
5142-75-6

tri(p-tolyl)bismuth

Conditions
ConditionsYield
In neat (no solvent) byproducts: Se-(4-CH3C6H4) 4-methylbenzenecarboselenoate; Bi-compound under N2 in an ampoule was heated at 150°C for 2 h; ppt. was filtered (Bi), washed with diethyl ether and CH2Cl2, evapd., column chromy. on silica gel (hexane-diethyl ether);A 1%
B 93%
(4-methoxybenzoylseleno)bis(4-methylphenyl)bismuth

(4-methoxybenzoylseleno)bis(4-methylphenyl)bismuth

A

bismuth
7440-69-9

bismuth

B

tris(4-methoxyphenyl)bismuth
33397-21-6

tris(4-methoxyphenyl)bismuth

Conditions
ConditionsYield
In neat (no solvent) byproducts: Se-(4-CH3C6H4)-4-methoxybenzenecarboselenoate; Bi-compound under N2 in an ampoule was heated at 150°C for 2 h; ppt. was filtered (Bi), washed with diethyl ether and CH2Cl2, evapd., column chromy. on silica gel (hexane-diethyl ether);A 1%
B 92%
(3-chloro-2,6-dimethoxybenzoylseleno)bis(4-methylphenyl)bismuth

(3-chloro-2,6-dimethoxybenzoylseleno)bis(4-methylphenyl)bismuth

A

bismuth
7440-69-9

bismuth

B

tri(p-tolyl)bismuth
5142-75-6

tri(p-tolyl)bismuth

Conditions
ConditionsYield
In neat (no solvent) byproducts: Se-(4-CH3C6H4) 3-Cl-2,6-CH3Obenzenecarboselenoate; Bi-compound under N2 in an ampoule was heated at 150°C for 2 h; ppt. was filtered (Bi), washed with diethyl ether and CH2Cl2, evapd., column chromy. on silica gel (hexane-diethyl ether);A 1%
B 92%
bismuth(III) sulfide

bismuth(III) sulfide

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

bismuth
7440-69-9

bismuth

Conditions
ConditionsYield
With carbon dioxide In neat (no solvent) byproducts: SO2, (BiO)2SO4; reaction in stream of CO2 under layer of salt;;90%
With iron; pyrographite In melt melting with C in a flame- or crucible furnace; addition of Na2CO3 with formation of dross; complete reduction by addition of Fe;; removal of As and Sb as speiss;;
With pyrographite In melt melting an ore containing 25-30 % Bi with Fe oxide and C in a cupola furnace;; Bi with impurities of Sb, Pb, As and a small amount of Cu; Bi containing speiss, dross (0.2-0.6 % Bi) and further products;;
triphenylbismuthane
603-33-8

triphenylbismuthane

A

bismuth
7440-69-9

bismuth

B

benzene
71-43-2

benzene

Conditions
ConditionsYield
With sodium In ammoniaA n/a
B 90%
bismuth(III) chloride
7787-60-2

bismuth(III) chloride

5-aza-2,2,8,8-tetramethylnonane-3,7-dione
88686-46-8

5-aza-2,2,8,8-tetramethylnonane-3,7-dione

A

bismuth
7440-69-9

bismuth

tris(4-aza-1,7-dioxa-2,6-ditert-butylhepta-2,5-dien-1,4,7-triyl)bismuth

tris(4-aza-1,7-dioxa-2,6-ditert-butylhepta-2,5-dien-1,4,7-triyl)bismuth

Conditions
ConditionsYield
With (C2H5)3N In tetrahydrofuran byproducts: (C2H5)3NHCl; at -78 °C; extd. (pentane), crystd. from pentane at -28 °C;A n/a
B 90%
Yb(C4H8O)6(2+)*2(C6H5)3C(1-)=[Yb(C4H8O)6][(C6H5)3C]2

Yb(C4H8O)6(2+)*2(C6H5)3C(1-)=[Yb(C4H8O)6][(C6H5)3C]2

triphenylbismuthane
603-33-8

triphenylbismuthane

A

bismuth
7440-69-9

bismuth

B

2C(C6H5)3(1-)*YbC6H5(C4H8O)3(2+)=(C(C6H5)3)2YbC6H5(C4H8O)3

2C(C6H5)3(1-)*YbC6H5(C4H8O)3(2+)=(C(C6H5)3)2YbC6H5(C4H8O)3

Conditions
ConditionsYield
In tetrahydrofuran Ph3Bi in THF was added to soln. of Yb-complex in THF, heated at 40-50°C for 24 h in evacuated sealed ampules; sepd. by centrifugation; elem. anal.;A 90%
B 68%
(benzoylseleno)bis(4-methylphenyl)bismuth

(benzoylseleno)bis(4-methylphenyl)bismuth

A

bismuth
7440-69-9

bismuth

B

tri(p-tolyl)bismuth
5142-75-6

tri(p-tolyl)bismuth

Conditions
ConditionsYield
In neat (no solvent) byproducts: Se-(4-CH3C6H4) benzenecarboselenoate; Bi-compound under N2 in an ampoule was heated at 150°C for 2 h; ppt. was filtered (Bi), washed with diethyl ether and CH2Cl2, evapd., column chromy. on silica gel (hexane-diethyl ether);A 1%
B 90%
α-naphthol
90-15-3

α-naphthol

tri(naphthalen-1-yl)bismuth
33397-22-7

tri(naphthalen-1-yl)bismuth

bismuth
7440-69-9

bismuth

Conditions
ConditionsYield
130°C, 3 h;89.1%
bismuth(III) sulfide

bismuth(III) sulfide

A

bismuth
7440-69-9

bismuth

B

bismuth(III) sulfate

bismuth(III) sulfate

Conditions
ConditionsYield
reaction at 800 °C;;A 87.41%
B 4.83%
reaction at 800 °C;;A 87.41%
B 4.83%
reaction at 700 °C;;A 74.63%
B 7.61%
tris(pentafluorophenyl)bismuth
34422-57-6

tris(pentafluorophenyl)bismuth

A

bismuth
7440-69-9

bismuth

B

bismuth hydroxide

bismuth hydroxide

C

Pentafluorobenzene
363-72-4

Pentafluorobenzene

D

decafluorobiphenyl
434-90-2

decafluorobiphenyl

Conditions
ConditionsYield
With waterA 0%
B n/a
C 87%
D 0%
With H2OA 0%
B n/a
C 87%
D 0%
With waterA 0%
B n/a
C n/a
D 0%
water
7732-18-5

water

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

bismuth
7440-69-9

bismuth

Conditions
ConditionsYield
With Zn; HCl In water BiCl3 added to water with stirring, Zn powder added, stirred at room temp. for 2-4 h, mixture added to diluted aq. HCl for several min; ppt. filtered, washed (water), dried (vac., 60°C, 4 h); elem. anal.;80%
triethylsilane
617-86-7

triethylsilane

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

A

bismuth
7440-69-9

bismuth

B

triethylsilyl chloride
994-30-9

triethylsilyl chloride

Conditions
ConditionsYield
byproducts: H2; heating dry powdered BiCl3 with triethyl silane under reflux;;A n/a
B 79%
byproducts: H2; heating dry powdered BiCl3 with triethyl silane under reflux;;A n/a
B 79%
bismuth(III) 2-ethylhexanoate

bismuth(III) 2-ethylhexanoate

bismuth
7440-69-9

bismuth

Conditions
ConditionsYield
With 1-dodecylthiol In tetrahydrofuran-d8 byproducts: 2-ethylhexanoic acid, CH3(CH2)11SS(CH2)11CH3; Irradiation (UV/VIS); (N2); addn. of thiol deriv. to soln. of bismuth compd. in THF-d8, exposure to 365 nm light for 4 d at power of 7mW/cm**2; NMR monitoring;75%
With 1-dodecylthiol In tetrahydrofuran byproducts: 2-ethylhexanoic acid, CH3(CH2)11SS(CH2)11CH3; Irradiation (UV/VIS); (N2); addn. of 3 equiv. of thiol deriv. to soln. of bismuth compd. in dry THF, exposure to ambient light at room temp. for 24 h or 2 wks; exposure to air, cenrifugation for 2 min at 9000 rpm, removing supernatant, suspending in THF, centrifugation, drying at room temp. in vac.;
tri(naphthalen-1-yl)bismuth
33397-22-7

tri(naphthalen-1-yl)bismuth

2-hydroxyresorcinol
87-66-1

2-hydroxyresorcinol

bismuth
7440-69-9

bismuth

Conditions
ConditionsYield
130°C, 4 h;70.5%
130°C, 3 h;64.9%
130°C, 2 h;49.9%
130°C, 1 h;17.5%
praseodymium

praseodymium

bis[tris(pentafluorophenyl)germyl]mercury

bis[tris(pentafluorophenyl)germyl]mercury

{(C6F5)3Ge}2BiC2H5
69202-61-5

{(C6F5)3Ge}2BiC2H5

A

bismuth
7440-69-9

bismuth

B

praseodymium heptakis[tris(pentafluorophenyl)germanyl]dimercurate*3(dimethoxyethane)

praseodymium heptakis[tris(pentafluorophenyl)germanyl]dimercurate*3(dimethoxyethane)

C

mercury

mercury

Conditions
ConditionsYield
In 1,2-dimethoxyethane fivefold excess of compound I in evacuated ampul shaken for 5 h at 20°C; centrifugated, decanted, solvent removed (vac.), ppt. washed (toluene);dried (vac.);A 70%
B 263.6 %
C 22.5%
diphenylbismuth(III) chloride
5153-28-6

diphenylbismuth(III) chloride

A

bismuth
7440-69-9

bismuth

B

Bi(3+)*C6H5(1-)

Bi(3+)*C6H5(1-)

C

Bi(3+)*2C6H5(1-)

Bi(3+)*2C6H5(1-)

Conditions
ConditionsYield
other Radiation; on neutron radiation;A 56.5%
B 16.4%
C 2.4%
other Radiation; on neutron radiation;A 56.5%
B 16.4%
C 2.4%
Et2BiTeEt

Et2BiTeEt

A

bismuth
7440-69-9

bismuth

Bi2Te

Bi2Te

Conditions
ConditionsYield
With (Z)-9-octadecen-1-amine at 100℃; for 14h; Inert atmosphere; Schlenk technique;A n/a
B 55.4%
Li[Al(perfluoro-tertbutoxide)4]

Li[Al(perfluoro-tertbutoxide)4]

Bi5(3+)*3AsF6(1-)*SO2=[Bi5](AsF6)3*SO2

Bi5(3+)*3AsF6(1-)*SO2=[Bi5](AsF6)3*SO2

Hexamethylbenzene
87-85-4

Hexamethylbenzene

A

bismuth
7440-69-9

bismuth

B

[(C6Me6)H][Al(OC(CF3)3)4]
874445-84-8

[(C6Me6)H][Al(OC(CF3)3)4]

C

[Bi5(hexamethylbenzene)4][Al(OC(CF3)3)4]3

[Bi5(hexamethylbenzene)4][Al(OC(CF3)3)4]3

D

[Bi4OF2Cl6(hexamethylbenzene)4][Al(OC(CF3)3)4]2*hexamethylbenzene

[Bi4OF2Cl6(hexamethylbenzene)4][Al(OC(CF3)3)4]2*hexamethylbenzene

Conditions
ConditionsYield
In dichloromethane byproducts: LiAsF6; under N2, 1 equiv. of Li-compd., 1 equiv. of Bi-compd. and 2 equiv. of C6Me6 were stirred in CH2Cl2 for 4 h, 5 °C; soln. was concd., held at -24 °C for 2 d, crystals were sepd., another crop was given after 2 d at this temp., elem. anal.; keeping the mother liq. for 2 weeks, Bi, the Bi4OF2Cl6(2+) and C6Me6H(1+)-cation con tg. compds. were formed.;A n/a
B n/a
C 55%
D n/a
bismuth
7440-69-9

bismuth

aqueous H2 O2

aqueous H2 O2

sulfuric acid
7664-93-9

sulfuric acid

pyrographite
7440-44-0

pyrographite

2-butyl-5-hydroxymethyl-1H-imidazole
68283-19-2

2-butyl-5-hydroxymethyl-1H-imidazole

platinum
7440-06-4

platinum

2-butyl-1H-imidazole-5-carboxaldehyde
68282-49-5

2-butyl-1H-imidazole-5-carboxaldehyde

Conditions
ConditionsYield
With sodium hydroxide In water100%
With sodium hydroxide In water98.2%
With sodium hydroxide In methanol; water94.5%
bismuth
7440-69-9

bismuth

iodine
7553-56-2

iodine

bismuth(III) iodide
7787-64-6

bismuth(III) iodide

Conditions
ConditionsYield
In melt passing a stream of I2/inert gas into molten Bi with formation of volatile BiI3; description of the aparatus given;;100%
In melt passing a stream of I2/inert gas into molten Bi with formation of volatile BiI3; description of the aparatus given;;100%
In melt passing a stream of I2/inert gas into molten Bi with formation of volatile BiI3; description of the aparatus given;;100%
bismuth
7440-69-9

bismuth

bromine
7726-95-6

bromine

bismuth(III) bromide
7787-58-8

bismuth(III) bromide

Conditions
ConditionsYield
In melt passing a stream of Br2/inert gas into molten Bi with formation of volatile BiBr3; description of the aparatus given;;100%
In melt passing a stream of Br2/inert gas into molten Bi with formation of volatile BiBr3; description of the aparatus given;;100%
In melt passing a stream of Br2/inert gas into molten Bi with formation of volatile BiBr3; description of the aparatus given;;100%
bismuth
7440-69-9

bismuth

nitrogen
7727-37-9

nitrogen

bismuth nitride

bismuth nitride

Conditions
ConditionsYield
In neat (no solvent) Electrochem. Process; cothodic pulverization within 10 hours of Bi under pure N2 (0.1 - 0.3 Torr), glow-discharge at 1000-1500 V; anode Fe; description of the aparatus given;; 359.8 mg BiN; deposition of 12.1 weight % on cathode, of 45.4 weight % on anode, 25.2 weight % on glass parts of the aparatus, 17.3 weight % on Fe- (or Al-) protecting ring of the aparatus;;100%
In further solvent(s) Electric Arc; between Bi-cathode and Cu-anode in a liquid mixture of argon and nitrogen;;
In further solvent(s) Electric Arc; between Bi-cathode and Cu-anode in a liquid mixture of argon and nitrogen;;
In neat (no solvent) cathodic pulverization of Bi during glow discharge under N2 (0.1 - 0.3 torr);;
bismuth
7440-69-9

bismuth

sodium
7440-23-5

sodium

sodium bismuthide

sodium bismuthide

Conditions
ConditionsYield
In neat (no solvent) heating a mixture of Na and Bi (molar ratio 3 : 1) at 775°C under Ar;;100%
determined by thermal analysis;;
determined by chemical methods;;
bismuth
7440-69-9

bismuth

sulfur
7704-34-9

sulfur

bismuth(III) sulfide

bismuth(III) sulfide

Conditions
ConditionsYield
In neat (no solvent) under dry N2 atm. in vac. glovebox; mixt. of Bi and S was transferred inquartz tube, with was flame sealed under vac.; tube was heated to 650.d egree.C for 48 h; stayed at 650°C for 2 ds; cooled to 50°Cin 10 h; ground into powder;100%
In melt by melting at possible min. temp.;
In melt addition of S to molten Bi at 600-700°C;; Bi content 1 - 2 %;;
disulfur dichloride
10025-67-9

disulfur dichloride

bismuth
7440-69-9

bismuth

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
heating Bi with S2Cl2 at 138.6°C, 10 hours;;100%
addition of S2Cl2 to Bi;;
addition of S2Cl2 to Bi;;
bismuth
7440-69-9

bismuth

chlorine
7782-50-5

chlorine

bismuth(III) chloride
7787-60-2

bismuth(III) chloride

Conditions
ConditionsYield
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;100%
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;100%
In melt passing a stream of Cl2/inert gas into molten Bi with formation of volatile BiCl3; description of the aparatus given;;100%
bismuth
7440-69-9

bismuth

selenium
7782-49-2

selenium

bismuth(III) selenide

bismuth(III) selenide

Conditions
ConditionsYield
In neat (no solvent) under dry N2 atm. in vac. glovebox; mixt. of Bi and Se was transferred in quartz tube, with was flame sealed under vac.; tube was heated to 600°C for 48 h; stayed at 600°C for 2 ds; cooled to 50°C in 10 h; ground into powder;100%
high pressure at 420°C;
on Al plate at 47-180°C; tempering under m.p. of Se; no reaction at 130°C without tempering;
bismuth
7440-69-9

bismuth

iodine(I) bromide
7789-33-5

iodine(I) bromide

bismuth(III) bromide
7787-58-8

bismuth(III) bromide

Conditions
ConditionsYield
In melt100%
In melt100%
In melt addition of Bi powder to molten IBr;; extraction with CCl4;;
In melt addition of Bi powder to molten IBr;; extraction with CCl4;;
bismuth
7440-69-9

bismuth

tellurium

tellurium

bismuth telluride

bismuth telluride

Conditions
ConditionsYield
In neat (no solvent) Bi and Te ground, pressed at 650 K, homogenizing calcination (570 K, 400h) in evacuated quartz ampoules; single phase (X-ray- and electron-microprobe analyses);100%
bismuth
7440-69-9

bismuth

selenium
7782-49-2

selenium

tellurium

tellurium

Bi(x)(Te0.9Se0.1)3 x:1.96-2.04;

Bi(x)(Te0.9Se0.1)3 x:1.96-2.04;

Conditions
ConditionsYield
In neat (no solvent) Bi, Se and Te ground, pressed at 650 K, homogenizing calcination (570 K, 400h) in evacuated quartz ampoules; single phase (X-ray- and electron-microprobe analyses);100%
bismuth
7440-69-9

bismuth

selenium
7782-49-2

selenium

tellurium

tellurium

Bi(x)(Te0.8Se0.2)3 x:1.8-2.2;

Bi(x)(Te0.8Se0.2)3 x:1.8-2.2;

Conditions
ConditionsYield
In neat (no solvent) Bi, Se and Te ground, pressed at 650 K, homogenizing calcination (730 K, 400h) in evacuated quartz ampoules; single phase (X-ray- and electron-microprobe analyses);100%
bismuth
7440-69-9

bismuth

potassium sulfide

potassium sulfide

bismuth(III) sulfide

bismuth(III) sulfide

Bi2K8S7

Bi2K8S7

Conditions
ConditionsYield
differential thermal anal.;100%
bismuth
7440-69-9

bismuth

potassium
7440-09-7

potassium

sulfur
7704-34-9

sulfur

potassium metathiobismuthite

potassium metathiobismuthite

Conditions
ConditionsYield
In neat (no solvent)100%
differential thermal anal.;100%
bismuth
7440-69-9

bismuth

silver perchlorate

silver perchlorate

bismuth(III) perchlorate

bismuth(III) perchlorate

Conditions
ConditionsYield
In acetonitrile Electrolysis; electrolysis of AgClO4 in acetonitrile, Bi anode;; not isolated;;100%
bismuth
7440-69-9

bismuth

potassium sulfide

potassium sulfide

bismuth(III) sulfide

bismuth(III) sulfide

K2Bi4S7

K2Bi4S7

Conditions
ConditionsYield
differential thermal anal.;100%
bismuth
7440-69-9

bismuth

bismuth(III) sulfide

bismuth(III) sulfide

potassium metathiobismuthite

potassium metathiobismuthite

Bi3KS5, low temperature

Bi3KS5, low temperature

Conditions
ConditionsYield
annealing at 650°C; differential thermal anal.;100%
bismuth
7440-69-9

bismuth

bismuth(III) sulfide

bismuth(III) sulfide

potassium metathiobismuthite

potassium metathiobismuthite

Bi3KS5, high temperature

Bi3KS5, high temperature

Conditions
ConditionsYield
quenching from 830°C; differential thermal anal.;100%
bismuth
7440-69-9

bismuth

europium

europium

Eu4Bi3

Eu4Bi3

Conditions
ConditionsYield
In neat (no solvent) Ar atm.; stoichiometric ratio, heating (1100°C, 24-48 h);100%
In neat (no solvent) induction heating at 1400°C of stoich. amounts of elements in a sealed tungsten crucible; XRD;
In neat (no solvent, solid phase) Electric Arc; Bi and Eu were arc-melted under Ar in silica ampules, heated to 700°C for 6 h, at 1050°C for 6 h, quenched to room temp., reheatedat 1100°C for 36 h, cooled to room temp. at 3°C/h;
bismuth
7440-69-9

bismuth

manganese
7439-96-5

manganese

Yb

Yb

Yb14MnBi11

Yb14MnBi11

Conditions
ConditionsYield
Stage #1: bismuth; manganese; Yb for 1h; Milling; Inert atmosphere;
Stage #2: at 1125 - 1225℃; for 96h; Inert atmosphere; Sealed tube;
100%
bismuth
7440-69-9

bismuth

selenium
7782-49-2

selenium

caesium selenide

caesium selenide

cadmium
7440-43-9

cadmium

Cs1.13Cd1.13Bi2.87Se6

Cs1.13Cd1.13Bi2.87Se6

Conditions
ConditionsYield
In neat (no solvent) at 750℃; for 48h; Inert atmosphere;100%
bismuth
7440-69-9

bismuth

lithium sulfide

lithium sulfide

sulfur
7704-34-9

sulfur

Li0.97Sn2.06Bi4.97S10

Li0.97Sn2.06Bi4.97S10

Conditions
ConditionsYield
Stage #1: bismuth; tin; lithium sulfide; sulfur at 800℃; under 0.00150015 Torr; for 10h; Inert atmosphere; Glovebox; Sealed tube;
Stage #2: at 800℃; for 26h;
100%
bismuth
7440-69-9

bismuth

sulfuric acid
7664-93-9

sulfuric acid

bismuth(III) sulfate

bismuth(III) sulfate

Conditions
ConditionsYield
In further solvent(s) H2SO4 was added to Bi in HNO3 with stirring and heating; more H2SO4 wasadded and suspn. was heated for 40 h; heated in a muffle furnace at 648K; elem. anal.;99.8%
In sulfuric acid byproducts: SO2; by dissolving in boiling concd. H2SO4;;
In sulfuric acid byproducts: SO2; very weak reaction with diluted H2SO4.;;
In nitric acid Bi dissolved in HNO3 and treated with H2SO4, heated for several hours at 380 °C;;

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