CAS No.3811-04-9,Potassium chlorate Suppliers,MSDS download

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Synthetic route

: potassium chloride

A: 3811-04-9
potassium chlorate

B: potassium perchlorate

Conditions

Conditions	Yield
In water Electrolysis; anodic oxidation of 3.6 n chloride soln.;;

: potassium chloride

: 3811-04-9
potassium chlorate

Conditions

Conditions	Yield
In water Electrolysis;
Electrolysis; acidic electrolyte;
Electrolysis; alk. electrolyte, max. current efficiency 60-65 %;

: calcium chlorate

: potassium chloride

A: 3811-04-9
potassium chlorate

B: calcium chloride

Conditions

Conditions	Yield
In water equilibrium reaction; examination at different temperatures;;
In water equilibrium reaction; examination at different temperatures;;
In water equilibrium reaction; examination at different temperatures;;
In water
In water concd. CaCl2 soln. as by-product; stepwise concg.;;

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: 10049-04-4, 25052-55-5
chlorine dioxide

: 584-08-7
potassium carbonate

A: 3811-04-9
potassium chlorate

B: 14314-27-3
potassium chlorite

Conditions

Conditions	Yield
In water byproducts: H2O;
In water byproducts: H2O;

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: 584-08-7
potassium carbonate

: 7647-14-5
sodium chloride

: 3811-04-9
potassium chlorate

Conditions

Conditions	Yield
Electrolysis; electrolysis of NaCl, addn. of K2CO3 to obtained NaClO3;
Electrolysis; electrolysis of NaCl, addn. of K2CO3 to obtained NaClO3;

: 7790-93-4
chloric acid

: 584-08-7
potassium carbonate

: 3811-04-9
potassium chlorate

: 7782-50-5
chlorine

: 584-08-7
potassium carbonate

: 3811-04-9
potassium chlorate

Conditions

Conditions	Yield
With oxygen Addn. of O2 to introduced Cl2 does not increase yield.;

: dolomite

: potassium chloride

A: 3811-04-9
potassium chlorate

B: magnesium(II) chloride hexahydrate

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: dolomite

: potassium chloride

A: 3811-04-9
potassium chlorate

B: 7786-30-3
magnesium chloride

...Expand

: dolomite

: potassium chloride

: 3811-04-9
potassium chlorate

Conditions

Conditions	Yield
chlorination and treating obtd. soln. with KCl;
chlorination and treating obtd. soln. with KCl;

: 13444-99-0, 501680-61-1
perchloric acid monohydrate

A: 3811-04-9
potassium chlorate

B: potassium perchlorate

Conditions

Conditions	Yield
With 0.1n-KOH In neat (no solvent) byproducts: chlorine oxides, Cl2, O2; neutralisation of just melting HClO4*H2O with 0.1n KOH; yield of KClO3 much lower than expected from hydrolysis of Cl2O6; The products do not contain HCl;;

: 10049-04-4, 25052-55-5
chlorine dioxide

A: 3811-04-9
potassium chlorate

B: 7790-93-4
chloric acid

Conditions

Conditions	Yield
With potassium permanganate; water In water byproducts: MnO2;
With KMnO4; H2O In water byproducts: MnO2;

: 10049-04-4, 25052-55-5
chlorine dioxide

A: 3811-04-9
potassium chlorate

B: 14314-27-3
potassium chlorite

Conditions

Conditions	Yield
With potassium hydroxide In not given byproducts: KClO3, H2O;
With potassium hydroxide In water addn. of a KOH soln. to a ClO2 soln. containing CO2 and protected from light;; multiple evaporation in the vac. at 45 - 50 °C until KClO3 pptd.; pptn. of K2CO3 with alc.; evaporation in the cold and in the vac.; adding alc. (95 %) to the residue; filtration; evaporation of the filtrate in the cold and in the vac.;;
With potassium hydroxide In water addn. of a KOH soln. to a ClO2 soln. containing CO2 and protected from light;; multiple evaporation in the vac. at 45 - 50 °C until KClO3 pptd.; pptn. of K2CO3 with alc.; fractionated crystn. in the vac.;;

: 10049-04-4, 25052-55-5
chlorine dioxide

: 1310-73-2
sodium hydroxide

A: 3811-04-9
potassium chlorate

B: sodium chlorite trihydrate

Conditions

Conditions	Yield
With potassium hydroxide In not given byproducts: H2O; ClO2 contents max. 2% Cl2; crystn. at -8-5°C, grad of purification: 80%;
With potassium hydroxide In not given byproducts: H2O; ClO2 contents max. 2% Cl2; crystn. at -8-5°C, grad of purification: 80%;

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: 10049-04-4, 25052-55-5
chlorine dioxide

: potassium hydroxide

A: 3811-04-9
potassium chlorate

B: 14314-27-3
potassium chlorite

Conditions

Conditions	Yield
In water byproducts: H2O; dild. soln.;;
In water byproducts: H2O;
In water

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: 10049-04-4, 25052-55-5
chlorine dioxide

: potassium hydroxide

: 3811-04-9
potassium chlorate

: 7722-64-7
potassium permanganate

: 10049-04-4, 25052-55-5
chlorine dioxide

: 3811-04-9
potassium chlorate

: 14998-27-7
chlorite

: 3811-04-9
potassium chlorate

Conditions

Conditions	Yield
With potassium hydroxide; manganese(IV) oxide In not given
With KOH; manganese(IV) oxide In not given

: potassium chloride

A: 3811-04-9
potassium chlorate

B: potassium hydroxide

Conditions

Conditions	Yield
Electrolysis;
Electrolysis;

: potassium chloride

A: 3811-04-9
potassium chlorate

B: 14797-73-0
perchlorate(1-)

Conditions

Conditions	Yield
Electrolysis; perchlorate formation decreases at higher temps.;
Electrolysis; perchlorate formation decreases at higher temps.;

: potassium chloride

A: 3811-04-9
potassium chlorate

B: 14380-61-1
hypochlorite

Conditions

Conditions	Yield
Electrolysis; effect of cathode substance;
Electrolysis; effect of cathode substance;

: potassium chloride

A: 3811-04-9
potassium chlorate

B: 14989-30-1
hypochloric acid

Conditions

Conditions	Yield
With hydrogenchloride byproducts: Cl2; Electrolysis;

: potassium chloride

: 7647-14-5
sodium chloride

: 3811-04-9
potassium chlorate

Conditions

Conditions	Yield
Electrolysis; electrolysis of NaCl, addn. of KCl to obtained NaClO3;
Electrolysis; electrolysis of NaCl, addn. of KCl to obtained NaClO3;

: potassium chloride

: zinc(II) oxide

A: 3811-04-9
potassium chlorate

B: 7646-85-7
zinc(II) chloride

Conditions

Conditions	Yield
at 95-98 °C;
at 95-98 °C;

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: potassium chloride

: potassium perchlorate

: 3811-04-9
potassium chlorate

: potassium chloride

: calcium chloride

: 3811-04-9
potassium chlorate

Conditions

Conditions	Yield
Electrolysis; electrolysis of CaCl2 and addn. of KCl to obtained Ca(ClO3)2;
Electrolysis; electrolysis of CaCl2 and addn. of KCl to obtained Ca(ClO3)2;

: potassium chloride

: 7782-50-5
chlorine

: 1310-73-2
sodium hydroxide

: 3811-04-9
potassium chlorate

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: potassium chloride

: 7782-50-5
chlorine

: 497-19-8
sodium carbonate

: 3811-04-9
potassium chlorate

...Expand

: potassium chloride

: 14989-30-1
hypochloric acid

: 3811-04-9
potassium chlorate

: potassium chloride

: 7782-50-5
chlorine

: calcium hydroxide

A: 3811-04-9
potassium chlorate

B: calcium hydroxide chloride

Conditions

Conditions	Yield
addn. of Ca(OH)2 to soln. remained after crystn. of bulk of KClO3; Calciumoxychloride can be pptd. by cooling soln., causing negligible chlorate loss.;
addn. of Ca(OH)2 to soln. remained after crystn. of bulk of KClO3; Calciumoxychloride can be pptd. by cooling soln., causing negligible chlorate loss.;

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: 3811-04-9
potassium chlorate

: potassium chloride

Conditions

Conditions	Yield
In water byproducts: O2; Irradiation (UV/VIS); U.V. light;	100%
In water byproducts: O2; Irradiation (UV/VIS); U.V. light;	100%
In neat (no solvent) Kinetics; byproducts: O2, NO2, ((C4H9)2NCO)2(CH2)6; sample heating at 5 K/min from up to 620°C; thermosonimetry and TG, high temp. microscopy;

: 3811-04-9
potassium chlorate

: hexammine cobalt(III) chloride

: hexaamminecobalt(III) dichloride chlorate

Conditions

Conditions	Yield
In water hot soln. of KClO3 (0.0018 mol) added to hot soln. of Co(NH3)6Cl3 (0.0018 mol); cooled (4 d); crystals filtered off; dried in air; elem. anal.;	99%

: 3811-04-9
potassium chlorate

: hexaamminecobalt(III) bromide

: hexaamminecobalt(III) dibromide chlorate

Conditions

Conditions	Yield
In water hot soln. of KClO3 (0.0012 mol) added to hot soln. of Co(NH3)6Br3 (0.0012 mol); cooled (3 d); crystals filtered off; dried in air; elem. anal.;	99%

: 3811-04-9
potassium chlorate

: 14380-61-1
hypochlorite

Conditions

Conditions	Yield
With H In not given redn. of a boiling KClO3-soln. (1g in 100ml) by a foil of Pd, laden with hydrogen with addn. of 10ml 25% H2SO4;;	94%
With H In not given redn. of a boiling KClO3-soln. (1g in 100ml) by a foil of Pd, laden with hydrogen with addn. of 10ml 25% H2SO4;;	94%
With H redn. by hydrogen (Pd satd. with H);;

: 3811-04-9
potassium chlorate

: 19638-17-6, 16894-68-1
tetraphenylantimony(V) chloride

: 16894-73-8
tetraphenylantimony chlorate

Conditions

Conditions	Yield
In water mixt. of Ph4SbCl and KClO3 in H2O was kept for 24 h at 12°C; solvent removed; recrystd. (acetone); elem. anal.;	89%

: 3811-04-9
potassium chlorate

: {C5H5Ni(P(C4H9-n)3)2}Cl

: {C5H5Ni(P(C4H9-n)3)2}ClO3

Conditions

Conditions	Yield
In water anion exchange in aq. soln.; molar ratio (C5H5Ni(P(C4H9-n)3)2)(1+)Cl(1-):KClO3 = 1:3; between O°C and room temp.; product dissolved in benzene; recrystn. from hexane or benzene/hexane in the presence of P(C4H9-n)3;	87%
In water

: 3811-04-9
potassium chlorate

: 7789-60-8
phosphorus tribromide

: 7789-59-5
phosphorus(V) oxybromide

Conditions

Conditions	Yield
In neat (no solvent) refluxing at 170 to 190°C for 3 h;; distillation;;	80%

: 3811-04-9
potassium chlorate

: trans-bis(ethylenediamine)dinitrocobalt(III) nitrate

: trans-bis(ethylenediamine)dinitrocobalt(III) chlorate

Conditions

Conditions	Yield
In water byproducts: KNO3; Co complex dissolved in H2O; KClO3 dissolved in H2O at room temp.; two solns. mixed; crystd. for 0.5 h; crystals collected by drawing off the mother liquor; air dried; elem. anal.;	80%

: 3811-04-9
potassium chlorate

: 13408-72-5, 14040-32-5, 14040-33-6, 20594-10-9, 20594-11-0
trans-dichlorobis(ethylenediamine)cobalt(III) chloride

: 26388-78-3
trans-dichlorobis(ethylenediamine)cobalt(III) chlorate

Conditions

Conditions	Yield
In water mixing aqueous solns. of cobalt compd. and chlorate salt for 0.5 h; drawing off mother liquor, air drying, elem. anal.;	80%

: 3811-04-9
potassium chlorate

: {CoCO3phan2}Cl*H2O

: {CoCO3phan2}ClO3

Conditions

Conditions	Yield
In water byproducts: KCl; a soln. of Co-complex and KClO3 in water were mixed, allowed to stand for 1 d at room temp.; crystals were collected and dried in air; elem. anal.;	80%

: 3811-04-9
potassium chlorate

: 4426-72-6, 51433-48-8
hydrazine carboxamide

A: 124-38-9
carbon dioxide

B: 7727-37-9
nitrogen

C: 7664-41-7
ammonia

Conditions

Conditions	Yield
With hydrogenchloride	A n/a B 66% C n/a

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: 3811-04-9
potassium chlorate

: potassium perchlorate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: O2, KCl; heating;;	66%
In neat (no solvent) byproducts: O2, KCl; heating;;	66%
silica gel In neat (no solvent) various m,ixing proportions were investigated; 15 % SiO2 results the greatest yield of KClO4;;	59%

: 3811-04-9
potassium chlorate

: 7681-11-0
potassium iodide

A: 7758-05-6
potassium iodate

B: potassium chloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: O2; 1.5 mol KI/ mol KClO3; start at 350-400°C; violent reaction under formation of O2; mechanism discussed;; product mixture;;	A 65% B n/a

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: 3811-04-9
potassium chlorate

: 7758-05-6
potassium iodate

Conditions

Conditions	Yield
With potassium iodide molar ratio of KI:KIO3 = 1.5:1;	65%
With KI molar ratio of KI:KIO3 = 1.5:1;	65%
With iodine In water heating an aq. suspension of I2 with KClO3 and some drops concd. HNO3;

: 3811-04-9
potassium chlorate

: 7782-41-4
fluorine

: 7616-94-6
perchloryl fluoride

Conditions

Conditions	Yield
In neat (no solvent) below -20°C;; passing ClO3F over KI; cooling at -183°C; distillation at -183 - 130°C in vacuum;;	60%
In neat (no solvent) below -20°C;; passing ClO3F over KI; cooling at -183°C; distillation at -183 - 130°C in vacuum;;	60%

: 3811-04-9
potassium chlorate

: 10034-93-2
hydrazonium sulfate

A: 916329-38-9
hydrogen azide

B: 7664-41-7
ammonia

Conditions

Conditions	Yield
In not given yield is higher in presence of solid Ag2SO4;	A 22% B 48%
In not given yield is higher in presence of solid Ag2SO4;	A 22% B 48%

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: 3811-04-9
potassium chlorate

: 7782-41-4
fluorine

A: 7616-94-6
perchloryl fluoride

B: dichlorine hexaoxide

C: 10049-04-4, 25052-55-5
chlorine dioxide

D: 7790-89-8
chlorine monofluoride

E: 7782-50-5
chlorine

Conditions

Conditions	Yield
In neat (no solvent) byproducts: O2; transport reaction: passing F2-N2 mixture over KClO3 at 25 - 60°C;; washing with NaOH; passing ClO3F through Na2S2O3 soln.; drying over NaOH and P2O5;;	A 45% B n/a C n/a D n/a E n/a

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: 3811-04-9
potassium chlorate

: 7697-37-2
nitric acid

: potassium perchlorate

Conditions

Conditions	Yield
In not given multiple evapn. with ambient concd. HNO3; nearly no KClO4 is obtained using fuming HNO3;;	30%
In not given multiple evapn. using ambient concd. or water-free HNO3; nearly no KClO4 is formed, if fuming HNO3 is used;;	30%
In not given multiple evapn. with ambient concd. HNO3; nearly no KClO4 is obtained using fuming HNO3;;	30%

: 3811-04-9
potassium chlorate

: 7782-41-4
fluorine

: potassium perchlorate

Conditions

Conditions	Yield
With alkali	25%
With alkali	25%

: 3811-04-9
potassium chlorate

: 86119-84-8, 7664-38-2
phosphoric acid

: potassium perchlorate

Conditions

Conditions	Yield
In not given boiling until yellow color disappears;;	15%
In not given boiling until yellow color disappears;;	15%

: 3811-04-9
potassium chlorate

: 7664-93-9
sulfuric acid

: potassium perchlorate

Conditions

Conditions	Yield
In not given	11%
In not given	11%
In not given

: 3811-04-9
potassium chlorate

: bis(triethylammonium)-decahydro-closo-decaborate

: triethyl ammonium hexachloro decaborate(10)

Conditions

Conditions	Yield
In sulfuric acid addition of a solution of KClO3 in H2O (0.70 M ClO3(1-)) to a solution of the decaborate (0.20 M B10H10(2-)) in aq. H2SO4 (0.5 M H(1+)) and stirring at 25°C, 7 days;; filtration of ((C2H5)3NH)(B20H18);;	8%
In hydrogenchloride addition of a solution of KClO3 in H2O (0.70 M ClO3(1-)) to a solution of the decaborate (0.20 M B10H10(2-)) in aq. HCl (0.5 M H(1+)) and stirring at 25°C, 7 days;; filtration of ((C2H5)3NH)(B20H18);;	8%
In sulfuric acid addition of a solution of KClO3 in H2O (0.50 M ClO3(1-)) to a solution of the decaborate (0.20 M B10H10(2-)) in aq. H2SO4 (0.5 M H(1+)) and stirring at 25°C, 7 days;; filtration of ((C2H5)3NH)(B20H18);;	5%

: 3811-04-9
potassium chlorate

: ammonium chloride

: 7782-50-5
chlorine

Conditions

Conditions	Yield
decompn. of Nh4Cl with heating KClO3;	>99
decompn. of Nh4Cl with heating KClO3;
decompn. of Nh4Cl with heating KClO3;	>99
decompn. of Nh4Cl with heating KClO3;