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Cas:7616-94-6
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Cas:7616-94-6
Min.Order:5 Kiloliter
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Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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Cas:7616-94-6
Min.Order:1 Kilogram
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PERCHLORYL FLUORIDEAppearance:Off white to slight yellow solid Storage:Store in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/Pharmaceutical intermediates Transportation:By Sea,by Air,By courier li
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PERCHLORYL FLUORIDEAppearance:Off white to slight yellow solid Storage:Stored in shaded, cool and dry places Package:1L 5L 10L 25L bottle Application:pharma intermediate Transportation:Handle with cares to avoid damaging the packages. Protect them fr
Conditions | Yield |
---|---|
In neat (no solvent) heating at 105°C;; | 97% |
In neat (no solvent) heating at 105°C;; | 97% |
Conditions | Yield |
---|---|
In neat (no solvent) below -20°C;; passing ClO3F over KI; cooling at -183°C; distillation at -183 - 130°C in vacuum;; | 60% |
In neat (no solvent) below -20°C;; passing ClO3F over KI; cooling at -183°C; distillation at -183 - 130°C in vacuum;; | 60% |
potassium chlorate
fluorine
A
perchloryl fluoride
C
chlorine dioxide
D
chlorine monofluoride
E
chlorine
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: O2; transport reaction: passing F2-N2 mixture over KClO3 at 25 - 60°C;; washing with NaOH; passing ClO3F through Na2S2O3 soln.; drying over NaOH and P2O5;; | A 45% B n/a C n/a D n/a E n/a |
Conditions | Yield |
---|---|
In water reaction of 60 - 62% aq. HClO4 with SbF5 at 90 - 100°C;; | 36% |
In water reaction of 60 - 62% aq. HClO4 with SbF5 at 90 - 100°C;; | 36% |
In neat (no solvent) reaction of 1 mol perchlorate and 3 - 10 mol SbF5 at 100 - 120°C; cooling down;; washing with Na2S2O3; condenstion at temp. of liquid air;; | 36-53 |
perchloric acid
fluorine
A
difluoroether
B
perchloryl fluoride
Conditions | Yield |
---|---|
In water |
Conditions | Yield |
---|---|
In neat (no solvent) at 20 - 40°C;; | 0% |
In neat (no solvent) at 20 - 40°C;; | 0% |
hydrogen fluoride
A
difluoroether
B
perchloryl fluoride
C
hydrogen
D
oxygen
E
chlorine
Conditions | Yield |
---|---|
In neat (no solvent) Electrolysis; electrolysis of NaClO4 soln. in HF at 0 - 30°C;; condensation with liquid air; washing with Na2S2O3 soln.;; | |
In neat (no solvent) Electrolysis; electrolysis of NaClO4 soln. in HF at 0 - 30°C;; condensation with liquid air; washing with Na2S2O3 soln.;; |
Conditions | Yield |
---|---|
In neat (no solvent) heating perchlorate with excess of HSO3F;; | >80 |
In neat (no solvent) heating perchlorate with excess of HSO3F;; | >80 |
Conditions | Yield |
---|---|
With cesium fluoride byproducts: CO2, Cl2; A mixture of LiClO4 and CsF (as HF getter) was treated in a stainless steel cylinder with COF2; heating up to 120°C; | 0% |
Conditions | Yield |
---|---|
In neat (no solvent) heating perchlorate with excess of HSO3F;; | >80 |
In neat (no solvent) heating perchlorate with excess of HSO3F;; | >80 |
Conditions | Yield |
---|---|
In neat (no solvent) | |
In neat (no solvent) |
Conditions | Yield |
---|---|
In neat (no solvent) | |
In neat (no solvent) |
Conditions | Yield |
---|---|
In neat (no solvent) | |
In neat (no solvent) |
Conditions | Yield |
---|---|
In neat (no solvent) | |
In neat (no solvent) |
Conditions | Yield |
---|---|
In neat (no solvent) | |
In neat (no solvent) |
Conditions | Yield |
---|---|
In neat (no solvent) | |
In neat (no solvent) |
Conditions | Yield |
---|---|
In neat (no solvent) reaction of 1 mol perchlorate and 3 - 10 mol SbF5 at 100 - 120°C; cooling down;; washing with Na2S2O3; condenstion at temp. of liquid air;; | 36-53 |
Conditions | Yield |
---|---|
In not given | |
In fluorosulphonic acid mixt. of KClO4 in fluorosulfonic acid stirred under gradual warming up to about 95°C; FClO3 was flushed with moderate N2 flow; purified through column filled with sodium thiosulfate and ascarite; | |
In neat (no solvent) heating KClO4 and HSO3F (10:100) at 110°C;; | 52-60 |
Conditions | Yield |
---|---|
In neat (no solvent) heating perchlorate with excess of HSO3F;; | >80 |
In neat (no solvent) heating perchlorate with excess of HSO3F;; | >80 |
chloryl fluoride
perchloryl fluoride
Conditions | Yield |
---|---|
With water In water byproducts: H2; |
Conditions | Yield |
---|---|
In neat (no solvent) heating KClO3 and 98% HSO3F at 85°C;; passing ClO3F through thiosulfate soln. and over solid KOH; condensation at temp. of liquid air;; | |
In neat (no solvent) heating KClO3 and 98% HSO3F at 85°C;; passing ClO3F through thiosulfate soln. and over solid KOH; condensation at temp. of liquid air;; |
perchloric anhydride
fluorine
A
perchloryl fluoride
B
chloryl fluoride
C
chlorine monofluoride
D
oxygen
E
chlorine
Conditions | Yield |
---|---|
In neat (no solvent) Kinetics; thermal decompn. of Cl2O7 in presence of enough amounts of F2 at 100 - 120°C; reaction mechanism described;; |
perchloric anhydride
fluorine
A
perchloryl fluoride
B
chloryl fluoride
Conditions | Yield |
---|---|
In neat (no solvent) thermal decompn. in prescence of F2;; |
perchloric anhydride
fluorine
A
perchloryl fluoride
B
chloryl fluoride
C
chlorine monofluoride
Conditions | Yield |
---|---|
In neat (no solvent) decompn. of Cl2O7 in presence of F2 at 100 - 120°C;; | |
In neat (no solvent) decompn. of Cl2O7 in presence of F2 at 100 - 120°C;; |
Conditions | Yield |
---|---|
In neat (no solvent) formation as intermediate at 100 - 120°C;; | |
In neat (no solvent) formation as intermediate at 100 - 120°C;; |
Conditions | Yield |
---|---|
In neat (no solvent) formation of Cl2O6 as by-product;; | |
In neat (no solvent) formation of Cl2O6 as by-product;; |
potassium chlorate
fluorine
A
perchloryl fluoride
B
chloryl fluoride
C
chlorine monofluoride
D
chlorine
Conditions | Yield |
---|---|
In neat (no solvent) at -40°C;; | |
In neat (no solvent) at -40 or 100°C;; fractionated distillation;; | |
In neat (no solvent) at -40°C;; | |
In neat (no solvent) at -40 or 100°C;; fractionated distillation;; |
perchloryl fluoride
potassium trinitromethanide
fluorotrinitromethane
Conditions | Yield |
---|---|
In further solvent(s) in CH3O(CH2)2OCH3; | 77% |
In N,N-dimethyl-formamide | 77% |
In acetone | 77% |
Conditions | Yield |
---|---|
In further solvent(s) in CH3O(CH2)2OCH3; | 77% |
In N,N-dimethyl-formamide | 77% |
In acetone | 77% |
In methanol at 20°C 11 h; | 17.7% |
perchloryl fluoride
trinitromethane; ammonium salt
fluorotrinitromethane
Conditions | Yield |
---|---|
In further solvent(s) in CH3O(CH2)2OCH3; | 77% |
In N,N-dimethyl-formamide | 77% |
In acetone | 77% |
perchloryl fluoride
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: dimethylphenylamine, N-(4-chloriohenyl)-N-methyl-formamide; dimethyl-(4-trimethylstannanylphenyl)amine dissolved in dry THF was cooled at -60°C; FClO3/N2 mixt. passed through soln. for about 35 min; soln. warmed up to ambient temp. under stirring and stirred at about 60°C for 20 min (closed ....; isolated by semi-preparative thin-layer chromy. (silica gel 60, petroleum ether/ethyl acetate 10:1); | 52% |
Conditions | Yield |
---|---|
In methanol at 20°C 10 h; | 47% |
perchloryl fluoride
(4-methoxyphenyl)trimethylstannane
A
bis(4-methoxyphenyl)dimethylstannane
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: methoxybenzene; (4-methoxyphenyl)trimethylstannane dissolved in dry THF was cooled at -60°C; FClO3/N2 mixt. passed through soln. for about 35 min; soln. warmed up to ambient temp. under stirring and stirred at about 60°C for 20 min (closed conditions) or; isolated by semi-preparative thin-layer chromy. (silica gel 60, petroleum ether/ethyl acetate 10:1); | A n/a B 40% |
perchloryl fluoride
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: phenylcarbamic acid tert-butyl ester; (4-trimethylstannanylphenyl)carbamic acid tert-butyl ester dissolved in dry THF was cooled at -60°C; FClO3/N2 mixt. passed through soln. for about 35 min; soln. warmed up to ambient temp. under stirring and stirred at about 60°C for 20 min; isolated by semi-preparative thin-layer chromy. (silica gel 60, petroleum ether/ethyl acetate 10:1); | A 40% B n/a |
perchloryl fluoride
Na(1+)*CBr(NO2)2(1-)=NaCBr(NO2)2
fluoro bromo dinitromethane
Conditions | Yield |
---|---|
In further solvent(s) in CH3O(CH2)2OCH3; | 36% |
In N,N-dimethyl-formamide | 36% |
In acetone | 36% |
perchloryl fluoride
fluoro bromo dinitromethane
Conditions | Yield |
---|---|
In further solvent(s) in CH3O(CH2)2OCH3; | 36% |
In N,N-dimethyl-formamide | 36% |
In acetone | 36% |
perchloryl fluoride
bromo-dinitro-methane; potassium salt
fluoro bromo dinitromethane
Conditions | Yield |
---|---|
In further solvent(s) in CH3O(CH2)2OCH3; | 36% |
In N,N-dimethyl-formamide | 36% |
In acetone | 36% |
perchloryl fluoride
Na(1+)*CCl(NO2)2(1-)=NaCCl(NO2)2
fluorochlorodinitromethane
Conditions | Yield |
---|---|
In further solvent(s) in CH3O(CH2)2OCH3; | 33% |
In N,N-dimethyl-formamide | 33% |
In acetone | 33% |
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