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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Antimony pentafluoride

Cas:7783-70-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Antimony pentafluoride CAS 7783-70-2 In stock

Cas:7783-70-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Antimony fluoride(SbF5)

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Antimony pentafluoride

Cas:7783-70-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung, LG, Merck, Thermo Fisher Scientific and so o

7783-70-2 ANTIMONY PENTAFLUORIDE

Cas:7783-70-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

ANTIMONY PENTAFLUORIDE

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Antimony pentafluoride

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Other

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 7783-70-2 with best price

Cas:7783-70-2

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Antimony fluoride(SbF5)

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

Ocean inorganic department is a professional supplier and exporter engaging in inorganic chemical materials and metal organic compounds. Over the past years, our company is committed to improving the product quality and developing new products, in or

Antimony (V) Fluoride

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

Antimony pentafluoride CAS NO.7783-70-2 Application:Antimony pentafluoride CAS NO.7783-70-2

Antimony pentafluoride CAS NO.7783-70-2

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Other

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Hunan Longxianng Runhui Trading Co.,Ltd

Antimony pentafluoride CAS NO.7783-70-2Appearance:off-white fine crystalline powder Storage:Dry and ventilated Package:Standard or as customer's require Application:intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for sm

Antimony pentafluoride CAS NO.7783-70-2

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

ANTIMONY PENTAFLUORIDE 7783-70-2

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Trading Company

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#7783-70-2;CAT#A839231

Cas:7783-70-2

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

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Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Antimony pentafluoride

Cas:7783-70-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Bizhi Chemical Tech Co Ltd

Product Name: ANTIMONY PENTAFLUORIDE Synonyms: Antimony fluoride (SbF5);Antimony(V) pentafluoride;antimony(v)pentafluoride;ant

ANTIMONY PENTAFLUORIDE 7783-70-2 98.5%

Cas:7783-70-2

Min.Order:50 Kilogram

FOB Price: $149.3 / 179.2

Type:Trading Company

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HuBei Ipure Biotech CO.,ltd

HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of plant

Antimony fluoride(SbF5)

Cas:7783-70-2

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

sub/micron to mesh powders (near/spheres, whiskers, flake, fiber, porous) and grain/ball, thin/ thick metal / alloys pieces / parts, thin and thick (particle) film materials /target, and custom-made crystals, substrates/parts. In the industries and a

Antimony pentafluoride

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Antimony fluoride(SbF5)

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

Antimony fluoride(SbF5)

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei mingxing biotech co.,ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Prompt reaction, good quality and best service make us reliable and outstanding in this industry.Appearance:yellow to white solid or po

Antimony fluoride(SbF5)

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Other

inquiry

Pure Chemistry Scientific Inc.

ANTIMONY PENTAFLUORIDE Application:80062945

ANTIMONY PENTAFLUORIDE

Cas:7783-70-2

Min.Order:1 Gram

FOB Price: $500.0

Type:Trading Company

inquiry

changchun tuocai technology co.,ltld

Antimony pentafluoride CAS NO.7783-70-2Appearance:off-white fine crystalline powder Storage:Dry and ventilated Package:Standard or as customer's require Application:intermediates Transportation:Delivery by EMS, DHL, FEDEX, UPS, TNT

Antimony pentafluoride CAS NO.7783-70-2

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GZ HONESTCHEM CO., LTD

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

Antimony pentafluoride

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Minshang Biotechnology Co., Ltd

Antimony pentafluoride CAS NO.7783-70-2 Application:intermediates

7783-70-2

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Weihai Moochun Bio-Tech Co., Ltd.

high quality;competitive price Storage:keep sealed and keep from direct light Package:Sample: 50g/ bottle 100g/ bottle 1000g/ bottle bulk: 25kg/drum 50kg/drum 537kg/drum Application:Scientific research Transportation:For small batches, they will

ANTIMONY PENTAFLUORIDE

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Skyrun Industrial Co.,Ltd

Capacity, Prompt shipment Application:surface active agent

CSR1608-437

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fenjun Chemical Co Ltd.

Antimony pentafluoride CAS NO.7783-70-2 Application:Antimony pentafluoride CAS NO.7783-70-2

Antimony pentafluoride CAS NO.7783-70-2

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

7783-70-2

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Debye Scientific

Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen

Antimonypentafluoride

Cas:7783-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

antimony
7440-36-0

antimony

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) cylinder fiited with dry powdered element, NF3O condensed into cylinder at -196°C, mixt. heated at 210°C for 24h; not isolated, monitored by NMR, IR;90%
((pentafluorosulfanyl)imino)difluorosulfane
13774-70-4

((pentafluorosulfanyl)imino)difluorosulfane

antimonypentachloride
7647-18-9

antimonypentachloride

A

SF5N=SCl2
25502-15-2

SF5N=SCl2

B

((pentafluorosulfanyl)imino)chlorofluorosulfane
80997-19-9

((pentafluorosulfanyl)imino)chlorofluorosulfane

C

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
sulfane was condesed on SbCl5 at -196°C, heated at 100°C to initiate the reaction; fractionation through a series of traps at -6, -45, -78, -112 and -196°C in vac., a -45°C trap contained the product;A 35%
B n/a
C n/a
H2F(1+)*SbClF5(1-)=H2FSbClF5
128362-15-2

H2F(1+)*SbClF5(1-)=H2FSbClF5

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) byproducts: HCl, HF; decomposition above -50°C;;
antimony
7440-36-0

antimony

xenon difluoride
13709-36-9

xenon difluoride

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) powdered metal treated with XeF2 (air-tight autoclave, 200-300°C);
antimony
7440-36-0

antimony

fluorine
7782-41-4

fluorine

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
burning antimony filings in F2 atmosphere; without isolation of intermediates the end product liq. SbF5;
in a stream of HF-free F2; distn. in vac.;
In not given
hydrogen fluoride
7664-39-3

hydrogen fluoride

antimonypentachloride
7647-18-9

antimonypentachloride

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
HF free of water;;
HF free of water;;
at 100℃; for 3h; Autoclave; Inert atmosphere;
antimony(V) chloride
7647-18-9

antimony(V) chloride

hydrogen fluoride
7664-39-3

hydrogen fluoride

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In hydrogen fluoride
In hydrogen fluoride HF (liquid);
antimonic acid

antimonic acid

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
With hydrogen fluoride by addn. antimonic acid into HF soln.; evapn. in vac.; cannot be crystallized;
With calcium fluoride; sulfuric acid by distn.;0%
With hydrogen fluoride anhydrous antimonic acid with concd. HF soln.;0%
mercury(II) fluoride

mercury(II) fluoride

antimonic acid

antimonic acid

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
by glowing antimonic acid with dry HgF2;0%
by glowing antimonic acid with dry HgF2;0%
triethyloxonium hexafluoroantimonate

triethyloxonium hexafluoroantimonate

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
With diethyl ether In dichloromethane Kinetics; byproducts: Et2O, CH3CH2F; vac. line; 298 - 343 K;
With 1,3-dioxolan In dichloromethane Kinetics; byproducts: Et2O, CH3CH2F; vac. line; 298 - 343 K;
antimonypentachloride
7647-18-9

antimonypentachloride

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
With hydrogen fluoride
With hydrogen fluoride byproducts: HCl; with anhydrous HF excess; temp. programming is given; SbF5 in liq. form;
With HF byproducts: HCl; with anhydrous HF, at room temp., in dry conditions; HF excess; SbF5 in liq. form;
With HF byproducts: HCl; with anhydrous HF excess; temp. programming is given; SbF5 in liq. form;
With HF
SbF5*5HF

SbF5*5HF

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
byproducts: HF; at 80 °C;
2SbF5*I

2SbF5*I

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
at >240 °C;
at >240 °C;
antimony pentoxide

antimony pentoxide

Dichlorodifluoromethane
75-71-8

Dichlorodifluoromethane

A

antimony tetrachloride fluoride
14913-58-7

antimony tetrachloride fluoride

B

antimony dichloride trifluoride
7791-16-4

antimony dichloride trifluoride

C

SbF4Cl
15588-48-4

SbF4Cl

D

SbCl3F2
24626-20-8

SbCl3F2

E

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) reaction at 600°C;;
antimony
7440-36-0

antimony

difluoroether
7783-41-7

difluoroether

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) heating of antimony powder and OF2; inflammation;;
In neat (no solvent) heating of antimony powder and OF2; inflammation;;
perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)
6141-72-6

perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)

tris(trifluoromethyl)stibane
432-05-3

tris(trifluoromethyl)stibane

A

Perfluoro-2-azapropen
371-71-1

Perfluoro-2-azapropen

B

tris(trifluoromethyl)hydroxylamine
671-63-6

tris(trifluoromethyl)hydroxylamine

C

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
warming from -60°C to room temp. within 10 h;A >99
B >99
C >99
warming from -60°C to room temp. within 10 h;A >99
B >99
C >99
Ca(antimony hexafluoride)2

Ca(antimony hexafluoride)2

A

calcium fluoride

calcium fluoride

B

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) dry air atmosphere; melting and thermal decompn. above 600-650°C; TGA;
Ba(antimony hexafluoride)2

Ba(antimony hexafluoride)2

A

barium fluoride

barium fluoride

B

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) dry air atmosphere; melting and thermal decompn. above 600-650°C; TGA;
Sr(antimony hexafluoride)2

Sr(antimony hexafluoride)2

A

strontium fluoride

strontium fluoride

B

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) dry air atmosphere; melting and thermal decompn. above 600-650°C; TGA;
Mg(antimony hexafluoride)2

Mg(antimony hexafluoride)2

A

magnesium fluoride

magnesium fluoride

B

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) dry air atmosphere; melting and thermal decompn. above 600-650°C; TGA;
antimony(V) chloride
7647-18-9

antimony(V) chloride

hydrogen fluoride
7664-39-3

hydrogen fluoride

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In hydrogen fluoride solving of SbCl5 in liq. HF;;
In hydrogen fluoride solving of SbCl5 in liq. HF;;
plutonium hexafluoride
13693-06-6

plutonium hexafluoride

antimony(III) fluoride
7783-56-4

antimony(III) fluoride

A

PuF4
13709-56-3

PuF4

B

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
below room temp.; powder XRD;
iridium hexafluoride
7783-75-7

iridium hexafluoride

antimony(III) fluoride
7783-56-4

antimony(III) fluoride

A

iridium pentafluoride
14568-19-5

iridium pentafluoride

B

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) IrF6 condensed onto excess of SbF3 at -196°C, allowed to warm slowly to room temp.; volatiles species removed, fractionated; IR;
chromium pentafluoride
14884-42-5

chromium pentafluoride

KrF(1+)*SbF6(1-) = [KrF][SbF6]
52708-44-8

KrF(1+)*SbF6(1-) = [KrF][SbF6]

A

hexafluoro-chromium(VI)
13843-28-2

hexafluoro-chromium(VI)

B

krypton

krypton

C

antimony pentafluoride
7783-70-2

antimony pentafluoride

D

fluorine
7782-41-4

fluorine

Conditions
ConditionsYield
34°C;A 0%
B n/a
C n/a
D n/a
SbF5*S

SbF5*S

A

antimony(III) fluoride
7783-56-4

antimony(III) fluoride

B

antimony pentafluoride
7783-70-2

antimony pentafluoride

C

sulfur
7704-34-9

sulfur

Conditions
ConditionsYield
partial decompn. in wet air;
partial decompn. in wet air;
fluoro(trifluoromethylsulfenyl)phosphonium SbF6
124489-84-5

fluoro(trifluoromethylsulfenyl)phosphonium SbF6

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In liquid sulphur dioxide byproducts: HF, (CF3SP)99;
ruthenium(VI) fluoride
13693-08-8

ruthenium(VI) fluoride

antimony(III) fluoride
7783-56-4

antimony(III) fluoride

A

ruthenium(V) fluoride
14521-18-7

ruthenium(V) fluoride

B

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
RuF6 was condensed onto SbF3 at -196°C; was allowed to warm slowly to room temperature; volatiles were removed; IR;
antimonypentachloride
7647-18-9

antimonypentachloride

A

2SbF3*SbF5

2SbF3*SbF5

B

antimony(III) chloride
10025-91-9

antimony(III) chloride

C

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
With HF byproducts: HCl, Cl2; with anhydrous HF; distn. (8h) at 90 °C (distn. of HCl and HF), and up to 125 °C (distn. of SbCl5, SbCl3 and SbF5); distn. at 390 °C;
PF4(1+)*Sb3F16(1-) = PF4Sb3F16

PF4(1+)*Sb3F16(1-) = PF4Sb3F16

A

antimony pentafluoride
7783-70-2

antimony pentafluoride

B

phosphorus pentafluoride
7647-19-0, 874483-74-6

phosphorus pentafluoride

Conditions
ConditionsYield
in soln.; 194 K; 30 min;A >99
B >99
NF2O(1+)*SbF6(1-) = (NF2O)(SbF6)
25562-23-6

NF2O(1+)*SbF6(1-) = (NF2O)(SbF6)

A

trifluoroamine oxide
13847-65-9, 57526-95-1, 478286-98-5

trifluoroamine oxide

B

antimony pentafluoride
7783-70-2

antimony pentafluoride

(η5-C5H5)2niobium(V)(Cl2) hexafluoroantimonate

(η5-C5H5)2niobium(V)(Cl2) hexafluoroantimonate

antimony pentafluoride
7783-70-2

antimony pentafluoride

(η5-C5H5)2niobium(V)(Cl2) {Sb2F11}

(η5-C5H5)2niobium(V)(Cl2) {Sb2F11}

Conditions
ConditionsYield
In liquid sulphur dioxide under Ar; recrystn. (SO2), elem. anal.;100%
antimony pentafluoride
7783-70-2

antimony pentafluoride

triphenylgermanium fluoride
379-47-5

triphenylgermanium fluoride

Conditions
ConditionsYield
With pyrographite In diethyl ether under N2 a soln. of Co-complex in ether was added dropwise with stirring to a suspension of SbF5/C in ether at room temp., stood for 6 d; monitored by IR, filtered, pumped off, dissolved in pentane, filtered, cocnd., cooled to -20°C;100%
indium(I) tetrafluoroborate
62792-13-6

indium(I) tetrafluoroborate

hydrogen fluoride
7664-39-3

hydrogen fluoride

antimony pentafluoride
7783-70-2

antimony pentafluoride

indium(I) hexafluoroantimonate
877238-63-6

indium(I) hexafluoroantimonate

Conditions
ConditionsYield
In hydrogen fluoride HF (liquid); equimol., HF condenced onto reagent at 77 K, alowed to warm to room temp., left for 1 d; volatiles removed (vac.); elem. anal.;100%
(2,3,7,8,12,13,17,18-octaethylporphyrinato)zinc(II)
17632-18-7

(2,3,7,8,12,13,17,18-octaethylporphyrinato)zinc(II)

antimony pentafluoride
7783-70-2

antimony pentafluoride

C36H44N4Zn(2+)*2F6Sb(1-)

C36H44N4Zn(2+)*2F6Sb(1-)

Conditions
ConditionsYield
In dichloromethane at -78 - 20℃; Inert atmosphere;100%
hydrogen fluoride
7664-39-3

hydrogen fluoride

antimony pentafluoride
7783-70-2

antimony pentafluoride

acetonitrile
75-05-8

acetonitrile

C2H3N*F6Sb(1-)*H(1+)

C2H3N*F6Sb(1-)*H(1+)

Conditions
ConditionsYield
Stage #1: hydrogen fluoride; antimony pentafluoride at -196 - 20℃; Sealed tube;
Stage #2: acetonitrile at -196 - 20℃; for 0.5h; Sealed tube; Inert atmosphere;
100%
hydrogen fluoride
7664-39-3

hydrogen fluoride

antimony pentafluoride
7783-70-2

antimony pentafluoride

acetonitrile
75-05-8

acetonitrile

MeCNHSb2F11

MeCNHSb2F11

Conditions
ConditionsYield
Stage #1: hydrogen fluoride; antimony pentafluoride at -196 - 20℃; Sealed tube;
Stage #2: acetonitrile at -196 - 20℃; for 0.5h; Sealed tube; Inert atmosphere;
100%
propyl cyanide

propyl cyanide

antimony pentafluoride
7783-70-2

antimony pentafluoride

F5Sb*C4H7N

F5Sb*C4H7N

Conditions
ConditionsYield
at -196 - -64℃; for 0.166667h; Sealed tube;100%
antimony pentafluoride
7783-70-2

antimony pentafluoride

cyclopropropanecarbonitrile
5500-21-0

cyclopropropanecarbonitrile

C4H5N*F5Sb

C4H5N*F5Sb

Conditions
ConditionsYield
at -196 - -64℃; for 0.166667h; Sealed tube;100%
tert-butyl isocyanide
630-18-2

tert-butyl isocyanide

antimony pentafluoride
7783-70-2

antimony pentafluoride

C5H9N*F5Sb

C5H9N*F5Sb

Conditions
ConditionsYield
at -196 - -64℃; for 0.166667h; Sealed tube;100%
titanocene difluoride
309-89-7

titanocene difluoride

antimony pentafluoride
7783-70-2

antimony pentafluoride

(cyclopentadienyl)2Ti(SbF6)2

(cyclopentadienyl)2Ti(SbF6)2

Conditions
ConditionsYield
In sulfur dioxide condensation of SbF5 in SO2 into a soln. of Ti-compd. in SO2 at -50°C, warming to room temp. with stirring, then stirring at room temp. for 30 min; cooling to 10-15°C and condensation of SO2, formation of a solid, elem. anal.;99.8%
cis-difluorodiazene
13812-43-6

cis-difluorodiazene

antimony pentafluoride
7783-70-2

antimony pentafluoride

N2F(1+)*SbF6(1-)=[N2F][SbF6]
16871-11-7

N2F(1+)*SbF6(1-)=[N2F][SbF6]

Conditions
ConditionsYield
In hydrogen fluoride HF (liquid); (vac.); condensing HF onto SbF5 at -196°C, warming to room temp.,addn. of N2F2 at -196°C, warming to room temp., stirring for 10 min; pumping off at -64°C for 2 h;99.7%
cis-osmium tetrafluoride dioxide
143672-39-3

cis-osmium tetrafluoride dioxide

antimony pentafluoride
7783-70-2

antimony pentafluoride

F(cis-OsO2F3)2(+)Sb2F11(-)

F(cis-OsO2F3)2(+)Sb2F11(-)

B

[OsO2F3](1+)*[SbF6](1-)=[OsO2F3][SbF6]
1203648-84-3

[OsO2F3](1+)*[SbF6](1-)=[OsO2F3][SbF6]

Conditions
ConditionsYield
In hydrogen fluoride HF (liquid); SbF5 added to OsO2F4, HF condensed at -196°C, warmed to room temp.; pptd. at -78°C, pumped for 5 h at 0°C;A 99.4%
B 0%
In neat (no solvent) warmed to room temp.; pumped at 0°C for 6 d;A 107 %
B 0%
bis(pentafluoroethyl)selenium difluoride
59802-62-9

bis(pentafluoroethyl)selenium difluoride

antimony pentafluoride
7783-70-2

antimony pentafluoride

bis(pentafluoroethyl)selenium difluoride SbF5 adduct

bis(pentafluoroethyl)selenium difluoride SbF5 adduct

Conditions
ConditionsYield
20°C, 1.5 h;99%
Au fluorosulfate

Au fluorosulfate

carbon monoxide
201230-82-2

carbon monoxide

antimony pentafluoride
7783-70-2

antimony pentafluoride

bis(carbonyl)gold(I) undecafluorodiantimonate(V)

bis(carbonyl)gold(I) undecafluorodiantimonate(V)

Conditions
ConditionsYield
mild conditions, low CO pressure;99%
krypton difluoride
13773-81-4

krypton difluoride

antimony pentafluoride
7783-70-2

antimony pentafluoride

KrF(1+)*SbF6(1-) = [KrF][SbF6]
52708-44-8

KrF(1+)*SbF6(1-) = [KrF][SbF6]

Conditions
ConditionsYield
In hydrogen fluoride dry HF was distd. in 1 equiv of SbF5, homogenized at ambient temp., 1.06 equiv of KrF2 was transferred under vac. at -196°C, warmed to room temp., cooled, warmup was repeated three cycles; volatiles pumped off at -22°C;99%
carbon monoxide
201230-82-2

carbon monoxide

antimony pentafluoride
7783-70-2

antimony pentafluoride

gold(III) chloride
13453-07-1

gold(III) chloride

bis(carbonyl)gold(I) undecafluorodiantimonate(V)

bis(carbonyl)gold(I) undecafluorodiantimonate(V)

Conditions
ConditionsYield
In further solvent(s) byproducts: COF2; absence of air and moisture; stirring AuCl3 in SbF5 under 0.6 atm CO (60-70°C, 5 d); evapn. (vac., 55°C);99%
Pd(II)Pd(IV) fluorosulfate

Pd(II)Pd(IV) fluorosulfate

carbon monoxide
201230-82-2

carbon monoxide

antimony pentafluoride
7783-70-2

antimony pentafluoride

tetrakis(carbonyl)palladium(II) undecafluoroantimonate(V)

tetrakis(carbonyl)palladium(II) undecafluoroantimonate(V)

Conditions
ConditionsYield
mild conditions, low CO pressure;99%
platinum tetrakis(fluorosulfate)

platinum tetrakis(fluorosulfate)

carbon monoxide
201230-82-2

carbon monoxide

antimony pentafluoride
7783-70-2

antimony pentafluoride

tetrakis(carbonyl)platinum(II) undecafluoroantimonate(V)

tetrakis(carbonyl)platinum(II) undecafluoroantimonate(V)

Conditions
ConditionsYield
mild conditions, low CO pressure;99%
fluoroformyl chloride
353-49-1

fluoroformyl chloride

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) Teflon ampoule inside stainless-steel vac. line; excess COClF, mixing at-196°C, stirring at -78°C for 1 h; pumping at -110°C;99%
Carbonyl fluoride
353-50-4

Carbonyl fluoride

antimony pentafluoride
7783-70-2

antimony pentafluoride

Conditions
ConditionsYield
In neat (no solvent) Teflon ampoule inside stainless-steel vac. line; excess COF2, mixing at -196°C, stirring at -78°C for 1 h; pumping at -126°C;99%
osmium tris(fluorosulfate)

osmium tris(fluorosulfate)

carbon monoxide
201230-82-2

carbon monoxide

antimony pentafluoride
7783-70-2

antimony pentafluoride

[Os(carbonyl)6](fluoroantimonate(V))2

[Os(carbonyl)6](fluoroantimonate(V))2

Conditions
ConditionsYield
In neat (no solvent) byproducts: CO2, S2O5F2, Sb2F9(SO3F); liquid SbF5, ca. 1 atm CO, 60-90°C, 2-4 d;99%
With HF byproducts: CO2, S2O5F2, Sb2F9(SO3F); to the reactor charged with Os(SO3F)3 were added SbF5 and HF using a stainless steel vac. line, at -195°C CO was admitted to the reactor,heated to 50-60°C for 1-2 days without stirring; volatiles were removed in vac., crystals were washed with an SbF5/HF (2:1) mixt., volatiles were removed in vac.;87%
heating at 60-90°C in 1 atm CO;
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