SbCl5*SO3
A
pyrosulfuryl chloride
C
antimonypentachloride
D
sulfur trioxide
Conditions | Yield |
---|---|
70°C in vac.; | A n/a B n/a C n/a D 95% |
Conditions | Yield |
---|---|
In melt Reaction of SbCl3 melt with NOCl to give SbCl5; | 80% |
With chlorine In melt Reaction of SbCl3 melt with a mixt. of NOCl and Cl2 to give SbCl5; |
Conditions | Yield |
---|---|
With sulfur with melted Ag2F2 at 500°C; gaseous S2F2 formed; | A 48.9% B n/a |
With sulfur with melted Ag2F2 at 600°C; gaseous S2F2 formed; | A 40.6% B n/a |
With sulfur with melted Ag2F2 at 140-400°C; gaseous S2F2 formed; | A 65-67 B n/a |
With sulfur with melted Ag2F2; geseous S2F2 formed; | |
With S with melted Ag2F2; geseous S2F2 formed; |
Conditions | Yield |
---|---|
With chlorine with dry Cl2; refluxing over Sb; distn.; | |
With hydrogenchloride; dihydrogen peroxide In not given powdered Sb reacts with HCl soln. containing H2O2; | |
With Cl2 with dry Cl2; refluxing over Sb; distn.; | |
In not given |
Conditions | Yield |
---|---|
With chlorine heating; distillation; | |
With chlorine moderatly heating with dry Cl2; fire phonomenon; | |
With Cl2 heating; distillation; |
Conditions | Yield |
---|---|
With thionyl chloride byproducts: SO2, S2Cl2; SbCl3 and Sb2O3 formed in cold with excess of pwdered Sb; Sbl5 formed wth excess of SOCl2 in a sealed tube; |
antimony
selenium oxychloride
A
antimonypentachloride
B
antimony(III) chloride
C
diselenium dichloride
Conditions | Yield |
---|---|
with excess of SeOCl2; | A 0% B n/a C n/a |
antimony
dihydrogen peroxide
A
antimonypentachloride
B
antimony(III) chloride
Conditions | Yield |
---|---|
With hydrogenchloride In water | |
With HCl In water |
Conditions | Yield |
---|---|
over 100 °C; molibdenum fluoride forming as by-product; | |
over 100 °C; molibdenum fluoride forming as by-product; |
Conditions | Yield |
---|---|
With nitric acid In hydrogenchloride | A 0% B n/a C n/a |
In hydrogenchloride |
antimony(III) chloride
antimonypentachloride
Conditions | Yield |
---|---|
With chlorine In melt Reaction of SbCl3 melt with Cl2 to give SbCl5; | 93-94 |
With chlorine distillation; | |
With chlorine with molten SbCl3; distillation; |
Conditions | Yield |
---|---|
In melt Reaction of SbCl3 melt with NO2 to give SbCl5; |
Conditions | Yield |
---|---|
In neat (no solvent) stream of HCl; strong evolution of heat;; | |
In neat (no solvent) stream of HCl; strong evolution of heat;; |
Conditions | Yield |
---|---|
In neat (no solvent) Kinetics; react. at 200°C; |
Conditions | Yield |
---|---|
With aqua regia | |
With aqua regia |
Conditions | Yield |
---|---|
With chlorine In tetrachloromethane heating Sb2O3 with a soln. of Cl2 in CCl4 in a sealed tube at 100°C;; | |
With tetrachloromethane; chlorine at 100°C in sealed tube; | |
With Cl2 In tetrachloromethane heating Sb2O3 with a soln. of Cl2 in CCl4 in a sealed tube at 100°C;; | |
With Cl2; CCl4 at 100°C in sealed tube; |
Conditions | Yield |
---|---|
With thionyl chloride byproducts: SO2; with large excess of SOCl2; | |
With SOCl2 byproducts: SO2; with large excess of SOCl2; |
B
antimonypentachloride
C
antimony(III) chloride
Conditions | Yield |
---|---|
With chlorine by heating; | |
With Cl2 by heating; |
antimonypentachloride
Conditions | Yield |
---|---|
With chlorine | 0% |
With Cl2 | 0% |
Conditions | Yield |
---|---|
With chlorine dry Cl2; remowing SbCl5 over H2SO4; | |
With Cl2 dry Cl2; remowing SbCl5 over H2SO4; |
Conditions | Yield |
---|---|
at 420°C; |
Conditions | Yield |
---|---|
In neat (no solvent) |
rhenium(V) chloride
antimony(III) chloride
A
rhenium tetrachloride
B
antimonypentachloride
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: Re3Cl9; distiln. (vac.), sublimation; |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: SbCl5; passing dry HCl-stream over Sb2(SO4)3 with spontaneous heat evolution (up to melting temp.); cooling;; SbCl5 sublimes;; | |
In neat (no solvent) byproducts: SbCl5; passing dry HCl-stream over Sb2(SO4)3 with spontaneous heat evolution (up to melting temp.); cooling;; SbCl5 sublimes;; |
Conditions | Yield |
---|---|
without moisture of air; heating to 100 °C then in vac. (1-3 mmHg) at 180-200 °C (6h); max. purity 90%; | |
without moisture of air; heating to 100 °C then in vac. (1-3 mmHg) at 180-200 °C (6h); max. purity 90%; |
SbCl5*H2O
A
antimonypentachloride
B
antimony(III) chloride
Conditions | Yield |
---|---|
heating at 20 Torr; |
Conditions | Yield |
---|---|
byproducts: Cl2; with heating; SbCl3 and SbCl5 evaporate; |
18-crown-6 ether
antimonypentachloride
Conditions | Yield |
---|---|
In acetonitrile PbCl2 is dissolved by injection of SbCl5 in MeCN, addn. of 18-crown-6; concn. the volume under vac., standing for some time at 20°C, filtn., elem. anal.; | 100% |
Conditions | Yield |
---|---|
Stage #1: sulfuryl dichloride; tris[2-(2-pyridyl)phenyl]stibine In acetonitrile at -40℃; for 2h; Inert atmosphere; Stage #2: antimonypentachloride In dichloromethane at -40℃; for 2h; Inert atmosphere; | 100% |
hydrogenchloride
antimonypentachloride
water
H2O*H(1+)*SbCl6(1-)=H2O*HSbCl6
Conditions | Yield |
---|---|
In dichloromethane (He atm.) the calculated volumes of CH2Cl2-solns. of SbCl5, H2O and HCl were mixed; | 99% |
Conditions | Yield |
---|---|
In dichloromethane (He atm.) the calculated volumes of CH2Cl2-solns. of SbCl5, H2O and HCl were mixed; | 99% |
Conditions | Yield |
---|---|
In dichloromethane under N2, SbCl5 was added to equiv. amt. of BrCN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.; | 99% |
Conditions | Yield |
---|---|
In dichloromethane under N2, SbCl5 was added to equiv. amt. of ICN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.; | 99% |
Conditions | Yield |
---|---|
In dichloromethane under N2, SbCl5 was added to equiv. amt. of H2NCN in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.; | 99% |
methylsulphinyl chloride
antimonypentachloride
methyl(chloro)sulfinylantimony pentachloride
Conditions | Yield |
---|---|
In dichloromethane addn. of SbCl5 in CH2Cl2 at 243 K with stirring to CH3SOCl in CH2Cl2 within 1.5 h, further stirring (1 h); concn. (dynamic vac.), filtration at 233 K, drying (dynamic vac., 273 K); | 99% |
Conditions | Yield |
---|---|
In dichloromethane under N2, SbCl5 was added to equiv. amt. of pyridine in CH2Cl2 at room temp.; solvent was removed in dynamic vac., elem. anal.; | 99% |
antimonypentachloride
6-Methyl-7-oxo-8-phenyl-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo<3.3.1>nona-2,3,5(9)-trien-chlorid
6-Methyl-7-oxo-8-phenyl-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo[3.3.1]nona-2,3,5(9)-trien-chlorid
Conditions | Yield |
---|---|
In tetrachloromethane ppt. was recrystd. from CH3CN/CCl4 (1:15); elem. anal.; | 99% |
N,N-dimethylbenzylamine N-oxide
antimonypentachloride
N,N-dimethylbenzylamine oxide-SbCl5
Conditions | Yield |
---|---|
In tetrachloromethane soln. of PhCH2Me2NO in CCl4 added to soln. of SbCl5 in CCl4; filtered, washed with CCl4 and petroleum ether; elem. anal.; | 99% |
Conditions | Yield |
---|---|
In tetrachloromethane DMSO and SbCl5 (mole ratio 1:1) were mixed in CCl4 with cooling; the mixt was allowed to stand overnight;; the ppt. was collected by filtration, washed with CCl4, then with petroleum ether; elem. anal.;; | 98.7% |
Conditions | Yield |
---|---|
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.; | 98% |
antimonypentachloride
N-isopropyl-4-amino-3-penten-2-one
Conditions | Yield |
---|---|
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.; | 98% |
antimonypentachloride
6,8-Dimethyl-7-oxo-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo<3.3.1>nona-2,3,5(9)-trien-chlorid
6,8-Dimethyl-7-oxo-1λ3-thionia-3λ4,5λ4-dithia-2,4,6,8,9-pentaazabicyclo[3.3.1]nona-2,3,5(9)-trien-hexachloroantimonat
Conditions | Yield |
---|---|
In tetrachloromethane ppt. was recrystd. from CH3CN/CCl4 (1:15); elem. anal.; | 98% |
18-crown-6 ether
antimonypentachloride
Conditions | Yield |
---|---|
In acetonitrile PbCl2 is dissolved by injection of SbCl5 in MeCN, addn. of 15-crown-5; concn. the volume under vac., filtn., cooling the filtrate, filtn., washing with MeCN, vac. drying, elem. anal.; | 97% |
Conditions | Yield |
---|---|
In chloroform dropwise addn. of SbCl3 soln. to ketoamine soln. with stirring and exclusion of moisture; stirring, 8h; decanting; washing (chloroform); drying (30°C/0.1 mm, 5h); elem. anal.; | 97% |
Isopropylmethylcyanamide
antimonypentachloride
antimony pentachloride-isopropylmethylcyanamide
Conditions | Yield |
---|---|
In dichloromethane addn. dropwise, stirring -78°C for 1 h, then 22°C for 2h,; evapn. in vac., pptn.with pentane, washed with pentane, recrystn. from CH2Cl2, elem.anal.; | 97% |
N-methyl-N-cyclohexyl cyanamide
antimonypentachloride
antimony pentachloride-cyclohexylmethylcyanamide
Conditions | Yield |
---|---|
In dichloromethane addn. dropwise, stirring -78°C for 1 h, then 22°C for 2h,; evapn., in vac., pptn. with pentane, washed with pentane, recrystn. from CH2Cl2, elem.anal.; | 97% |
Conditions | Yield |
---|---|
In dichloromethane soln. of SbCl5 in CH2Cl2 added to soln. of Se-compound in CH2Cl2 at -40°C with stirring under Ar, stirred for 15 min at -40°C, CH2Cl2 soln. of styrene added dropwise, stirred for 30 min, warmed to room temp.; solvent evapd. in vacuo, recrystd. from CH2Cl2; elem. anal.; | 97% |
dichloromethane
antimonypentachloride
chlorine
1,2-dichloro-ethane
1,2-bis-(diphenylphosphino)ethane
Conditions | Yield |
---|---|
Stage #1: chlorine; 1,2-dichloro-ethane; 1,2-bis-(diphenylphosphino)ethane In 1,2-dichloro-ethane at -30℃; for 0.0833333h; Stage #2: dichloromethane; antimonypentachloride In dichloromethane; 1,2-dichloro-ethane at -30 - 23℃; for 1h; | 97% |
Conditions | Yield |
---|---|
Stage #1: 1,2-bis(methylthio)ethane With chlorine In 1,2-dichloro-ethane at -30℃; for 0.0833333h; Inert atmosphere; Stage #2: antimonypentachloride In dichloromethane at 23℃; for 1h; Inert atmosphere; | 97% |
Conditions | Yield |
---|---|
In chloroform byproducts: KCl; A soln. of potassium metal in isopropanol is added to an ice cold soln. of SbCl5, refluxed for 4 h under dry N2, cooling.; KCl is filtered off, elem. anal.; | 96% |
antimonypentachloride
nitrosylchloride
nitrosonium hexachloroantimonate
Conditions | Yield |
---|---|
In dichloromethane 0 - 10 °C, under N2; the product was filtered under N2, washed with CH2Cl2, dried in vac. at25 °C, elem. anal.; | 96% |
Conditions | Yield |
---|---|
In dichloromethane addn. of ligand soln. to soln. of SbCl5, pptn., stirred for 1h; ppt. filtered, washed with CH2Cl2, recrystd. from CHCl3/hexane, dried in vac. at 50°C; elem. anal.; | 96% |
Conditions | Yield |
---|---|
In chloroform stirring for 30 min; filtration of ppt., washing with CHCl3, drying, elem. anal.; | 96% |
Conditions | Yield |
---|---|
Stage #1: 1,2-bis(ethylthio)ethane With chlorine In 1,2-dichloro-ethane at -30℃; for 0.0833333h; Inert atmosphere; Stage #2: antimonypentachloride In dichloromethane at 23℃; for 1h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
With HCl In water High Pressure; SbCl5 dissolved in HCl at ambient temp.; H2O added; temp. increased to 50°C; mixed with stoich. amt. of thioacetamide; soln. transferred into stainless-steel autoclave; sealed autoclave maintained at 180°C for 3 h; cooled to room temp.; filtered; washed (soln. of tartaric acid, H2O); dried (vac.) at 60°C for 5 h; | 95% |
antimonypentachloride
{ClSeNSeCl}(1+)*SbCl6(1-)={ClSeNSeCl}SbCl6
Conditions | Yield |
---|---|
In sulfur dioxide N2-atmosphere; addn. of 1 equiv. SbCl5 to Se2NCl3 soln., stirring (room temp., 2 h); solvent removal (reduced pressure); | 95% |
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