CAS No.507-19-7,2-Bromo-2-methylpropane Suppliers,MSDS download

Dayang Chem (Hangzhou) Co.,Ltd.

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Trimethyl Bromoethane with high purity

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

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Henan Tianfu Chemical Co., Ltd.

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Henan Sinotech Import&Export Corporation

CAS 507-19-7 Name 2-Bromo-2-methylpropane Appearance Colorless Liquid Application Pharmaceutical Intermediates Appearance:Colorless transparent liqui

2-Bromo-2-methylpropane CAS: 507-19-7

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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:As

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Tert-Butyl bromide

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

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Hangzhou Lingrui Chemical Co.,Ltd.

Cyclopentyl bromide suppliersAppearance:Colorless liquid Storage:Keep in dry,cool and ventilated place Package:according to customers' requirements Application:Lab research Pharmaceutical Intermediates Transportation:By air(EMS or EUB or FedEx or TN

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Henan Wentao Chemical Product Co., Ltd.

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2-Bromo-2-methylpropaneCAS NO.: 507-19-7

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystalline powder Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used in organic synthes

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Wuhan Fortuna Chemical Co.,Ltd

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

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JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Tert-Butyl Bromide

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Trimethyl Bromoethane

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Enke Pharma-tech Co.,Ltd. （Cangzhou, China ）

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 507-19-7 with competitive price

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

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Hangzhou Ocean Chemical Co., Ltd.

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Changchun Artel lmport and Export trade company

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Hunan Russell Chemicals Technology Co.,Ltd

low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China

tert-Butyl bromide, 98%, stabilized 507-19-7

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Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

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Beantown Chemical

in stock Application:507-19-7

tert-Butyl bromide, 98%, stabilized

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Qingdao little fox Biological &Technology Co.,Ltd

Cyclopentyl bromide suppliersAppearance:Colorless liquid Storage:Keep in dry,cool and ventilated place Package:Aluminum foil bag or as your request Application:Lab research Pharmaceutical Intermediates Transportation:EMS, DHL, UPS, TNT, Fedex or cli

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HWRK Chem

in storeAppearance:Colorless - micro light yellow transparent liquid Package:1kg Application:Organic Chemicals

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Amadis Chemical Co., Ltd.

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HENAN SUNLAKE ENTERPRISE CORPORATION

Preview CBNumber: CB8463157 Chemical Name: 2-Bromo-2-methylpropane Molecular Formula:

2-Bromo-2-methylpropane

Cas:507-19-7

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Synthetic route

: 507-20-0
tertiary butyl chloride

: 507-19-7
t-butyl bromide

Conditions

Conditions	Yield
With hydrogen bromide; ferric(III) bromide In dichloromethane at 25℃; for 0.2h;	98%
With boron tribromide for 2h;	80%
With pyridine; tributyltin bromide at 100℃; Thermodynamic data; Equilibrium constant; Δ G;
With aluminum tri-bromide In various solvent(s) at -30℃;
With aluminium trichloride; hydrogen bromide

: 558-17-8
tert-Butyl iodide

: 507-19-7
t-butyl bromide

Conditions

Conditions	Yield
With bismuth(III) bromide In dichloromethane at 25℃; for 1.75h;	98%

: 78-86-4, 53178-20-4
s-butyl chloride

A: 507-19-7
t-butyl bromide

B: 78-76-2, 5787-31-5
s-butyl bromide

Conditions

Conditions	Yield
With hydrogen bromide; ferric(III) bromide In dichloromethane at 25℃; for 15h;	A 3% B 97%

: 75-65-0
tert-butyl alcohol

: 507-19-7
t-butyl bromide

Conditions

Conditions	Yield
With Silphos; bromine In acetonitrile for 0.583333h; Heating;	90%
With hydrogen bromide; lithium bromide at 0℃; for 2h;	87%
With allyltriphenoxyphosphonium bromide at 20℃;	62%

: 75-28-5
Isobutane

: 507-19-7
t-butyl bromide

Conditions

Conditions	Yield
With antimony pentafluoride; 1,2-dibromomethane 1.) -78 deg C, 2 h, 2.) RT, 24 h;	75%
With bromine
With bromine
With bromine

: 67-56-1
methanol

: 5-t-Butylperoxycyclo-octene

A: 507-19-7
t-butyl bromide

: 32654-19-6, 89071-84-1, 92617-21-5
trans-2-bromo-9-oxabicyclo<4.2.1>nonane

: 32654-27-6, 89071-85-2, 92617-22-6
trans-2-bromo-9-oxabicyclo<3.3.1>nonane

D: 77-76-9
2,2-dimethoxy-propane

Conditions

Conditions	Yield
With N-Bromosuccinimide for 0.75h; Product distribution; Mechanism; further in CD3OD;	A 1.5% B n/a C n/a D 74%

...Expand

: 1634-04-4
tert-butyl methyl ether

: 201230-82-2
carbon monoxide

: 100-39-0
benzyl bromide

A: 74-83-9
methyl bromide

B: 507-19-7
t-butyl bromide

C: 101-41-7
benzeneacetic acid methyl ester

Conditions

Conditions	Yield
1,5-hexadienerhodium(I)-chloride dimer; potassium iodide at 75 - 90℃; under 735.5 Torr; overnight or in n-heptane;	A n/a B n/a C 68%

...Expand

: 617-86-7
triethylsilane

: 5193-96-4
methyl methoxybromoacetate

A: 72719-00-7
dimethyl 2,3-dimethoxybutanedioate

B: 507-19-7
t-butyl bromide

C: 1112-48-7
triethyl-bromo-silane

D: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With di-tert-butyl peroxide In chlorobenzene at 30℃; for 0.1h; Product distribution; Irradiation;	A 7% B 6% C 40% D 19.5%

...Expand

: 109-69-3
n-Butyl chloride

A: 109-65-9
1-bromo-butane

B: 507-19-7
t-butyl bromide

C: 78-76-2, 5787-31-5
s-butyl bromide

Conditions

Conditions	Yield
With hydrogen bromide; ferric(III) bromide In dichloromethane at 25℃; for 15h;	A 5% B 3% C 13%

...Expand

: 78-77-3
Isobutyl bromide

: 507-19-7
t-butyl bromide

Conditions

Conditions	Yield
With pumice stone; thorium tetrachloride
With pumice stone; barium(II) chloride
at 210 - 220℃; im Rohr;

: 78-77-3
Isobutyl bromide

A: 507-19-7
t-butyl bromide

B: 78-76-2, 5787-31-5
s-butyl bromide

Conditions

Conditions	Yield
at 210℃;

: 594-34-3
1,2-dibromo-2-methyl-propane

A: 1458-98-6
2-methyl-3-bromo-1-propene

B: 507-19-7
t-butyl bromide

Conditions

Conditions	Yield
With copper at 390 - 400℃;

: 110-05-4
di-tert-butyl peroxide

A: 507-19-7
t-butyl bromide

B: 594-34-3
1,2-dibromo-2-methyl-propane

Conditions

Conditions	Yield
With hydrogen bromide at 0℃;

: 64-19-7
acetic acid

: 115-11-7
isobutene

A: 507-19-7
t-butyl bromide

B: 78-77-3
Isobutyl bromide

Conditions

Conditions	Yield
With hydrogen bromide

...Expand

: 513-36-0
isobutyryl chloride

: 507-19-7
t-butyl bromide

Conditions

Conditions	Yield
With aluminium trichloride; hydrogen bromide

: 513-36-0
isobutyryl chloride

A: 507-19-7
t-butyl bromide

B: 78-77-3
Isobutyl bromide

Conditions

Conditions	Yield
With aluminium trichloride; hydrogen bromide

: 2465-56-7
methylene

: 75-26-3
isopropyl bromide

A: 507-19-7
t-butyl bromide

B: 78-77-3
Isobutyl bromide

C: 78-76-2, 5787-31-5
s-butyl bromide

...Expand

: 115-11-7
isobutene

: 507-19-7
t-butyl bromide

Conditions

Conditions	Yield
With peroxidene; hydrogen bromide
With hydrogen bromide
With hydrogen bromide
With bromine
With peroxidene; hydrogen bromide

: 115-11-7
isobutene

A: 507-19-7
t-butyl bromide

B: 78-77-3
Isobutyl bromide

Conditions

Conditions	Yield
With hydrogen bromide; acetic acid

: 115-17-3
bromal

: 13121-31-8
2-tert-butoxy-4,5-benzo-1,3,2-dioxaphospholane

A: 507-19-7
t-butyl bromide

B: 3039-13-2
dibromoacetaldehyde

C: 3492-46-4
2-bromo-2-oxo-4,5-benzo-1,3,2-dioxaphospholane

D: 125910-85-2
2-(2',2'-dibromovinyloxy)-2-oxo-4,5-benzo-1,3,2-dioxaphospholane

E: 125910-86-3
2,3-dibenzo-1,4-dioxa-5-oxo-6-hydroxy-7,7,7-tribromo-5-phospha<4>heptane

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 24h; Product distribution; Mechanism;

...Expand

: 115-17-3
bromal

: 13121-31-8
2-tert-butoxy-4,5-benzo-1,3,2-dioxaphospholane

A: 507-19-7
t-butyl bromide

B: 3492-46-4
2-bromo-2-oxo-4,5-benzo-1,3,2-dioxaphospholane

C: 125910-85-2
2-(2',2'-dibromovinyloxy)-2-oxo-4,5-benzo-1,3,2-dioxaphospholane

D: 125910-86-3
2,3-dibenzo-1,4-dioxa-5-oxo-6-hydroxy-7,7,7-tribromo-5-phospha<4>heptane

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 24h; Further byproducts given;

...Expand

: 128-08-5
N-Bromosuccinimide

: 2406-25-9, 44871-19-4
di-tert-butyl nitroxide

A: 123-56-8
Succinimide

B: 507-19-7
t-butyl bromide

C: 917-95-3
t-butylnitrite

D: 115-11-7
isobutene

Conditions

Conditions	Yield
Mechanism;

...Expand

: 1605-73-8
t-Butyl radical

: 507-19-7
t-butyl bromide

Conditions

Conditions	Yield
With bromine at 26.9℃; Kinetics; other temperatures;

: 506-96-7
Acetyl bromide

: 507-20-0
tertiary butyl chloride

A: 507-19-7
t-butyl bromide

B: 75-36-5
acetyl chloride

Conditions

Conditions	Yield
With iron(III) chloride at 25℃; for 192h; Equilibrium constant; Thermodynamic data; ΔG;
With aluminium trichloride In nitromethane-d3 at 25℃; for 48h; Equilibrium constant; Thermodynamic data; ΔG;

...Expand

: 540-88-5
acetic acid tert-butyl ester

: 507-19-7
t-butyl bromide

Conditions

Conditions	Yield
With trimethylsilyl bromide; iodine(I) bromide for 0.1h; Ambient temperature;	100 % Spectr.

: 75-28-5
Isobutane

A: 507-19-7
t-butyl bromide

B: 78-77-3
Isobutyl bromide

Conditions

Conditions	Yield
With norborn-2-ene; N-bromobis(trimethylsilyl)amine at 44.9℃; for 2h; Product distribution; Mechanism; Irradiation; variation of temperature, time, reagent concentration, initiation method;
With N-Bromosuccinimide In dichloromethane at 15℃; Product distribution; Irradiation; CH2CCl2; influence of additive - BrCCl3;
With N-Bromosuccinimide; 1,1-Dichloroethylene In dichloromethane at 14 - 15℃;	A 0.133 mmol B 0.084 mmol

: 75-28-5
Isobutane

A: 507-20-0
tertiary butyl chloride

B: 507-19-7
t-butyl bromide

C: 78-77-3
Isobutyl bromide

D: 513-36-0
isobutyryl chloride

E: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With IVTPP(OIPh)>2O; BrMnIIITPP In chlorobenzene at 25℃; Product distribution; Mechanism;	A 6 % Chromat. B 18 % Chromat. C 2 % Chromat. D 2 % Chromat. E 11 % Chromat.

...Expand

: 75-28-5
Isobutane

A: 507-20-0
tertiary butyl chloride

B: 507-19-7
t-butyl bromide

C: 78-77-3
Isobutyl bromide

D: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With (5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride; IVTPP(OIPh)>2O In chlorobenzene at 25℃; Product distribution; Mechanism;	A 7 % Chromat. B 11 % Chromat. C 2 % Chromat. D 10 % Chromat.

...Expand

: 75-28-5
Isobutane

A: 507-19-7
t-butyl bromide

B: 78-77-3
Isobutyl bromide

C: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With IVTPP(OIPh)>2O In chlorobenzene at 25℃; for 1h; Product distribution; Mechanism; further reagents (BrMnIIITPP);	A 13 % Chromat. B 2 % Chromat. C 11 % Chromat.

...Expand

: Di-tert-butyloxoammonium bromide

A: 507-19-7
t-butyl bromide

B: 917-95-3
t-butylnitrite

Conditions

Conditions	Yield
With N-Bromosuccinimide

: 491-35-0
C6H4NCH2CHCCH2

: 507-19-7
t-butyl bromide

: 97691-25-3
2-tert-butyl-4-methylquinoline

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane; trifluoroacetic acid In benzene for 0.25h; Heating;	100%
With tris-(trimethylsilyl)silane; [Ir[2-(2,4-difluorophenyl)-5-trifluoromethylpyridine]2(4,4′-di-t-Bu-2,2′-bipyridine)]PF6; oxygen; trifluoroacetic acid In acetone at 20℃; for 24h; Minisci Aromatic Substitution; Irradiation; regioselective reaction;	81%

: 2-([{4-but-2-ynyloxy-benzene}sulfonyl]amino)-3-methyl-3-[(methyl)sufanyl]-butyric acid

: 507-19-7
t-butyl bromide

: 287407-28-7
2-([{4-but-2-ynyloxy-benzene}sulfonyl]amino)-3-methyl-3-[(methyl)sulfanyl]-butyric acid tert-butyl ester

Conditions

Conditions	Yield
Stage #1: 2-([{4-but-2-ynyloxy-benzene}sulfonyl]amino)-3-methyl-3-[(methyl)sufanyl]-butyric acid; t-butyl bromide With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In ISOPROPYLAMIDE at 50℃; Stage #2: Stage #3: With hydrogenchloride In water pH=3;	100%

: aluminum tri-bromide

: 507-19-7
t-butyl bromide

: 72427-54-4
C4H9(1+)*Al2Br7(1-)

Conditions

Conditions	Yield
With hydrogen bromide In neat (no solvent) at 0 - 20℃; Inert atmosphere; Glovebox;	100%

: 507-19-7
t-butyl bromide

: 13716-12-6
tri-tert-butyl phosphine

: 4,8,12-trioxatriangulenium tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate

A: C19H9BrO3

B: 115-11-7
isobutene

C: C32H12BF24(1-)*C12H27P*H(1+)

Conditions

Conditions	Yield
In acetonitrile at 20℃;	A 100% B n/a C 100%

...Expand

: 507-19-7
t-butyl bromide

: 177750-24-2
N-(1-(naphthalen-2-yl)vinyl)acetamide

: C18H21NO

Conditions

Conditions	Yield
With palladium(II) trifluoroacetate; potassium acetate; triphenylphosphine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane; water at 20℃; for 24h; Irradiation; Inert atmosphere; stereoselective reaction;	99%

: 188290-36-0
thiophene

: 507-19-7
t-butyl bromide

: 1689-77-6
2,5-di-tert-butylthiophene

Conditions

Conditions	Yield
With sodium carbonate; silica gel In tetrachloromethane at 78℃; for 40h;	98%

: 507-19-7
t-butyl bromide

: 95-47-6
o-xylene

: 7397-06-0
4-t-butyl-o-xylene

Conditions

Conditions	Yield
With pyrographite for 24h; Heating;	98%

: 507-19-7
t-butyl bromide

: 13504-85-3
(2S,4R)-1-(benzyloxycarbonyl)-4-hydroxypyrrolidine-2-carboxylic acid

: 4-Hydroxy-pyrrolidine-1,2-dicarboxylic Acid 1-Benzyl Ester 2-tert-Butyl Ester

Conditions

Conditions	Yield
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In 2,4-dichlorophenoxyacetic acid dimethylamine	98%

: 478183-66-3
Boc-3-iodo-D-phenylalanine

: 507-19-7
t-butyl bromide

: Boc-D-Phe(3-I)-O-tBu

Conditions

Conditions	Yield
With tetrabutylammomium bromide; potassium carbonate In N,N-dimethyl acetamide at 0 - 55℃; for 2.5h;	98%

: 507-19-7
t-butyl bromide

: 106871-53-8
2-(p-tolylthio)-2-oxoacetic acid

: S-(p-tolyl) 3-methylbutanethioate

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In N,N-dimethyl acetamide at 80℃; for 8h; Inert atmosphere; Schlenk technique;	98%

: 507-19-7
t-butyl bromide

: 4-fluoro-N-(1-phenylvinyl)benzamide

: C19H20FNO

Conditions

Conditions	Yield
With palladium(II) trifluoroacetate; potassium acetate; triphenylphosphine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane; water at 20℃; for 24h; Irradiation; Inert atmosphere; stereoselective reaction;	98%

: 507-19-7
t-butyl bromide

: N-(1-(4-(methylthio)phenyl)vinyl)acetamide

: C15H23NOS

Conditions

Conditions	Yield
Stage #1: t-butyl bromide; N-(1-(4-(methylthio)phenyl)vinyl)acetamide With palladium(II) trifluoroacetate; potassium acetate; triphenylphosphine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane; water at 20℃; for 24h; Irradiation; Inert atmosphere; Stage #2: With sodium tetrahydroborate; acetic acid at 20℃; for 3h; stereoselective reaction;	98%

Yield

Stage #1: t-butyl bromide; N-(1-(4-(methylthio)phenyl)vinyl)acetamide With palladium(II) trifluoroacetate; potassium acetate; triphenylphosphine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane; water at 20℃; for 24h; Irradiation; Inert atmosphere;
Stage #2: With sodium tetrahydroborate; acetic acid at 20℃; for 3h; stereoselective reaction;

98%

: 507-19-7
t-butyl bromide

: 100-66-3
methoxybenzene

: 5396-38-3
1-(tert-butyl)-4-methoxybenzene

Conditions

Conditions	Yield
With o-tetrachloroquinone; C16H21IMoO3 In 1,2-dichloro-ethane at 80℃; for 8h; Friedel-Crafts Alkylation; Inert atmosphere; Schlenk technique; Green chemistry; regioselective reaction;	97.9%
With aluminium trichloride In nitromethane at 25℃; for 0.0166667h; Product distribution;	100 % Chromat.

: 507-19-7
t-butyl bromide

: 1149-26-4
(S)-N-(benzyloxycarbonyl)valine

: 16874-02-5
benzyl (S)-1-(tert-butoxycarbonyl)-2-methylpropylcarbamate

Conditions

Conditions	Yield
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In N,N-dimethyl acetamide at 55℃; for 24h;	97%

: 507-19-7
t-butyl bromide

: 19728-63-3
N-benzyloxycarbonyl-L-treonine

: 72289-51-1
tert-butyl (2S,3R)-2-(benzyloxycarbonyl)amino-3-hydroxybutanoate

Conditions

Conditions	Yield
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In N,N-dimethyl acetamide at 55℃; for 24h;	97%
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In N,N-dimethyl acetamide at 55℃; for 24h;	51%

: 1008-89-5
2-phenylpyridine

: 507-19-7
t-butyl bromide

: 2-(3′-tert-butylphenyl)pyridine

Conditions

Conditions	Yield
With diphenyl hydrogen phosphate; (rac)-chloro(η6-p-cumene)(2-phenylpyridine-κC,N)ruthenium(II); potassium carbonate In 1,4-dioxane at 25 - 30℃; for 24h; Catalytic behavior; Mechanism; Reagent/catalyst; Solvent; Time; Inert atmosphere; Sealed tube; Irradiation;	97%
With C17H24N5Ru(1+)*F6P(1-); potassium trifluoroacetate; potassium carbonate In 1,4-dioxane at 35℃; for 48h; Reagent/catalyst; Solvent; Time; Schlenk technique; Inert atmosphere; Sealed tube;	80%
With potassium phosphate; {bis(triphenylphosphine)ruthenium diacetate} In 1,4-dioxane at 100℃; for 18h; Inert atmosphere; Schlenk technique; chemoselective reaction;	74%
With [RuCl(Piv-Val-O)(p-cymene)]; potassium carbonate In 1,4-dioxane at 100℃; for 20h; Reagent/catalyst; Inert atmosphere; Schlenk technique; regioselective reaction;	66%
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; potassium acetate In 1,4-dioxane at 120℃; for 15h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Time; Inert atmosphere; regioselective reaction;	7%

: 507-19-7
t-butyl bromide

: 1373120-02-5
N-(1-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)vinyl)acetamide

: C16H21NO3

Conditions

Conditions	Yield
With palladium(II) trifluoroacetate; potassium acetate; triphenylphosphine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane; water at 20℃; for 24h; Irradiation; Inert atmosphere; stereoselective reaction;	97%

: 507-19-7
t-butyl bromide

: 61608-80-8
1,3-diphenylallyllithium

: 82537-22-2, 82537-24-4, 107847-46-1
C19H22

Conditions

Conditions	Yield
With N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran; hexane at 20℃; for 1h;	96%

: 507-19-7
t-butyl bromide

: 100-51-6
benzyl alcohol

: 3459-80-1
t-butoxymethylbenzene

Conditions

Conditions	Yield
With 2PbCO3Pb(OH)2 at 40℃; for 1.8h;	96%
With 2PbCO3*Pb(OH)2 at 110℃; for 0.0333333h; microwave irradiation;	96%
With pyridine; zinc(II) oxide In benzene for 30h; Heating;	72%
With potassium hydroxide; tetrafluoroboric acid; mercury(II) oxide In dichloromethane 1.) room temp., 1 h;	68%
With silver(l) oxide In water; acetonitrile at 60℃; for 4h;	61%

: 507-19-7
t-butyl bromide

: 75-66-1
2-methylpropan-2-thiol

Conditions

Conditions	Yield
With hydrosulfide exchange resin In acetonitrile at 25℃; for 0.25h;	96%
Stage #1: t-butyl bromide With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere; Stage #2: With sulfur In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Inert atmosphere;

: (pentadeuteriocyclopentadienyl)bis(trimethylphosphane)cobalt(I)

: 507-19-7
t-butyl bromide

: (tert-butyltetradeuteriocyclopentadienyl)deuteriobis(trimethylphosphane)cobalt(III) bromide

Conditions

Conditions	Yield
In diethyl ether at -78°C, pptd. in 5 min after removal of cooling bath; washed with ether/pentane several times, dried in high vac.;	96%

: 507-19-7
t-butyl bromide

: 119-36-8
methyl salicylate

: 52888-72-9
5-(tert-butyl)-2-hydroxybenzoic acid methyl ester

Conditions

Conditions	Yield
Stage #1: methyl salicylate With PPA at 20℃; for 1h; Stage #2: t-butyl bromide at 90℃; for 7h; Heating / reflux;	96%

: 507-19-7
t-butyl bromide

: 57957-24-1
N-(1-phenylvinyl)acetamide

: C14H19NO

Conditions

Conditions	Yield
With palladium(II) trifluoroacetate; potassium acetate; triphenylphosphine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane; water at 20℃; for 24h; Irradiation; Inert atmosphere; stereoselective reaction;	96%

: 507-19-7
t-butyl bromide

: 13686-33-4
t-butyl azide

Conditions

Conditions	Yield
With sodium azide In water; N,N-dimethyl-formamide at 20℃; Large scale; Green chemistry;	95.5%
With sodium azide; hemin copolymer 1 1.) water, 12 h, 2.) benzene, 10 h, 60 deg C; Yield given. Multistep reaction;
With sodium azide In tetrahydrofuran; water for 1.5h; Reflux;

: 507-19-7
t-butyl bromide

: 108-88-3
toluene

: 98-51-1
4-tert-butyltoluene

Conditions

Conditions	Yield
With [(η5-C5H4)2(C(CH2)5)][Re(CO)3]2 In 1,2-dichloro-ethane at 80℃; for 24h; Catalytic behavior; Reagent/catalyst; Temperature; Friedel-Crafts Alkylation; Inert atmosphere; Schlenk technique; regioselective reaction;	95.3%
With silica-supported aluminum chloride In dichloromethane at 140℃; for 0.0833333h; Friedel-Crafts Alkylation; Microwave irradiation;	88%
With o-tetrachloroquinone; C16H21IMoO3 In 1,2-dichloro-ethane at 80℃; for 12h; Friedel-Crafts Alkylation; Inert atmosphere; Schlenk technique; Green chemistry; regioselective reaction;	69.7%
With phosphoric acid at 80℃;
With metal-organic framework catalyst at 80℃; for 6h; Friedel Crafts alkylation;

: 507-19-7
t-butyl bromide

: 621-82-9
Cinnamic acid

: 14990-09-1
tert-butyl cinnamate

Conditions

Conditions	Yield
With pyridine; zinc(II) oxide In benzene for 10h; Heating;	95%

: 507-19-7
t-butyl bromide

: 623-70-1
ethyl (E)-crotonate

: 106325-27-3
3,4,4-Trimethyl-pentanoic acid ethyl ester

Conditions

Conditions	Yield
With zinc copper In ethanol for 1h; Irradiation;	95%

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