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Shandong Xingshun New Material Co., Ltd.

Xingshun's expertise and flexibility have made the company become one of the leading manufacturer of Naphthalene series, Biphenylseries , Phenanthrene series, Anthracene series, which are wildly used in the field of electronic chemical and polyam

Supply Methyl 6-bromo-2-naphthoate 99% factory/suppliers

Cas:33626-98-1

Min.Order:1 Kilogram

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Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Methyl 6-bromo-2-naphthoate Manufacturer/High quality/Best price/In stock

Cas:33626-98-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Methyl 6-Bromo-2-Naphthoate supplier in China

Cas:33626-98-1

Min.Order:0 Metric Ton

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Kono Chem Co.,Ltd

Specifications: 33626-98-1 Methyl 6-bromo-2-naphthoate High purity Fast deliver:Professional partner Product Name Methyl 6-bromo-2-naphthoate CAS No. 33626-98-1 EINECS

CAS:33626-98-1 Methyl 6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:1 Kilogram

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Type:Other

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages for Methyl 6-bromo-2-naphthoate Cas 33626-98-1 Guaranteed the purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:White Powder Package:1kg/foil bag, 25kg/drum or as y

Manufacture high quality Methyl 6-bromo-2-naphthoate Cas 33626-98-1 with factory low price

Cas:33626-98-1

Min.Order:1 Kilogram

FOB Price: $130.0

Type:Trading Company

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 33626-98-1 Methyl 6-bromo-2-naphthoate Manufacturer

Cas:33626-98-1

Min.Order:1 Gram

FOB Price: $0.1

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Chemwill Asia Co., Ltd.

Methyl 6-bromo-2-naphthoate CAS 33626-98-1 6-Bromo-2-Naphtoic Acid Methyl Ester CAS no 33626-98-1 Methyl 6-bromo-2-naphthoate Manufacturer High quality Best price In stock factory CAS 33626-98-1 Methyl 6-bromo-2-naphthoate COA TDS price MSDS

Methyl 6-bromo-2-naphthoate CAS 33626-98-1 6-Bromo-2-Naphtoic Acid Methyl Ester CAS no 33626-98-1

Cas:33626-98-1

Min.Order:5 Kiloliter

FOB Price: $3.5 / 5.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name Methyl 6-bromo-2-naphthoate CAS No. 33626-98-1

Methyl 6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:1 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Methyl 6-bromo-2-naphthoate with top quality

Cas:33626-98-1

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Methyl 6-bromo-2-naphthoate Basic information Product Name: Methyl 6-bromo-2-naphthoate Synonyms: 6-BROMO-2-NAPHTHALENECARBOXYLIC ACID METHYL ESTER;6-BROMO-2-NAPHTHOIC ACID METHYL ESTER;

Methyl 6-bromo-2-naphthoate CAS:33626-98-1

Cas:33626-98-1

Min.Order:1 Kilogram

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 33626-98-1 with high-quality service

Cas:33626-98-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name Methyl 6-bromo-2-naphthoate Synonyms 6-Bromo-2-naphthoic acid methyl ester methyl 6-bromonaphthalene-2-carboxylate Methyl 6-Bromo-2-naphthalenecarboxylate

Methyl 6-bromo-2-naphthoate CAS: 33626-98-1

Cas:33626-98-1

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Methyl 6-bromo-2-naphthoate 33626-98-1

Cas:33626-98-1

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pharmaceutical Intermediate, Methyl 6-bromo-2-naphthoate CAS:33626-98-1

Cas:33626-98-1

Min.Order:1 Kilogram

FOB Price: $36.9 / 42.8

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Methyl 6-bromo-2-naphthoate CAS: 33626-98-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality orga

Methyl 6-bromo-2-naphthoate CAS: 33626-98-1

Cas:33626-98-1

Min.Order:1 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Methyl 6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:1 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:33626-98-1

Cas:33626-98-1

Min.Order:0

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Wuhan Zenuo Biological Medicine Technology Co Ltd

Product Name: Methyl 6-bromo-2-naphthoate Synonyms: Adapalene Impurity G (USP RC A);6-Bromonaphthalene-2-carboxylic acid methyl ester;Methyl 6-bromo-2-naphthoate,98%;Methyl-6-Bromo-2-Naphtoat;Methyl 6-bromo-2-nap;Adapalene Related Compound A (50

Methyl 6-bromo-2-naphthoate high purity best quality

Cas:33626-98-1

Min.Order:100 Gram

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methyl 6-Bromo-2-Naphthoate

Cas:33626-98-1

Min.Order:0

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Methyl 6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:0 Metric Ton

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl 6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:0

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl 6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:0 Metric Ton

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Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Methyl 6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High purity Methyl 6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:10 Gram

FOB Price: $100.0

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Pale yellow or light brown powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:For medicine ,

Methyl 6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:1 Kilogram

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Type:Trading Company

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Siwei Development Group Ltd.

Product name: Methyl 6-Bromo-2-Naphthoate CAS No.:33626-98-1 Molecule Formula:C12H9BrO2 Molecule Weight:265.10 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise standard TES

High Quality Methyl 6-Bromo-2-Naphthoate

Cas:33626-98-1

Min.Order:1 Kilogram

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Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Methyl 6-bromo-2-naphthoate Manufacturer/High quality/Best price/In stock

Cas:33626-98-1

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Buy Top Purity Methyl 6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:0

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Type:Trading Company

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Methyl6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:1 Milligram

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Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

Product Name: Methyl 6-bromo-2-naphthoate Synonyms: 6-Bromo-2-Naphtoic Acid Methyl Ester;2-Bromo-6-naphthoic acid methylester;6-BROMO-2-NAPHTHALENECARBOXYLIC ACID METHYL ESTER;6-BROMO-2-NAPHTHOIC ACID METHYL ESTER;METHYL 6-BROMO-2-NAPHTHALENECA

Methyl 6-bromo-2-naphthoate

Cas:33626-98-1

Min.Order:1 Gram

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Synthetic route

methanol
67-56-1

methanol

6-bromo-2-naphthoic acid
5773-80-8

6-bromo-2-naphthoic acid

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

Conditions
ConditionsYield
With sulfuric acid; trimethyl orthoformate for 48h; Reflux;100%
With sulfuric acid for 36h; Reflux;100%
With sulfuric acid Reflux;100%
methanol
67-56-1

methanol

naphthalene-2-carboxylate
93-09-4

naphthalene-2-carboxylate

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

Conditions
ConditionsYield
Stage #1: methanol; naphthalene-2-carboxylate at 150℃; under 4560.31 Torr; for 1h;
Stage #2: With sodium hypobromite; benzenesulfonic acid; sodium bromide In water at 170℃; under 11400.8 Torr; for 6h; Pressure; Temperature;
98.3%
6-bromo-1-naphthoic acid
51934-38-4

6-bromo-1-naphthoic acid

methyl iodide
74-88-4

methyl iodide

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere;98%
2-[1-(4-Bromo-phenyl)-meth-(Z)-ylidene]-3,3-dimethoxy-butyric acid methyl ester
123207-11-4

2-[1-(4-Bromo-phenyl)-meth-(Z)-ylidene]-3,3-dimethoxy-butyric acid methyl ester

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

Conditions
ConditionsYield
at 475 - 500℃; vapor-phase pyrolysis; Yield given;
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

6-bromo-2-naphthalenyl trifluoromethanesulfonate
151600-02-1

6-bromo-2-naphthalenyl trifluoromethanesulfonate

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

Conditions
ConditionsYield
With 1,3-bis-(diphenylphosphino)propane; palladium diacetate
6-bromo-naphthoic acid-(2)

6-bromo-naphthoic acid-(2)

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

Conditions
ConditionsYield
With diethyl ether
6-bromo-naphthalen-2-ol
15231-91-1

6-bromo-naphthalen-2-ol

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: DIEA
2: dppp / Pd(OAc)2
View Scheme
C16H23BrO4

C16H23BrO4

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

Conditions
ConditionsYield
With sulfuric acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In methanol; water at 0 - 20℃; for 1h;
4-((2,2,2-trifluoroacetamido)methyl)phenylboronic acid
528894-31-7

4-((2,2,2-trifluoroacetamido)methyl)phenylboronic acid

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

methyl 6-[4-(N-trifluoroacetylamino)methylphenyl]-2-naphthalenecarboxylate
869748-83-4

methyl 6-[4-(N-trifluoroacetylamino)methylphenyl]-2-naphthalenecarboxylate

Conditions
ConditionsYield
With potassium fluoride; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran for 20h; Suzuki-Miyaura cross-coupling reaction; Heating;100%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

(6-bromo-2-naphthy)methanol
100751-63-1

(6-bromo-2-naphthy)methanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at -10 - -5℃; for 1.33333h;99%
With diisobutylaluminium hydride In tetrahydrofuran; hexane at 20℃; for 40h; Inert atmosphere;99%
With diisobutylaluminium hydride In tetrahydrofuran; n-heptane at -78 - 20℃; for 14h; Inert atmosphere;98%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

phenylboronic acid
98-80-6

phenylboronic acid

6-(phenyl)-2-naphthoic acid methyl ester
904688-59-1

6-(phenyl)-2-naphthoic acid methyl ester

Conditions
ConditionsYield
With potassium carbonate In water; N,N-dimethyl-formamide at 20℃; for 2h; Catalytic behavior; Suzuki Coupling; Inert atmosphere; Irradiation;99%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 80℃; for 18h; Suzuki coupling; Inert atmosphere;73%
With potassium carbonate; bis-triphenylphosphine-palladium(II) chloride In 1,2-dimethoxyethane; water at 80℃; for 3.5h;
4-Phenyl-1-butene
768-56-9

4-Phenyl-1-butene

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

(E)-methyl 6-(4-phenylbut-1-en-1-yl)-2-naphthoate

(E)-methyl 6-(4-phenylbut-1-en-1-yl)-2-naphthoate

Conditions
ConditionsYield
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 100℃; for 18h; Heck Reaction; Inert atmosphere;98%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

C22H22O2

C22H22O2

Conditions
ConditionsYield
With potassium phosphate monohydrate; C50H60F3NO6PPdS In water at 55℃; for 7h; Suzuki-Miyaura Coupling;97%
With C35H47O3P*C15H16N(1-)*CH3O3S(1-)*Pd(2+); triethylamine In water at 45℃; for 21h; Suzuki-Miyaura Coupling;96%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

6-bromo-2-naphthoic acid
5773-80-8

6-bromo-2-naphthoic acid

Conditions
ConditionsYield
With water; lithium hydroxide In tetrahydrofuran at 20℃; for 5h;96%
With lithium hydroxide In tetrahydrofuran; water at 20℃; for 5h;96%
Stage #1: methyl 6-bromo-2-naphthoate With lithium hydroxide monohydrate In tetrahydrofuran; water
Stage #2: With hydrogenchloride In tetrahydrofuran; water pH=3;
92%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

Dimethyl phosphite
868-85-9

Dimethyl phosphite

methyl 6-(dimethoxyphosphoryl)-2-naphthoate
1402577-09-6

methyl 6-(dimethoxyphosphoryl)-2-naphthoate

Conditions
ConditionsYield
With potassium phosphate; 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In 1,4-dioxane at 100℃; Inert atmosphere;96%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

2,4-dimethylbenzeneboronic acid
55499-44-0

2,4-dimethylbenzeneboronic acid

methyl 6-(2,4-dimethylphenyl)-2-naphthoate

methyl 6-(2,4-dimethylphenyl)-2-naphthoate

Conditions
ConditionsYield
With potassium phosphate monohydrate; C66H84O10P2Pd In water; ethyl acetate; toluene at 45℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere;96%
With potassium phosphate monohydrate; palladium diacetate; N2Phos In water; toluene at 45℃; for 1.5h; Suzuki-Miyaura Coupling;96%
allylcyclopentane
3524-75-2

allylcyclopentane

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

(E)-methyl 6-(3-cyclopentylprop-1-en-1-yl)naphthalene-2-carboxylate

(E)-methyl 6-(3-cyclopentylprop-1-en-1-yl)naphthalene-2-carboxylate

Conditions
ConditionsYield
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 100℃; for 18h; Heck Reaction; Inert atmosphere;96%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

6-bromo-naphthalene-2-carboxaldehyde
170737-46-9

6-bromo-naphthalene-2-carboxaldehyde

Conditions
ConditionsYield
Stage #1: methyl 6-bromo-2-naphthoate With diisobutylaluminium hydride In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
Stage #2: With pyridinium chlorochromate In dichloromethane at 60℃; for 6h; Inert atmosphere;
95%
Stage #1: methyl 6-bromo-2-naphthoate With diisobutylaluminium hydride In tetrahydrofuran at 0 - 20℃; for 12h;
Stage #2: With pyridinium chlorochromate In dichloromethane for 5h; Reflux;
95%
With manganese dioxide; dibal In methanol; dichloromethane; toluene61%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

Diphenylphosphine oxide
4559-70-0

Diphenylphosphine oxide

methyl 6-(diphenylphosphoryl)-2-naphthoate
1378042-98-8

methyl 6-(diphenylphosphoryl)-2-naphthoate

Conditions
ConditionsYield
With potassium phosphate; 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In 1,4-dioxane at 100℃; Inert atmosphere;95%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

6-bromonaphthalene-2-carbohydrazide
948859-96-9

6-bromonaphthalene-2-carbohydrazide

Conditions
ConditionsYield
With hydrazine In methanol at 20 - 80℃; for 22h;94%
With hydrazine hydrate In ethanol for 3h; Reflux;81%
With hydrazine hydrate In methanol at 60 - 65℃; for 2h; Time;
With hydrazine hydrate In methanol at 60℃;
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

allylmagnesium bromide
1730-25-2

allylmagnesium bromide

4-(6-bromonaphth-2-yl)hepta-1,6-dien-4-ol
1126524-60-4

4-(6-bromonaphth-2-yl)hepta-1,6-dien-4-ol

Conditions
ConditionsYield
In diethyl ether at 0℃; for 0.0833333h; Inert atmosphere;94%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

6-(5,5-dimethyl-[1,3,2]dioxaborinan-2-yl)-1,4,4-trimethyl-1,2,3,4-tetrahydroquinoline

6-(5,5-dimethyl-[1,3,2]dioxaborinan-2-yl)-1,4,4-trimethyl-1,2,3,4-tetrahydroquinoline

6-(1,4,4-trimethyl-1,2,3,4-tetrahydroquinolin-6-yl)-naphthalene-2-carboxylic acid methyl ester

6-(1,4,4-trimethyl-1,2,3,4-tetrahydroquinolin-6-yl)-naphthalene-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; tripotassium phosphate dihydrate In water; dimethyl sulfoxide at 80℃; for 18h; Inert atmosphere; Glovebox;94%
4-methylpentyne
7154-75-8

4-methylpentyne

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

methyl 6-(4-methylpent-1-yn-1-yl)-2-naphthoate

methyl 6-(4-methylpent-1-yn-1-yl)-2-naphthoate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diethylamine In tetrahydrofuran at 50℃; for 18h; Inert atmosphere;94%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

2,2-difluoroethenyl 4-methylbenzene-1-sulfonate
185739-14-4

2,2-difluoroethenyl 4-methylbenzene-1-sulfonate

C14H10F2O2

C14H10F2O2

Conditions
ConditionsYield
With [2,2]bipyridinyl; nickel dichloride; zinc In N,N-dimethyl acetamide at 90℃; for 16h;94%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

methyl 6-iodonaphthalene-2-carboxylate
5042-98-8

methyl 6-iodonaphthalene-2-carboxylate

Conditions
ConditionsYield
With copper(l) iodide; sodium iodide; N,N`-dimethylethylenediamine In 1,4-dioxane at 110℃; for 65h; Finkelstein reaction; Inert atmosphere;93%
With copper(l) iodide; sodium iodide; N,N`-dimethylethylenediamine In 1,4-dioxane at 110℃; for 65h; Inert atmosphere;90%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

methyl 6-((trimethylsilyl)ethynyl)-2-naphthoate

methyl 6-((trimethylsilyl)ethynyl)-2-naphthoate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In dichloromethane at 90℃; for 16h; Inert atmosphere; Schlenk technique;93%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 90℃; for 16h; Inert atmosphere; Schlenk technique;93%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In acetonitrile at 80℃; for 16h; Inert atmosphere;83%
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

methyl 6-(2,2,2-trifluoroethoxy)-2-naphthoate

methyl 6-(2,2,2-trifluoroethoxy)-2-naphthoate

Conditions
ConditionsYield
With C43H59NO2PPd(1+)*CH3O3S(1-); caesium carbonate In toluene at 80℃; Schlenk technique; Inert atmosphere;93%
3-(1-adamantyl)-4-methoxyphenylboronic acid
459423-32-6

3-(1-adamantyl)-4-methoxyphenylboronic acid

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

6-(3-adamantan-1-yl-4-methoxyphenyl)naphthalene-2-carboxylic acid methyl ester
106685-41-0

6-(3-adamantan-1-yl-4-methoxyphenyl)naphthalene-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With sodium carbonate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium(0) In tetrahydrofuran; water Product distribution / selectivity; Suzuki-Miyaura cross-coupling; Inert atmosphere; Reflux;92%
Suzuki-Miyaura coupling;
n-octyne
629-05-0

n-octyne

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

methyl 6-(octynyl)-2-naphthoate
1242239-82-2

methyl 6-(octynyl)-2-naphthoate

Conditions
ConditionsYield
With triethylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide; toluene at 20℃; for 31.5h; Inert atmosphere;92%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-naphthalene-2-carboxylic acid methyl ester
736989-93-8

6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-naphthalene-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate In dimethyl sulfoxide at 80℃; for 12h; Inert atmosphere;91%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium acetate In dimethyl sulfoxide for 24h; Schlenk technique; Inert atmosphere; Reflux;87%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium acetate In dimethyl sulfoxide for 24h; Schlenk technique; Inert atmosphere; Reflux;87%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

4-butoxyphenylboronic acid
105365-51-3

4-butoxyphenylboronic acid

methyl 6-(4-butoxyphenyl)-2-naphthoate

methyl 6-(4-butoxyphenyl)-2-naphthoate

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate monohydrate; methylmagnesium chloride at 45℃; for 24h; Suzuki-Miyaura Coupling;91%
1-penten
109-67-1

1-penten

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

(E)-methyl 6-(pent-1-en-1-yl)-2-naphthoate

(E)-methyl 6-(pent-1-en-1-yl)-2-naphthoate

Conditions
ConditionsYield
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 100℃; for 18h; Heck Reaction; Inert atmosphere;91%
ethyl 2-methyl-4-pentenoate
53399-81-8

ethyl 2-methyl-4-pentenoate

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

C20H22O4

C20H22O4

Conditions
ConditionsYield
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 100℃; for 18h; Heck Reaction; Inert atmosphere;91%
methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

methyl 6-<3-(1-adamantyl)-4-<<(2,3-dimethyl-1,3-dioxolan-4-yl)methyl>oxy>phenyl>-2-naphthoate
146966-02-1

methyl 6-<3-(1-adamantyl)-4-<<(2,3-dimethyl-1,3-dioxolan-4-yl)methyl>oxy>phenyl>-2-naphthoate

Conditions
ConditionsYield
Stage #1: 3-(1-adamantyl)-4-<<(2,3-dimethyl-1,3-dioxolan-4-yl)methyl>oxy>bromobenzene With magnesium; ethylene dibromide In tetrahydrofuran for 1.5h; Heating / reflux;
Stage #2: With zinc(II) chloride In tetrahydrofuran at 20℃; for 1.5h;
Stage #3: methyl 6-bromo-2-naphthoate; cis-[NiCl2(1,2-bis(diphenylphosphino)ethane)] In tetrahydrofuran at 20℃; for 15h;
89%
4-Methyl-1-pentene
691-37-2

4-Methyl-1-pentene

methyl 6-bromo-2-naphthoate
33626-98-1

methyl 6-bromo-2-naphthoate

(E)-methyl 6-(4-methylpent-1-en-1-yl)-2-naphthoate

(E)-methyl 6-(4-methylpent-1-en-1-yl)-2-naphthoate

Conditions
ConditionsYield
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 100℃; for 18h; Heck Reaction; Inert atmosphere;89%
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