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Shanghai Minstar Chemical Co., Ltd

3-METHOXYPHENYLMAGNESIUM BROMIDE Basic information Product Name: 3-METHOXYPHENYLMAGNESIUM BROMIDE CAS: 36282-40-3 MF: C7H7BrMgO MW: 211.34 EINECS: Product Categories: Aryl;Grignard Reagents;Organometallic Reagents;Chemical Synthesis;Grignard Reage

3-METHOXYPHENYLMAGNESIUM BROMIDE solution best Grignard reagents

Cas:36282-40-3

Min.Order:1 Liter

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Type:Lab/Research institutions

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Magnesium,bromo(3-methoxyphenyl)-

Cas:36282-40-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

BP Standard CAS 36282-40-3 with best price

Cas:36282-40-3

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Magnesium,bromo(3-methoxyphenyl)-

Cas:36282-40-3

Min.Order:1 Gram

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Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:36282-40-3

Cas:36282-40-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Magnesium,bromo(3-methoxyphenyl)-

Cas:36282-40-3

Min.Order:0

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

3-METHOXYPHENYLMAGNESIUM BROMIDE

Cas:36282-40-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

3-methoxyphenylmagnesium bromide

Cas:36282-40-3

Min.Order:0

Negotiable

Type:Other

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GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

3-Methoxyphenylmagnesium bromide solution

Cas:36282-40-3

Min.Order:0

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Type:Lab/Research institutions

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 3-Methoxyphenylmagnesium bromide 500ml

Cas:36282-40-3

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

3-methoxyphenylmagnesium bromide

Cas:36282-40-3

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

3-MethoxyphenylMagnesiuM broMide, 1.0 M solution in THF/toluene(38/62), J&KSeal

Cas:36282-40-3

Min.Order:0

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Type:Lab/Research institutions

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Hangzhou Fandachem Co.,Ltd

Magnesium,bromo(3-methoxyphenyl)- cas 36282-40-3Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Magnesium,bromo(3-methoxyphenyl)- cas 36282-40-3

Cas:36282-40-3

Min.Order:0

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Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:Clear colorless to brown solution Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

3-methoxyphenylmagnesiumbromide

Cas:36282-40-3

Min.Order:0

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Type:Lab/Research institutions

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

3-METHOXYPHENYLMAGNESIUM BROMIDE

Cas:36282-40-3

Min.Order:0

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Type:Lab/Research institutions

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

36282-40-3

Cas:36282-40-3

Min.Order:0

Negotiable

Type:Trading Company

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

3-METHOXYPHENYLMAGNESIUM BROMIDE

Cas:36282-40-3

Min.Order:0

Negotiable

Type:Trading Company

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Magnesium,bromo(3-methoxyphenyl)-

Cas:36282-40-3

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

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Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

Magnesium,bromo(3-methoxyphenyl)- CAS NO.36282-40-3

Cas:36282-40-3

Min.Order:0

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Type:Trading Company

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Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

3-MethoxyphenylMagnesiuM broMide, 1.0 M in 2-

Cas:36282-40-3

Min.Order:1 Gram

Negotiable

Type:Other

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yuyongmei

YUYONGMEI was established in Aug,1999, located in the industrial park of Nanjing University of Technology, It is a private enterprises in Jiangsu Province with 1200 square meters’ R&D center. Our R&D center has a well-equipped synthetic laboratory a

Magnesium,bromo(3-methoxyphenyl)-

Cas:36282-40-3

Min.Order:0

Negotiable

Type:Trading Company

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Vasista life Sciences Pvt Ltd

3-Methoxy Phenyl Magnesium Bromide (1.0 M In THF)

Magnesium,bromo(3-methoxyphenyl)-

Cas:36282-40-3

Min.Order:0

Negotiable

Type:Trading Company

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Sigma-Aldrich Chemie GmbH

Package:100, 800 mL in Sure/Seal(TM)

3-Methoxyphenylmagnesium bromide solution

Cas:36282-40-3

Min.Order:0

Negotiable

Type:Trading Company

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PLATTE

more information,pls contact with us!

Magnesium,bromo(3-methoxyphenyl)-

Cas:36282-40-3

Min.Order:0

Negotiable

Type:Trading Company

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D’Orland KEG Ltd

Magnesium,bromo(3-methoxyphenyl)-

Cas:36282-40-3

Min.Order:0

Negotiable

Type:Trading Company

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The Lithium Company

more information,please contact us

Magnesium,bromo(3-methoxyphenyl)-

Cas:36282-40-3

Min.Order:0

Negotiable

Type:Trading Company

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Synthetic route

2,3-dihydro-4H-1-benzopyran-4-one
491-37-2

2,3-dihydro-4H-1-benzopyran-4-one

3-methoxyphenyl bromide
2398-37-0

3-methoxyphenyl bromide

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran
3-methoxyphenyl bromide
2398-37-0

3-methoxyphenyl bromide

magnesium
7439-95-4

magnesium

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

Conditions
ConditionsYield
In tetrahydrofuran
3-methoxyphenyl bromide
2398-37-0

3-methoxyphenyl bromide

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

Conditions
ConditionsYield
With magnesium; iodine In tetrahydrofuran at 20℃; Heating / reflux;
With magnesium In tetrahydrofuran Inert atmosphere;
With iodine; magnesium In tetrahydrofuran for 2h; Inert atmosphere; Reflux;
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

cyclohexanone
108-94-1

cyclohexanone

1-(m-Methoxyphenyl)cyclohexanol
1884-42-0

1-(m-Methoxyphenyl)cyclohexanol

Conditions
ConditionsYield
Stage #1: (3-methoxyphenyl)magnesium bromide; cyclohexanone In diethyl ether at 0 - 20℃; for 4h;
Stage #2: With water at 0℃;
100%
In tetrahydrofuran for 0.333333h;
In tetrahydrofuran; toluene at 0℃; for 5.5h; Inert atmosphere;
m-bromobenzoic aldehyde
3132-99-8

m-bromobenzoic aldehyde

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

3-bromo-α-(3-methoxyphenyl)benzenemethanol
76778-33-1

3-bromo-α-(3-methoxyphenyl)benzenemethanol

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.25h;100%
Stage #1: m-bromobenzoic aldehyde; (3-methoxyphenyl)magnesium bromide In tetrahydrofuran at 80℃; for 3h; Grignard reaction; Inert atmosphere;
Stage #2: With water; sodium chloride In tetrahydrofuran at 20℃;
3-(4-methoxy-benzyl)-3-aza-bicyclo[3.2.1]octan-8-one

3-(4-methoxy-benzyl)-3-aza-bicyclo[3.2.1]octan-8-one

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

3-(4-methoxy-benzyl)-8-(3-methoxy-phenyl)-3-aza-bicyclo[3.2.1]octan-8-ol

3-(4-methoxy-benzyl)-8-(3-methoxy-phenyl)-3-aza-bicyclo[3.2.1]octan-8-ol

Conditions
ConditionsYield
Stage #1: 3-(4-methoxy-benzyl)-3-aza-bicyclo[3.2.1]octan-8-one; (3-methoxyphenyl)magnesium bromide In tetrahydrofuran at -78 - 20℃;
Stage #2: With hydrogenchloride In water pH=1;
100%
ethyl 3-(3,4-methylenedioxyphenyl)-1-oxoindene-2-carboxylate
150356-32-4

ethyl 3-(3,4-methylenedioxyphenyl)-1-oxoindene-2-carboxylate

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

Ethyl (1RS)-1-Hydroxy-1-(3-methoxyphenyl)-3-(3,4-methylenedioxyphenyl)indene-2-carboxylate
150356-38-0

Ethyl (1RS)-1-Hydroxy-1-(3-methoxyphenyl)-3-(3,4-methylenedioxyphenyl)indene-2-carboxylate

Conditions
ConditionsYield
In tetrahydrofuran100%
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

tert-butyl 2-oxopyrrolidine-1-carboxylate
85909-08-6

tert-butyl 2-oxopyrrolidine-1-carboxylate

tert-butyl (4-(3-methoxyphenyl)-4-oxobutyl)carbamate
914954-34-0

tert-butyl (4-(3-methoxyphenyl)-4-oxobutyl)carbamate

Conditions
ConditionsYield
In tetrahydrofuran at -40 - 0℃; for 3h;100%
In tetrahydrofuran at -78 - 20℃; for 14h; Inert atmosphere; Schlenk technique;45%
diethyl 2-(4-bromobenzylidene)malonate
22399-01-5

diethyl 2-(4-bromobenzylidene)malonate

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

2-[(4-bromo-phenyl)-(3-methoxy-phenyl)-methyl]-malonic acid diethyl ester

2-[(4-bromo-phenyl)-(3-methoxy-phenyl)-methyl]-malonic acid diethyl ester

Conditions
ConditionsYield
Stage #1: diethyl 2-(4-bromobenzylidene)malonate; (3-methoxyphenyl)magnesium bromide In tetrahydrofuran; diethyl ether at 0℃; for 3.3h;
Stage #2: With water; ammonium chloride
100%
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

(4-bromo-phenyl)-(3-methoxy-phenyl)-methanol
134446-26-7

(4-bromo-phenyl)-(3-methoxy-phenyl)-methanol

Conditions
ConditionsYield
Stage #1: (3-methoxyphenyl)magnesium bromide; 4-bromo-benzaldehyde In tetrahydrofuran at 80℃; for 3h; Grignard reaction; Inert atmosphere;
Stage #2: With water; sodium chloride In tetrahydrofuran at 20℃;
100%
1-Chlorohexane
544-10-5

1-Chlorohexane

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

3-n-hexyl-1-methoxybenzene

3-n-hexyl-1-methoxybenzene

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one; palladium diacetate; tricyclohexylphosphine In tetrahydrofuran at 20℃; for 20h; Kumada coupling;99%
With 1,3-bis(mesityl)imidazolium chloride; palladium diacetate In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 20℃; for 1h; Kumada reaction;99%
C17H16O3

C17H16O3

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

C24H24O4

C24H24O4

Conditions
ConditionsYield
Stage #1: C17H16O3; (3-methoxyphenyl)magnesium bromide In tetrahydrofuran at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: With water In tetrahydrofuran at 0℃; diastereoselective reaction;
99%
3-iodo-1,2-dicarba-closo-dodecaborane
137495-63-7

3-iodo-1,2-dicarba-closo-dodecaborane

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

A

3-meta-hydroxyphenyl-o-carborane

3-meta-hydroxyphenyl-o-carborane

B

3-meta-methoxyphenyl-o-carborane
1159494-39-9

3-meta-methoxyphenyl-o-carborane

Conditions
ConditionsYield
With copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran Ar, a soln. of Mg compd. (8.5 equiv.) added dropwise to a soln. of B compd., CuI and catalyst, refluxed for 34 h; quenched (dilute HCl), extd. (ethyl acetate), washed (water), dried (MgSO4), concd., chromy. (silica gel);A 0%
B 99%
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

1-[1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hept-5-en-2-yl]ethanone

1-[1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hept-5-en-2-yl]ethanone

1-(1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hept-5-en-2-yl)-1-m-tolylethanol

1-(1,4,5,6-tetrachloro-7,7-dimethoxybicyclo[2.2.1]hept-5-en-2-yl)-1-m-tolylethanol

Conditions
ConditionsYield
at 20℃; for 13h; Inert atmosphere;99%
8-methoxy-3,4-dihydroisocoumarin
30404-50-3

8-methoxy-3,4-dihydroisocoumarin

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

[2-(2-hydroxy-ethyl)-6-methoxy-phenyl]-(3-methoxy-phenyl)-methanone
891829-94-0

[2-(2-hydroxy-ethyl)-6-methoxy-phenyl]-(3-methoxy-phenyl)-methanone

Conditions
ConditionsYield
In tetrahydrofuran; dichloromethane at -78 - 20℃;98%
3-bromobenzoyl chloride
1711-09-7

3-bromobenzoyl chloride

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

(3-bromophenyl)-(3-methoxyphenyl)-methanone
750633-66-0

(3-bromophenyl)-(3-methoxyphenyl)-methanone

Conditions
ConditionsYield
Stage #1: 3-bromobenzoyl chloride With tributylphosphine In tetrahydrofuran at 20℃; for 0.333333h;
Stage #2: (3-methoxyphenyl)magnesium bromide In tetrahydrofuran at 20℃; for 0.166667h;
98%
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

(2-isocyanophenyl)(phenyl)methanone
521270-76-8

(2-isocyanophenyl)(phenyl)methanone

2-(3-methoxyphenyl)-3-phenyl-3H-indol-3-ol
1253396-21-2

2-(3-methoxyphenyl)-3-phenyl-3H-indol-3-ol

Conditions
ConditionsYield
Stage #1: (3-methoxyphenyl)magnesium bromide; (2-isocyanophenyl)(phenyl)methanone In tetrahydrofuran; diethyl ether at 0℃;
Stage #2: With water; ammonium chloride In tetrahydrofuran; diethyl ether at 0℃;
98%
quinolin-6-yl 4-methylbenzene-1-sulfonate
426265-40-9

quinolin-6-yl 4-methylbenzene-1-sulfonate

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

6-(3'-methoxyphenyl)quinoline
1023531-31-8

6-(3'-methoxyphenyl)quinoline

Conditions
ConditionsYield
Stage #1: (3-methoxyphenyl)magnesium bromide With C24H52Cl2O12P4Pd2 In tetrahydrofuran; 1,4-dioxane at 20℃; for 0.0833333h; Kumada-Corriu cross-coupling reaction; Inert atmosphere;
Stage #2: quinolin-6-yl 4-methylbenzene-1-sulfonate In tetrahydrofuran; 1,4-dioxane at 80℃; for 24h; Kumada-Corriu cross-coupling reaction; Inert atmosphere; regioselective reaction;
98%
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

cyclohept-1-en-1-yl dimethylcarbamate

cyclohept-1-en-1-yl dimethylcarbamate

(E)-1-(3-methoxyphenyl)cyclohept-1-en
75209-54-0

(E)-1-(3-methoxyphenyl)cyclohept-1-en

Conditions
ConditionsYield
With N,N'-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene hydrochloride; palladium diacetate In tetrahydrofuran at 50℃; for 3h; Schlenk technique; Inert atmosphere; Sealed tube;98%
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

(S)-diethyl 5-phenyl-1-(trimethylsilyl)pent-1-yn-3-yl phosphate

(S)-diethyl 5-phenyl-1-(trimethylsilyl)pent-1-yn-3-yl phosphate

(S)-1-(3-methoxyphenyl)-5-phenyl-1-trimethylsilylpenta-1,2-diene

(S)-1-(3-methoxyphenyl)-5-phenyl-1-trimethylsilylpenta-1,2-diene

Conditions
ConditionsYield
With copper acetylacetonate In tetrahydrofuran at -18 - 0℃; for 2h; enantiospecific reaction;98%
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

allyl bromide
106-95-6

allyl bromide

1-allyl-3-methoxybenzene
24743-14-4

1-allyl-3-methoxybenzene

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 24h;97%
In tetrahydrofuran; toluene at 0 - 20℃; for 18h;81%
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

3-methoxy-benzaldehyde
591-31-1

3-methoxy-benzaldehyde

bis(3-methoxyphenyl)methanol
55360-45-7

bis(3-methoxyphenyl)methanol

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 3h; Grignard Reaction;97%
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

propionic acid anhydride
123-62-6

propionic acid anhydride

1-(3-methoxyphenyl)propan-1-one
37951-49-8

1-(3-methoxyphenyl)propan-1-one

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at -70℃;97%
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

(1E)-4,4-bis(methylthio)-2-nitro-1-pyrrolidino-1,3-butadiene
389838-05-5

(1E)-4,4-bis(methylthio)-2-nitro-1-pyrrolidino-1,3-butadiene

(E)-4-(3-methoxyphenyl)-1,1-bis(methylthio)-3-nitro-1,3-butadiene
467421-88-1

(E)-4-(3-methoxyphenyl)-1,1-bis(methylthio)-3-nitro-1,3-butadiene

Conditions
ConditionsYield
In tetrahydrofuran at -78℃;97%
4-benzyloxy-6-bromo-3-methoxybenzaldehyde
40705-22-4

4-benzyloxy-6-bromo-3-methoxybenzaldehyde

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

[4-(benzyloxy)-2-bromo-5-methoxyphenyl](3-methoxyphenyl)methanol
1569316-45-5

[4-(benzyloxy)-2-bromo-5-methoxyphenyl](3-methoxyphenyl)methanol

Conditions
ConditionsYield
In diethyl ether at 0 - 20℃; for 3h; Inert atmosphere;97%
1-bromo-3,5-dimethoxybenzene
20469-65-2

1-bromo-3,5-dimethoxybenzene

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

3,3',5-trimethoxy-1,1'-biphenyl
33580-34-6

3,3',5-trimethoxy-1,1'-biphenyl

Conditions
ConditionsYield
With nickel(II) fluoride; 1,3-bis(3,6-diisopropylphenyl)imidazolium hydrochloride In tetrahydrofuran at 0 - 80℃; for 12.5h; Inert atmosphere;97%
(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

3,3'-dimethoxybiphenyl
6161-50-8

3,3'-dimethoxybiphenyl

Conditions
ConditionsYield
With iron(III) chloride; 1,2-dichloro-ethane In tetrahydrofuran at 20℃; for 0.166667h;96%
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical In tetrahydrofuran at 66℃; for 0.166667h; Inert atmosphere;87%
With 4-oxo-2,2,6,6-tetramethylpiperidin-oxyl In tetrahydrofuran at 66℃; for 0.166667h; Inert atmosphere;87%
(4aR*,6R*,7R*)-6,7-bis(tert-butyldimethylsilyloxy)-1,2,3,4,4a,5,6,7-octahydronaphthalene-4a-carbaldehyde

(4aR*,6R*,7R*)-6,7-bis(tert-butyldimethylsilyloxy)-1,2,3,4,4a,5,6,7-octahydronaphthalene-4a-carbaldehyde

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

C30H52O4Si2

C30H52O4Si2

Conditions
ConditionsYield
In tetrahydrofuran for 0.5h; Grignard reaction;96%
(triphenylphosphine)gold(I) chloride
14243-64-2

(triphenylphosphine)gold(I) chloride

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

(3-methoxyphenyl)(triphenyl-λ5-phosphanyl)gold
870485-34-0

(3-methoxyphenyl)(triphenyl-λ5-phosphanyl)gold

Conditions
ConditionsYield
In tetrahydrofuran 3-methoxyphenylmagnesium bromide added dropwise at -78°C to soln.ClAuPPh3 in THF in Schlenk techniques under Ar; mixt. warmed to room te mp., mixed for 16 h; treated with satd. soln. of NH4Cl, extd. with Et2O; org. layers washed with satd. soln. of NaCl, dried over MgSO4; solvents removed under vac.; crystals obtained via crystn. from CHCl3;96%
(1RS,5RS,6RS,7RS)-3-methoxy-6-methyl-7-phenylbicyclo[3.2.1]-oct-3-ene-2,8-dione

(1RS,5RS,6RS,7RS)-3-methoxy-6-methyl-7-phenylbicyclo[3.2.1]-oct-3-ene-2,8-dione

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

(1RS,4SR,5SR,6RS,7RS)-4-hydroxy-3-methoxy-4-(3-methoxyphenyl)-7-methyl-6-phenylbicyclo[3.2.1]oct-2-en-8-one

(1RS,4SR,5SR,6RS,7RS)-4-hydroxy-3-methoxy-4-(3-methoxyphenyl)-7-methyl-6-phenylbicyclo[3.2.1]oct-2-en-8-one

Conditions
ConditionsYield
Stage #1: (1RS,5RS,6RS,7RS)-3-methoxy-6-methyl-7-phenylbicyclo[3.2.1]-oct-3-ene-2,8-dione; (3-methoxyphenyl)magnesium bromide In tetrahydrofuran at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: With water In tetrahydrofuran at 0℃; diastereoselective reaction;
96%
1-bromocyclohexane
108-85-0

1-bromocyclohexane

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

1-cyclohexyl-3-methoxybenzene
41876-58-8

1-cyclohexyl-3-methoxybenzene

Conditions
ConditionsYield
With Iron(III) amine-bis(phenolate) complex In diethyl ether at 20℃; for 0.5h; Inert atmosphere;96%
With C54H80Cl2Fe2N2O4 In diethyl ether at 22℃; for 0.5h; Inert atmosphere;> 95 %Chromat.
With [Fe(n-propylamino-N,N-bis(2-methylene-4-tert-butyl-6-methylphenolate))(chloride)]2 In diethyl ether at 22℃; for 0.5h; Catalytic behavior;> 95 %Chromat.
4-vinylbenzyl chloride
1073-67-2

4-vinylbenzyl chloride

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

C15H14O
244159-74-8

C15H14O

Conditions
ConditionsYield
Stage #1: 4-vinylbenzyl chloride With cobalt(III) acetylacetonate In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 30℃; for 1h;
Stage #2: (3-methoxyphenyl)magnesium bromide In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 30℃; for 0.333333h;
96%
5-benzyloxy-2-bromo-4-methoxybenzaldehyde
6451-86-1

5-benzyloxy-2-bromo-4-methoxybenzaldehyde

(3-methoxyphenyl)magnesium bromide
36282-40-3

(3-methoxyphenyl)magnesium bromide

[5-(benzyloxy)-2-bromo-4-methoxyphenyl](3-methoxyphenyl)methanol
1569316-44-4

[5-(benzyloxy)-2-bromo-4-methoxyphenyl](3-methoxyphenyl)methanol

Conditions
ConditionsYield
In diethyl ether at 0 - 20℃; for 3h; Inert atmosphere;96%

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