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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

N,N'-di-tert-Butylethylenediamine

Cas:4062-60-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Factory supply N,N'-Di-Tert-Butylethylenediamine CAS 4062-60-6 with fast delivery Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermed

Factory supply N,N'-Di-Tert-Butylethylenediamine CAS 4062-60-6 with fast delivery

Cas:4062-60-6

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply N,N'-bis(tert-butyl)ethylenediamine

Cas:4062-60-6

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

N,N'-Di-tert-butylethylenediamine

Cas:4062-60-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 4062-60-6 with best quality

Cas:4062-60-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: N,N'-di-tert-butylethane-1,2-diamine Synonyms: Dibutylethylenediamine CAS: 4062-60-6 MF: C10H24N2 Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg/drum Application:Organic intermediate Transp

N,N'-di-tert-butylethane-1,2-diamine

Cas:4062-60-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--4062-60-6--High purity N,N'-DI-TERT-BUTYLETHYLENEDIAMINE factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had est

TIANFUCHEM--4062-60-6--High purity N,N'-DI-TERT-BUTYLETHYLENEDIAMINE factory price

Cas:4062-60-6

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1,2-Ethanediamine,N1,N2-bis(1,1-dimethylethyl)-

Cas:4062-60-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

N,N'-DI-TERT-BUTYLETHYLENEDIAMINE CAS:4062-60-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qual

N,N'-DI-TERT-BUTYLETHYLENEDIAMINE CAS:4062-60-6

Cas:4062-60-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,2-Ethanediamine,N1,N2-bis(1,1-dimethylethyl)-

Cas:4062-60-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1,2-Ethanediamine,N1,N2-bis(1,1-dimethylethyl)-

Cas:4062-60-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

N,N'-Di-Tert-Butylethylenediamine

Cas:4062-60-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products N,N'-DI-TERT-BUTYLETHYLENEDIAMINE

Cas:4062-60-6

Min.Order:100 Gram

Negotiable

Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

N,N'-di-tert-butylethylenediamine manufacturer

Cas:4062-60-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

N,N'-di-tert-Butylethylenediamine

Cas:4062-60-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

N1,N2-Di-tert-butylethane-1,2-diamine

Cas:4062-60-6

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

N,N'-DI-TERT-BUTYLETHYLENEDIAMINE Chemical Properties Melting point 53.35°C Boiling point 196-198 °C(lit.) density 0.799 g/mL at 25 °C(lit.) refractive index n20/D 1.43(lit.) Fp 144 °F solubility Soluble (3

N,N'-Di-tert-butylethylenediamine

Cas:4062-60-6

Min.Order:1 Gram

FOB Price: $65.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: N,N'-Di-Tert-Butylethylenediamine CAS No.: 4062-60-6 Molecule Formula:C10H24N2 Molecule Weight:172.31 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard

Lower Price N,N'-Di-Tert-Butylethylenediamine

Cas:4062-60-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

N,N'-DI-TERT-BUTYLETHYLENEDIAMINE

Cas:4062-60-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

N,N'-di-tert-butylethylenediamine cas no. 4062-60-6 98%

Cas:4062-60-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

N,N'-di-tert-Butylethylenediamine

Cas:4062-60-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

N,N'-di-tert-butylethylenediamine

Cas:4062-60-6

Min.Order:0

Negotiable

Type:Other

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 1,2-Bis(Tert-Butylamino)Ethane 500g

Cas:4062-60-6

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

N,N'-Di-tert-butylethylenediaMine

Cas:4062-60-6

Min.Order:0

Negotiable

Type:Manufacturers

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

N,N'-DI-TERT-BUTYLETHYLENEDIAMINE

Cas:4062-60-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,2-Ethanediamine,N1,N2-bis(1,1-dimethylethyl)-

Cas:4062-60-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

N1,N2-Di-tert-butylethane-1,2-diamine

Cas:4062-60-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

DB BIOTECH CO., LTD

best seller Application:API

N,N'-DI-TERT-BUTYLETHYLENEDIAMINE

Cas:4062-60-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:clear liquid Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary a

1,2-Bis(tert-butylamino)ethane

Cas:4062-60-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

N,N'-DI-TERT-BUTYLETHYLENEDIAMINEAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:pharmaceutical intermediate Transportation:by air, by sea, by express

N,N'-DI-TERT-BUTYLETHYLENEDIAMINE

Cas:4062-60-6

Min.Order:0

Negotiable

Type:Other

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Synthetic route

1,4-di-tert-butyl-1,4-diazabutadiene
28227-42-1, 30834-74-3

1,4-di-tert-butyl-1,4-diazabutadiene

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

Conditions
ConditionsYield
With lithium aluminium tetrahydride at 0 - 20℃;89%
With sodium tetrahydroborate In methanol at 0 - 25℃; Inert atmosphere;
N-((E,2E)-2-{[(E)-1,1-dimethylethyl]imino}ethylidene)-2-methyl-2-propanamine
30834-74-3

N-((E,2E)-2-{[(E)-1,1-dimethylethyl]imino}ethylidene)-2-methyl-2-propanamine

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In ethanol for 3h;81%
ethylene dibromide
106-93-4

ethylene dibromide

tert-butylamine
75-64-9

tert-butylamine

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

Conditions
ConditionsYield
In hexane; water for 72h; Heating;72%
In water 1.) 0 deg C to ambient temperature (slowly), 2.) reflux, overnight;70%
Stage #1: ethylene dibromide; tert-butylamine With sodium hydroxide In water at 0℃; for 1h;
Stage #2: In water at 25℃; for 72h;
56%
With water
ethylene dibromide
106-93-4

ethylene dibromide

tert-butylamine
75-64-9

tert-butylamine

A

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

B

1,4,7-tri-tert-butyl-1,4,7-triazaheptane
24426-18-4

1,4,7-tri-tert-butyl-1,4,7-triazaheptane

C

1,4-di-tert-butylpiperazine
10125-77-6

1,4-di-tert-butylpiperazine

Conditions
ConditionsYield
In water at 20℃; for 72h;A 70%
B 2%
C 9%
N-((E,2E)-2-{[(E)-1,1-dimethylethyl]imino}ethylidene)-2-methyl-2-propanamine
30834-74-3

N-((E,2E)-2-{[(E)-1,1-dimethylethyl]imino}ethylidene)-2-methyl-2-propanamine

A

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

B

1-tert-Butyl-3-(tert-butylamino)pyrrol
117203-10-8

1-tert-Butyl-3-(tert-butylamino)pyrrol

C

1-tert-Butyl-3,4-bis(tert-butylamino)pyrrol
117203-11-9

1-tert-Butyl-3,4-bis(tert-butylamino)pyrrol

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In ethanol for 1.5h;A 8%
B 30%
C 24%
1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

tert-butylamine
75-64-9

tert-butylamine

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

tert-butylamine
75-64-9

tert-butylamine

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 24h;
N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

1,3-di-tert-butyl-2-chloro-1,3,2-diazaphospholidine
89437-94-5

1,3-di-tert-butyl-2-chloro-1,3,2-diazaphospholidine

Conditions
ConditionsYield
With triethylamine; phosphorus trichloride In toluene at 20℃; for 2h;100%
With phosphorus trichloride In benzene 1) 18h, r.t., 2) reflux, 24h;87%
With triethylamine; phosphorus trichloride In toluene at 0 - 20℃; Inert atmosphere; Glovebox; Schlenk technique;81%
N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

1,2-bis(t-butylamino)ethane dihydrochloride
4495-50-5, 22687-37-2

1,2-bis(t-butylamino)ethane dihydrochloride

Conditions
ConditionsYield
With hydrogenchloride In ethanol; water100%
With hydrogenchloride In ethanol
N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

C10H22(2)H2N2

C10H22(2)H2N2

Conditions
ConditionsYield
With water-d2 In dimethylsulfoxide-d6 at 25℃; for 1h; Inert atmosphere;100%
With deuteromethanol at 20℃; for 1h;98%
N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

5,5-Dimethyl-5,6-dihydro-4H-1,3-dioxinium tetrafluoroborate

5,5-Dimethyl-5,6-dihydro-4H-1,3-dioxinium tetrafluoroborate

1,3-Di-tert-butyl-4,5-dihydro-3H-imidazol-1-ium tetrafluoroborate

1,3-Di-tert-butyl-4,5-dihydro-3H-imidazol-1-ium tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane at 20℃;98%
formaldehyd
50-00-0

formaldehyd

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

N,N'-di-tert-butyl-N,N'-dimethyl-ethylenediamine
88619-02-7

N,N'-di-tert-butyl-N,N'-dimethyl-ethylenediamine

Conditions
ConditionsYield
With formic acid In water for 16h; Eschweiler-Clarke reaction; Heating;97%
With formic acid In water Heating;65%
N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

chloroacetyl chloride
79-04-9

chloroacetyl chloride

N,N′-bis(2-chloroacetyl)-N,N′-di-tert-butylethylenediamine

N,N′-bis(2-chloroacetyl)-N,N′-di-tert-butylethylenediamine

Conditions
ConditionsYield
Stage #1: chloroacetyl chloride In dichloromethane for 0.25h; Inert atmosphere; Cooling with ice;
Stage #2: N,N'-di-tert-butylethylenediamine In dichloromethane at 20℃; Inert atmosphere;
94%
With potassium carbonate In dichloromethane at 50℃; for 12h; Inert atmosphere;68.9%
N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

dichloroglyoxime
2038-44-0

dichloroglyoxime

1,4-Di-tert-butyl-piperazine-2,3-dione dioxime

1,4-Di-tert-butyl-piperazine-2,3-dione dioxime

Conditions
ConditionsYield
In methanol at -40 - 20℃;92%
4,4'-bis(dibromoboryl)biphenyl
107384-84-9

4,4'-bis(dibromoboryl)biphenyl

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

4,4'-bis(1,3-di-tert-butyl-1,3,2-diazaborolidinyl)biphenyl

4,4'-bis(1,3-di-tert-butyl-1,3,2-diazaborolidinyl)biphenyl

Conditions
ConditionsYield
Stage #1: 4,4'-bis(dibromoboryl)biphenyl With triethylamine In toluene at 0 - 20℃;
Stage #2: N,N'-di-tert-butylethylenediamine In hexane for 3h; Heating;
92%
With Et3N In toluene under Ar; soln. of B compd. in toluene added dropwise to chilled soln. (0°C) of Et3N in toluene; warmed to 20°C; neat (t-BuNHCH2)2added; heated under reflux for 3 h; cooled to room temp.; filtered; filtrate concd.; crystd. at -30°C for 12 h; recrystd. from toluene; elem. anal.;92%
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

3,5-di-tert-butyl-o-benzoquinone
3383-21-9

3,5-di-tert-butyl-o-benzoquinone

(N1,N2-di-tert-butylethane-1,2-diamine)(3,5-di-tert-butylsemiquinone)copper(II) hexafluorophosphate

(N1,N2-di-tert-butylethane-1,2-diamine)(3,5-di-tert-butylsemiquinone)copper(II) hexafluorophosphate

Conditions
ConditionsYield
In tetrahydrofuran under N2; soln. of diamine added to soln. of Cu complex in dry THF; stirred at room temp. for 5 min; treated with t-Bu2C6H2O2; stirred for 2 h; concd.; Et2O added; filtered; solid rinsed with pentane; dried under N2 for 4 h;90%
trimethylamine alane
16842-00-5, 855944-65-9

trimethylamine alane

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

Al((CH3)3CNCH2CH2NHC(CH3)3)((CH3)3CNCH2CH2NC(CH3)3)
154990-93-9

Al((CH3)3CNCH2CH2NHC(CH3)3)((CH3)3CNCH2CH2NC(CH3)3)

Conditions
ConditionsYield
In diethyl ether byproducts: H2; molar ratio ligand:Al-compd.=2:1, -80°C (30 min), then 20°C (2.5 h); solvent removal (vac.), recrystn. (hexane, -30°C, 9 days);89.2%
formaldehyd
50-00-0

formaldehyd

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

1,3-bis(1,1-dimethylethyl)imidazolidin-2-ylidene
224453-32-1

1,3-bis(1,1-dimethylethyl)imidazolidin-2-ylidene

Conditions
ConditionsYield
89%
In diethyl ether
2,5-bis(dibromoboryl)thiophene
910655-65-1

2,5-bis(dibromoboryl)thiophene

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

2,5-bis(1,3-di-tert-butyl-2'-1',3',2'-diazaborolidinyl)thiophene

2,5-bis(1,3-di-tert-butyl-2'-1',3',2'-diazaborolidinyl)thiophene

Conditions
ConditionsYield
With triethylamine In hexane for 3h; Heating;89%
With triethylamine In hexane (Ar); using Schlenk techniques; addn. dropwise soln. of C4H2S(BBr2)2 in hexane to soln. of NEt3 in hexane at 0°C; pptn., sepn. of ppt., warming to ambient temp.; addn. of N,N'-di-tert-butyl-ethylenediamine; reflux for 3 h; filtration, evapn. to dryness; crystn. from pentane at -30°C, elem. anal.;89%
N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

trimethylaminealane
16842-00-5

trimethylaminealane

Al((CH3)3CNCH2CH2NHC(CH3)3)((CH3)3CNCH2CH2NC(CH3)3)
154990-93-9

Al((CH3)3CNCH2CH2NHC(CH3)3)((CH3)3CNCH2CH2NC(CH3)3)

Conditions
ConditionsYield
In diethyl ether byproducts: H2, NMe3; (argon); addn. of diamine to AlH3*NMe3 in Et2O at -80°C, stirring(30 min), warming to 20°C, stirring (2.5 h); filtration, removal of volatiles (vac.), recrystn. (hexane, -30°C, 9 d); elem. anal.;89%
C8H4Cl2F5OP

C8H4Cl2F5OP

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

1,3-di(tert-butyl)-2-[1-(pentafluorophenyl)ethoxy]-1,3,2-diazaphospholidine

1,3-di(tert-butyl)-2-[1-(pentafluorophenyl)ethoxy]-1,3,2-diazaphospholidine

Conditions
ConditionsYield
With triethylamine In diethyl ether at 20℃; for 2h;86%
(ferrocenyl)dibromoborane

(ferrocenyl)dibromoborane

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

[(η5-C5H4BNa(tBu)CH2CH2Nb(tBu))(η5-C5H5)Fe](B-Nb)
901146-92-7

[(η5-C5H4BNa(tBu)CH2CH2Nb(tBu))(η5-C5H5)Fe](B-Nb)

Conditions
ConditionsYield
With NEt3 In hexane byproducts: (Et3NH)Br; under dry O2-free N2; soln. (10 ml) of (C5H5)Fe(C5H4)BBr2 (7.8 mmol) added to chilled (0°C) soln. (50 ml) of NEt3 (15.6 mmol); warmed toroom temp.; neat N,N'-di-tert-butylethane-1,2-diamine (8.00 mmol) added dropwise; refluxed (3 h); filtered; filtrate concd. to dryness; residue distd. (250°C, 1E-6bar); elem. anal.;86%
Glyoxal
131543-46-9

Glyoxal

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

trans-1,4-di-tert-butyl-2,3-dihydroxypiperazine
96444-67-6

trans-1,4-di-tert-butyl-2,3-dihydroxypiperazine

Conditions
ConditionsYield
In water for 0.166667h; Mechanism; var. temp. and solvent; other N,N'-disubstituted ethylenediamines;85%
In water for 0.166667h;85%
Glyoxal
131543-46-9

Glyoxal

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

1,3-di-tert-butyl-2-imidazolidinecarboxaldehyde
96444-68-7

1,3-di-tert-butyl-2-imidazolidinecarboxaldehyde

Conditions
ConditionsYield
In water at 60℃; for 0.0833333h;85%
(S)-3,3'-diphenyl-2,2'-dihydroxy-1,1'-dinaphthyl
102490-05-1, 75640-70-9, 75684-93-4

(S)-3,3'-diphenyl-2,2'-dihydroxy-1,1'-dinaphthyl

dichloromethane
75-09-2

dichloromethane

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

diethylzinc
557-20-0

diethylzinc

((S)-3,3'-diphenyl-2,2'-dioxy-1,1'-dinaphthyl)Zn(N,N'-di-tert-butylethylenediamine) * CH2Cl2

((S)-3,3'-diphenyl-2,2'-dioxy-1,1'-dinaphthyl)Zn(N,N'-di-tert-butylethylenediamine) * CH2Cl2

Conditions
ConditionsYield
In dichloromethane under N2; soln. of Et2Zn in CH2Cl2 added to soln. of the (S)-dinaphthyl and diamine in CH2Cl2, stirred at room temp. for 30 min; diffusion of hexane vapor into soln., crystals washed with Et2O and dried in vacuo; elem. anal.;85%
methylcymantrenyl(3-dibromo)borane
61649-79-4

methylcymantrenyl(3-dibromo)borane

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

[((3-Me)[1-BNa(tBu)CH2CH2Nb(tBu)]C5H3)Mn(CO)3](B-Nb)
901147-08-8

[((3-Me)[1-BNa(tBu)CH2CH2Nb(tBu)]C5H3)Mn(CO)3](B-Nb)

Conditions
ConditionsYield
With NEt3 In hexane byproducts: (Et3NH)Br; under dry O2-free N2; neat CH3(C5H3)BBr2Mn(CO)3 (13.6 mmol) added to chilled (0°C) soln. (100 ml) of NEt3 (27.1 mmol); warmed to room temp.; neat N,N'-di-tert-butylethane-1,2-diamine (27.1 mmol) added dropwise; refluxed (3 h); filtered; evapd.; residue distd. (150°C, 1E-6 bar); dissolved in n-pentane (40 ml); kept (-30°C, 7 d); elem. anal.;85%
trimethylamine alane
16842-00-5, 855944-65-9

trimethylamine alane

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

(AlH2)(NH(C(CH3)3)CH2CH2N(C(CH3)3))
154990-91-7

(AlH2)(NH(C(CH3)3)CH2CH2N(C(CH3)3))

Conditions
ConditionsYield
In diethyl ether byproducts: H2; molar ratio ligand:Al-compd.=1:1, -80°C, then 20°C (1 h); filtration, concn. (vac.), crystn. (-26°C, 7 days); elem. anal.;85%
1,1'-bis(dibromoboryl)ferrocene

1,1'-bis(dibromoboryl)ferrocene

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

1,1'-bis(1,3-di-tert-butyl-1,3,2-diazaborolidinyl)ferrocene
901147-00-0

1,1'-bis(1,3-di-tert-butyl-1,3,2-diazaborolidinyl)ferrocene

Conditions
ConditionsYield
With NEt3 In hexane byproducts: (Et3NH)Br; under dry O2-free N2; soln. (40 ml) of Fe((C5H4)BBr2)2 (7.6 mmol) addedto chilled (0°C) soln. (100 ml) of NEt3 (30.4 mmol); warmed to r oom temp.; neat N,N'-di-tert-butylethane-1,2-diamine (8.00 mmol) added dropwise; refluxed (4 h); filtered; filtrate concd. to dryness; residue dissolved in n-hexane (20 ml); kept (-80°C, 7 d); elem. anal.;85%
With NEt3 In hexane byproducts: Et3NHBr; under Ar or N2 using Schlenk technique; to ferrocene deriv. soln. in hexane at 5°C, added mixt. of amines with stirring at 0°C; stirred for 1 h; ppt. removed by filtration; 50% solvent removed from filtrate in vacuo; recrystd. from hexane at -30°C;78%
N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

trimethylaminealane
16842-00-5

trimethylaminealane

[AlH(CH3)3CNCH2CH2NC(CH3)3]2

[AlH(CH3)3CNCH2CH2NC(CH3)3]2

Conditions
ConditionsYield
In diethyl ether byproducts: H2, NMe3; (argon); addn. at -80°C, warming to ca. 20°C, stirring (1 h); filtration, concn. (vac.), crystn. after 7 d at -26°C; elem. anal.;85%
C8H6Cl2F3OP

C8H6Cl2F3OP

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

1,3-di(tert-butyl)-2-(2,2,2-trifluoro-1-phenylethoxy)-1,3,2-diazaphospholidine

1,3-di(tert-butyl)-2-(2,2,2-trifluoro-1-phenylethoxy)-1,3,2-diazaphospholidine

Conditions
ConditionsYield
With triethylamine In diethyl ether at 20℃; for 2h;84%
N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

boron tribromide
10294-33-4

boron tribromide

2-bromo-1,3-di-tert-butyl-1,3,2-diazaborolidine
869309-50-2

2-bromo-1,3-di-tert-butyl-1,3,2-diazaborolidine

Conditions
ConditionsYield
With triethylamine In hexane under inert atm. soln. BBr3 in hexane was added slowly at 0°C to soln. Et3N on hexane, warmed to room temp., soln. N,N'-di-tert-butylethylenediamine in hexane was added and heated under reflux for 3 h; soln. was filtered and evapd. to dryness; elem. anal.;84%
1,3,5-tris(dibromoboryl)benzene
758695-82-8

1,3,5-tris(dibromoboryl)benzene

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

1,3,5-tris(1,3-di-tert-butyl-1,3,2-diazaborollidinyl)benzene

1,3,5-tris(1,3-di-tert-butyl-1,3,2-diazaborollidinyl)benzene

Conditions
ConditionsYield
Stage #1: 1,3,5-tris(dibromoboryl)benzene With triethylamine In toluene at 0 - 20℃;
Stage #2: N,N'-di-tert-butylethylenediamine In hexane for 3h; Heating;
82%
With Et3N In toluene under Ar; soln. of B compd. in toluene added dropwise to chilled soln. (0°C) of Et3N in toluene; warmed to 20°C; neat (t-BuNHCH2)2added; heated under reflux for 3 h; cooled to room temp.; filtered; filtrate concd.; crystd. at -30°C for 12 h; recrystd. from toluene; elem. anal.;82%
N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

copper(II) acetate monohydrate
6046-93-1

copper(II) acetate monohydrate

[Cu(OAc)2(N,N'-di-tert-butylethylenediamine)]

[Cu(OAc)2(N,N'-di-tert-butylethylenediamine)]

Conditions
ConditionsYield
In ethyl acetate Glovebox; Inert atmosphere;82%
cis-bis(dimethylsulfoxide)dichloroplatinum(II)
15274-33-6

cis-bis(dimethylsulfoxide)dichloroplatinum(II)

N,N'-di-tert-butylethylenediamine
4062-60-6

N,N'-di-tert-butylethylenediamine

cis(PtCl2(t-Bu2en))
114613-17-1

cis(PtCl2(t-Bu2en))

Conditions
ConditionsYield
In methanol slow addn. of educts dissolved in methanol, 65 h stirring at room temp., yellow soln., concn. under reduced pressure, filtration; crystn. by cooling to 0 ° C, filtration, washing (MeOH), drying, elem. anal;80%

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