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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

methyl (E,Z)-2,4-decadienoate

Cas:4493-42-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

2,4-Decadienoic acid,methyl ester, (2E,4Z)-

Cas:4493-42-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2,4-DECADIENOIC ACID METHYL ESTER CAS:4493-42-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality

2,4-DECADIENOIC ACID METHYL ESTER CAS:4493-42-9

Cas:4493-42-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2,4-Decadienoic acid,methyl ester, (2E,4Z)-

Cas:4493-42-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2,4-Decadienoic acid,methyl ester, (2E,4Z)-

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Methyl E, 4-2,4-Decadienoate

Cas:4493-42-9

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2,4-decadienoic Acid Methyl Ester

Cas:4493-42-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2,4-DECADIENOIC ACID METHYL ESTER

Cas:4493-42-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2,4-Decadienoic acid methyl ester

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

2,4-Decadienoic acid,methyl ester, (2E,4Z)-

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as:

Methyl E, 4-2,4-Decadienoate

Cas:4493-42-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2,4-Decadienoic acid,methyl ester, (2E,4Z)-

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

2,4-DECADIENOIC ACID METHYL ESTER China manufacture

Cas:4493-42-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2,4-DECADIENOIC ACID METHYL ESTER

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

4493-42-9

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2,4-DECADIENOIC ACID METHYL ESTER

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Kunming Biohome Technology Co. Ltd.

BIOHOMEAppearance:Colorless?to?pale?yellow?liquid Application:Brown stinkbug (Euschistus servus), Consperse stinkbug (Euschistus conspersus), Dusky stinkbug (Euschistus tristigmus), Green stinkbug (Acrosternum hilare), Six-spot burnet (Zygaena filipe

Methyl E, Z-2,4-Decadienoate

Cas:4493-42-9

Min.Order:0

Negotiable

Type:

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

(2E,4Z)-2,4-Decadienoic Acid Methyl Ester (98%)

Cas:4493-42-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

Zhengzhou Kingorgchem Chemical Technology Co., Ltd. was founded on the basis of Organophosphorus Chemistry Lab of Institute of Chemistry Henan Academy of Sciences in 2015. The laboratory covers 600 m2 and the pilot plant covers 2000 m2. Kingorgchem i

National Research Platform ISO 9001 4493-42-9

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HuBei Ipure Biotech CO.,ltd

HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of pl

2,4-decadienoic Acid Methyl Ester

Cas:4493-42-9

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

U-Chemo Holding Co.,Limited

U-CHEMO Holding Co.,Limited is a very fast developing high-technology enterprise combining with manufacture and sales.U-CHEMO supply high quality products and excellent service to our customers.We make the insect pheromones, censor in the quality con

methyl (E,Z)-2,4-decadienoate

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

2,4-Decadienoic acid,methyl ester, (2E,4Z)-

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 2,4-DECADIENOIC ACID METHYL ESTER, CAS:4493-42-9 with the most competitive price and

2,4-DECADIENOIC ACID METHYL ESTER

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Nanjing Raymon Biotech Co., Ltd.

2,4-decadienoic Acid Methyl Ester Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen

2,4-decadienoic Acid Methyl Ester

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Petrochemical Co.,Ltd

intermediateAppearance:powder/liquid Storage:Normal temperature Package:1kg/25kg/customized Application:intermediate Transportation:By Ship/Air

2E,4Z-10COOMe

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Other

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

4493-42-9

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Debye Scientific

Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen

2,4-Decadienoic acid methyl ester

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemical Co.Ltd

2,4-Decadienoic acid,methyl ester, (2E,4Z)-Appearance:Off white to slight yellow solid Storage:Stored in shaded, cool and dry places Package:1L 5L 10L 25L bottle Application:pharma intermediate Transportation:Handle with cares to avoid damaging the p

2,4-Decadienoic acid,methyl ester, (2E,4Z)-

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Scandinavian Formulas,Inc

more information,pls contact with us!

2,4-Decadienoic acid,methyl ester,(2E,4Z)-

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Transo-Pharm

2,4-Decadienoic acid,methyl ester,(2E,4Z)-

Cas:4493-42-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

n-pentylmagnesium bromide
693-25-4

n-pentylmagnesium bromide

methyl (2E,4Z)-5-chloropenta-2,4-dienoate
38666-08-9

methyl (2E,4Z)-5-chloropenta-2,4-dienoate

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one; iron(III)-acetylacetonate In tetrahydrofuran at 0 - 20℃; for 0.5h; Inert atmosphere;78%
1-Heptyne
628-71-7

1-Heptyne

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

Conditions
ConditionsYield
With carbonylchlorohydridotris(triphenylphosphine)ruthenium (II) In N,N-dimethyl-formamide at 100℃; for 24h; Inert atmosphere; optical yield given as %de; regioselective reaction;69%
methyl (E)-dec-2-en-4-ynoate
118793-68-3, 94133-53-6

methyl (E)-dec-2-en-4-ynoate

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

Conditions
ConditionsYield
With quinoline; methanol; Lindlar's catalyst Hydrogenation;
methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

A

methyl (2Z,4E)-2,4-decadienoate
108965-84-0

methyl (2Z,4E)-2,4-decadienoate

B

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

Conditions
ConditionsYield
In pentane Irradiation; photoisomerization with, or witout iodine;
methyl deca-(2Z)-en-4-ynoate
118793-68-3

methyl deca-(2Z)-en-4-ynoate

A

methyl (2Z,4Z)-2,4-decadienoate
108965-86-2

methyl (2Z,4Z)-2,4-decadienoate

B

methyl (2Z,4E)-2,4-decadienoate
108965-84-0

methyl (2Z,4E)-2,4-decadienoate

C

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

D

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
With quinoline; hydrogen; Lindlar's catalyst In hexane Yield given;
methyl 4-(diethylphosphono)crotonate
67629-62-3

methyl 4-(diethylphosphono)crotonate

hexanal
66-25-1

hexanal

A

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

B

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
With n-butyllithium; diisopropylamine 1.)THF, -78 deg C, 2.) -78 deg C 1 h,; Yield given. Multistep reaction. Yields of byproduct given;
(E)-(2S,3S)-2-Hydroxy-3-trimethylsilanyl-dec-4-enoic acid methyl ester
108965-81-7, 108965-82-8

(E)-(2S,3S)-2-Hydroxy-3-trimethylsilanyl-dec-4-enoic acid methyl ester

A

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

B

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
With potassium hydride In tetrahydrofuran at -78 - -40℃; Yield given. Yields of byproduct given;
propyllithium
2417-93-8

propyllithium

propynoic acid methyl ester
922-67-8

propynoic acid methyl ester

acetylene
74-86-2

acetylene

A

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

B

methyl (2E,4Z,6Z)-2,4,6-decatrienoate
200125-18-4

methyl (2E,4Z,6Z)-2,4,6-decatrienoate

Conditions
ConditionsYield
With copper(I) bromide dimethylsulfide complex 1.) hexane, ether, -30 deg C, 30 min, 2.) ether, -50 - -10 deg C, 1 h, 3.) THF, -78 deg C, 30 min; Yield given. Multistep reaction;
methanol
67-56-1

methanol

commercial ethyl (2E,4Z)-2,4-decadienoate

commercial ethyl (2E,4Z)-2,4-decadienoate

A

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

B

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

C

Me deca-trans-3, trans-5-dienoate
77761-46-7

Me deca-trans-3, trans-5-dienoate

Conditions
ConditionsYield
With sodium methylate Yield given;
methanol
67-56-1

methanol

(2E,4E/4Z)-2,4-Decadienal
1050222-52-0

(2E,4E/4Z)-2,4-Decadienal

A

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

B

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
With manganese(IV) oxide; sodium cyanide; acetic acid at 20℃; for 48h; Title compound not separated from byproducts;
methyl (E)-4-oxo-2-butenoate
5837-72-9

methyl (E)-4-oxo-2-butenoate

hexyltriphenylphosphonium bromide
4762-26-9

hexyltriphenylphosphonium bromide

A

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

B

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
Stage #1: hexyltriphenylphosphonium bromide With sodium amide In tetrahydrofuran for 1h; Heating;
Stage #2: methyl (E)-4-oxo-2-butenoate In tetrahydrofuran for 1h; Wittig reaction; Title compound not separated from byproducts;
(3-methoxycarbonyl-2-propenyl)triphenylphosphonium bromide
72967-11-4

(3-methoxycarbonyl-2-propenyl)triphenylphosphonium bromide

hexanal
66-25-1

hexanal

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

Conditions
ConditionsYield
In tetrahydrofuran at -40℃; for 1.33333h; Wittig condensation;
crotonic acid methyl ester
623-43-8

crotonic acid methyl ester

((C6H5)(CH3)2Si)2CuLi

((C6H5)(CH3)2Si)2CuLi

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: NBS / CCl4 / 12 h / Heating
2: benzene / 70 h / 20 °C
3: tetrahydrofuran / 1.33 h / -40 °C
View Scheme
methyl-4-bromo-2-butenoate
1117-71-1, 56699-18-4, 6000-00-6

methyl-4-bromo-2-butenoate

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: benzene / 70 h / 20 °C
2: tetrahydrofuran / 1.33 h / -40 °C
View Scheme
monofumaraldehyde dimethylacetal monomethylester
32815-00-2

monofumaraldehyde dimethylacetal monomethylester

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 70 percent / aq. p-TsOH / acetone / 1.5 h / Heating
2.1: NaNH2 / tetrahydrofuran / 1 h / Heating
2.2: tetrahydrofuran / 1 h
View Scheme
Hydroxy-acetic acid 1-((E)-2-trimethylsilanyl-vinyl)-hexyl ester
108965-76-0

Hydroxy-acetic acid 1-((E)-2-trimethylsilanyl-vinyl)-hexyl ester

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1.) (Me3Si)2NLi, Me3SiCl / 1.) THF, -78 deg C, 2 h, 1 h to RT, 2 h, RT
2: KH / tetrahydrofuran / -78 - -40 °C
View Scheme
1-Heptyne
628-71-7

1-Heptyne

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 88 percent / Pd(OAc)2, triphenylphosphine, triethylamine / 24 h
2: hydrogen, quinoline / Lindlar catalyst / hexane
View Scheme
(E)-dec-2-en-4-ynoic acid
78651-48-6

(E)-dec-2-en-4-ynoic acid

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
2: Lindlar-catalyst; quinoline; methanol / Hydrogenation
View Scheme
1-Octyn-3-ol
818-72-4

1-Octyn-3-ol

A

methyl (2Z,4Z)-2,4-decadienoate
108965-86-2

methyl (2Z,4Z)-2,4-decadienoate

B

methyl (2Z,4E)-2,4-decadienoate
108965-84-0

methyl (2Z,4E)-2,4-decadienoate

C

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

D

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: propionic acid / 1.5 h / 145 °C
1.2: 2 h / 160 - 170 °C
2.1: aluminum oxide / o-xylene / 2 h / 160 °C / Inert atmosphere
View Scheme
(+/-)-methyl 3,4-decadienoate
1360440-03-4

(+/-)-methyl 3,4-decadienoate

A

methyl (2Z,4Z)-2,4-decadienoate
108965-86-2

methyl (2Z,4Z)-2,4-decadienoate

B

methyl (2Z,4E)-2,4-decadienoate
108965-84-0

methyl (2Z,4E)-2,4-decadienoate

C

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

D

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
With aluminum oxide In o-xylene at 160℃; for 2h; Inert atmosphere;
methyl (E)-dec-2-en-4-ynoate
118793-68-3, 94133-53-6

methyl (E)-dec-2-en-4-ynoate

A

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

B

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
Stage #1: methyl (E)-dec-2-en-4-ynoate With dimethylsulfide borane complex; cyclohexene In tetrahydrofuran at 0 - 20℃; for 2.5h; Inert atmosphere;
Stage #2: With acetic acid In tetrahydrofuran at 50℃; for 2.33333h; Inert atmosphere;
1-Heptyne
628-71-7

1-Heptyne

A

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

B

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: morpholine; iodine / benzene / 21 h / 45 °C
2.1: tetrabutyl-ammonium chloride; palladium diacetate; potassium carbonate / N,N-dimethyl-formamide / 0.08 h / 20 °C / Inert atmosphere
2.2: 4.5 h / 20 °C / Inert atmosphere
3.1: dimethylsulfide borane complex; cyclohexene / tetrahydrofuran / 2.5 h / 0 - 20 °C / Inert atmosphere
3.2: 2.33 h / 50 °C / Inert atmosphere
View Scheme
1-iodo-hept-1-yne
54573-13-6

1-iodo-hept-1-yne

A

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

B

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: tetrabutyl-ammonium chloride; palladium diacetate; potassium carbonate / N,N-dimethyl-formamide / 0.08 h / 20 °C / Inert atmosphere
1.2: 4.5 h / 20 °C / Inert atmosphere
2.1: dimethylsulfide borane complex; cyclohexene / tetrahydrofuran / 2.5 h / 0 - 20 °C / Inert atmosphere
2.2: 2.33 h / 50 °C / Inert atmosphere
View Scheme
acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

1-iodo-1-heptene

1-iodo-1-heptene

A

methyl (2Z,4Z)-2,4-decadienoate
108965-86-2

methyl (2Z,4Z)-2,4-decadienoate

B

methyl (2Z,4E)-2,4-decadienoate
108965-84-0

methyl (2Z,4E)-2,4-decadienoate

C

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

D

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
With tetrabutyl-ammonium chloride; palladium diacetate; potassium carbonate In N,N-dimethyl-formamide at 20℃; for 1h; Heck reaction; Inert atmosphere;
1-Heptene
592-76-7

1-Heptene

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

A

methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

B

methyl (2E,4E)-decadienoate
7328-33-8

methyl (2E,4E)-decadienoate

Conditions
ConditionsYield
With (2S,3S)-N-acetyl-2-amino-3-methylpentanoic acid; sodium acetate; palladium diacetate; silver carbonate In N,N-dimethyl acetamide at 60℃; for 48h; Overall yield = 63 %; stereoselective reaction;A n/a
B n/a
methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

(2E,4Z)-2,4-decadien-1-ol
16195-71-4

(2E,4Z)-2,4-decadien-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; diethyl ether
methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

(2E,4Z)-decadienoic acid
544-48-9

(2E,4Z)-decadienoic acid

Conditions
ConditionsYield
With potassium hydroxide
methyl (2E,4Z)-deca-2,4-dienoate
4493-42-9

methyl (2E,4Z)-deca-2,4-dienoate

2E,4Z-decadienic acid-N-isobutylamide
639086-18-3

2E,4Z-decadienic acid-N-isobutylamide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: methanol. KOH-solution
2: oxalyl chloride; benzene / Behandeln des Reaktionsprodukts mit Isobutylamin und Aether
View Scheme

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