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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

methyl 2,4-dihydroxy-6-pentylbenzoate CAS NO.58016-28-7

Cas:58016-28-7

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: methyl 2,4-dihydroxy-6-pentylbenzoate Synonyms: methyl 2,4-dihydroxy-6-pentylbenzoate;Methyl olivetolate;methyl 2,4-dihydroxy-6-pentylbenzoate58016-28-7;Olivetol Methyl Ester;Methyl olivetolate Other Name Methyl 2,4-dihydroxy-6-pe

methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:1 Gram

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Hangzhou Keyingchem Co.,Ltd

Hangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global pharmaceutical,

METHYL 2,4-DIHYDROXY-6-PENTYLBENZOATE

Cas:58016-28-7

Min.Order:1 Metric Ton

FOB Price: $3.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Off-white to yellow or Khaki powder Storage:cool dry place Package:1kg/foil bag;25kg/drum Application:pharmaceutic

Manufacturer high quality methyl 2,4-dihydroxy-6-pentylbenzoate Cas 58016-28-7 with good price

Cas:58016-28-7

Min.Order:1 Kilogram

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Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:1

Negotiable

Type:Other

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥98% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can

methyl 2,4-dihydroxy-6-pentylbenzoate CAS:58016-28-7

Cas:58016-28-7

Min.Order:1 Metric Ton

FOB Price: $1150.0 / 1250.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 58016-28-7 with competitive price

Cas:58016-28-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoic acid, 2,4-dihydroxy-6-pentyl-, methyl ester 58016-28-7

Cas:58016-28-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

methyl 2,4-dihydroxy-6-pentylbenzoate CAS:58016-28-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qua

methyl 2,4-dihydroxy-6-pentylbenzoate CAS:58016-28-7

Cas:58016-28-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzoic acid, 2,4-dihydroxy-6-pentyl-, methyl ester

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Zenuo Biological Medicine Technology Co Ltd

Product Name: methyl 2,4-dihydroxy-6-pentylbenzoate Synonyms: methyl 2,4-dihydroxy-6-pentylbenzoate;Methyl olivetolate;methyl 2,4-dihydroxy-6-pentylbenzoate58016-28-7;Olivetol Methyl Ester CAS: 58016-28-7 MF: C13H18O4 MW: 238.29 EINECS:

methyl 2,4-dihydroxy-6-pentylbenzoate Manufactory best quality

Cas:58016-28-7

Min.Order:100 Gram

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Triumph International Development Limilted

Appearance:solid or liquid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:for pharma use Transportation:Common products:Sea/Air/Courier Dangerous Chem:Sea/Air Po

Benzoic acid, 2,4-dihydroxy-6-pentyl-, methyl ester

Cas:58016-28-7

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als

methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: 2,4-Dihydroxy-6-Propyl-Benzoic Acid Methyl Ester CAS No.:58016-28-7 Molecule Formula:C13H18O4 Molecule Weight:238.28 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard

Best Quality 2,4-Dihydroxy-6-Propyl-Benzoic Acid Methyl Ester

Cas:58016-28-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Methyl 2,4-dihydroxy-6-pentylbenzoate cas no. 58016-28-7 98%

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Benzoic acid, 2,4-dihydroxy-6-pentyl-, methyl ester

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Our own factory produces direct sales with absolute price advantage Application:Pharmaceutical industry Transportation:By sea Port:Shanghai/tianjin

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

Methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Guangdong Juda Chemical Industrial Co.,Limited

Factory supply high purity low priceAppearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

Methyl 2,4-dihydroxy-6-pentylbenzoate CAS No.58016-28-7

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Trading Company

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Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:White to Off-White Solid Storage:Keep it in dry,shady and cool place Package:as your requirement Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by Sea

methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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DB BIOTECH CO., LTD

best seller Application:API

methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Trading Company

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

Trimeric sodium phosphate detergent auxiliary agent is a kind of excellent properties, is one of the biggest component of detergent consumption during the production, it has four aspects: 1, chelation of heavy metal ions, heavy metal ions in the wate

methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Bright Chemical Co., Ltd.

best seller Application:API

methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Other

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Shanghai Terui OP New Material Technology Co., Ltd.

The factory supplies Application:manufacturing supplies

Benzoicacid,2,4-dihydroxy-6-pentyl-,methylester

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

58016-28-7

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Muhuang Technology Co., Ltd

best seller Application:API

methyl 2,4-dihydroxy-6-pentylbenzoate

Cas:58016-28-7

Min.Order:0

Negotiable

Type:Trading Company

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Synthetic route

1,3-bis(trimethylsiloxy)-1-methoxybuta-1,3-diene
74590-73-1

1,3-bis(trimethylsiloxy)-1-methoxybuta-1,3-diene

(2-Pentyl-[1,3]dioxolan-2-yl)-acetyl chloride
83578-33-0

(2-Pentyl-[1,3]dioxolan-2-yl)-acetyl chloride

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
With titanium tetrachloride In dichloromethane55%
1-(1-imidazolyl)-1-hexanone
60988-34-3

1-(1-imidazolyl)-1-hexanone

1,3,5-tris(trimethylsiloxy)-1-methoxyhexa-1,3,5-triene
102342-54-1

1,3,5-tris(trimethylsiloxy)-1-methoxyhexa-1,3,5-triene

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
With titanium(IV) isopropylate; titanium tetrachloride In dichloromethane 1.) -78 deg C, 5 h, 2.) RT, overnight;52%
N,N-dimethylhexanamide
5830-30-8

N,N-dimethylhexanamide

3,5-dioxohexanoic acid methyl ester
29736-80-9

3,5-dioxohexanoic acid methyl ester

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran at -20℃; for 5h;36%
Hexanoyl chloride
142-61-0

Hexanoyl chloride

1,3,5-tris(trimethylsiloxy)-1-methoxyhexa-1,3,5-triene
102342-54-1

1,3,5-tris(trimethylsiloxy)-1-methoxyhexa-1,3,5-triene

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
With titanium(IV) isopropylate; titanium tetrachloride In dichloromethane 1.) -78 deg C, 2-3 h, 2.) RT, overnight;21%
2,4-nonanedione
6175-23-1

2,4-nonanedione

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
With sodium hydride; lithium diisopropyl amide In tetrahydrofuran; hexane for 48h; Heating;10%
2,4-dihydroxy-6-pentylbenzoic acid
491-72-5

2,4-dihydroxy-6-pentylbenzoic acid

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
With diethyl ether
methanol
67-56-1

methanol

anziaic acid
641-68-9

anziaic acid

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

N,N-dimethylhexanamide
5830-30-8

N,N-dimethylhexanamide

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

acetylacetone
123-54-6

acetylacetone

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
Yield given. Multistep reaction;
anziaic acid methyl ester

anziaic acid methyl ester

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
With sulfuric acid
2-hydroxy-4-(2-hydroxy-4-methoxy-6-pentylbenzoyloxy)-6-pentylbenzoic acid
529-47-5

2-hydroxy-4-(2-hydroxy-4-methoxy-6-pentylbenzoyloxy)-6-pentylbenzoic acid

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: methanol. KOH-solution
2: diethyl ether
View Scheme
2,4-dihydroxy-6-pentylbenzaldehyde
855875-40-0

2,4-dihydroxy-6-pentylbenzaldehyde

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: acetone; pyridine / Erwaermen des Reaktionsprodukts mit Kaliumpermanganat in wss. Aceton
2: aqueous ammonia
3: diethyl ether
View Scheme
2,4-bis-ethoxycarbonyloxy-6-pentyl-benzoic acid

2,4-bis-ethoxycarbonyloxy-6-pentyl-benzoic acid

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous ammonia
2: diethyl ether
View Scheme
(E)-non-3-en-2-one
18402-83-0

(E)-non-3-en-2-one

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
Stage #1: (E)-non-3-en-2-one; malonic acid dimethyl ester With sodium In methanol at 0℃; for 8h; Reflux;
Stage #2: With bromine In N,N-dimethyl-formamide at 0 - 80℃; for 17h;
Stage #1: (E)-non-3-en-2-one; malonic acid dimethyl ester With sodium In methanol for 8h; Reflux;
Stage #2: With bromine In N,N-dimethyl-formamide at 0 - 80℃; for 17h;
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Olivetol
500-66-3

Olivetol

Conditions
ConditionsYield
With water; potassium hydroxide at 50 - 100℃;94%
4-dimethylamino-1-butanol
13330-96-6

4-dimethylamino-1-butanol

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

C18H29NO4

C18H29NO4

Conditions
ConditionsYield
With potassium hydroxide at 130℃; for 4h; Inert atmosphere;83%
6-(N,N-dimethylamino)-1-hexanol
1862-07-3

6-(N,N-dimethylamino)-1-hexanol

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

C20H33NO4

C20H33NO4

Conditions
ConditionsYield
With potassium hydroxide at 130℃; for 4h; Inert atmosphere;81%
2-(dipropylamino)ethanol
3238-75-3

2-(dipropylamino)ethanol

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

C20H33NO4

C20H33NO4

Conditions
ConditionsYield
With potassium hydroxide at 130℃; for 4h; Inert atmosphere;81%
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

benzyl bromide
100-39-0

benzyl bromide

methyl 4-benzyloxy-2-hydroxy-6-pentylbenzoate
94103-01-2

methyl 4-benzyloxy-2-hydroxy-6-pentylbenzoate

Conditions
ConditionsYield
With potassium carbonate In acetone for 24h; Heating;77%
With potassium carbonate In acetone for 22h; Heating;43%
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol
861892-40-2

(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol

methyl (1'R,2'R)-2,6-dihydroxy-5'-methyl-4-pentyl-2'-(prop-1 -en-2- yl)-1',2',3',4'-tetrahydro-[1,1'-biphenyl]-3-carboxylate
55658-71-4

methyl (1'R,2'R)-2,6-dihydroxy-5'-methyl-4-pentyl-2'-(prop-1 -en-2- yl)-1',2',3',4'-tetrahydro-[1,1'-biphenyl]-3-carboxylate

Conditions
ConditionsYield
Stage #1: methyl 2,6-dihydroxy-6-pentylbenzoate; (4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol With boron trifluoride diethyl etherate In chlorobenzene at 22℃;
Stage #2: With sodium hydrogencarbonate In chlorobenzene at 20℃; for 0.333333h;
70%
With boron trifluoride diethyl etherate In chlorobenzene at 20℃; for 1h; Reagent/catalyst; Temperature; Solvent;70%
Stage #1: methyl 2,6-dihydroxy-6-pentylbenzoate; (4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol With boron trifluoride diethyl etherate In chlorobenzene at 22℃; Flow reactor;
Stage #2: With sodium hydrogencarbonate In chlorobenzene at 22℃; for 0.333333h;
With boron trifluoride diethyl etherate In chlorobenzene at 20℃; for 1h; Solvent;
2-(N,N-dimethylamino)ethanol
108-01-0

2-(N,N-dimethylamino)ethanol

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

C16H25NO4

C16H25NO4

Conditions
ConditionsYield
With potassium hydroxide at 130℃; for 4h; Inert atmosphere;70%
(1S,4R)-p-mentha-2,8-dien-1-ol
22972-51-6

(1S,4R)-p-mentha-2,8-dien-1-ol

methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

Methyl tetrahydrocannabinolate
16850-65-0

Methyl tetrahydrocannabinolate

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; magnesium sulfate In dichloromethane at 0℃; for 1.5h;55%
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

2-hydroxy-4-methoxy-6-pentylbenzoic acid
52189-68-1

2-hydroxy-4-methoxy-6-pentylbenzoic acid

Conditions
ConditionsYield
With potassium carbonate; methyl iodide weiteres Reagens: Aceton; Behandeln des Reaktionsprodukts mit wss. Alkalilauge;
With silver(l) oxide; methyl iodide weiteres Reagens: Aceton; Behandeln des Reaktionsprodukts mit wss. Alkalilauge;
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

isopropyl bromide
75-26-3

isopropyl bromide

methyl 2-hydroxy-4-isopropyloxy-6-pentylbenzoate
78135-63-4

methyl 2-hydroxy-4-isopropyloxy-6-pentylbenzoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide for 24h; Heating;15.7 g
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

methyl 4-benzyloxy-2,5-dihydroxy-6-pentylbenzoate
113487-78-8

methyl 4-benzyloxy-2,5-dihydroxy-6-pentylbenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 43 percent / potassium carbonate / acetone / 22 h / Heating
2: 19 percent / potassium persulfate, 20percent sodium hydroxide, dimethyl sulfoxide / 24 h / 10 - 20 °C
View Scheme
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

8-hydroxy-3-methoxy-6-pentyl-1propyl-11-oxo-11H-dibenzo<1,4>dioxepin-7-carboxylic acid (stenosporonic acid)
103538-04-1

8-hydroxy-3-methoxy-6-pentyl-1propyl-11-oxo-11H-dibenzo<1,4>dioxepin-7-carboxylic acid (stenosporonic acid)

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1: 43 percent / potassium carbonate / acetone / 22 h / Heating
2: 19 percent / potassium persulfate, 20percent sodium hydroxide, dimethyl sulfoxide / 24 h / 10 - 20 °C
3: 76 percent / trifluofoacetic anhydride / toluene / 2 h / Ambient temperature
4: 13 percent / potassium carbonate / dimethylsulfoxide / 75 - 76 °C
5: 36 percent / potassium hydroxide / dimethylsulfoxide / 8 h / 90 - 95 °C
6: 98 percent / H2 / 10percent Pd/C / ethyl acetate / 15 h
7: 26 percent / trifluoroacetic anhydride / toluene / 2 h / Ambient temperature
View Scheme
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

2-(5'-carboxy-2',4'-dihydro-6'-pentylphenoxy)-4-methoxy-6-propylbenzoic acid
113487-85-7

2-(5'-carboxy-2',4'-dihydro-6'-pentylphenoxy)-4-methoxy-6-propylbenzoic acid

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: 43 percent / potassium carbonate / acetone / 22 h / Heating
2: 19 percent / potassium persulfate, 20percent sodium hydroxide, dimethyl sulfoxide / 24 h / 10 - 20 °C
3: 76 percent / trifluofoacetic anhydride / toluene / 2 h / Ambient temperature
4: 13 percent / potassium carbonate / dimethylsulfoxide / 75 - 76 °C
5: 36 percent / potassium hydroxide / dimethylsulfoxide / 8 h / 90 - 95 °C
6: 98 percent / H2 / 10percent Pd/C / ethyl acetate / 15 h
View Scheme
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

methyl 4-benzyloxy-3-(2'-hydroxy-4'-methoxy-6'-propylbenzoyloxy)-6-hydroxy-2-pentylbenzoate
113487-80-2

methyl 4-benzyloxy-3-(2'-hydroxy-4'-methoxy-6'-propylbenzoyloxy)-6-hydroxy-2-pentylbenzoate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 43 percent / potassium carbonate / acetone / 22 h / Heating
2: 19 percent / potassium persulfate, 20percent sodium hydroxide, dimethyl sulfoxide / 24 h / 10 - 20 °C
3: 76 percent / trifluofoacetic anhydride / toluene / 2 h / Ambient temperature
View Scheme
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

2-(2'-benzyloxy-5'-carboxy-4'-hydroxy-6'-pentylphenoxy)-4-methoxy-6-propylbenzoic acid
113500-97-3

2-(2'-benzyloxy-5'-carboxy-4'-hydroxy-6'-pentylphenoxy)-4-methoxy-6-propylbenzoic acid

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 43 percent / potassium carbonate / acetone / 22 h / Heating
2: 19 percent / potassium persulfate, 20percent sodium hydroxide, dimethyl sulfoxide / 24 h / 10 - 20 °C
3: 76 percent / trifluofoacetic anhydride / toluene / 2 h / Ambient temperature
4: 13 percent / potassium carbonate / dimethylsulfoxide / 75 - 76 °C
5: 36 percent / potassium hydroxide / dimethylsulfoxide / 8 h / 90 - 95 °C
View Scheme
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

2-(2'-benzyloxy-4'-hydroxy-5'-mrthoxycarbonyl-6'-pentylphenoxy)-4-methoxy-6-propylbenzoic acid
113487-82-4

2-(2'-benzyloxy-4'-hydroxy-5'-mrthoxycarbonyl-6'-pentylphenoxy)-4-methoxy-6-propylbenzoic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 43 percent / potassium carbonate / acetone / 22 h / Heating
2: 19 percent / potassium persulfate, 20percent sodium hydroxide, dimethyl sulfoxide / 24 h / 10 - 20 °C
3: 76 percent / trifluofoacetic anhydride / toluene / 2 h / Ambient temperature
4: 13 percent / potassium carbonate / dimethylsulfoxide / 75 - 76 °C
View Scheme
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

methyl 4-benzyloxy-3-formyl-6-methoxy-2-pentylbenzoate
122849-76-7

methyl 4-benzyloxy-3-formyl-6-methoxy-2-pentylbenzoate

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 15.7 g / K2CO3 / dimethylformamide / 24 h / Heating
2: 15.7 g / K2CO3 / acetone / 20 h / Heating
3: tin(IV) chloride / CH2Cl2 / 4 h / 0 °C
4: 7.3 g / TiCl4 / CH2Cl2 / 3 h / 0 °C
5: 10.3 g / K2CO3 / dimethylformamide / 18 h / Ambient temperature
View Scheme
Multi-step reaction with 3 steps
1: 77 percent / potassium carbonate / acetone / 24 h / Heating
2: 89 percent / potassium carbonate / acetone / Heating
3: 80 percent / phosphoryl chloride / 24 h / 70 °C
View Scheme
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

6-benzyloxy-4-methoxy-3-methoxycarbonyl-2-pentylbenzoic acid
78135-68-9

6-benzyloxy-4-methoxy-3-methoxycarbonyl-2-pentylbenzoic acid

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: 15.7 g / K2CO3 / dimethylformamide / 24 h / Heating
2: 15.7 g / K2CO3 / acetone / 20 h / Heating
3: tin(IV) chloride / CH2Cl2 / 4 h / 0 °C
4: 7.3 g / TiCl4 / CH2Cl2 / 3 h / 0 °C
5: 10.3 g / K2CO3 / dimethylformamide / 18 h / Ambient temperature
6: 7.5 g / tetrabutylammonium permanganate, pyridine / 5 h
View Scheme
Multi-step reaction with 4 steps
1: 77 percent / potassium carbonate / acetone / 24 h / Heating
2: 89 percent / potassium carbonate / acetone / Heating
3: 80 percent / phosphoryl chloride / 24 h / 70 °C
4: 97 percent / sodium chlorite, sulphamic acid / H2O; dioxane / 0.67 h
View Scheme
methyl 2,4-dihydroxy-6-pentylbenzoate
58016-28-7

methyl 2,4-dihydroxy-6-pentylbenzoate

methyl 3-(2,4-dihydroxy-6-pentylbenzoyl)-4-hydroxy-6-methoxy-2-pentylbenzoate
78135-69-0

methyl 3-(2,4-dihydroxy-6-pentylbenzoyl)-4-hydroxy-6-methoxy-2-pentylbenzoate

Conditions
ConditionsYield
Multi-step reaction with 8 steps
1: 15.7 g / K2CO3 / dimethylformamide / 24 h / Heating
2: 15.7 g / K2CO3 / acetone / 20 h / Heating
3: tin(IV) chloride / CH2Cl2 / 4 h / 0 °C
4: 7.3 g / TiCl4 / CH2Cl2 / 3 h / 0 °C
5: 10.3 g / K2CO3 / dimethylformamide / 18 h / Ambient temperature
6: 7.5 g / tetrabutylammonium permanganate, pyridine / 5 h
7: trifluoroacetic anhydride / CH2Cl2 / 2 h / Ambient temperature
8: 3.65 g / H2
View Scheme

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