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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Dioctyl ether

Cas:629-82-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:Whit

n-Octyl Ether

Cas:629-82-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Dioctyl ether

Cas:629-82-3

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory price Cosmetic DICAPRYLYL ETHER 629-82-3 Manufacturer

Cas:629-82-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Dioctyl ether

Cas:629-82-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

DIOCTYL ETHER

Cas:629-82-3

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 629-82-3 with best quality

Cas:629-82-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS 629-82-3 ,DIOCTYL ETHER

Cas:629-82-3

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Dioctyl ether 629-82-3

Cas:629-82-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

DIOCTYL ETHER CAS:629-82-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates

DIOCTYL ETHER CAS:629-82-3

Cas:629-82-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Dioctyl ether

Cas:629-82-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Dioctyl ether

Cas:629-82-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Dioctyl Ether

Cas:629-82-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

DIOCTYL ETHER

Cas:629-82-3

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediat

Dioctyl ether

Cas:629-82-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name:DIOCTYL ETHERSynonyms:1-(Octyloxy)octane;1,1’-oxybis-octan;1,1’-oxybisoctane;Antar;Caprylic ether;caprylicether;di-n-octyl-ethe;Ether, di-n-octyl-CAS:629-82-3MF:C16H34OMW:242.44EINECS:211-112-6Product Categories:Building B

TIANFUCHEM--629-82-3--DIOCTYL ETHER

Cas:629-82-3

Min.Order:1 Metric Ton

FOB Price: $10.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity Dioctyl ether

Cas:629-82-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Top Purity Dioctyl ether

Cas:629-82-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

DIOCTYL ETHER

Cas:629-82-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Dioctyl ether

Cas:629-82-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

DIOCTYL ETHER

Cas:629-82-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

DIOCTYL ETHER

Cas:629-82-3

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

Dioctyl ether

Cas:629-82-3

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

DIOCTYL ETHER

Cas:629-82-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

N-Octyl Ether

Cas:629-82-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

octyl ether

Cas:629-82-3

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Octane, 1,1'-oxybis-

Cas:629-82-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Dioctyl Ether

Cas:629-82-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

Dioctyl ether

Cas:629-82-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

Dioctyl ether

Cas:629-82-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

N-Methylformamide
123-39-7

N-Methylformamide

A

octanol
111-87-5

octanol

B

di-n-octyl ether
629-82-3

di-n-octyl ether

C

octyl formate
112-32-3

octyl formate

D

N-methylmethanimidamide hydroiodide

N-methylmethanimidamide hydroiodide

Conditions
ConditionsYield
With 1-Iodooctane at 146℃;A n/a
B n/a
C n/a
D 100%
N-Methylformamide
123-39-7

N-Methylformamide

A

octanol
111-87-5

octanol

B

di-n-octyl ether
629-82-3

di-n-octyl ether

C

octyl formate
112-32-3

octyl formate

D

N-methylmethanimidamide hydrobromide

N-methylmethanimidamide hydrobromide

Conditions
ConditionsYield
With 1-bromo-octane at 146℃;A n/a
B n/a
C n/a
D 100%
octanol
111-87-5

octanol

1-bromo-octane
111-83-1

1-bromo-octane

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With potassium hydroxide; aliquat 366 In neat (no solvent) at 20℃; for 2h;98%
With potassium hydroxide; tetrabutylammomium bromide; potassium carbonate at 158℃; for 0.0152778h;90%
With sodium In xylene
Octanal
124-13-0

Octanal

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With Dimethylphenylsilane In 1,1,2,2-tetrachloroethane at 100℃; for 3h;98%
With hydrogen; Pd-C93%
With triethylsilane; bismuth(III) bromide In acetonitrile for 2h; Ambient temperature;88%
With Dimethylphenylsilane In 1,1,2,2-tetrachloroethane at 100℃; for 3h; chemoselective reaction;
octanol
111-87-5

octanol

Octanal
124-13-0

Octanal

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal at 160℃; under 760 Torr; for 18h; Etherification;97%
With hydrogen; palladium on activated charcoal at 160℃; for 10h; atmospheric pressure;97%
With Pd/Al2O3; hydrogen; ethyl iodide at 60℃; under 15001.5 Torr; for 15h; Sealed tube;
octanol
111-87-5

octanol

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With yttrium iron garnet In neat (no solvent) at 80℃; for 0.25h; Green chemistry;93%
With C19H26IrN3O2(2+)*2C2F6NO4S2(1-); hydrogen In toluene at 160℃; for 20h; Reagent/catalyst; Temperature;90%
With boron tri(hydrogen sulphate); silica gel at 60℃; for 0.116667h; Neat (no solvent);87%
trimethyl phosphite
512-56-1

trimethyl phosphite

octanol
111-87-5

octanol

A

1-methoxyoctane
929-56-6

1-methoxyoctane

B

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With bismuth(lll) trifluoromethanesulfonate In neat (no solvent) at 100℃; Reagent/catalyst;A 91%
B 6%
octanol
111-87-5

octanol

benzyl alcohol
100-51-6

benzyl alcohol

A

di-n-octyl ether
629-82-3

di-n-octyl ether

B

dibenzyl ether
103-50-4

dibenzyl ether

C

((octyloxy)methyl)benzene
54852-64-1

((octyloxy)methyl)benzene

Conditions
ConditionsYield
With copper acetylacetonate; carbon tetrabromide at 150℃; for 8h; Inert atmosphere; Sealed tube;A 10%
B 18%
C 82%
trimethyl(oct-1-yloxy)silane
14246-16-3

trimethyl(oct-1-yloxy)silane

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With sulfuric acid; silica gel In hexane at 20℃; for 0.25h;80%
With Nafion-H(R) In hexane at 20℃; for 0.333333h;80%
carbon-based solid acid In hexane at 20℃; for 0.133333h;80%
1-Chlorooctane
111-85-3

1-Chlorooctane

A

octanol
111-87-5

octanol

B

1-Fluoro-octane
463-11-6

1-Fluoro-octane

C

oct-1-ene
111-66-0

oct-1-ene

D

di-n-octyl ether
629-82-3

di-n-octyl ether

E

octyl formate
112-32-3

octyl formate

Conditions
ConditionsYield
With potassium fluoride; formamide; tetrabutylammomium bromide at 120℃; for 72h; Mechanism; Product distribution; vari. of proportion of reagents, time, also with chlorure de benzyl and chlorure de phenethyl;A 8%
B 72%
C 4%
D 4%
E 4%
With potassium fluoride In formamide at 120℃; for 3h; Product distribution; effect of change water to formamide as solvent, reaction time, effect of molar ratio of KF/HCONH2;A 8.0 % Chromat.
B 72.3 % Chromat.
C 4.5 % Chromat.
D 4.3 % Chromat.
E 3.7 % Chromat.
1-Chlorooctane
111-85-3

1-Chlorooctane

A

octanol
111-87-5

octanol

B

1-Fluoro-octane
463-11-6

1-Fluoro-octane

C

di-n-octyl ether
629-82-3

di-n-octyl ether

D

octyl formate
112-32-3

octyl formate

Conditions
ConditionsYield
With potassium fluoride; formamide; tetrabutylammomium bromide at 120℃; for 72h; Further byproducts given;A 72%
B 72%
C 4%
D 4%
With potassium fluoride; formamide; tetrabutylammomium bromide at 120℃; for 72h; Further byproducts given;A 8%
B 72%
C 4%
D 4%
With potassium fluoride; formamide; tetrabutylammomium bromide at 120℃; for 72h; Further byproducts given;A 8%
B 72%
C 72%
D 4%
With potassium fluoride; formamide; tetrabutylammomium bromide at 120℃; for 72h; Further byproducts given;A 8%
B 72%
C 4%
D 72%
4-tetrahydrofuran-2-yl-butan-2-ol
3208-43-3, 4527-76-8

4-tetrahydrofuran-2-yl-butan-2-ol

A

octanol
111-87-5

octanol

B

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With hydrogen; 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide at 150℃; under 90009 Torr; for 4h; Autoclave;A 29%
B 66%
With 2.5% Ru/[BSO3BIM][NTf2]; hydrogen at 150℃; under 90009 Torr; for 15h; Reagent/catalyst;A 44.9%
B 26.1%
With 5% active carbon-supported ruthenium; hydrogen at 150℃; under 60006 Torr; for 6h; Reagent/catalyst; Autoclave;
4-tetrahydrofuran-2-yl-butan-2-ol
3208-43-3, 4527-76-8

4-tetrahydrofuran-2-yl-butan-2-ol

ruthenium nanoparticles immobilized onto acidic supported ionic liquid phase

ruthenium nanoparticles immobilized onto acidic supported ionic liquid phase

A

octanol
111-87-5

octanol

B

ethyl octyl ether
929-61-3

ethyl octyl ether

C

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With hydrogen; 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide at 150℃; under 90009 Torr; for 4h; Autoclave;A 25%
B 7%
C 66%
n-octyl triflate
71091-89-9

n-octyl triflate

dicyclohexylammonium α-cyanoacrylate

dicyclohexylammonium α-cyanoacrylate

A

n-octyl 2-cyanoacrylate

n-octyl 2-cyanoacrylate

B

di-n-octyl ether
629-82-3

di-n-octyl ether

C

CHF3O3S*C12H23N
1215021-90-1

CHF3O3S*C12H23N

D

octyl 2-cyanoacetate
15666-97-4

octyl 2-cyanoacetate

E

2-cyanoacrylic acid
15802-18-3

2-cyanoacrylic acid

Conditions
ConditionsYield
With trifluoroacetic acid In dichloromethane at 22℃; Product distribution / selectivity;A 65%
B n/a
C n/a
D n/a
E n/a
octanol
111-87-5

octanol

A

trans-4-Octene
14850-23-8

trans-4-Octene

B

(E)-3-octene
14919-01-8

(E)-3-octene

C

trans-2-Octene
13389-42-9

trans-2-Octene

D

oct-1-ene
111-66-0

oct-1-ene

E

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
Act Alu at 270℃; Product distribution; various temperatures, also using Act Alu Cl and Alu C Cl as catalysts;A n/a
B n/a
C n/a
D n/a
E 60%
4-tetrahydrofuran-2-yl-butan-2-ol
3208-43-3, 4527-76-8

4-tetrahydrofuran-2-yl-butan-2-ol

A

2-propyltetrahydropyran
3857-17-8, 113611-56-6

2-propyltetrahydropyran

B

octanol
111-87-5

octanol

C

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With hydrogen; 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide at 150℃; under 90009 Torr; for 4h; Autoclave;A 6%
B 28%
C 60%
4-tetrahydrofuran-2-yl-butan-2-ol
3208-43-3, 4527-76-8

4-tetrahydrofuran-2-yl-butan-2-ol

A

2-butanyltetrahydrofuran
1004-29-1

2-butanyltetrahydrofuran

B

octanol
111-87-5

octanol

C

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With ruthenium-carbon composite; 1-(4-butylcarboxylic acid)-3-(n-butyl)-imidazolium bis(trifluoromethylsulfonyl)imide; hydrogen at 150℃; under 90009 Torr; for 15h; Reagent/catalyst; Ionic liquid;A 58.6%
B 27.1%
C 9.1%
With 1-(4-butylcarboxylic acid)-3-(n-butyl)-imidazolium bis(trifluoromethylsulfonyl)imide; hydrogen at 150℃; under 90009 Torr; for 15h; Reagent/catalyst; Ionic liquid;A 25.8%
B 44.9%
C 26.1%
With N,N,N-tributyl-1-(4-butylsulfonic acid)-aminium bis(trifluoromethylsulfonyl)imide; hydrogen at 150℃; under 90009 Torr; for 15h; Reagent/catalyst; Ionic liquid;A 11.7%
B 41.5%
C 34.5%
With 5 wt% ruthenium/carbon; hydrogen at 150℃; under 90009 Torr; for 15h; Ionic liquid;
1-bromo-octane
111-83-1

1-bromo-octane

potassium octylate
56281-85-7

potassium octylate

A

oct-1-ene
111-66-0

oct-1-ene

B

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With Aliquat 336 at 100℃; for 7h;A 35%
B 57%
4-(furan-2-yl)but-3-en-2-one
623-15-4

4-(furan-2-yl)but-3-en-2-one

A

octane
111-65-9

octane

B

octanol
111-87-5

octanol

C

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
Stage #1: 4-(furan-2-yl)but-3-en-2-one With ruthenium-carbon composite; hydrogen; toluene-4-sulfonic acid at 120℃; under 90009 Torr; for 2h;
Stage #2: With hydrogen at 150℃; under 90009 Torr; for 45h; Reagent/catalyst; Acidic conditions; Ionic liquid;
A 16.9%
B 18.1%
C 53%
Stage #1: 4-(furan-2-yl)but-3-en-2-one With ruthenium-carbon composite; hydrogen at 120℃; under 90009 Torr; for 2h;
Stage #2: With toluene-4-sulfonic acid at 150℃; under 90009 Torr; for 45h; Ionic liquid;
A 16.9%
B 18.1%
C 53%
4-tetrahydrofuran-2-yl-butan-2-ol
3208-43-3, 4527-76-8

4-tetrahydrofuran-2-yl-butan-2-ol

A

2-butanyltetrahydrofuran
1004-29-1

2-butanyltetrahydrofuran

B

octane
111-65-9

octane

C

octanol
111-87-5

octanol

D

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With ruthenium-carbon composite; hydrogen; toluene-4-sulfonic acid at 150℃; under 90009 Torr; for 15h; Reagent/catalyst;A 8.7%
B 8.5%
C 24.7%
D 51.9%
4-tetrahydrofuran-2-yl-butan-2-ol
3208-43-3, 4527-76-8

4-tetrahydrofuran-2-yl-butan-2-ol

A

octane
111-65-9

octane

B

octanol
111-87-5

octanol

C

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With 5% active carbon-supported ruthenium; hydrogen; toluene-4-sulfonic acid at 150℃; under 90009 Torr; for 15h;A 8.5%
B 24.7%
C 51.9%
4-(furan-2-yl)but-3-en-2-one
623-15-4

4-(furan-2-yl)but-3-en-2-one

A

2-methyl-5-propyl-tetrahydrofuran
3214-40-2

2-methyl-5-propyl-tetrahydrofuran

B

octane
111-65-9

octane

C

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With palladium/alumina; niobium phosphate; hydrogen In cyclohexane at 170℃; under 15001.5 Torr; for 24h; Inert atmosphere;A 16%
B 51%
C 20%
4-(furan-2-yl)but-3-en-2-one
623-15-4

4-(furan-2-yl)but-3-en-2-one

A

2-butanyltetrahydrofuran
1004-29-1

2-butanyltetrahydrofuran

B

octanol
111-87-5

octanol

C

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
Stage #1: 4-(furan-2-yl)but-3-en-2-one With ruthenium-carbon composite; 1-(4-butylcarboxylic acid)-3-(n-butyl)-imidazolium bis(trifluoromethylsulfonyl)imide; hydrogen at 120℃; under 90009 Torr; for 2h; Ionic liquid;
Stage #2: With hydrogen at 150℃; under 90009 Torr; for 45h; Reagent/catalyst; Acidic conditions; Ionic liquid;
A 5.4%
B 48.4%
C 44.2%
Stage #1: 4-(furan-2-yl)but-3-en-2-one With 5 wt% ruthenium/carbon; hydrogen at 120℃; under 90009 Torr; for 2h;
Stage #2: With hydrogen at 150℃; under 90009 Torr; for 60h; Ionic liquid;
4-(furan-2-yl)but-3-en-2-one
623-15-4

4-(furan-2-yl)but-3-en-2-one

A

octanol
111-87-5

octanol

B

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
Stage #1: 4-(furan-2-yl)but-3-en-2-one With ruthenium-carbon composite; hydrogen at 120℃; under 90009 Torr; for 2h;
Stage #2: With 4-(3'-butyl-1'-imidazolio)-1-butanesulfonic acid bis(trifluoromethylsulfonyl)imidide at 150℃; under 90009 Torr; for 45h; Time; Ionic liquid;
A 48.4%
B 44.2%
Stage #1: 4-(furan-2-yl)but-3-en-2-one With 5 wt% ruthenium/carbon; hydrogen at 120℃; under 90009 Torr; for 2h;
Stage #2: With hydrogen at 150℃; under 90009 Torr; for 60h; Ionic liquid;
Multi-step reaction with 2 steps
1: hydrogen; 5% active carbon-supported ruthenium / cyclohexane / 2 h / 50 °C / 60006 Torr / Autoclave
2: hydrogen; 5% active carbon-supported ruthenium / 6 h / 150 °C / 60006 Torr / Autoclave
View Scheme
1-bromo-octane
111-83-1

1-bromo-octane

potassium hydrogencarbonate
298-14-6

potassium hydrogencarbonate

A

di-n-octyl ether
629-82-3

di-n-octyl ether

B

dioctyl carbonate
1680-31-5

dioctyl carbonate

Conditions
ConditionsYield
tetrabutyl phosphonium bromide In various solvent(s) at 150℃; Solvent: NMP;A n/a
B 47%
1-bromo-octane
111-83-1

1-bromo-octane

A

oct-1-ene
111-66-0

oct-1-ene

B

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With sodium hydroxide; triphenylmethyl alcohol; tetrabutylammomium bromide In 1,2-dichloro-benzene at 105℃; for 1.5h; phase transfer conditions;A 45%
B n/a
4-(furan-2-yl)but-3-en-2-one
623-15-4

4-(furan-2-yl)but-3-en-2-one

A

2-methyl-5-propyl-tetrahydrofuran
3214-40-2

2-methyl-5-propyl-tetrahydrofuran

B

2-butanyltetrahydrofuran
1004-29-1

2-butanyltetrahydrofuran

C

octane
111-65-9

octane

D

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With hydrogen In cyclohexane at 170℃; under 15001.5 Torr; for 24h; Reagent/catalyst; Inert atmosphere;A 37%
B 17%
C 24%
D 5%
With hydrogen In cyclohexane at 170℃; under 18751.9 Torr; for 24h; Autoclave; Sealed tube;
furfural
98-01-1

furfural

acetone
67-64-1

acetone

A

2-butanyltetrahydrofuran
1004-29-1

2-butanyltetrahydrofuran

B

octanol
111-87-5

octanol

C

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
Stage #1: furfural; acetone With sodium hydroxide at 20℃; for 15h;
Stage #2: With ruthenium-carbon composite; 1-(4-butylcarboxylic acid)-3-(n-butyl)-imidazolium bis(trifluoromethylsulfonyl)imide; hydrogen at 120℃; under 90009 Torr; for 2h; Ionic liquid;
Stage #3: With hydrogen at 150℃; under 90009 Torr; for 60h; Acidic conditions; Ionic liquid;
A 23.5%
B 32.5%
C 19.8%
Stage #1: furfural; acetone With sodium hydroxide at 20℃; for 16h;
Stage #2: With ruthenium-carbon composite; hydrogen at 120℃; under 90009 Torr; for 2h; Ionic liquid;
Stage #3: With ruthenium-carbon composite; hydrogen at 150℃; under 90009 Torr; for 60h; Ionic liquid;
n-octyl acetate
112-14-1

n-octyl acetate

di-n-octyl ether
629-82-3

di-n-octyl ether

Conditions
ConditionsYield
With hafnium(IV) trifluoromethanesulfonate; palladium 10% on activated carbon; hydrogen In neat (no solvent) at 125℃; under 750.075 Torr; for 18h;9%
Multi-step reaction with 2 steps
1: hafnium tetrakis(trifluoromethanesulfonate); water / neat (no solvent) / 3 h / 170 °C
2: iron(III) trifluoromethanesulfonate / neat (no solvent) / 6 h / 180 °C
View Scheme
1-bromo-octane
111-83-1

1-bromo-octane

sodium octanolate
17158-60-0

sodium octanolate

di-n-octyl ether
629-82-3

di-n-octyl ether

di-n-octyl ether
629-82-3

di-n-octyl ether

1-Chlorooctane
111-85-3

1-Chlorooctane

Conditions
ConditionsYield
With molybdenum(V) chloride In dichloromethane at 80℃; for 3h;93%
With molybdenum(V) chloride In 1,2-dichloro-ethane at 80℃; for 3h;93 % Chromat.
di-n-octyl ether
629-82-3

di-n-octyl ether

octane
111-65-9

octane

Conditions
ConditionsYield
With hafnium tetrakis(trifluoromethanesulfonate); palladium 10% on activated carbon; hydrogen In water at 180℃; under 30003 Torr; for 6h; Sealed tube; Inert atmosphere; Green chemistry;86%
With di-tert-butyl peroxide; trichlorosilane at 140℃; for 16h;52 % Chromat.
Multi-step reaction with 2 steps
1: palladium 10% on activated carbon; hydrogen; hafnium tetrakis(trifluoromethanesulfonate) / water / 3 h / 180 °C / 30003 Torr / Sealed tube; Inert atmosphere; Green chemistry
2: palladium 10% on activated carbon; hydrogen; hafnium tetrakis(trifluoromethanesulfonate) / neat (no solvent) / 6 h / 180 °C / 30003 Torr / Sealed tube; Inert atmosphere; Green chemistry
View Scheme
di-n-octyl ether
629-82-3

di-n-octyl ether

A

Octanoic acid
124-07-2

Octanoic acid

B

octyl octylate
2306-88-9

octyl octylate

C

octyl 2-bromooctanoate

octyl 2-bromooctanoate

Conditions
ConditionsYield
With sodium bromate; sodium hydrogensulfite In water at 20℃; for 16h; Oxidation; bromination;A 18%
B 82%
C n/a
With sodium bromate; sodium hydrogensulfite In water; acetonitrile at 20℃; for 16h; Oxidation; bromination;A 27%
B 67%
C 1%
With sodium bromate; sodium hydrogensulfite In water at 60℃; for 16h; Oxidation; bromination;A 14%
B 40%
C 32%
di-n-octyl ether
629-82-3

di-n-octyl ether

Hexanoyl chloride
142-61-0

Hexanoyl chloride

n-octyl hexanoate
4887-30-3

n-octyl hexanoate

Conditions
ConditionsYield
With molybdenum(V) chloride In dichloromethane at 80℃; for 3h;82%
di-n-octyl ether
629-82-3

di-n-octyl ether

Hexanoyl chloride
142-61-0

Hexanoyl chloride

A

1-Chlorooctane
111-85-3

1-Chlorooctane

B

n-octyl hexanoate
4887-30-3

n-octyl hexanoate

Conditions
ConditionsYield
With molybdenum(V) chloride In 1,2-dichloro-ethane at 80℃; for 3h;A 56%
B 82%
propene
187737-37-7

propene

di-n-octyl ether
629-82-3

di-n-octyl ether

octyl prop-2-ene-1-sulfinate
1235334-81-2

octyl prop-2-ene-1-sulfinate

Conditions
ConditionsYield
Stage #1: propene With sulfur dioxide; boron trichloride In dichloromethane at -196 - -20℃; for 3h;
Stage #2: di-n-octyl ether In dichloromethane for 48h;
79%
di-n-octyl ether
629-82-3

di-n-octyl ether

benzoyl chloride
98-88-4

benzoyl chloride

n-octyl benzoate
94-50-8

n-octyl benzoate

Conditions
ConditionsYield
With molybdenum(V) chloride In dichloromethane at 80℃; for 1h;78%
With rhenium(I) pentacarbonyl bromide In 1,2-dichloro-ethane at 80℃; for 5h; Inert atmosphere;35%
di-n-octyl ether
629-82-3

di-n-octyl ether

benzoyl chloride
98-88-4

benzoyl chloride

A

1-Chlorooctane
111-85-3

1-Chlorooctane

B

n-octyl benzoate
94-50-8

n-octyl benzoate

Conditions
ConditionsYield
With molybdenum(V) chloride In 1,2-dichloro-ethane at 80℃; for 1h;A 34%
B 78%
di-n-octyl ether
629-82-3

di-n-octyl ether

A

octanol
111-87-5

octanol

B

Octanoic acid
124-07-2

Octanoic acid

C

octyl octylate
2306-88-9

octyl octylate

Conditions
ConditionsYield
With dihydrogen peroxide; bromine In dichloromethane; water at 20℃; for 4h;A 9%
B 8%
C 71%
di-n-octyl ether
629-82-3

di-n-octyl ether

Octanoic acid
124-07-2

Octanoic acid

Conditions
ConditionsYield
With nitric acid In water at 50℃; for 2h;64%
di-n-octyl ether
629-82-3

di-n-octyl ether

A

octyl nitrate
629-39-0

octyl nitrate

B

Octanoic acid
124-07-2

Octanoic acid

Conditions
ConditionsYield
With sulfuric acid; nitric acid at 15℃; for 0.5h; Product distribution; Further Variations:; Reagents;A 55%
B n/a
N-hydroxyphthalimide
524-38-9

N-hydroxyphthalimide

di-n-octyl ether
629-82-3

di-n-octyl ether

C24H37NO4

C24H37NO4

Conditions
ConditionsYield
With copper(II) acetate monohydrate; Selectfluor In diethyl ether; acetonitrile at 20℃; for 4h;54%
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