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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

Supply high quality low price Benzenehexathiol

Cas:62968-45-0

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% Benzenehexathiol 62968-45-0 ISO Manufacturer

Cas:62968-45-0

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Benzenehexathiol

Cas:62968-45-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 62968-45-0 with competitive price

Cas:62968-45-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzenehexathiol 62968-45-0

Cas:62968-45-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Benzenehexathiol CAS:62968-45-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermed

Benzenehexathiol CAS:62968-45-0

Cas:62968-45-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzenehexathiol

Cas:62968-45-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzenehexathiol

Cas:62968-45-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis: Trading(Raw Mater

benzene-1,2,3,4,5,6-hexathiol

Cas:62968-45-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Benzenehexathiol

Cas:62968-45-0

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

benzene-1,2,3,4,5,6-hexathiol

Cas:62968-45-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Benzenehexathiol

Cas:62968-45-0

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Benzenehexathiol Basic information Product Name: Benzenehexathiol Synonyms: Benzenehexathiol;1,2,3,4,5,6-Benzenehexathiol CAS: 62968-45-0 MF: C6H6S6 MW: 270.50184 Control parameters Occupational Exposure limit values no data available Bi

62968-45-0 Benzenehexathiol

Cas:62968-45-0

Min.Order:1 Kilogram

FOB Price: $1100.0 / 1400.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Benzenehexathiol

Cas:62968-45-0

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Top Purity SupplierBenzenehexathiol

Cas:62968-45-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Benzenehexathiol

Cas:62968-45-0

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Benzenehexathiol

Cas:62968-45-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Benzenehexathiol

Cas:62968-45-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

benzene-1,2,3,4,5,6-hexathiol

Cas:62968-45-0

Min.Order:1 Gram

FOB Price: $1000.0

Type:Trading Company

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Benzenehexathiol

Cas:62968-45-0

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Benzenehexathiol

Cas:62968-45-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

Benzenehexathiol

Cas:62968-45-0

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Benzenehexathiol

Cas:62968-45-0

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

benzene-1,2,3,4,5,6-hexathiol

Cas:62968-45-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Benzenehexathiol

Cas:62968-45-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

benzene-1,2,3,4,5,6-hexathiol

Cas:62968-45-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

Benzenehexathiol

Cas:62968-45-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

benzene-1,2,3,4,5,6-hexathiol

Cas:62968-45-0

Min.Order:0

Negotiable

Type:Other

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

Benzenehexathiol

Cas:62968-45-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

Benzenehexathiol

Cas:62968-45-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

Hexa-natrium-benzen-hexathiolat
110431-65-7

Hexa-natrium-benzen-hexathiolat

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Conditions
ConditionsYield
With hydrogenchloride96%
With hydrogenchloride In water93%
hexakis(benzylthio)benzene
127022-77-9

hexakis(benzylthio)benzene

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Conditions
ConditionsYield
With ammonia; sodium
hexakis(isopropylthio)benzene
74542-72-6

hexakis(isopropylthio)benzene

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Na, liq. NH3 / -78 °C
2: 96 percent / 5percent aq. HCl
View Scheme
Stage #1: hexakis(isopropylthio)benzene With sodium at 100℃;
Stage #2: With hydrogenchloride In methanol; water
Hexafluorobenzene
392-56-3

Hexafluorobenzene

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1,3-dimethyl-2-imidazolidinone / 0 °C / Inert atmosphere
2: sodium / 100 °C
View Scheme
Multi-step reaction with 2 steps
1: 1,3-dimethyl-2-imidazolidinone / 0 °C / Inert atmosphere
2: sodium / 100 °C
View Scheme
Multi-step reaction with 2 steps
1: 1,3-dimethyl-2-imidazolidinone / 0 °C / Inert atmosphere
2: sodium / 100 °C
View Scheme
hexabromobenzene
87-82-1

hexabromobenzene

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1,3-dimethyl-2-imidazolidinone / 100 °C / Inert atmosphere
2: sodium / 100 °C
View Scheme
Multi-step reaction with 2 steps
1: 1,3-dimethyl-2-imidazolidinone / 100 °C / Inert atmosphere
2: sodium / 100 °C
View Scheme
Multi-step reaction with 2 steps
1: 1,3-dimethyl-2-imidazolidinone / 100 °C / Inert atmosphere
2: sodium / 100 °C
View Scheme
hexakis(methylthio) benzene
58468-22-7

hexakis(methylthio) benzene

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Conditions
ConditionsYield
Stage #1: hexakis(methylthio) benzene With sodium at 100℃;
Stage #2: With hydrogenchloride In methanol; water
hexakis(ethylthio)benzene
70648-34-9

hexakis(ethylthio)benzene

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Conditions
ConditionsYield
Stage #1: hexakis(ethylthio)benzene With sodium at 100℃;
Stage #2: With hydrogenchloride In methanol; water
pyridine
110-86-1

pyridine

carbon disulfide
75-15-0

carbon disulfide

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

7-mercapto-2,5-dithioxobenzo<1,2-d:3,4-d'>bis<1,3>dithiole-8-thiolate
134172-93-3

7-mercapto-2,5-dithioxobenzo<1,2-d:3,4-d'>bis<1,3>dithiole-8-thiolate

Conditions
ConditionsYield
for 0.25h; Ambient temperature;97%
hexamercaptobenzene
62968-45-0

hexamercaptobenzene

silver nitrate

silver nitrate

C6S6(6-)*4Ag(1+)*Ag(2+)

C6S6(6-)*4Ag(1+)*Ag(2+)

Conditions
ConditionsYield
In water; toluene at 60℃; for 49h;95%
tetrakis(acetonitrile)copper(I)tetrafluoroborate

tetrakis(acetonitrile)copper(I)tetrafluoroborate

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Cu5.5C6S6

Cu5.5C6S6

Conditions
ConditionsYield
Stage #1: tetrakis(acetonitrile)copper(I)tetrafluoroborate In 1,2-dimethoxyethane at 45℃; for 1h; Inert atmosphere;
Stage #2: hexamercaptobenzene In 1,2-dimethoxyethane at 45℃; for 168h; Inert atmosphere;
93.6%
tetrakis(acetonitrile)copper(I)tetrafluoroborate

tetrakis(acetonitrile)copper(I)tetrafluoroborate

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Cu4C6S6

Cu4C6S6

Conditions
ConditionsYield
Stage #1: tetrakis(acetonitrile)copper(I)tetrafluoroborate In methanol at 45℃; for 1h; Inert atmosphere;
Stage #2: hexamercaptobenzene In methanol at 45℃; for 168h; Inert atmosphere;
91%
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Ir3(η5-C5Me5)3(S6C6)
1147522-92-6

Ir3(η5-C5Me5)3(S6C6)

Conditions
ConditionsYield
With triethylamine In dichloromethane (under N2, Schlenk); triethylamine added to soln. of C6(SH)6 in CH2Cl2, CH2Cl2 soln. of Ir-complex added, stirred for 2 h at room temp.; filtered, solvent evapd. under vac., alumina column chromy. with CH2Cl2-hexane (1:1), recrystd. from CH2Cl2-hexane; elem. anal.;90%
dibutyltin chloride
683-18-1

dibutyltin chloride

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

C30H54S6Sn3

C30H54S6Sn3

Conditions
ConditionsYield
Stage #1: hexamercaptobenzene With triethylamine In tetrahydrofuran Schlenk technique; Inert atmosphere;
Stage #2: dibutyltin chloride for 4h; Inert atmosphere; Schlenk technique;
85%
lead acetate
301-04-2

lead acetate

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

[Pb3(benzenehexathiolato)](n)

[Pb3(benzenehexathiolato)](n)

Conditions
ConditionsYield
In ethylenediamine for 16 h at 60°C;83%
hexamercaptobenzene
62968-45-0

hexamercaptobenzene

copper(II) nitrate

copper(II) nitrate

copper(II) benzenehexathiolate

copper(II) benzenehexathiolate

Conditions
ConditionsYield
In chloroform; water for 24h; Inert atmosphere;82%
[(divinyl)(phenyl)phosphine] gold(I) chloride
286384-11-0

[(divinyl)(phenyl)phosphine] gold(I) chloride

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

([(C2H3)2(C6H5)P]Au)6(C6S6)*3(CH3CH2)3NH(1+)*3Cl(1-) = ([(C2H3)2(C6H5)P]Au)6(C6S6)*3(CH3CH2)3NHCl

([(C2H3)2(C6H5)P]Au)6(C6S6)*3(CH3CH2)3NH(1+)*3Cl(1-) = ([(C2H3)2(C6H5)P]Au)6(C6S6)*3(CH3CH2)3NHCl

Conditions
ConditionsYield
With triethylamine In dichloromethane byproducts: Et3NHCl; stirred at room temp., 2 h; soln. filtered; solvent removed under reduced pressure; residue recrystd. at room temp. (CH2Cl2/hexane); elem. anal.;80%
[(P(C6H5)3)2PtCl2]*(CH3CH2)3NH(1+)*Cl(1-)*3CH2Cl2 = [(P(C6H5)3)2PtCl2]*(CH3CH2)3NHCl*3CH2Cl2

[(P(C6H5)3)2PtCl2]*(CH3CH2)3NH(1+)*Cl(1-)*3CH2Cl2 = [(P(C6H5)3)2PtCl2]*(CH3CH2)3NHCl*3CH2Cl2

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

[(P(C6H5)3)2Pt]3(C6S6)*(CH3CH2)3NH(1+)*Cl(1-)*3CH2Cl2 = [(P(C6H5)3)2Pt]3(C6S6)*(CH3CH2)3NHCl*3CH2Cl2

[(P(C6H5)3)2Pt]3(C6S6)*(CH3CH2)3NH(1+)*Cl(1-)*3CH2Cl2 = [(P(C6H5)3)2Pt]3(C6S6)*(CH3CH2)3NHCl*3CH2Cl2

Conditions
ConditionsYield
With sodium carbonate; triethylamine In methanol; dichloromethane stirred, room temp., 2 h; solvent removed under reduced pressure; residue dissolved (CH2Cl2); ppt. (hexane), room temp.; elem. anal.;80%
dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Rh3(η5-C5Me5)3(S6C6)
1147522-90-4

Rh3(η5-C5Me5)3(S6C6)

Conditions
ConditionsYield
With triethylamine In dichloromethane (under N2, Schlenk); triethylamine added to soln. of C6(SH)6 in CH2Cl2, CH2Cl2 soln. of Rh-complex added, stirred for 2 h at room temp.; filtered, solvent evapd. under vac., alumina column chromy. with CH2Cl2-hexane (1:1), recrystd. from CH2Cl2-hexane; elem. anal.;77%
hexamercaptobenzene
62968-45-0

hexamercaptobenzene

A

benzo<1,2-d><3,4-d'><5,6-d''>-tris-1,2,3-trithiole
167564-25-2

benzo<1,2-d><3,4-d'><5,6-d''>-tris-1,2,3-trithiole

B

benzo<3,4-d><5,6-d'>-bis-1,2,3-trithiolo-<1,2-d''>pentathiepin

benzo<3,4-d><5,6-d'>-bis-1,2,3-trithiolo-<1,2-d''>pentathiepin

Conditions
ConditionsYield
With sulfur dichloride; methyllithium 1.) THF, 30 min; 2.) THF, 1 h, r.t.;A 74%
B 20%
[(cis-bis(diphenylphosphino)ethylene)dichloroplatinum(II)] * triethylammonium chloride * 3 methylene chloride

[(cis-bis(diphenylphosphino)ethylene)dichloroplatinum(II)] * triethylammonium chloride * 3 methylene chloride

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

[(cis-bis(diphenylphosphino)ethylene)platinum(II)]3(C6S6) * triethylammonium chloride * 3 methylene chloride

[(cis-bis(diphenylphosphino)ethylene)platinum(II)]3(C6S6) * triethylammonium chloride * 3 methylene chloride

Conditions
ConditionsYield
With sodium carbonate; triethylamine In methanol; dichloromethane stirred, room temp., 2 h; solvent removed under reduced pressure; residue dissolved (CH2Cl2); ppt. (hexane), room temp.; elem. anal.;70%
[(1,2-bis(dimethylphosphino)ethane)dichloroplatinum(II)]* 7 water

[(1,2-bis(dimethylphosphino)ethane)dichloroplatinum(II)]* 7 water

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

[(1,2-bis(dimethylphosphino)ethane)platinum(II)]3(C6S6) * 7 water

[(1,2-bis(dimethylphosphino)ethane)platinum(II)]3(C6S6) * 7 water

Conditions
ConditionsYield
With sodium carbonate; triethylamine In methanol; dichloromethane stirred, room temp., 2 h; solvent removed under reduced pressure; residue dissolved (CH2Cl2); ppt. (hexane), room temp.; elem. anal.;70%
[(bis(diphenylphosphino)methane)dichloroplatinum(II)] * triethylammonium chloride * 3 methylene chloride

[(bis(diphenylphosphino)methane)dichloroplatinum(II)] * triethylammonium chloride * 3 methylene chloride

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

[(bis(diphenylphosphino)methane)platinum(II)]3(C6S6) * triethylammonium chloride * 3 methylene chloride

[(bis(diphenylphosphino)methane)platinum(II)]3(C6S6) * triethylammonium chloride * 3 methylene chloride

Conditions
ConditionsYield
With sodium carbonate; triethylamine In methanol; dichloromethane stirred, room temp., 2 h; solvent removed under reduced pressure; residue dissolved (CH2Cl2); ppt. (hexane), room temp.;69%
carbonyl(pentamethylcyclopentadienyl)cobalt diiodide

carbonyl(pentamethylcyclopentadienyl)cobalt diiodide

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Co3(η5-C5Me5)3(S6C6)*H2O

Co3(η5-C5Me5)3(S6C6)*H2O

Conditions
ConditionsYield
With triethylamine In acetone (under N2, Schlenk); triethylamine added to soln. of C6(SH)6 in acetone,acetone soln. of Co-complex added, stirred for 2 h at room temp.; filtered, solvent evapd. under vac., alumina column chromy. with CH2Cl2-hexane (1:1), recrystd. from CH2Cl2-hexane;59%
With triethylamine In dichloromethane (under N2, Schlenk); triethylamine added to soln. of C6(SH)6 in CH2Cl2, CH2Cl2 soln. of Co-complex added, stirred for 2 h at room temp.; filtered, solvent evapd. under vac., alumina column chromy. with CH2Cl2-hexane (1:1), recrystd. from CH2Cl2-hexane; elem. anal.;53%
With triethylamine In tetrahydrofuran (under N2, Schlenk); triethylamine added to soln. of C6(SH)6 in THF, THFsoln. of Co-complex added, stirred for 2 h at room temp.; filtered, solvent evapd. under vac., alumina column chromy. with CH2Cl2-hexane (1:1), recrystd. from CH2Cl2-hexane;38%
With NaOCH3 In methanol; dichloromethane (under N2, Schlenk); NaOCH3 added to soln. of C6(SH)6 in CH2Cl2-MeOH, CH2Cl2-MeOH soln. of Co-complex added, stirred for 2 h at room temp.; filtered, solvent evapd. under vac., alumina column chromy. with CH2Cl2-hexane (1:1), recrystd. from CH2Cl2-hexane;32%
With Na2CO3 In methanol; dichloromethane (under N2, Schlenk); Na2CO3 added to soln. of C6(SH)6 in CH2Cl2-MeOH, CH2Cl2-MeOH soln. of Co-complex added, stirred for 2 h at room temp.; filtered, solvent evapd. under vac., alumina column chromy. with CH2Cl2-hexane (1:1), recrystd. from CH2Cl2-hexane;11%
carbonyl(η-5-cyclopentadienyl)diiodocobalt(III)

carbonyl(η-5-cyclopentadienyl)diiodocobalt(III)

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

Co3(η5-C5H5)3(S6C6)
168281-33-2

Co3(η5-C5H5)3(S6C6)

Conditions
ConditionsYield
With triethylamine In dichloromethane (under N2, Schlenk); triethylamine added to soln. of C6(SH)6 in CH2Cl2, CH2Cl2 soln. of Co-complex added, stirred for 2 h at room temp.; filtered, solvent evapd. under vac., alumina column chromy. with CH2Cl2-hexane (1:1), recrystd. from CH2Cl2-hexane; elem. anal.;58%
(triphenylphosphine)gold(I) chloride
14243-64-2

(triphenylphosphine)gold(I) chloride

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

A

[CSAu(P(C6H5)3)]6

[CSAu(P(C6H5)3)]6

B

[CSAu(P(C6H5)3)]6*2N(C2H5)3H(1+)*2Cl(1-)*4CHCl3=[CSAu(P(C6H5)3)]6*2[N(C2H5)3H]Cl*4CHCl3

[CSAu(P(C6H5)3)]6*2N(C2H5)3H(1+)*2Cl(1-)*4CHCl3=[CSAu(P(C6H5)3)]6*2[N(C2H5)3H]Cl*4CHCl3

Conditions
ConditionsYield
With NEt3 In dichloromethane molar ratio Au-complex:thiol:NEt3=6:1:6; stirring (room temp., 2 h); filtration, solvent removal (vac.), recrystn. (CH2Cl2/hexane=1:1);A 30%
B n/a
hexamercaptobenzene
62968-45-0

hexamercaptobenzene

triiron dodecacarbonyl
100447-70-9

triiron dodecacarbonyl

C24Fe6O18S6

C24Fe6O18S6

Conditions
ConditionsYield
In toluene at 130℃; for 2h;17%
hexamercaptobenzene
62968-45-0

hexamercaptobenzene

acetonitrile
75-05-8

acetonitrile

[((Ph2PCH2CH2PPh2)Ni)3(hexathiolatobenzene)]*8CH3CN

[((Ph2PCH2CH2PPh2)Ni)3(hexathiolatobenzene)]*8CH3CN

Conditions
ConditionsYield
In not given reaction of nickel compd. with hexamercaptobenzene in presence of base; chromy. (alumina), NMR and MS;14%
cyclohexane
110-82-7

cyclohexane

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

[((pentamethylcyclopentadienyl)Ru)3(hexathiolatobenzene)]*C6H12

[((pentamethylcyclopentadienyl)Ru)3(hexathiolatobenzene)]*C6H12

Conditions
ConditionsYield
In not given reaction of ruthenium compd. with hexamercaptobenzene in presence of base; chromy. (alumina), NMR annd MS;5%
hexamercaptobenzene
62968-45-0

hexamercaptobenzene

[((4,4'-di-tert-butyl-2,2'-pyridine)Pt)3(hexathiolatobenzene)]
1313753-76-2

[((4,4'-di-tert-butyl-2,2'-pyridine)Pt)3(hexathiolatobenzene)]

Conditions
ConditionsYield
In not given reaction of platinum compd. with hexamercaptobenzene in presence of base; chromy. (alumina), NMR and MS;1%
carbon disulfide
75-15-0

carbon disulfide

diiodomethane
75-11-6

diiodomethane

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

1,3,4,6,7,9-Hexathia-trindene-2,5-dithione
134172-99-9

1,3,4,6,7,9-Hexathia-trindene-2,5-dithione

Conditions
ConditionsYield
With pyridine 1) RT, 15 min, 2) 10 min; Yield given. Multistep reaction;
carbon disulfide
75-15-0

carbon disulfide

amyl iodide
628-17-1

amyl iodide

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

4,5-Bis-pentylsulfanyl-benzo[1,2-d;3,4-d']bis[1,3]dithiole-2,7-dithione
134172-98-8

4,5-Bis-pentylsulfanyl-benzo[1,2-d;3,4-d']bis[1,3]dithiole-2,7-dithione

Conditions
ConditionsYield
With pyridine 1) RT, 15 min, 2) 10 min; Yield given. Multistep reaction;
carbon disulfide
75-15-0

carbon disulfide

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

ethyl iodide
75-03-6

ethyl iodide

4,5-Bis-ethylsulfanyl-benzo[1,2-d;3,4-d']bis[1,3]dithiole-2,7-dithione
134172-97-7

4,5-Bis-ethylsulfanyl-benzo[1,2-d;3,4-d']bis[1,3]dithiole-2,7-dithione

Conditions
ConditionsYield
With pyridine 1) RT, 15 min, 2) 10 min; Yield given. Multistep reaction;
carbon disulfide
75-15-0

carbon disulfide

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

methyl iodide
74-88-4

methyl iodide

4,5-Bis-methylsulfanyl-benzo[1,2-d;3,4-d']bis[1,3]dithiole-2,7-dithione
134172-94-4

4,5-Bis-methylsulfanyl-benzo[1,2-d;3,4-d']bis[1,3]dithiole-2,7-dithione

Conditions
ConditionsYield
With pyridine 1) RT, 15 min, 2) 10 min; Yield given. Multistep reaction;
4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

hexamercaptobenzene
62968-45-0

hexamercaptobenzene

A

2,5,8-tri-p-tolyl-1,3,4,6,7,9-hexathia-trindene

2,5,8-tri-p-tolyl-1,3,4,6,7,9-hexathia-trindene

B

2,5,8-tri-p-tolyl-1,3,4,6,7,9-hexathia-trindene

2,5,8-tri-p-tolyl-1,3,4,6,7,9-hexathia-trindene

Conditions
ConditionsYield
With zinc trifluoromethanesulfonate In chloroform Heating;
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