103497-78-5

Basic information

• Product Name: Benzeneacetic acid, a-(methoxymethylene)-2-(phenylmethoxy)-, methyl ester, (E)-
• Synonyms: E-methyl 3-methoxy-2-(2'-benzyloxyphenyl)propenoate;(E)-methyl 2-(2'-benzyloxyphenyl)-3-methoxyacrylate;methyl (E)-2-(2-benzyloxy)phenyl-3-methoxyacrylate;E -methyl 2-(2-benzyloxy)phenyl-3-methoxyacrylate;E-methyl 2-(2-benzyloxy)phenyl-3-methoxyacrylate
• CAS NO: 103497-78-5
• Molecular Formula: C18H18O4
• Molecular Weight: 298.339
• Mol File: 103497-78-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzeneacetic acid, a-(methoxymethylene)-2-(phenylmethoxy)-, methyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetic acid, a-(methoxymethylene)-2-(phenylmethoxy)-, methyl ester, (E)-(103497-78-5)
• EPA Substance Registry System: Benzeneacetic acid, a-(methoxymethylene)-2-(phenylmethoxy)-, methyl ester, (E)-(103497-78-5)

Safety Data

• Hazardous Substances Data: 103497-78-5(Hazardous Substances Data)

Upstream product

• 107-31-3 Methyl formate 
• 40525-65-3 2-benzyloxyphenylacetic acid methyl ester 
• 77-78-1 dimethyl sulfate 
• 103474-03-9 methyl 3-hydroxy-2-[2'-benzyloxyphenyl]propenoate 
• 913846-52-3 methyl 2-[(2-benzyloxy)phenyl]-(3,3-dimethoxy)propanoate 
• 163041-47-2 (Z)-3-methoxy-2-iodo-acrylic acid methyl ester 
• 190661-29-1 2-benzyloxyphenylboronic acid 
• 5788-17-0 methyl (2E)-3-methoxy-2-propenoate 
• 31575-75-4 2-bromophenyl benzyl ether 
• 100-39-0 benzyl bromide 
• 95-56-7 2-hydroxybromobenzene 
• 22446-37-3 methyl (2-hydroxyphenyl)acetate 
• 614-75-5 2-Hydroxyphenylacetic acid 
• 34846-90-7 methyl 3-methoxyprop-2-enoate 

Downstream Products

• 114077-42-8 (E)-3-methoxy-2-(2-hydroxyphenyl)-acrylic acid methyl ester 
• 131860-97-4 (E)-methyl 2-[2-(6-chloropyrimidin-4-yloxy)phenyl]-3-methoxy-propenoate 
• 215934-32-0 azoxystrobin 

Relevant articles and documents

A concise synthesis of azoxystrobin using a Suzuki cross-coupling reaction

A simple, efficient and eco-friendly process for the synthesis in good yield of azoxystrobin from 2-bromophenol has been developed using phenolic hydroxyl protection, Grignard reaction, Suzuki cross-coupling, hydrogenation and a nucleophilic reaction on a 2-chloropyrimidine.

Measuring method for measuring and using a kit or flagment autoantibody autoantibody or fragments thereof, and their azoxystrobin deriv., azoxystrobin

PROBLEM TO BE SOLVED: To provide a method for measuring the levels of an azoxystrobin as a fungicide left in samples such as of farm products or processed products. SOLUTION: An antibody specific to azoxystrobin is obtained by using a composite, as an immunogen, of an azoxystrobin derivative and a polymeric compound. The method for assaying azoxystrobin using such an antibody is provided. An assay kit therefor is prepared. COPYRIGHT: (C)2011,JPOandINPIT

CHEMICAL PROCESS

The present invention relates, inter alia, to a process for preparing a compound of formula (I): which comprises either (a) reacting a compound of formula (II): with 2-cyanophenol, or a salt thereof, in the presence of between 0.1 and 2 mol % of 1 ,4-diazabicyclo[2.2.2]octane, or (b) reacting a compound of the formula (III): with a compound of the formula (IV): in the presence of between 0.1 and 2 mol % of l,4-diazabicyclo[2.2.2]octane; where W is the methyl (E)-2-(3-methoxy)acrylate group C(CO 2CH 3)=CHOCH 3 or the methyl 2-(3,3-dimethoxy)propanoate group C(CO 2CH 3)CH(OCH 3) 2, or a mixture of the two groups. In addition, the present invention relates to a novel precursors of the compound of formula (I) and methods for making them.