13296-87-2

Basic information

• Product Name: Benzamide, 2,4-dinitro-
• CAS NO: 13296-87-2
• Molecular Formula: C7H5N3O5
• Molecular Weight: 211.134
• Mol File: 13296-87-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzamide, 2,4-dinitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, 2,4-dinitro-(13296-87-2)
• EPA Substance Registry System: Benzamide, 2,4-dinitro-(13296-87-2)

Safety Data

• Hazardous Substances Data: 13296-87-2(Hazardous Substances Data)

Upstream product

• 7664-93-9 sulfuric acid 
• 4110-33-2 2,4-dinitrobenzonitrile 
• 3236-33-7 2,4-dinitro-benzaldehyde-oxime 
• 1336-21-6 ammonium hydroxide 
• 79-37-8 oxalyl dichloride 
• 610-30-0 2,4-dinitrobenzoic acid 
• 528-75-6 2,4-dinitrobenzaldehyde 
• 20195-22-6 2,4-dinitrobenzoyl chloride 
• 121-14-2 2,4-dinitrotoluene 

Downstream Products

• 515884-27-2 4-nitro-2-propylsulfanyl-benzamide 
• 515884-28-3 2-(butylsulfanyl)-4-nitrobenzamide 
• 515884-29-4 4-nitro-2-octylsulfanyl-benzamide 
• 515884-30-7 2-(tert-butylsulfanyl)-4-nitrobenzamide 
• 31930-18-4 2-amino-4-nitrobenzamide 
• 857434-94-7 (2,4-dinitro-benzoyl)-amidophosphoryl chloride 
• 335434-42-9 (4-nitro-2-phenylmethanesulfonyl-phenyl)-carbamic acid methyl ester 
• 335434-38-3 4-nitro-2-phenylmethanesulfonyl-benzamide 
• 515884-46-5 2-(ethylsulfinyl)-4-nitrobenzamide 
• 22952-24-5 6-nitrosaccharin 
• 445470-57-5 2-ethylsulfanyl-4-nitro-benzamide 
• 515884-31-8 4-nitro-2-(phenylsulfanyl)benzamide 
• 309735-34-0 2-Benzylthio-4-nitrobenzamide 
• 610-30-0 2,4-dinitrobenzoic acid 

Relevant articles and documents

Highly efficient synthesis of primary amides: Via aldoximes rearrangement in water under air atmosphere catalyzed by an ionic ruthenium pincer complex

The transformation of aldoximes to primary amides has been evaluated using pincer ruthenium complexes a-c, among which the ionic Ru catalyst a proved to be the most efficient in water under air atmosphere. A variety of (hetero)arene aldoximes proceeded smoothly to afford amides in high yields with good functional group compatibilities. Furthermore, a direct synthetic route of amides from aldehydes, hydroxylamine hydrochloride and sodium carbonate was also described with broad substrates including conjugated and aliphatic aldehydes. This protocol is operationally simple and proceeds with a low catalyst loading (0.5 mol%).

Synthesis of 2,3-dihydrobenzothiazol-1,1-dioxide and 2,3-dihydro-1,4-benzothiazin-3-one nitroderivatives from 2,4-di- and 2,4,6-trinitrobenzamides

Synthetic methods for the conversion of readily available 2,4-di- and 2,4,6-trinitrobenzamides to the previously unknown 2,3-dihydrobenzothiazol-1,1-dioxide, 2,3-dihydro- 1,4-benzothiazin-3-one, and 2,3-dihydro-1,4-benzothiazin-3-one-1,1-dioxide nitroderivatives have been developed. The methods involve selective nucleophilic substitution of an ortho-nitrogroup in polynitrobenzamides by benzylthio or methoxycarbonylmethylthio group followed by oxidation of sulfur atom with hydrogen peroxide and transformation of the amido group to the methoxycarbonylamino group by reaction with diacetoxyiodobenzene in methanol under non-basic conditions. Cyclization of the resulting compounds under the action of diacetoxyiodobenzene or sodium methoxide leads to the 2,3-dihydrobenzothiazole and 2,3-dihydro-1,4-benzothiazin-3one derivatives, respectively.

TRICYCLIC SUBSTITUTED HEXAHYDROBENZ [E]ISOINDOLE ALPHA-1 ADRENERGIC ANTAGONISTS

The present invention relates to a compound of the formula STR1 and the pharmaceutically acceptable salts thereof wherein W is a tricyclic heterocyclic ring system; which is an α-1 adrenergic antagonist and is useful in the treatment of BPH; also disclosed are . alpha.-1 antagonist compositions and a method for antagonizing α-1 receptors and treating BPH.