15359-98-5

Basic information

• Product Name: tert-butyl 4-methylphenyl ether
• Synonyms: tert-butyl 4-methylphenyl ether;1-tert-Butoxy-4-methylbenzene;4-tert-Butoxytoluene;tert-Butyl p-tolyl ether;tert-Butyl(p-tolyl) ether;Benzene, 1-(1,1-dimethylethoxy)-4-methyl-;4-tert-butyloxytoluene;4-Methylphenyl tert-butyl ether
• CAS NO: 15359-98-5
• Molecular Formula: C₁₁H₁₆O
• Molecular Weight: 164.24414
• Mol File: 15359-98-5.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 220℃
• Flash Point: 90℃
• Appearance: /
• Density: 0.916
• Vapor Pressure: 0.173mmHg at 25°C
• Refractive Index: 1.4882
• Storage Temp.: 2-8°C
• CAS DataBase Reference: tert-butyl 4-methylphenyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 4-methylphenyl ether(15359-98-5)
• EPA Substance Registry System: tert-butyl 4-methylphenyl ether(15359-98-5)

Safety Data

• Hazardous Substances Data: 15359-98-5(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 81, p. 4230, 1959 DOI: 10.1021/ja01525a028

InChI:InChI=1/C11H16O/c1-9-5-7-10(8-6-9)12-11(2,3)4/h5-8H,1-4H3

Upstream product

• 614-45-9 tert-Butyl peroxybenzoate 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 106-44-5 p-cresol 
• 115-11-7 isobutene 
• 507-20-0 tertiary butyl chloride 
• 106-38-7 para-bromotoluene 
• 865-47-4 potassium tert-butylate 
• 624-31-7 4-tolyl iodide 
• 71-43-2 benzene 
• 106-49-0 p-toluidine 
• 36719-51-4 3,3-diethyl-1-(4-methylphenyl)-1-triazene 
• 75-65-0 tert-butyl alcohol 
• 1634-04-4 tert-butyl methyl ether 

Downstream Products

• 2409-55-4 2-tert-Butyl-4-methylphenol 
• 77249-33-3 4-fluoro-4-methylcyclohexa-2,5-dien-1-one 
• 106-44-5 p-cresol 
• 132307-87-0 3-(4-tert-butoxyphenyl)-propan-1-ol 
• 941293-00-1 3-(4-tert-butoxyphenyl)propionaldehyde 
• 941293-02-3 (S)-β-4-tert-butoxyphenyl-γ-(S)-N-benzyl-α-methylbenzylamino-propylalcohol 
• 941293-01-2 C₁₄H₂₃NO₂ 
• 941293-03-4 (s)-β-4-tert-butoxylphenyl-γ-Fmoc-amino-propylalcohol 

Relevant articles and documents

-

-

C60-catalyzed direct C-H arylation of benzene with aryl iodides in air

C60 at 1 mol % loading catalyzed the direct C-H arylation of benzene with aryl iodides in air to yield biaryls. The in situ generation of electron-rich C60(OH)2-, from C60 and OH-, reduced the aryl iodides to aryl radicals for arylation of benzene. The large surface area and spherical shape of C60 facilitated this process.

Aromatic fluoro-de-triazenation with boron trifluoride diethyl etherate under non-protic acid conditions

Fluoro-de-triazenation of 3,3-diethyl-1-aryltriazenes can be achieved by conventional or under microwave heating in carbon tetrachloride, in the presence of boron trifluoride diethyl etherate without any protic acid to avoid corresponding unwanted byproduct formation.