24070-10-8

Basic information

• Product Name: Benzeneethanamine, N-(1,1-dimethylethyl)-
• Synonyms: tert-butyl(2-phenylethyl)amine;tert-Butyl-phenaethyl-amin;N-phenethyl-tert-butylamine;2-methyl-N-phenethylpropan-2-amine;Benzeneethanamine,N-(1,1-dimethylethyl);tert-butyl-phenethyl-amine;phenylethyl-tert-butylamine
• CAS NO: 24070-10-8
• Molecular Formula: C12H19N
• Molecular Weight: 177.29
• Mol File: 24070-10-8.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 77-86 °C(Press: 2 Torr)
• Density: 0.899±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzeneethanamine, N-(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneethanamine, N-(1,1-dimethylethyl)-(24070-10-8)
• EPA Substance Registry System: Benzeneethanamine, N-(1,1-dimethylethyl)-(24070-10-8)

Safety Data

• Hazardous Substances Data: 24070-10-8(Hazardous Substances Data)

Upstream product

• 122-78-1 phenylacetaldehyde 
• 75-64-9 tert-butylamine 
• 6125-24-2 2-Phenylnitroethane 
• 536-74-3 phenylacetylene 
• 100-42-5 styrene 
• 140-29-4 phenylacetonitrile 
• 60-12-8 2-phenylethanol 
• 103-63-9 1-phenyl-2-bromoethane 
• 6941-21-5 N-tert-butylphenylacetamide 

Downstream Products

• 151813-49-9 N-tert-butyl-N-(2-phenylethyl)acetoacetamide 
• 1431792-07-2 N-(t-butyl)-2-cyano-N-phenethylacetamide 
• 138984-17-5 N-(tert-butyl)-2-diazo-3-oxo-N-phenethylbutanamide 
• 138984-02-8 N-tert-butyl-N-(2-phenylethyl)diazoacetamide 
• 138984-08-4 N-tert-butyl-4-phenyl-2-pyrrolidone 
• 323186-53-4 2-amino-N-tert-butyl-N-phenethyl-benzamide 
• 628729-74-8 α-bromoacetyl-N-(tert-butyl)-N-(phenylethyl)amide 
• 70161-03-4 tert-butyl-methyl-phenethyl-amine 

Relevant articles and documents

Ru(II) complexes containing (2-(pyren-1-ylmethylene)hydrazinyl)benzothiazole: Synthesis, solid-state structure, computational study and catalysis in N-alkylation reactions

Reactions of (2-(pyren-1-ylmethylene)hydrazinyl)benzothiazole (L) with ruthenium(II) prefabricated precursors [RuHCl(CO)(EPh3)3] and [RuH2(CO)(EPh3)3] (E = P or As) afforded new Ru(II) complexes [RuCl(CO)(EPh3)2(L)] and [RuH(CO)(EPh3)2(L)] (E = P or As) (1–4). All the Ru(II) complexes (1–4) were characterized by IR, NMR spectroscopies, ESI-mass spectrometry and elemental analyses. The solid-state structures of Ru(II) complexes (2 and 3) were established by single crystal X-ray analyses and revealed distorted octahedral geometries around the ruthenium(II) ion and mono anionic bidentate N^N coordination mode for hydrazine ligand. The Ru(II) complexes 2 and 3 were also analyzed using Hirshfeld surface analysis and DFT calculations. Moreover, all the complexes (1–4) were utilized in the N-alkylation reactions of amines using alcohol. Complex 3 was found to be highly active towards N-alkylation of different aromatic amines with alcohol.

Visible Light-Mediated Decarboxylation Rearrangement Cascade of Aryl- N-(acyloxy)phthalimides

A Smiles-type radical rearrangement induced by visible-light-mediated decarboxylation of w-aryl-N-(acyloxy)phthalimides was developed, giving rise to pharmacologically important substance classes: phenylethylamine derivatives, dihydroisoquinolinones, and

Facile Synthesis and Isolation of Secondary Amines via a Sequential Titanium(IV)-Catalyzed Hydroamination and Palladium-Catalyzed Hydrogenation

An atom economical and catalytic route for the synthesis of aryl- and alkyl-substituted secondary amines has been developed. Using a bis(amidate)bis(amido)titanium(IV) precatalyst, the hydroamination of terminal alkynes with a range of amines results in the selective formation of the anti-Markovnikov product. The crude enamine/imine mixtures are effectively hydrogenated using palladium on carbon (Pd/C) and H2 to afford the corresponding secondary amine in excellent yields. Simple work-up procedures allow for the isolation of pure compounds while avoiding purification via column chromatography.