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2724-58-5

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  • Isostearic acid CAS 2724-58-5 16-Methylheptadecanoic acid CAS no 2724-58-5 Isooctadecanoic Acid

    Cas No: 2724-58-5

  • USD $ 3.5-5.0 / Kiloliter

  • 5 Kiloliter

  • 3000 Metric Ton/Month

  • Chemwill Asia Co., Ltd.
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2724-58-5 Usage

Description

ISOSTEARIC ACID, also known as 16-Methylheptadecanoic acid, is a methyl-branched fatty acid derived from heptadecanoic acid (margaric acid) with a methyl group substitution at position 16. It is a solid chemical compound and shares similar properties with stearic or oleic acids.

Uses

Used in Chemical Synthesis:
ISOSTEARIC ACID is used as a key component in the synthesis of various materials, such as methyl-branched poly(hydroxyalkanoate)s, biosurfactants, and silver nanoparticles. Its unique chemical structure allows for the creation of novel compounds with specific properties and applications.
Used in Personal Care and Cosmetics Industry:
ISOSTEARIC ACID is used as an emollient, emulsifier, and viscosity increasing agent in the personal care and cosmetics industry. Its ability to provide a smooth and soft texture to formulations makes it a valuable ingredient in various products, such as creams, lotions, and makeup.
Used in Lubricants and Greases Industry:
ISOSTEARIC ACID is used as an additive in the lubricants and greases industry to improve the performance and stability of these products. Its solid state at room temperature and compatibility with various base oils make it suitable for use in a wide range of applications, including automotive, industrial, and marine lubricants.
Used in Plastics and Polymers Industry:
ISOSTEARIC ACID is used as a plasticizer and processing aid in the plastics and polymers industry. Its compatibility with various polymers and ability to improve processability and flexibility make it a valuable additive in the production of films, coatings, and other plastic products.
Used in Textile Industry:
ISOSTEARIC ACID is used as a softening agent and lubricant in the textile industry. Its ability to provide a soft and smooth finish to fabrics, as well as improve their durability and resistance to wear, makes it a popular choice for various textile applications, such as clothing, upholstery, and industrial fabrics.

Check Digit Verification of cas no

The CAS Registry Mumber 2724-58-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,7,2 and 4 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 2724-58:
(6*2)+(5*7)+(4*2)+(3*4)+(2*5)+(1*8)=85
85 % 10 = 5
So 2724-58-5 is a valid CAS Registry Number.
InChI:InChI=1/C18H36O2/c1-17(2)15-13-11-9-7-5-3-4-6-8-10-12-14-16-18(19)20/h17H,3-16H2,1-2H3,(H,19,20)

2724-58-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 16-methylheptadecanoic acid

1.2 Other means of identification

Product number -
Other names 16-methylheptadecenoic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Adhesives and sealant chemicals,Finishing agents,Intermediates,Lubricants and lubricant additives,Paint additives and coating additives not described by other categories,Solvents (for cleaning or degreasing),Surface active agents,Viscosity adjustors
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2724-58-5 SDS

2724-58-5Synthetic route

isostearyl Alcohol
41744-75-6

isostearyl Alcohol

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Conditions
ConditionsYield
With potassium permanganate; tetrabutylammomium bromide; acetic acid In dichloromethane; water for 24h; Reflux;82%
8-methylnonanoic acid
5963-14-4

8-methylnonanoic acid

sebacic acid mono methyl ester
818-88-2

sebacic acid mono methyl ester

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Conditions
ConditionsYield
With methanol; sodium und bei der Elektrolyse des Reaktionsgemisches und Behandlung des Reaktionsprodukts mit wss.-methanol.Alkalilauge;
adipic acid monomethyl ester
627-91-8

adipic acid monomethyl ester

isomyristic acid
2724-57-4

isomyristic acid

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

methyl isostearate
5129-61-3

methyl isostearate

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

16-methyl-10-oxo-heptadecanoic acid
95318-26-6

16-methyl-10-oxo-heptadecanoic acid

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Conditions
ConditionsYield
With hydroxide; hydrazine
5-oxo-2-methyl-heptadecanoic acid (17)

5-oxo-2-methyl-heptadecanoic acid (17)

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Conditions
ConditionsYield
With hydrogenchloride; amalgamated zinc; acetic acid
8-oxo-2-methyl-heptadecanoic acid (17)

8-oxo-2-methyl-heptadecanoic acid (17)

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Conditions
ConditionsYield
With hydrogenchloride; amalgamated zinc; acetic acid
1-chloro-5-iodopentane
60274-60-4

1-chloro-5-iodopentane

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: liquid ammonia
2: ethanol / Erhitzen der Reaktionsloesung mit wss.Natronlauge
3: platinum; ethyl acetate / Hydrogenation
View Scheme
1-chloro-11-methyl-dodec-6-yne

1-chloro-11-methyl-dodec-6-yne

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: ethanol / Erhitzen der Reaktionsloesung mit wss.Natronlauge
2: platinum; ethyl acetate / Hydrogenation
View Scheme
12-methyl-tridec-7-ynoic acid
857078-90-1

12-methyl-tridec-7-ynoic acid

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: platinum; ethyl acetate / Hydrogenation
View Scheme
sebacic acid mono methyl ester
818-88-2

sebacic acid mono methyl ester

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: methanol; sodium / Electrolysis.und anschliessend Hydrolyse
View Scheme
10-(5-isobutyl-thiophen-2-yl)-10-oxo-decanoic acid
82854-47-5

10-(5-isobutyl-thiophen-2-yl)-10-oxo-decanoic acid

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: (i) Raney-Ni, aq. Na2CO3, (ii) CrO3
2: N2H4, OH-
View Scheme
16-methylheptadecane-1,16-diol

16-methylheptadecane-1,16-diol

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: boron trifluoride diethyl etherate; triethylsilane / dichloromethane / 0.75 h / 0 - 20 °C / Inert atmosphere
2: tetrabutylammomium bromide; potassium permanganate; acetic acid / dichloromethane; water / 24 h / Reflux
View Scheme
16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

betulin 28-O-isostearylic acid

betulin 28-O-isostearylic acid

Conditions
ConditionsYield
titanium(IV) isopropylate In toluene for 3 - 5h; Product distribution / selectivity; Heating / reflux;81%
16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

betulin
473-98-3

betulin

28-O-isostearylic acid ester of betulin

28-O-isostearylic acid ester of betulin

Conditions
ConditionsYield
titanium(IV) isopropylate In toluene for 3h; Product distribution / selectivity; Heating / reflux;81%
sebacic acid mono methyl ester
818-88-2

sebacic acid mono methyl ester

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

24-methyl-pentacosanoic acid
6006-91-3

24-methyl-pentacosanoic acid

Conditions
ConditionsYield
With methanol; sodium Electrolysis.an Platin-Elektroden und Behandlung des Reaktionsprodukts mit wss.-aethanol.Kalilauge;
16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

isostearyl Alcohol
41744-75-6

isostearyl Alcohol

Conditions
ConditionsYield
With lithium aluminium tetrahydride
16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

16-methylheptadecanoic acid chloride
33144-09-1

16-methylheptadecanoic acid chloride

Conditions
ConditionsYield
With thionyl chloride at 60℃;
With thionyl chloride at 20 - 40℃; for 1.33333h;
With thionyl chloride Heating / reflux;
With oxalyl dichloride In N,N-dimethyl-formamide; toluene at 40℃; for 0.5h; Inert atmosphere;
With thionyl chloride In benzene for 4h; Reflux;
16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol
100-79-8

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol

16-methyl-heptadecanoic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

16-methyl-heptadecanoic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In tetrachloromethane Esterification;
16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

A

betulin 28-O-isostearylic acid

betulin 28-O-isostearylic acid

B

betulin 3,28-O-isostearylic acid diester

betulin 3,28-O-isostearylic acid diester

Conditions
ConditionsYield
toluene-4-sulfonic acid In toluene for 4.5 - 5h; Product distribution / selectivity; Heating / reflux;
16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

betulin
473-98-3

betulin

A

28-O-isostearylic acid ester of betulin

28-O-isostearylic acid ester of betulin

B

3,28-O-isostearylic acid diester of betulin

3,28-O-isostearylic acid diester of betulin

Conditions
ConditionsYield
toluene-4-sulfonic acid In toluene for 4.5h; Product distribution / selectivity; Heating / reflux;
16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

glycerol monoisostearate

glycerol monoisostearate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 4-(dimethylamino)pyridine (DMAP); N,N'-dicyclohexyl-carbodiimide (DCC) / CCl4
2: hydrogen chloride (HCl) gas / 0.17 h / -75 °C
View Scheme
16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

C33H48N2O6

C33H48N2O6

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: thionyl chloride / 60 °C
2: 1.) pyridine, 2.) N,N'-dicyclohexylcarbodiimide, N,N-dimethyl-4-aminopyridine / 1.) a) RT, 3 h, b) 60 deg C, 1 h, 2.) CH2Cl2, RT, 14 h
View Scheme
16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

24-methyl-pentacosan-1-ol
63785-24-0

24-methyl-pentacosan-1-ol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: methanol; sodium / Electrolysis.an Platin-Elektroden und Behandlung des Reaktionsprodukts mit wss.-aethanol.Kalilauge
2: lithium alanate
View Scheme
1-Tetradecanol
112-72-1

1-Tetradecanol

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

myristyl isostearate
1073730-25-2

myristyl isostearate

Conditions
ConditionsYield
ZrOCl2 hydrate In 1,3,5-trimethyl-benzene at 165℃; for 24h; Product distribution / selectivity;34 %Chromat.
1-dodecyl alcohol
112-53-8

1-dodecyl alcohol

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

C30H60O2
1073730-23-0

C30H60O2

Conditions
ConditionsYield
ZrOCl2 hydrate In 1,3,5-trimethyl-benzene at 165℃; for 24h; Product distribution / selectivity;35 %Chromat.
1-octadecanol
112-92-5

1-octadecanol

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

C36H72O2
178997-50-7

C36H72O2

Conditions
ConditionsYield
ZrOCl2 hydrate In 1,3,5-trimethyl-benzene at 165℃; for 24h; Product distribution / selectivity;28 %Chromat.
1-Hexadecanol
36653-82-4

1-Hexadecanol

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

hexadecyl isostearate

hexadecyl isostearate

Conditions
ConditionsYield
ZrOCl2 hydrate In 1,3,5-trimethyl-benzene at 165℃; for 24h; Product distribution / selectivity;31 %Chromat.
ZrOCl2 hydrate In tetralin at 207℃; for 24h; Product distribution / selectivity;55 %Chromat.
In 1,3,5-trimethyl-benzene at 165℃; for 24h; Product distribution / selectivity;73 %Chromat.
decan-2-ol
1120-06-5

decan-2-ol

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

C28H56O2
1073730-29-6

C28H56O2

Conditions
ConditionsYield
aluminum chloride hexahydrate In 1,3,5-trimethyl-benzene at 162℃; for 24h; Product distribution / selectivity;10.8 %Chromat.
magnesium silicate

magnesium silicate

16-methylheptadecanoic acid
2724-58-5

16-methylheptadecanoic acid

Reaxys ID: 11384627

Reaxys ID: 11384627

2724-58-5Relevant articles and documents

A practical synthesis of long-chain iso-fatty acids (iso-C 12-C19) and related natural products

Richardson, Mark B.,Williams, Spencer J.

supporting information, p. 1807 - 1812 (2013/10/22)

A gram-scale synthesis of terminally-branched iso-fatty acids (iso-C 12-C19) was developed commencing with methyl undec-10-enoate (methyl undecylenate) (for iso-C12-C14) or the C15 and C16 lactones pentadecanolide (for iso-C 15-C17) and hexadecanolide (for iso-C18-C 19). Central to the approaches outlined is the two-step construction of the terminal isopropyl group through addition of methylmagnesium bromide to the ester/lactones and selective reduction of the resulting tertiary alcohols. Thus, the C12, C17 and C18 iso-fatty acids were obtained in three steps from commercially-available starting materials, and the remaining C13-C16 and C19 iso-fatty acids were prepared by homologation or recursive dehomologations of these fatty acids or through intercepting appropriate intermediates. Highlighting the synthetic potential of the iso-fatty acids and various intermediates prepared herein, we describe the synthesis of the natural products (S)-2,15-dimethylpalmitic acid, (S)-2-hydroxy-15-methylpalmitic acid, and 2-oxo-14-methylpentadecane.

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