• Name

  Butane, 1,1,3-triethoxy-

• EINECS
• CAS No. 5870-82-6
• Article Data25
• CAS DataBase
• Density 0.891g/cm³
• Solubility
• Melting Point
• Formula C10H22 O3
• Boiling Point 225.5°Cat760mmHg
• Molecular Weight 190.283
• Flash Point 79.6°C
• Transport Information
• Appearance
• Safety A poison by ingestion and skin contact. Low toxicity by inhalation. A mild skin irritant. When heated to decomposition it emits acrid smoke and irritating vapors.
• Risk Codes
• Molecular Structure
• Hazard Symbols A poison by ingestion and skin contact. Low toxicity by inhalation. A mild skin irritant.
• Synonyms Butyraldehyde,3-ethoxy-, diethyl acetal (6CI,7CI,8CI); 1,1,3-Triethoxybutane; NSC 406853
• PSA 27.69000
• LogP 2.20060

Synthetic route

105-57-7

diethyl acetal

109-92-2

ethyl vinyl ether

5870-82-6

1,1,3-triethoxy-butane

Conditions

Conditions	Yield
NdNaY at 0 - 25℃; for 0.5h;	49%
With boron trifluoride diethyl etherate at 35 - 40℃;
With iron(III) chloride; butan-1-ol

105-57-7

diethyl acetal

928-55-2

ethyl 1-propenyl ether

109-63-7

trifluoroborane diethyl ether

A

5870-82-6

1,1,3-triethoxy-butane

B

869-33-0

1,1,3,5-tetraethoxy-hexane

C

870-82-6

1,1,3,5,7-pentaethoxy-octane

Conditions

Conditions	Yield
at 35 - 40℃;

...Expand

105-57-7

diethyl acetal

929-05-5

1-ethoxybut-1-ene

109-63-7

trifluoroborane diethyl ether

A

5870-82-6

1,1,3-triethoxy-butane

B

869-33-0

1,1,3,5-tetraethoxy-hexane

C

870-82-6

1,1,3,5,7-pentaethoxy-octane

Conditions

Conditions	Yield
at 35 - 40℃;

...Expand

105-57-7

diethyl acetal

41183-53-3

1-ethoxy-2-ethyl-hex-1-ene

109-63-7

trifluoroborane diethyl ether

A

5870-82-6

1,1,3-triethoxy-butane

B

869-33-0

1,1,3,5-tetraethoxy-hexane

C

870-82-6

1,1,3,5,7-pentaethoxy-octane

Conditions

Conditions	Yield
at 35 - 40℃;

...Expand

105-57-7

diethyl acetal

5870-82-6

1,1,3-triethoxy-butane

Conditions

Conditions	Yield
With boron fluoride ether
With zinc(II) chloride
beim Erhitzen mit Bleicherde;
With boron trifluoride diethyl etherate; zinc(II) chloride

72663-76-4

3-ethoxy-butyraldehyde

A

5870-82-6

1,1,3-triethoxy-butane

B

123-73-9

crotonaldehyde

Conditions

Conditions	Yield

105-57-7

diethyl acetal

109-63-7

trifluoroborane diethyl ether

109-92-2

ethyl vinyl ether

A

5870-82-6

1,1,3-triethoxy-butane

B

869-33-0

1,1,3,5-tetraethoxy-hexane

C

870-82-6

1,1,3,5,7-pentaethoxy-octane

Conditions

Conditions	Yield
at 35 - 40℃;

...Expand

78-10-4

tetraethoxy orthosilicate

123-73-9

crotonaldehyde

5870-82-6

1,1,3-triethoxy-butane

Conditions

Conditions	Yield
With hydrogenchloride

64-17-5

ethanol

123-73-9

crotonaldehyde

5870-82-6

1,1,3-triethoxy-butane

Conditions

Conditions	Yield
With sulfuric acid
With imino-methyl ether hydrochloride

105-57-7

diethyl acetal

108-05-4

vinyl acetate

5870-82-6

1,1,3-triethoxy-butane

Conditions

Conditions	Yield
With boron trifluoride; acetic acid; mercury(II) oxide

N,N-dimethyl-formamide; compound with diethyl sulfate (1:1)

123-73-9

crotonaldehyde

5870-82-6

1,1,3-triethoxy-butane

Conditions

Conditions	Yield
In ethanol

7647-01-0

hydrogenchloride

78-10-4

tetraethoxy orthosilicate

64-17-5

ethanol

123-73-9

crotonaldehyde

5870-82-6

1,1,3-triethoxy-butane

Conditions

Conditions	Yield

...Expand

64-17-5

ethanol

7664-93-9

sulfuric acid

123-73-9

crotonaldehyde

A

72663-76-4

3-ethoxy-butyraldehyde

B

5870-82-6

1,1,3-triethoxy-butane

Conditions

Conditions	Yield

...Expand

105-57-7

diethyl acetal

109-92-2

ethyl vinyl ether

BF3+ ether

BF3+ ether

A

5870-82-6

1,1,3-triethoxy-butane

B

869-33-0

1,1,3,5-tetraethoxy-hexane

C

870-82-6

1,1,3,5,7-pentaethoxy-octane

Conditions

Conditions	Yield
at 35 - 40℃;

...Expand

7647-01-0

hydrogenchloride

123-73-9

trans-Crotonaldehyde

64-17-5

ethanol

A

4-ethoxy-2-(2-ethoxy-propyl)-6-methyl-[1,3]dioxane

B

72663-76-4

3-ethoxy-butyraldehyde

C

5870-82-6

1,1,3-triethoxy-butane

Conditions

Conditions	Yield

...Expand

64-17-5

ethanol

123-73-9

crotonaldehyde

A

7647-01-0

hydrogenchloride

B

5870-82-6

1,1,3-triethoxy-butane

Conditions

Conditions	Yield
With dichloromethane unter Entfernen des entstandenen Wassers;

...Expand

5870-82-6

1,1,3-triethoxy-butane

3296-60-4

bis(hydroxymethyl)phenylphosphine sulfide

111514-38-6, 111514-39-7

2-propenyl-5-phenyl-5-thio-1,3,5-dioxaphosphorinane

Conditions

Conditions	Yield
at 180℃;	80%

5870-82-6

1,1,3-triethoxy-butane

197565-89-2

1,2-Dithiomethyl-4,5-dimethylbenzol

10153-31-8

1,5-dihydro-3,7,8-trimethyl-3H-2,4-benzodithiepin

Conditions

Conditions	Yield
With boron trifluoride In chloroform; acetic acid at 65℃; Mechanism; Product distribution; other mono- and dialkyl-substituted 1,1,3-triethoxypropanes;	25%

5870-82-6

1,1,3-triethoxy-butane

123-73-9

trans-Crotonaldehyde

Conditions

Conditions	Yield
With hydrogenchloride

5870-82-6

1,1,3-triethoxy-butane

19774-34-6

(E)-1-ethoxybuta-1,3-diene

Conditions

Conditions	Yield
With sodium dihydrogenphosphate at 320℃; bei vermindertem Druck;
With trimagnesium phosphate; silica gel at 200 - 350℃; under 8 - 18 Torr; und andere Katalysatoren;
With barium metasilicate at 270 - 312℃;
With ammonium dihydrogen phosphate at 200℃;
With quinoline; toluene-4-sulfonic acid at 240℃;

5870-82-6

1,1,3-triethoxy-butane

5614-32-4

1-ethoxybuta-1,3-diene

Conditions

Conditions	Yield
at 200 - 350℃; ueber verschiedenen Katalysatoren;
at 250 - 350℃; ueber Katalysatoren;

5870-82-6

1,1,3-triethoxy-butane

72663-76-4

3-ethoxy-butyraldehyde

Conditions

Conditions	Yield
With hydrogenchloride at 25℃;
With sulfuric acid at 30 - 40℃;
With hydrogenchloride at 25℃;

5870-82-6

1,1,3-triethoxy-butane

1,3-diethoxy-but-1-ene

Conditions

Conditions	Yield
With aluminum oxide

5870-82-6

1,1,3-triethoxy-butane

101883-07-2

3,5-diethoxy-2-(1-ethoxy-ethyl)-hexanal-diethylacetal

Conditions

Conditions	Yield
With Fuller's Earth unter Entfernen des entstehenden Aethanols;

5870-82-6

1,1,3-triethoxy-butane

109-92-2

ethyl vinyl ether

869-33-0

1,1,3,5-tetraethoxy-hexane

Conditions

Conditions	Yield
With iron(III) chloride; butan-1-ol
With boron trifluoride diethyl etherate

5870-82-6

1,1,3-triethoxy-butane

109-92-2

ethyl vinyl ether

870-81-5

1,1,3,5,7,9-hexaethoxy-decane

Conditions

Conditions	Yield
With iron(III) chloride; butan-1-ol

88996-98-9

diketene

5870-82-6

1,1,3-triethoxy-butane

(E)-2-Acetyl-5-ethoxy-hex-2-enoic acid ethyl ester

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate

5870-82-6

1,1,3-triethoxy-butane

112793-89-2

1-Chloro-1,3-diethoxy-butane

Conditions

Conditions	Yield
With boron trichloride In dichloromethane at 0℃; for 2.5h;

5870-82-6

1,1,3-triethoxy-butane

506-59-2

N,N-dimethylammonium chloride

68-12-2, 33513-42-7

N,N-dimethyl-formamide

<5-(dimethylamino)-2,4-pentadienylidene>dimethylammonium perchlorate

Conditions

Conditions	Yield
With sodium hydroxide; sodium perchlorate; trichlorophosphate 3.) water; Yield given. Multistep reaction;

...Expand

5870-82-6

1,1,3-triethoxy-butane

631-61-8

ammonium acetate

ammonium hydroxide

104-90-5

5-ethyl-2-methyl-pyridine

Conditions

Conditions	Yield
at 220 - 228℃;

...Expand

1,1,3-TRIETHOXYBUTANE Chemical Properties

1,1,3-TRIETHOXYBUTANE Toxicity Data With Reference

1,1,3-TRIETHOXYBUTANE Safety Profile