1,1-Dichloro-1-propene supplier

Name
1,1-Dichloropropene
EINECS
CAS No. 563-58-6
Article Data20
CAS DataBase
Density 1.177g/cm³
Solubility
Melting Point
Formula C₃H₄Cl₂
Boiling Point 78.1°Cat760mmHg
Molecular Weight 110.971
Flash Point 0.6°C
Transport Information
Appearance
Safety Mutation data reported. When heated to decomposition it emits toxic vapors of Cl⁻.
Risk Codes R11; R23/24/25; R52/53; R25; R39/23/24/25
Molecular Structure
Hazard Symbols F,T
Synonyms 1,1-DICHLOROPROPENE;1-Propene, 1,1-dichloro-;
PSA 0.00000
LogP 2.32530

Synthetic route

: 617-86-7
triethylsilane

: 2233-00-3
3,3,3-trichloro-1-propene

A: 7789-89-1
1,1,1-trichloropropane

B: 563-58-6
1,1-dichloropropene

C: 17873-97-1
3,3,3-trichloropropyltriethylsilane

D: 17955-48-5
hexa-Si-ethyl-Si,Si'-propanediyl-bis-silane

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate; isopropyl alcohol at 20℃; for 48h; Further byproducts given. Title compound not separated from byproducts;	A 17% B 55% C 7% D 0.4%

...Expand

: 617-86-7
triethylsilane

: 2233-00-3
3,3,3-trichloro-1-propene

A: 563-58-6
1,1-dichloropropene

B: 17873-97-1
3,3,3-trichloropropyltriethylsilane

C: 17955-48-5
hexa-Si-ethyl-Si,Si'-propanediyl-bis-silane

D: 114700-65-1
((E)-1-Chloro-propenyl)-triethyl-silane

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate; isopropyl alcohol at 20℃; for 48h; Further byproducts given. Title compound not separated from byproducts;	A 55% B 7% C 0.4% D n/a

...Expand

: 617-86-7
triethylsilane

: 2233-00-3
3,3,3-trichloro-1-propene

A: 563-58-6
1,1-dichloropropene

B: 17873-97-1
3,3,3-trichloropropyltriethylsilane

C: 17955-48-5
hexa-Si-ethyl-Si,Si'-propanediyl-bis-silane

D: 114700-64-0
((Z)-1-Chloro-propenyl)-triethyl-silane

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate; isopropyl alcohol at 20℃; for 48h; Further byproducts given. Title compound not separated from byproducts;	A 55% B 7% C 0.4% D n/a

...Expand

: 2233-00-3
3,3,3-trichloro-1-propene

A: 7789-89-1
1,1,1-trichloropropane

B: 563-58-6
1,1-dichloropropene

C: 17873-97-1
3,3,3-trichloropropyltriethylsilane

D: 17955-48-5
hexa-Si-ethyl-Si,Si'-propanediyl-bis-silane

Conditions

Conditions	Yield
With triethylsilane; dihydrogen hexachloroplatinate; isopropyl alcohol at 20℃; for 48h; Further byproducts given;	A 17% B 55% C 7% D 0.4%

...Expand

: 2233-00-3
3,3,3-trichloro-1-propene

A: 7789-89-1
1,1,1-trichloropropane

B: 563-58-6
1,1-dichloropropene

C: 114700-65-1
((E)-1-Chloro-propenyl)-triethyl-silane

D: 114700-64-0
((Z)-1-Chloro-propenyl)-triethyl-silane

Conditions

Conditions	Yield
With triethylsilane; dihydrogen hexachloroplatinate; isopropyl alcohol at 20℃; for 48h; Further byproducts given;	A 17% B 55% C n/a D n/a

...Expand

: 7789-89-1
1,1,1-trichloropropane

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
With iron(III) chloride

: 598-77-6
1,1,2-trichloropropane

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
With sodium hydroxide
With benzyltrimethylammonium chloride; sodium hydroxide In water at 70℃; for 4h;
With sodium hydroxide

: 21700-31-2
1,1,1,2,3-pentachloro-propane

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
With ethanol; zinc at 65℃;

: 2567-14-8
3,3-dichloroallyl chloride

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
With ethanol; zinc at 65℃;

: 4358-76-3
1,1-dichloro-3-iodo-propene

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
With lithium aluminium tetrahydride; diethyl ether

: 76-36-8
2,2,3-trichlorobutyraldehyde

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
With potassium hydroxide

: 19376-15-9
2-acetoxy-1,1,1-trichloropropane

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
With ethanol; zinc

: 187737-37-7
propene

A: 6262-54-0
1,1,1,3,3-pentachloropropene

B: 563-58-6
1,1-dichloropropene

C: 2567-14-8
3,3-dichloroallyl chloride

D: 1888-71-7
perchloropropene

E: 18611-43-3
1,1,3,3-tetrachloro-1-propene

F: 590-21-6
propenyl chloride

Conditions

Conditions	Yield
With hydrogenchloride; oxygen; CuCl2 on calcined alumina at 490℃; Product distribution; several conditions investigated;

...Expand

: 2088-35-9
1,1-dichlorocyclopropane

A: 78-88-6
2,3-Dichloroprop-1-ene

B: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
In gas at 336.9 - 451.9℃; under 10.5 Torr; Kinetics; Product distribution;

2.2.3-trichlorobutyrate sodium: 2.2.3-trichlorobutyrate sodium

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
Bei der Destillation;

: 598-77-6
1,1,2-trichloropropane

20 percent NaOH: 20 percent NaOH

: 563-58-6
1,1-dichloropropene

alcoholate of butyrchloroas: alcoholate of butyrchloroas

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
With potassium hydroxide

asymm.trichloro-isopropyl alcohol: asymm.trichloro-isopropyl alcohol

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
With acetic acid; zinc

: 1-ethoxy-2,2,3-trichloro-butan-1-ol

diluted KOH-solution: diluted KOH-solution

: 563-58-6
1,1-dichloropropene

: 64-17-5
ethanol

: 21700-31-2
1,1,1,2,3-pentachloro-propane

zinc: zinc

: 563-58-6
1,1-dichloropropene

...Expand

: 64-17-5
ethanol

: 2567-14-8
3,3-dichloroallyl chloride

zinc: zinc

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
at 65℃;

...Expand

: 76-00-6
1,1,1-trichloropropan-2-ol

: 64-19-7
acetic acid

zinc: zinc

: 563-58-6
1,1-dichloropropene

...Expand

: 76-40-4
2,2,3-tri-chlorobutane-1,1-diol

KOH-solution: KOH-solution

A: 64-18-6
formic acid

B: 563-58-6
1,1-dichloropropene

...Expand

: 563-58-6
1,1-dichloropropene

: phenylmagnesium bromide

: 4541-85-9
(Z)-(1-Chloro-1-propenyl)benzene

Conditions

Conditions	Yield
With PdCl2(dbbp) In diethyl ether for 2h; Heating;	90%

: 563-58-6
1,1-dichloropropene

: 36469-73-5
3,3-dichloro-2-propen-1-yl bromide

Conditions

Conditions	Yield
With N-Bromosuccinimide; Perbenzoic acid In tetrachloromethane for 4h; Heating;	75%
With N-Bromosuccinimide
With N-Bromosuccinimide; dibenzoyl peroxide
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane

: 563-58-6
1,1-dichloropropene

: 3294-57-3
phenyltrichloromethylmercury

: 164783-82-8
1,1,2,2-tetrachloro-3-methylcyclopropane

Conditions

Conditions	Yield
In benzene for 18h; Heating;	27%

: 563-58-6
1,1-dichloropropene

: 650-51-1
sodium trichloroacetate

: 164783-82-8
1,1,2,2-tetrachloro-3-methylcyclopropane

Conditions

Conditions	Yield
In 1,2-dimethoxyethane for 30h; Heating;	24%

: 67-66-3
chloroform

: 563-58-6
1,1-dichloropropene

: 164783-82-8
1,1,2,2-tetrachloro-3-methylcyclopropane

Conditions

Conditions	Yield
With sodium hydroxide; cetyltrimethylammonim bromide In water for 24h; Ambient temperature;	14%

: 563-58-6
1,1-dichloropropene

A: 421-07-8
1,1,1-trifluoropropane

B: 421-02-3
1-chloro-1,1-difluoro-propane

Conditions

Conditions	Yield
With hydrogen fluoride at 90 - 100℃;

: 563-58-6
1,1-dichloropropene

: 421-02-3
1-chloro-1,1-difluoro-propane

Conditions

Conditions	Yield
With hydrogen fluoride at 100℃;

: 563-58-6
1,1-dichloropropene

A: 421-02-3
1-chloro-1,1-difluoro-propane

B: 7799-56-6
1,1-dichloro-1-fluoro-propane

Conditions

Conditions	Yield
With hydrogen fluoride at 100℃; under 14710.2 Torr;

: 563-58-6
1,1-dichloropropene

: 7789-89-1
1,1,1-trichloropropane

Conditions

Conditions	Yield
With hydrogenchloride; aluminium trichloride at 5 - 10℃;

: 563-58-6
1,1-dichloropropene

: 812-03-3
1,1,1,2-tetrachloropropane

Conditions

Conditions	Yield
With chlorine; iron(III) chloride
With chlorine unter Lichtausschluss;
With carbon disulfide; chlorine

: 563-58-6
1,1-dichloropropene

: 872826-15-8
1,2-dibromo-1,1-dichloro-propane

Conditions

Conditions	Yield
With bromine

: 563-58-6
1,1-dichloropropene

: 64240-29-5
1,1,1,2,2-pentachloropropane

Conditions

Conditions	Yield
With chlorine

: 563-58-6
1,1-dichloropropene

: 2567-14-8
3,3-dichloroallyl chloride

Conditions

Conditions	Yield
With chlorine at 550℃;

: 563-58-6
1,1-dichloropropene

: 590-93-2
2-Butynoic acid

Conditions

Conditions	Yield
anschliesssend Behandeln mit Wasser,Alkohol und Aether und CO2;

: 563-58-6
1,1-dichloropropene

: 98134-66-8
bis-(β,β,β-trichloro-isopropyl)-disulfide

Conditions

Conditions	Yield
With disulfur dichloride; iron(III) chloride

: 563-58-6
1,1-dichloropropene

: 1071-35-8
sodium but-2-ynoate

Conditions

Conditions	Yield
With sodium bei der Einw. von CO2 auf das Reaktionsprodukts;

: 563-58-6
1,1-dichloropropene

: 74-99-7
prop-1-yne

Conditions

Conditions	Yield
With potassium hydroxide; ethanol at 150℃;
With sodium Zers. des Reaktionsproduktes mit Wasser;

: 563-58-6
1,1-dichloropropene

: 17356-08-0
thiourea

: 103854-82-6
S-(1-chloro-allyl)-isothiourea

1,1-Dichloro-1-propene Chemical Properties

IUPAC Name: 1,1-Dichloroprop-1-ene
Synonyms: 1,1-Dichloro-1-propene ; 1,1-Dichloroprop-1-ene ; 1,1-Dichloropropene ; 1-Propene, 1,1-dichloro-
Product Categories: Analytical Chemistry;Standard Solution of Volatile Organic Compounds for Water & Soil Analysis;Standard Solutions (VOC)
CAS NO:563-58-6
Molecular Formula of 1,1-Dichloro-1-propene (CAS NO.563-58-6) :C₃H₄Cl₂
Molecular Weight of 1,1-Dichloro-1-propene (CAS NO.563-58-6) :110.97
Molecular Structure of 1,1-Dichloro-1-propene (CAS NO.563-58-6) :
EINECS: 209-253-3
Index of Refraction: 1.454
Surface Tension: 25.5 dyne/cm
Density: 1.177 g/cm³
Flash Point: 0.6 °C
Enthalpy of Vaporization: 30.58 kJ/mol
Boiling Point: 78.1 °C at 760 mmHg
Vapour Pressure: 104 mmHg at 25°C
Storage temp:Refrigerator

1,1-Dichloro-1-propene Toxicity Data With Reference

mmo-sat 750 nL/plate

BCPCA6 Biochemical Pharmacology. 35 (1986),195.

1,1-Dichloro-1-propene Safety Profile

Mutation data reported. When heated to decomposition it emits toxic vapors of Cl⁻.
Hazard CodesF, Toxic T
Risk Statements 11-23/24/25-52/53-39
R11:Highly flammable.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R39:Danger of very serious irreversible effects.
Safety Statements 16-26-36/37/39-61-45-33-29-7
S7:Keep container tightly closed.
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S33:Take precautionary measures against static discharges.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR 2047
RTECS UC8290000
HazardClass 3.1
PackingGroup II

Product Name

1,1-Dichloropropene

Synthetic route

1,1-Dichloro-1-propene Chemical Properties

1,1-Dichloro-1-propene Toxicity Data With Reference

1,1-Dichloro-1-propene Safety Profile

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