1,1-Dimethylhydrazine hydrochloride supplier

Name
1,1-Dimethylhydrazine hydrochloride
EINECS
CAS No. 593-82-8
Article Data7
CAS DataBase
Density 0.829g/cm³
Solubility almost transparency
Melting Point 85°C
Formula C2H8 N2 . Cl H
Boiling Point 63.9°Cat760mmHg
Molecular Weight 96.5599
Flash Point 1.1°C
Transport Information
Appearance
Safety Poison by ingestion, intraperitoneal, and intravenous routes. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of HCl and NO_x.
Risk Codes R20/21; R28
Molecular Structure
Hazard Symbols
Synonyms 1,1-Dimethylhydrazinehydrochloride; N,N-Dimethylhydrazine hydrochloride
PSA 29.26000
LogP 0.92400

Synthetic route

: 882037-58-3
1,2-dichlorovinyl propyl ketone

: 57-14-7
1,1-dimethylhydrazine

: 593-82-8
N,N-dimethylhydrazine hydrochloride

Conditions

Conditions	Yield
In diethyl ether	89%

: 506-59-2
N,N-dimethylammonium chloride

: 593-82-8
N,N-dimethylhydrazine hydrochloride

Conditions

Conditions	Yield
Stage #1: N,N-dimethylammonium chloride With sodium nitrite In water at 20℃; Cooling with ice; Stage #2: With zinc In water at 20℃; Cooling with ice;	63.2%

: 6439-49-2
1-(2-carbamylethyl)-1,1-dimethylhydrazinium chloride

A: 593-82-8
N,N-dimethylhydrazine hydrochloride

B: 6487-38-3
3-hydroxypropanoic acid sodium salt

Conditions

Conditions	Yield
With sodium hydroxide for 1.5h; Heating;	A 54% B n/a

: 62-75-9
N-Nitrosodimethylamine

: 593-82-8
N,N-dimethylhydrazine hydrochloride

Conditions

Conditions	Yield
With acetic acid; zinc at 25 - 30℃; Dampfdestillation und nachfolgendes Abdampfen mit Salzsaeure;

: 1730-69-4
dibutylchloroborane

: 57-14-7
1,1-dimethylhydrazine

A: 14575-27-0
(n-C4H9)2BNHN(CH3)2

B: 593-82-8
N,N-dimethylhydrazine hydrochloride

...Expand

: 58758-48-8
2-(prop-2-ynyloxy)-1-naphthaldehyde

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 108120-55-4
2,2-Dimethyl-1,2,4,11c-tetrahydro-5-oxa-1-aza-2-azonia-cyclopenta[c]phenanthrene; chloride

Conditions

Conditions	Yield
In ethanol for 3h; Heating;	100%

: 19530-43-9
2-allyloxy-1-naphthaldehyde

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 108120-49-6
2,2-dimethyl-1,2,3,3a,4,11c-hexahydronaphtho<1',2':5,6>pyrano<4,3-c>pyrazolium chloride

Conditions

Conditions	Yield
In ethanol for 3h; Heating;	100%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 96601-25-1
(E)-ethyl 4-(1-formyl-2-naphthoxy)but-2-enoate

: 108120-53-2
3-Ethoxycarbonyl-2,2-dimethyl-1,2,3,3a,4,11c-hexahydro-5-oxa-1-aza-2-azonia-cyclopenta[c]phenanthrene; chloride

Conditions

Conditions	Yield
In ethanol for 3h; Heating;	100%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 131685-20-6
2-<2-(benzyloxy)ethyl>cyclopentanone

: 1488133-66-9
C16H24N2O

Conditions

Conditions	Yield
With triethylamine In ethanol for 16h; Inert atmosphere; Reflux;	98%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 3-oxo-2-(phenylhydrazono)-3-(2-thienyl)propanal

: (2Z,3Z)-3-(2,2-dimethylhydrazono)-2-(2-phenylhydrazono)-1-(thiophen-2-yl)propan-1-one

Conditions

Conditions	Yield
With sodium acetate In methanol at 25℃; Inert atmosphere;	97%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 3-oxo-3-phenyl-2-(2-phenylhydrazono)propanal

: (2Z,3Z)-3-(2,2-dimethylhydrazono)-1-phenyl-2-(2-phenylhydrazono)propan-1-one

Conditions

Conditions	Yield
With sodium acetate In methanol at 25℃; Inert atmosphere;	96%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 3-(2-furyl)-3-oxo-2-(phenylhydrazono)propanal

: (2Z,3Z)-3-(2,2-dimethylhydrazono)-1-(furan-2-yl)-2-(2-phenylhydrazono)propan-1-one

Conditions

Conditions	Yield
With sodium acetate In methanol at 25℃; Inert atmosphere;	94%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 108120-33-8
(E)-4-(1-Formyl-naphthalen-2-yloxy)-but-2-enenitrile

: 108120-52-1
3-Cyano-2,2-dimethyl-1,2,3,3a,4,11c-hexahydro-5-oxa-1-aza-2-azonia-cyclopenta[c]phenanthrene; chloride

Conditions

Conditions	Yield
In ethanol for 3h; Heating;	90%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 120-92-3
cyclopentanone

: 14090-60-9
2-cyclopentylidene-1,1-dimethylhydrazine

Conditions

Conditions	Yield
With triethylamine In ethanol for 3.5h; Inert atmosphere; Reflux;	89%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: N-(2-n-octyldodecyl)-2-pyrrolecarbaldehyde

: C27H51N3

Conditions

Conditions	Yield
With sodium acetate In tetrahydrofuran; methanol at 85℃; for 8h; Inert atmosphere;	82%

: 630-72-8
trinitroacetonitrile

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: dimethylhydrazinium salt of dinitroacetonitrile

Conditions

Conditions	Yield
In methanol; tetrachloromethane for 2h;	80%

: pentacyanonitrosylferrate(III)

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: pentacyano(1,1-dimethylhydrazine)ferrate(II)(3-)

Conditions

Conditions	Yield
With NaOH; NaCl In water Kinetics; byproducts: Me2NH, N2O; hydrazine soln. contg. buffer and solid Fe complex mixed at 25.0°C, pH 6-10, ionic strength 0.1 M (NaCl); not isolated; monitored spectrophotometrically;	80%

: 687970-88-3
(15)N-pentacyanonitrosylferrate(II)(2-)

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: pentacyano(1,1-dimethylhydrazine)ferrate(II)(3-)

Conditions

Conditions	Yield
With NaOH; NaCl In water byproducts: Me2NH, N(15)NO; hydrazine soln. contg. buffer and solid Fe complex mixed at 25.0°C, pH 9.4, ionic strength 0.1 M (NaCl); not isolated; monitored spectrophotometrically;	80%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 108120-31-6
2-[((E)-but-2-enyl)oxy]-naphthalene-1-carbaldehyde

: 108120-50-9
2,2,3-Trimethyl-1,2,3,3a,4,11c-hexahydro-5-oxa-1-aza-2-azonia-cyclopenta[c]phenanthrene; chloride

Conditions

Conditions	Yield
In ethanol for 3h; Heating;	79%

: 698-63-5
5-nitrofurane-2-carboxaldehyde

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 69819-71-2
5-nitro-2-furancarboxaldehyde dimethylhydrazone

Conditions

Conditions	Yield
In methanol; water at 20℃; Darkness;	75%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 108120-32-7
2-((E)-3-phenyl-allyloxy)-naphthalene-1-carbaldehyde

: 108120-51-0
2,2-Dimethyl-3-phenyl-1,2,3,3a,4,11c-hexahydro-5-oxa-1-aza-2-azonia-cyclopenta[c]phenanthrene; chloride

Conditions

Conditions	Yield
In ethanol for 3h; Heating;	70%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 100-52-7
benzaldehyde

: 292638-85-8
acrylic acid methyl ester

: 108120-67-8
1,1-dimethyl-4-(methoxycarbonyl)-3-phenylpyrazolidinium chloride

Conditions

Conditions	Yield
With hydroquinone In methanol for 4h; Heating;	66%

...Expand

: 69690-06-8
4-formyl-3-methyl-2-butenyl phenyl sulfide

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 1606991-83-6
(E)-1,1-dimethyl-2-((E)-2-methyl-4-(phenylthio)but-2-enylidene)hydrazine

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 24h; Inert atmosphere;	63%

: 59987-69-8
trinitromethyladamantane

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: N'-[1-Adamantan-1-yl-1-nitro-meth-(Z)-ylidene]-N,N-dimethyl-hydrazine

Conditions

Conditions	Yield
In methanol for 120h;	59%

: 12093-10-6
ferrocenecarboxaldehyde

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: C10H9FeCHNN(CH3)2

Conditions

Conditions	Yield
In ethanol boiling;	56%
In ethanol boiling;	56%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 57597-64-5
7-diethylaminocoumarine-3-aldehyde

: (E)-7-(diethylamino)-3-((2,2-dimethylhydrazineylidene)methyl)-2H-chromen-2-one

Conditions

Conditions	Yield
In ethanol at 20℃; for 36h;	56%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 74605-73-5
2-Adamantan-1-yl-N-(2,2,2-trinitro-ethyl)-acetamide

: 2-Adamantan-1-yl-N-[2-(dimethyl-hydrazono)-2-nitro-ethyl]-acetamide

Conditions

Conditions	Yield
In methanol for 120h;	54%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 3-Bromo-adamantane-1-carboxylic acid (2,2,2-trinitro-ethyl)-amide

: 3-Bromo-adamantane-1-carboxylic acid [2-(dimethyl-hydrazono)-2-nitro-ethyl]-amide

Conditions

Conditions	Yield
In methanol for 120h;	53%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 74605-68-8
Adamantane-1-carboxylic acid (2,2,2-trinitro-ethyl)-amide

: Adamantane-1-carboxylic acid [2-(dimethyl-hydrazono)-2-nitro-ethyl]-amide

Conditions

Conditions	Yield
In methanol for 120h;	52%

: 58758-47-7
2-(3-methylbut-2-enyloxy)naphthalene-1-carbaldehyde

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 108120-54-3
2,2,3,3-Tetramethyl-1,2,3,3a,4,11c-hexahydro-5-oxa-1-aza-2-azonia-cyclopenta[c]phenanthrene; chloride

Conditions

Conditions	Yield
In ethanol for 3h; Heating;	51%

: 517-25-9
trinitromethane

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 6421-08-5
dinitroformaldehyde dimethylhydrazone

Conditions

Conditions	Yield
In methanol at 20℃;	47%

: 593-82-8
N,N-dimethylhydrazine hydrochloride

: 74605-69-9
3-Hydroxy-adamantane-1-carboxylic acid (2,2,2-trinitro-ethyl)-amide

: 3-Hydroxy-adamantane-1-carboxylic acid [2-(dimethyl-hydrazono)-2-nitro-ethyl]-amide

Conditions

Conditions	Yield
In methanol for 120h;	47%

1,1-Dimethylhydrazine hydrochloride Chemical Properties

IUPAC Name: 1,1-Dimethylhydrazine hydrochloride
Synonyms:1,1-Dimethylhydrazine hydrochloride ; 1,1-Dimethylhydrazine ; Hydrazine, 1,1-dimethyl-, hydrochloride
CAS NO: 593-82-8
Molecular Formula of 1,1-Dimethylhydrazine hydrochloride (CAS NO.593-82-8) :C₂H₉ClN₂
Molecular Weight of 1,1-Dimethylhydrazine hydrochloride (CAS NO.593-82-8) :96.56
Molecular structure of 1,1-Dimethylhydrazine hydrochloride (CAS NO.593-82-8) :
EINECS: 209-811-6
Flash Point: 1.1 °C
Enthalpy of Vaporization: 30.6 kJ/mol
Boiling Point: 63.9 °C at 760 mmHg
Vapour Pressure: 168 mmHg at 25°C
Melting point: 85°C

1,1-Dimethylhydrazine hydrochloride Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
dog	LD50	intravenous	96mg/kg (96mg/kg)	BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: EXCITEMENT	AMA Archives of Industrial Health. Vol. 13, Pg. 34, 1956.
mouse	LD50	intraperitoneal	466mg/kg (466mg/kg)	BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: EXCITEMENT BEHAVIORAL: REGIDITY	AMA Archives of Industrial Health. Vol. 13, Pg. 34, 1956.
mouse	LD50	intravenous	402mg/kg (402mg/kg)	BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: REGIDITY BEHAVIORAL: EXCITEMENT	AMA Archives of Industrial Health. Vol. 13, Pg. 34, 1956.
mouse	LD50	oral	426mg/kg (426mg/kg)	BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: EXCITEMENT BEHAVIORAL: REGIDITY	AMA Archives of Industrial Health. Vol. 13, Pg. 34, 1956.
rat	LD50	intraperitoneal	210mg/kg (210mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	AMA Archives of Industrial Health. Vol. 13, Pg. 34, 1956.
rat	LD50	intravenous	191mg/kg (191mg/kg)	BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: EXCITEMENT BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	AMA Archives of Industrial Health. Vol. 13, Pg. 34, 1956.
rat	LD50	oral	196mg/kg (196mg/kg)	BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: EXCITEMENT	AMA Archives of Industrial Health. Vol. 13, Pg. 34, 1956.

1,1-Dimethylhydrazine hydrochloride Safety Profile

Poison by ingestion, intraperitoneal, and intravenous routes. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of HCl and NO_x.
Risk Statements 20/21-28
R20/21:Harmful by inhalation and in contact with skin.
R28:Very toxic if swallowed.
Safety Statements 22-36/37/39-45
S22:Do not breathe dust.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR 2811
RTECS MV2900000

1,1-Dimethylhydrazine hydrochloride Standards and Recommendations

NIOSH REL: (Hydrazines) CL 0.15 mg/m³/2H

Product Name

1,1-Dimethylhydrazine hydrochloride

Synthetic route

1,1-Dimethylhydrazine hydrochloride Chemical Properties

1,1-Dimethylhydrazine hydrochloride Toxicity Data With Reference

1,1-Dimethylhydrazine hydrochloride Safety Profile

1,1-Dimethylhydrazine hydrochloride Standards and Recommendations

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