1,3,5-Triacryloylhexahydro-1,3,5-triazine supplier

Name
1,3,5-Triacryloylhexahydro-1,3,5-triazine
EINECS 213-501-6
CAS No. 959-52-4
Article Data12
CAS DataBase
Density 1.197 g/cm³
Solubility Slightly soluble in water
Melting Point 156 °C (dec.)(lit.)
Formula C12H15 N3 O3
Boiling Point 579.6 °C at 760 mmHg
Molecular Weight 249.269
Flash Point 301 °C
Transport Information UN 2928
Appearance
Safety Poison by ingestion and skin contact routes. Mutation data reported. A severe eye irritant. When heated to decomposition it emits toxic vapors of NO_x.
Risk Codes R23/24/25;R34;R42/43
Molecular Structure
Hazard Symbols
Synonyms 1,3,5-Triazine,hexahydro-1,3,5-tris(1-oxo-2-propenyl)- (9CI); s-Triazine, 1,3,5-triacryloylhexahydro-(6CI,7CI,8CI); 1,3,5-Triacryloyl-s-triazine;1,3,5-Triacryloylaminohexahydro-s-triazine;1,3,5-Triacryloylhexahydro-1,3,5-triazine;1,3,5-Triacryloylhexahydro-s-triazine; 1,3,5-Triacryloylhexahydrotriazine;1,3,5-Triacryloyltrimethylenetriamine;1,3,5-Tris(acryloyl)hexahydro-s-triazine; DU 801; Fixierer P; Fixing Agent P;Hexahydro-1,3,5-triacryloyl-s-triazine; Hexahydrotris(acryloyl)-s-triazine; NSC63839; NSC 8185; TAF; TAF (crosslinking agent);Tri(N-acryloyl)hexahydrotriazine; Triacrylformal;Triacryloylhexahydro-s-triazine; Triacryloylhexahydrotriazine;Triacryloylperhydrotriazine; Tris(N-acryloyl)hexahydrotriazine;Tris(acryloyl)hexahydro-s-triazine
PSA 60.93000
LogP -0.27000

Synthetic route

: 110-88-3
1,3,5-Trioxan

: 107-13-1
acrylonitrile

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

Conditions

Conditions	Yield
Stage #1: 1,3,5-Trioxan; acrylonitrile With sulfuric acid In chlorobenzene at 80℃; for 5h; Stage #2: With sodium hydroxide In chlorobenzene at 5 - 20℃; for 2h;	95.1%
With sulfuric acid; hydroquinone In tetrachloromethane; water at 80℃; for 1h; effect of the ratio between the catalyst and water present in the system;	91%
With sulfuric acid; hydroquinone In tetrachloromethane at 80℃; for 1h;	91%

: 50-00-0
formaldehyd

: 107-13-1
acrylonitrile

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

Conditions

Conditions	Yield
Amberlyst 15 resin In chlorobenzene at 80℃; for 4h;	95%
With sulfuric acid In chlorobenzene at 70℃; for 3h; Temperature; Solvent;	88.2%
With sulfuric acid
With sulfuric acid; acetic anhydride

: 96-27-5
rac-3-sulfanylpropane-1,2-diol

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 1123041-92-8
1,1′,1″-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2,3-dihydroxypropylthio)propan-1-one)

Conditions

Conditions	Yield
With propylamine In methanol for 0.166667h; Michael type addition;	96%
In methanol at 30℃; for 0.25h;	79.7%
Stage #1: rac-3-sulfanylpropane-1,2-diol; 1,3,5-triacryloylhexahydro-s-triazine In methanol at 20℃; for 0.25h; Stage #2: With hexan-1-amine In methanol at 20℃;	68%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 60-24-2
2-hydroxyethanethiol

: 40549-57-3
1,1',1''-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2-hydroxyethylthio)propan-1-one)

Conditions

Conditions	Yield
With propylamine In methanol	96%
With propylamine In methanol for 0.166667h; Michael type addition;	92%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 60-23-1
Cysteamine

: 1123041-98-4
1,1',1"-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2-aminoethylthio)propan-1-one)

Conditions

Conditions	Yield
In methanol for 0.166667h; Michael type addition;	95%
In methanol at 23℃; for 0.166667h;

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 2365-48-2
Methyl thioglycolate

: 1123041-93-9
trimethyl 2,2',2''-(3,3',3''-(1,3,5-triazinane-1,3,5-triyl)tris(3-oxopropane-3,1-diyl))tris(sulfanediyl)triacetate

Conditions

Conditions	Yield
With propylamine In methanol; chloroform for 0.166667h; Michael type addition;	94%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 147-93-3
Thiosalicylic acid

: 1123042-01-2
2,2',2''-(3,3',3''-(1,3,5-triazinane-1,3,5-triyl)tris(3-oxopropane-3,1-diyl))tris(sulfanediyl)tribenzoic acid

Conditions

Conditions	Yield
Stage #1: Thiosalicylic acid With potassium hydrogencarbonate In methanol at 60℃; for 1h; Stage #2: 1,3,5-triacryloylhexahydro-s-triazine In methanol at 20℃; for 0.166667h; Michael type addition;	90%

: 921-01-7, 3374-22-9, 4371-52-2, 40143-64-4, 40143-66-6, 40143-69-9, 52-90-4
rac-cysteine

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 1123042-03-4
3,3',3''-(3,3',3''-(1,3,5-triazinane-1,3,5-triyl)tris(3-oxopropane-3,1-diyl))tris(sulfanediyl)tris(2-aminopropanoic acid)

Conditions

Conditions	Yield
In methanol; water for 0.416667h; Michael type addition;	88%

: 33941-15-0
1-aza-18-crown-6

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 1-[3,5-bis-(3-1,4,7,10,13-pentaoxa-16-aza-cyclooctadec-16-yl-propionyl)-[1,3,5]triazinan-1-yl]-3-(1,4,7,10,13-pentaoxa-16-aza-cyclooctadec-16-yl)-propan-1-one

Conditions

Conditions	Yield
In methanol at 50℃; for 24h;	85.7%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 66943-05-3
1,4,7,10-tetraoxa-15-azacyclopentadecane

: 1-[3,5-bis-(3-1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl-propionyl)-[1,3,5]triazinan-1-yl]-3-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)-propan-1-one

Conditions

Conditions	Yield
In methanol at 50℃; for 24h;	84.9%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 1193-02-8
4-aminotiophenol

: 3-(4-aminophenyl)sulfanyl-1-[3,5-bis[3-(4-aminophenyl)sulfanylpropanoyl]-1,3,5-triazinan-1-yl]propan-1-one

Conditions

Conditions	Yield
With Dimethyl(phenyl)phosphine In methanol for 16h; Reflux;	84%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 137-07-5
2-amino-benzenethiol

: 1123041-99-5
1,1',1''-(1,3,5-triazinane-1,3,5-triyl)tris(3-(2-aminophenylthio)propan-1-one)

Conditions

Conditions	Yield
In methanol; chloroform for 0.166667h; Michael type addition;	82%

: 60835-71-4
4'-aminobenzo-15-crown-5-ether

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: C54H78N6O18

Conditions

Conditions	Yield
With triethylamine In methanol at 50℃; for 144h;	76.5%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 68941-06-0
4-aminobenzo-18-crown-6

: C60H90N6O21

Conditions

Conditions	Yield
With triethylamine In methanol at 50℃; for 144h;	76.4%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 83585-56-2
2-aminomethyl-15-crown-5

: 1-(3,5-Bis-{3-[(1,4,7,10,13-pentaoxa-cyclopentadec-2-ylmethyl)-amino]-propionyl}-[1,3,5]triazinan-1-yl)-3-[(1,4,7,10,13-pentaoxa-cyclopentadec-2-ylmethyl)-amino]-propan-1-one

Conditions

Conditions	Yield
In methanol at 50℃; for 24h;	72.2%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 83585-61-9
2-(aminomethyl)-18-crown-6

: 1-(3,5-Bis-{3-[(1,4,7,10,13,16-hexaoxa-cyclooctadec-2-ylmethyl)-amino]-propionyl}-[1,3,5]triazinan-1-yl)-3-[(1,4,7,10,13,16-hexaoxa-cyclooctadec-2-ylmethyl)-amino]-propan-1-one

Conditions

Conditions	Yield
In methanol at 50℃; for 24h;	71.8%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 829-85-6
diphenylphosphane

: C48H48N3O3P3

Conditions

Conditions	Yield
In 2-methyltetrahydrofuran at 90℃; for 12h; Inert atmosphere; Sealed tube; Green chemistry; regioselective reaction;	68%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 23978-55-4
1,4,10,13-tetraoxa-7,16-diazacyclooctadecane

: 868852-74-8
1-[3-acryloyl-5-(3-{16-[3-(3,5-diacryloyl-[1,3,5]triazinan-1-yl)-3-oxo-propyl]-1,4,10,13-tetraoxa-7,16-diaza-cyclooctadec-7-yl}-propionyl)-[1,3,5]triazinan-1-yl]-propenone

Conditions

Conditions	Yield
In methanol at 50℃; for 30h; Michael addition;	65.3%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 107-96-0
3-mercaptopropionic acid

: 63074-18-0
3,3',3''-(3,3',3''-(1,3,5-triazinane-1,3,5-triyl)tris(3-oxopropane-3,1-diyl))tris(sulfanediyl)tripropanoic acid

Conditions

Conditions	Yield
Stage #1: 3-mercaptopropionic acid With potassium hydrogencarbonate In methanol at 60℃; for 1h; Stage #2: 1,3,5-triacryloylhexahydro-s-triazine In methanol at 20℃; for 0.166667h; Michael type addition;	63%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 2-(3,5-bis((bis(pyridin-2-ylmethyl)amino)methyl)phenoxy)-N-(2-mercaptoethyl)acetamide

A: C48H54N10O5S

B: C84H93N17O7S2

Conditions

Conditions	Yield
With potassium carbonate In water; acetonitrile for 1h; pH=8; Inert atmosphere;	A 59% B 28%

...Expand

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 2-(3,5-bis((bis(pyridin-2-ylmethyl)amino)methyl)phenoxy)-N-(2-mercaptoethyl)acetamide

: C120H132N24O9S3

Conditions

Conditions	Yield
With potassium carbonate In [D3]acetonitrile; water-d2 for 1h; pH=8; Inert atmosphere;	58%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 68-11-1
mercaptoacetic acid

: C14H19N3O5S

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃;	40.1%
With triethylamine In dichloromethane for 24h; Cooling with ice;
With triethylamine In dichloromethane at 20℃;	1.87 g

: mercapto acetic acid

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: C14H19N3O5S

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃; for 12h;	36.87%

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: RCFRLPCRQLRCR

: TATA-FXII618

Conditions

Conditions	Yield
In acetonitrile for 0.25h;	27%
With ammonium bicarbonate In water; acetonitrile at 30℃; for 1h; pH=8;
In acetonitrile at 30℃; for 1h; pH=8;

: 1159680-21-3
(S)-2-(((9H-fluoren-9-yl)methoxy)carbonylamino)-6-(3-(2,2,4,6,7-pentamethyl-2,3-dihydrobenzofuran-5-ylsulfonyl)guanidino)hexanoic acid

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 35737-10-1
N-Fmoc-β-alanine

: 103213-32-7
N-(9-fluorenylmethoxycarbonyl)-S-trityl-L-cysteine

: 71989-14-5, 112883-39-3
N-(9-fluorenylmethoxycarbonyl)-4-O-tert-butyl-D-aspartic acid

: 77128-70-2
N-(9-fluorenylmethoxycarbonyl)sarcosine

: (2S,4R)-4-tert-butoxy-1-(9H-fluoren-9-ylmethoxycarbonyl)pyrrolidine-2-carboxylic acid

(pg)NH-Trp(*)-OH: (pg)NH-Trp(*)-OH

(pg)NH-Pro-OH: (pg)NH-Pro-OH

(pg)NH-His(*)-OH: (pg)NH-His(*)-OH

(pg)NH-Leu-OH: (pg)NH-Leu-OH

(pg)NH-Asn(*)-OH: (pg)NH-Asn(*)-OH

(pg)NH-Val-OH: (pg)NH-Val-OH

(pg)NH-Asp(*)-OH: (pg)NH-Asp(*)-OH

(pg)NH-Ala-OH: (pg)NH-Ala-OH

: C138H217N43O38S3

Conditions

Conditions	Yield
Stage #1: N-(9-fluorenylmethoxycarbonyl)-S-trityl-L-cysteine With 1-hydroxy-7-aza-benzotriazole; diisopropyl-carbodiimide In N,N-dimethyl-formamide for 1h; Stage #2: With piperidine In N,N-dimethyl-formamide Stage #3: (S)-2-(((9H-fluoren-9-yl)methoxy)carbonylamino)-6-(3-(2,2,4,6,7-pentamethyl-2,3-dihydrobenzofuran-5-ylsulfonyl)guanidino)hexanoic acid; 1,3,5-triacryloylhexahydro-s-triazine; N-Fmoc-β-alanine; N-(9-fluorenylmethoxycarbonyl)-S-trityl-L-cysteine; N-(9-fluorenylmethoxycarbonyl)-4-O-tert-butyl-D-aspartic acid; N-(9-fluorenylmethoxycarbonyl)sarcosine; (2S,4R)-4-tert-butoxy-1-(9H-fluoren-9-ylmethoxycarbonyl)pyrrolidine-2-carboxylic acid; (pg)NH-Trp()-OH; (pg)NH-Pro-OH; (pg)NH-His()-OH; (pg)NH-Leu-OH; (pg)NH-Asn()-OH; (pg)NH-Val-OH; (pg)NH-Asp()-OH; (pg)NH-Ala-OH Further stages;	16.3%

Yield

Stage #1: N-(9-fluorenylmethoxycarbonyl)-S-trityl-L-cysteine With 1-hydroxy-7-aza-benzotriazole; diisopropyl-carbodiimide In N,N-dimethyl-formamide for 1h;
Stage #2: With piperidine In N,N-dimethyl-formamide
Stage #3: (S)-2-(((9H-fluoren-9-yl)methoxy)carbonylamino)-6-(3-(2,2,4,6,7-pentamethyl-2,3-dihydrobenzofuran-5-ylsulfonyl)guanidino)hexanoic acid; 1,3,5-triacryloylhexahydro-s-triazine; N-Fmoc-β-alanine; N-(9-fluorenylmethoxycarbonyl)-S-trityl-L-cysteine; N-(9-fluorenylmethoxycarbonyl)-4-O-tert-butyl-D-aspartic acid; N-(9-fluorenylmethoxycarbonyl)sarcosine; (2S,4R)-4-tert-butoxy-1-(9H-fluoren-9-ylmethoxycarbonyl)pyrrolidine-2-carboxylic acid; (pg)NH-Trp(*)-OH; (pg)NH-Pro-OH; (pg)NH-His(*)-OH; (pg)NH-Leu-OH; (pg)NH-Asn(*)-OH; (pg)NH-Val-OH; (pg)NH-Asp(*)-OH; (pg)NH-Ala-OH Further stages;

16.3%

...Expand

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 109-89-7
diethylamine

: 32112-69-9
1,3-diacryloyl-5-(N,N-diethyl-β-alanyl)-hexahydro-[1,3,5]triazine

Conditions

Conditions	Yield
With chloroform

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 30805-19-7
1,3,5-tripropionylperhydro-1,3,5-triazine

: 187737-37-7
propene

: 959-52-4
1,3,5-triacryloylhexahydro-s-triazine

: 31401-10-2
6-methyl-2-vinyl-5,6-dihydro-4H-[1,3]oxazine

1,3,5-Triacryloylhexahydro-1,3,5-triazine Chemical Properties

IUPAC Name: 1,3,5-Triacryloylhexahydro-1,3,5-triazine
The MF of 1,3,5-Triacryloylhexahydro-1,3,5-triazine (959-52-4) is C₁₂H₁₅N₃O₃.

The MW of 1,3,5-Triacryloylhexahydro-1,3,5-triazine (959-52-4) is 249.27.
Synonyms of 1,3,5-Triacryloylhexahydro-1,3,5-triazine (959-52-4): 1,3,5-Triacryloylhexahydro-s-triazine ; 1-(3,5-diacryloyl-1,3,5-triazinan-1-yl)-2-propen-1-one ; 1,1',1'-(1,3,5-Triazinane-1,3,5-triyl)tris(2-propen-1-one) ; 1,3,5-Triacryloyl-1,3,5-triazinane ; 2-Propen-1-one,1,1',1''-(1,3,5-triazine-1,3,5(2H,4H,6H)-triyl)tris- ; 1,3,5-Triacryloylhexahydro-1,3,5-triazine
Product Categories: Acrylic Monomers;Monomers;Polyfunctional Acrylics
Index of Refraction: 1.539
EINECS: 213-501-6
Density: 1.197 g/ml
Flash Point: 301 °C
Boiling Point: 579.6 °C
Melting Point: 156 °C

1,3,5-Triacryloylhexahydro-1,3,5-triazine Uses

1,3,5-Triacryloylhexahydro-1,3,5-triazine (959-52-4) is used as environmentally-friendly light-curing coatings,the best cross-linking agent of light-curing coating performance.

1,3,5-Triacryloylhexahydro-1,3,5-triazine Toxicity Data With Reference

1.	eye-rbt 500 µg SEV	TXCYAC Toxicology. 40 (1986),145.
2.	mnt-mus-ipr 9300 µg/kg	TXCYAC Toxicology. 40 (1986),145.
3.	cyt-ham:ovr 700 µg/L	TXCYAC Toxicology. 40 (1986),145.
4.	orl-rat LD50:350 mg/kg	TXCYAC Toxicology. 40 (1986),145.
5.	skn-rbt LD50:70 mg/kg	TXCYAC Toxicology. 40 (1986),145.

1,3,5-Triacryloylhexahydro-1,3,5-triazine Consensus Reports

Reported in EPA TSCA Inventory.

1,3,5-Triacryloylhexahydro-1,3,5-triazine Safety Profile

Poison by ingestion and skin contact routes. Mutation data reported. A severe eye irritant. When heated to decomposition it emits toxic vapors of NO_x.Safety information of 1,3,5-Triacryloylhexahydro-1,3,5-triazine (959-52-4):
Hazard Codes T,Xi
Risk Statements
23/24/25 Toxic by inhalation, in contact with skin and if swallowed
34 Causes burns
42/43 May cause sensitization by inhalation and skin contact
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR UN 2928 6.1/PG 2
WGK Germany 3
RTECS XY9260000
HazardClass 4.2
PackingGroup II

Product Name

1,3,5-Triacryloylhexahydro-1,3,5-triazine

Synthetic route

1,3,5-Triacryloylhexahydro-1,3,5-triazine Chemical Properties

1,3,5-Triacryloylhexahydro-1,3,5-triazine Uses

1,3,5-Triacryloylhexahydro-1,3,5-triazine Toxicity Data With Reference

1,3,5-Triacryloylhexahydro-1,3,5-triazine Consensus Reports

1,3,5-Triacryloylhexahydro-1,3,5-triazine Safety Profile

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