• Name

  1-Prop-2-enoxy-4-(4-prop-2-enoxyphenyl)sulfonyl-benzene

• EINECS 1533716-785-6
• CAS No. 41481-63-4
• Article Data10
• CAS DataBase
• Density 1.172 g/cm³
• Solubility
• Melting Point 141-142 °C(Solv: ethanol (64-17-5))
• Formula C₁₈H₁₈O₄S
• Boiling Point 500.7 °C at 760 mmHg
• Molecular Weight 330.405
• Flash Point 256.6 °C
• Transport Information
• Appearance white powder
• Safety
• Risk Codes
• Molecular Structure
• Hazard Symbols
• Synonyms 4,4'-Diallyloxydiphenyl sulfone;Bis(4-hydroxyphenyl)sulfone diallyl ether;Bisphenol S diallyl ether;NSC 85530;
• PSA 60.98000
• LogP 4.72980

Synthetic route

80-09-1

4,4'-sulfonediphenol

107-05-1

3-chloroprop-1-ene

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

Conditions

Conditions	Yield
With potassium iodide; sodium hydroxide In methanol at 35 - 65℃; for 5h; Reagent/catalyst; Solvent;	98%
Stage #1: 4,4'-sulfonediphenol With sodium hydroxide for 0.166667h; Stage #2: 3-chloroprop-1-ene at 60 - 100℃; for 5h; Inert atmosphere; Sealed tube;	93%
With sodium hydroxide In methanol at 45℃;
With sodium hydroxide In water at 55 - 60℃; under 600.06 - 750.075 Torr; for 8h; Concentration; Temperature; Time;	612 g
Stage #1: 4,4'-sulfonediphenol With sodium hydroxide In water; toluene at 80℃; for 8h; Stage #2: 3-chloroprop-1-ene at 75℃; for 8h;

187737-37-7

propene

80-09-1

4,4'-sulfonediphenol

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

Conditions

Conditions	Yield
Stage #1: 4,4'-sulfonediphenol With chlorine; sodium hydroxide for 0.166667h; Stage #2: propene at 60 - 100℃; for 5h; Inert atmosphere; Sealed tube;	96%

80-09-1

4,4'-sulfonediphenol

106-95-6

allyl bromide

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

Conditions

Conditions	Yield
Stage #1: 4,4'-sulfonediphenol With potassium carbonate In acetone for 1h; Inert atmosphere; Reflux; Stage #2: allyl bromide In acetone Reflux; Inert atmosphere;	94%
With sodium hydroxide; tetramethylammonium bromide In water; toluene at 49.9 - 59.9℃; for 15h;
In methanol; water; toluene	30.5 parts (91.2%)
With potassium carbonate In acetone at 80℃; Inert atmosphere;

80-09-1

4,4'-sulfonediphenol

107-05-1

3-chloroprop-1-ene

A

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

B

4-allyloxy-4'-hydroxydiphenyl-sulfone

Conditions

Conditions	Yield
With sodium hydroxide In water at 55 - 60℃; under 600.06 - 750.075 Torr; for 8h; Concentration; Temperature; Time;	A n/a B 93.5%
With sodium hydroxide In water at 55 - 60℃; under 600.06 - 750.075 Torr; for 4h; Concentration; Temperature; Time;	A 73.98% B 25.32%

...Expand

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

tetrabromobisphenol-S-bis-(2,3-dibromopropyl ether)

Conditions

Conditions	Yield
With tetrabutylammomium bromide; bromine In chloroform; water at 15 - 35℃; for 2h; Solvent; Temperature;	98%

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

41481-66-7

3,3′-diallyl-4,4′-dihydroxydiphenylsulfone

Conditions

Conditions	Yield
With α-alanine-N-diacetic acid at 198 - 200℃; for 7h; Temperature; Inert atmosphere;	96.2%
With 1,10-Phenanthroline; ethylenediaminetetraacetic acid; sodium hydroxide In paraffin oil at 203 - 207℃; for 7h; Inert atmosphere;	93.7%
With iron(III) chloride In 1,2-dichloro-ethane at 60℃; for 15h; Reagent/catalyst; Solvent; Temperature;	93.9%

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

A

3-allyl-4,4'-dihydroxydiphenyl sulfone

B

737795-84-5

3-allyl-4'-allyloxy-4-hydroxydiphenyl sulfone

C

5-(3-allyl-4-hydroxyphenylsulfonyl)-1-oxa-2-methylindane

D

41481-66-7

3,3′-diallyl-4,4′-dihydroxydiphenylsulfone

Conditions

Conditions	Yield
With dmap at 160 - 280℃; for 0.0833333 - 0.333333h; Product distribution / selectivity; Microwave irradiation;
With 1,10-Phenanthroline; ascorbic acid In 1,2,3-trichlorobenzene at 210℃; for 7h; Product distribution / selectivity;
With 1,10-Phenanthroline; ascorbic acid at 160 - 280℃; for 0.266667h; Product distribution / selectivity; Microwave irradiation;

...Expand

48%-caustic soda

48%-caustic soda

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

41481-66-7

3,3′-diallyl-4,4′-dihydroxydiphenylsulfone

Conditions

Conditions	Yield
With 1,2,3-trichlorobenzene In water	14.0 parts (93.3%)

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

122438-87-3

4,4’-sulfonylbis(2-allyl-1-(allyloxy)benzene)

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: 4 h / 220 °C / Inert atmosphere 2.1: potassium carbonate / acetone / 1 h / Inert atmosphere; Reflux 2.2: Reflux; Inert atmosphere View Scheme

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

1636900-13-4

C32H42O8S5

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1.1: 4 h / 220 °C / Inert atmosphere 2.1: potassium carbonate / acetone / 1 h / Inert atmosphere; Reflux 2.2: Reflux; Inert atmosphere 3.1: 2,2'-azobis(isobutyronitrile) / tetrahydrofuran / 16.5 h / 20 - 65 °C / Inert atmosphere View Scheme

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

1636900-15-6

C24H34O4S5

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1.1: 4 h / 220 °C / Inert atmosphere 2.1: potassium carbonate / acetone / 1 h / Inert atmosphere; Reflux 2.2: Reflux; Inert atmosphere 3.1: 2,2'-azobis(isobutyronitrile) / tetrahydrofuran / 16.5 h / 20 - 65 °C / Inert atmosphere 4.1: hydrogenchloride; water / tetrahydrofuran; methanol / 24 h / 60 °C / Inert atmosphere View Scheme

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

C24H26O6S

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 1,2-dichloro-benzene / 8 h / 190 °C / Inert atmosphere 2: sodium hydroxide / isopropyl alcohol; water / 3 h / 60 °C / Inert atmosphere View Scheme

41481-63-4

4,4’-sulfonylbis((allyloxy)benzene)

C36H58O12S3Si2

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 1,2-dichloro-benzene / 8 h / 190 °C / Inert atmosphere 2: sodium hydroxide / isopropyl alcohol; water / 3 h / 60 °C / Inert atmosphere 3: 2,2-dimethoxy-2-phenylacetophenone / 24 h / 20 °C / Inert atmosphere; Darkness View Scheme

1-Prop-2-enoxy-4-(4-prop-2-enoxyphenyl)sulfonyl-benzene Specification