1H,1H-Pentadecafluoro-1-octanol supplier

Name
1H,1H-PENTADECAFLUORO-1-OCTANOL
EINECS 206-197-1
CAS No. 307-30-2
Article Data16
CAS DataBase
Density 1,338 g/cm³
Solubility
Melting Point 44-47 °C(lit.)
Formula C8H3 F15 O
Boiling Point 163-165 °C(lit.)
Molecular Weight 400.087
Flash Point >110°C
Transport Information
Appearance white crystalline mass
Safety 26-36
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms (Pentadecafluoroheptyl)methanol;(Perfluoroheptyl)methanol; 1,1-Dihydropentadecafluorooctan-1-ol; 1,1-Dihydropentadecafluorooctanol;1,1-Dihydroperfluorooctanol; 1,1-Dihydroperfluorooctyl alcohol;1H,1H-Pentadecafluoro-1-octanol; 1H,1H-Pentadecafluoro-n-octanol;1H,1H-Pentadecafluorooctanol; 1H,1H-Perfluoro-1-octanol;1H,1H-Perfluorooctanol; Pentadecafluoro-1,1-dihydrooctanol; Unitex DJ 10; a,a-Dihydroperfluorooctanol
PSA 20.23000
LogP 4.35280

Synthetic route

: 106608-82-6
isopropyl 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoate

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

Conditions

Conditions	Yield
With RuCl2(DPPEA)(±DAIPEN); hydrogen; sodium methylate In isopropyl alcohol; benzene at 100℃; under 750.075 - 45004.5 Torr; for 40h; Autoclave;	95%

: 335-67-1
Perfluorooctanoic acid

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

Conditions

Conditions	Yield
With diethyl ether; pyrographite; ruthenium at 175℃; under 257428 Torr; Hydrogenation;
Multi-step reaction with 2 steps 1: 90 percent / thionyl chloride, N,N-dimethylformamide / 4 h / Heating 2: 77 percent / sodium bis(2-methoxyethoxy)aluminum hydride / diethyl ether; toluene / 0.5 h / Heating View Scheme
Multi-step reaction with 2 steps 1: chloroform 2: lithium alanate; diethyl ether View Scheme

: 335-64-8
pentadecafluorooctanoyl chloride

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

Conditions

Conditions	Yield
With sodium bis(2-methoxyethoxy)aluminium dihydride In diethyl ether; toluene for 0.5h; Heating;	77%
With lithium aluminium tetrahydride; diethyl ether

: 335-67-1
Perfluorooctanoic acid

A: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol-d2

B: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

Conditions

Conditions	Yield
With formic acid; water-d2; ruthenium trichloride; triphenylphosphine at 200℃; for 8h;
With hydrogen; water-d2; 5 wt% Ru/C at 160℃; under 44134.3 Torr; for 8h;

: 3108-24-5
ethyl perfluorooctanoate

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride

: 376-27-2
methyl perfluorooctanoate

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride

: 307-96-0
pentadecafluoro-octanoic acid butyl ester

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride; diethyl ether

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 20769-85-1
2-bromoisobutyric acid bromide

: 2-bromo-2-methylbutyrylic acid-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl) ester

Conditions

Conditions	Yield
With dmap; triethylamine In tetrahydrofuran at 20℃;	97%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 36653-82-4
1-Hexadecanol

: 1-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluoro-octyloxy)-hexadecane

Conditions

Conditions	Yield
With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine In benzene at 65℃; for 2h;	96%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 107-05-1
3-chloroprop-1-ene

: 812-72-6
8-(allyloxyl)-1,1,1,2,2,3,3,4,4,5,5,6,6,7,7-pentadecafluorooctane

Conditions

Conditions	Yield
With sodium hydroxide; tetramethylammonium hydrogen sulfate at 40℃; for 12h;	96%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 375-72-4
Nonafluorobutanesulfonyl fluoride

: 187039-77-6
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctyl nonafluorobutanesulfonate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃;	96%
With triethylamine In diethyl ether	95%
With triethylamine In diethyl ether at 0 - 20℃; for 24h;	95%
With triethylamine In dichloromethane at -15℃;	49%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 79-08-3
bromoacetic acid

: 287411-18-1
1H,1H-perfluorooctyloxyacetic acid

Conditions

Conditions	Yield
Stage #1: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol With sodium hydride In tetrahydrofuran at 20℃; for 1.5h; deprotonation; Stage #2: bromoacetic acid In tetrahydrofuran at 20℃; for 24h; Alkylation;	96%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 106-28-5
Farnesol

: (2E,6E)-3,7,11-Trimethyl-1-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-octyloxy)-dodeca-2,6,10-triene

Conditions

Conditions	Yield
With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine In benzene for 2h; Ambient temperature;	95%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 358-23-6
trifluoromethylsulfonic anhydride

: 17352-09-9
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-n-octyl trifluoromethanesulfonate

Conditions

Conditions	Yield
With pyridine In dichloromethane at 0 - 20℃;	91.5%
With triethylamine In diethyl ether at -50 - 0℃; for 0.333333h;
With pyridine In dichloromethane at 0 - 20℃; Inert atmosphere;
With pyridine In dichloromethane

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 421-83-0
trifluoromethane sulfonyl chloride

: 17352-09-9
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-n-octyl trifluoromethanesulfonate

Conditions

Conditions	Yield
With triethylamine In dichloromethane for 6h; Ambient temperature;	90%
With triethylamine In dichloromethane for 1h; Ambient temperature;	85%
With triethylamine In dichloromethane

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 1608-26-0
Hexamethylphosphorous triamide

: hexafluorophosphate de 1H,1H-perfluoro-octyloxy(trisdimethylamino) phosphonium

Conditions

Conditions	Yield
With potassium hexafluorophosphate; tetrachloromethane In tetrahydrofuran at -30℃; for 0.5h;	90%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 73748-48-8
<(4-nitrophenyl)oxy>sulfonyl isocyanate

: Perfluoroheptylmethyl-N-(4-nitrophenoxysulfonyl)carbamate

Conditions

Conditions	Yield
at 20℃; for 0.0166667h; Addition;	90%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 1592-20-7
4-Vinylbenzyl chloride

: 4-vinylbenzyl(1H,1H-pentadecafluorooctyl)ether

Conditions

Conditions	Yield
With sodium hydroxide; tert-butyl alcohol at 65 - 70℃; for 7h;	90%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 14793-41-0
isocyanate de chloro-4 phenoxysulfonyle

: Perfluoroheptylmethyl-N-(4-chlorosulfonyl)carbamate

Conditions

Conditions	Yield
at 20℃; for 0.0166667h; Addition;	89%

: 100-25-4
para-dinitrobenzene

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 142706-75-0
4-nitro-1-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyloxy)benzene

Conditions

Conditions	Yield
With tetrabutyl ammonium fluoride In N,N-dimethyl-formamide at 20℃; for 2h;	89%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 1077-28-7, 62-46-4
Thioctic acid

: C16H15F15O2S2

Conditions

Conditions	Yield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; Cooling with ice;	88%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane

: Trimethyl-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-octyloxy)-silane

Conditions

Conditions	Yield
With saccharin sodium salt at 80 - 90℃; for 2h;	87.5%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 14754-44-0
isocyanatosulfuric acid 2,6-dimethyl-phenyl ester

: Perfluoroheptylmethyl-N-(2,6-dimethylphenoxysulfonyl)carbamate

Conditions

Conditions	Yield
at 20℃; for 0.416667h; Addition;	87%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 25440-14-6
tetrakis(pentafluorophenyl)porphyrin

: 5,10,15,20-tetrakis[2,3,5,6-tetrafluoro-4-(1H,1H-perfluorooctyloxy)phenyl]porphyrin

Conditions

Conditions	Yield
With potassium hydroxide In tetrahydrofuran at 20℃; for 24h; Inert atmosphere; regioselective reaction;	87%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 1663-67-8
malonoyl dichloride

: 24120-25-0
bis (1.1-dihydroperfluorooctyl) malonate

Conditions

Conditions	Yield
In toluene	86.5%
In toluene	86.5%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 75668-23-4
Fluorosulfuric acid pentadecafluoroheptyl ester

Conditions

Conditions	Yield
With potassium fluorosulfonate; fluorosulphonic acid at 25℃; anodic oxidation; 6.5 F/mol;	85%

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 106-96-7
propargyl bromide

: 1334419-25-8
3-((1-perfluoroheptyl)methoxy)prop-1-yne

Conditions

Conditions	Yield
With sodium hydroxide In tetrahydrofuran at 20℃; Cooling with ice;	85%
With sodium hydroxide In tetrahydrofuran at 20℃;

: 307-30-2
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octanol

: 98-59-9
p-toluenesulfonyl chloride

: 24962-65-0
2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro-1-octyl 4-toluenesulfonate

Conditions

Conditions	Yield
With potassium hydroxide In diethyl ether at -4℃; for 24h;	85%
With triethylamine In dichloromethane at 0 - 20℃;	77%

1H,1H-Pentadecafluoro-1-octanol Chemical Properties

IUPAC Name: 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctan-1-ol
Product Name: 1H,1H-Pentadecafluoro-1-octanol
The MF of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctan-1-ol (CAS NO.307-30-2) is C₈H₃F₁₅O.

The MW of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctan-1-ol (CAS NO.307-30-2) is 400.08.
Synonyms of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctan-1-ol (CAS NO.307-30-2): 1-Octanol, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluoro- ; 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctan-1-ol ; 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctyl alcohol ; 1H,1H-Pentadecafluoro-1-octanol ; 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluoro-1-octanol
Product Categories: Fluorous Chemistry;Fluorous Compounds;Synthetic Organic Chemistry;Fluorous Synthesis;Rf-Tagged Building Blocks and Precursors
Apperance: white crystalline mass
Index of Refraction: 1.285
EINECS: 206-197-1
Density: 1.665 g/ml
Flash Point: 49.2 °C
Boiling Point: 164 °C
Melting Point: 38-40 °C
BRN: 1716494

1H,1H-Pentadecafluoro-1-octanol Uses

2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctan-1-ol (CAS NO.307-30-2) is used as fine chemicals, chemical synthesis, medicine, pesticide intermediates.

1H,1H-Pentadecafluoro-1-octanol Safety Profile

Safety information of 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctan-1-ol (CAS NO.307-30-2):
Hazard Codes Irritant Xi
Risk Statements
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36 Wear suitable protective clothing
WGK Germany 3
Hazard Note Irritant
TSCA T

Product Name

1H,1H-PENTADECAFLUORO-1-OCTANOL

Synthetic route

1H,1H-Pentadecafluoro-1-octanol Chemical Properties

1H,1H-Pentadecafluoro-1-octanol Uses

1H,1H-Pentadecafluoro-1-octanol Safety Profile

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