2-Ethoxypropene supplier | CasNO.926-66-9

Name
2-Ethoxypropene
EINECS
CAS No. 926-66-9
Article Data34
CAS DataBase
Density 0.766 g/cm³
Solubility
Melting Point
Formula C₅H₁₀O
Boiling Point 64.1 °C at 760 mmHg
Molecular Weight 86.1338
Flash Point
Transport Information
Appearance colorless liquid
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Ether,ethyl isopropenyl (6CI,7CI,8CI);2-Ethoxy-1-propene;Ethyl1-methylvinyl ether;Ethyl isopropenyl ether;
PSA 9.23000
LogP 1.55650

Synthetic route

: 116-11-0
2-Methoxypropene

: Ir(C5(CH3)5)(P(CH3)3)H(CHOC2H5)(1+)*B(C6H5)4(1-)=[Ir(C5(CH3)5)(P(CH3)3)H(CHOC2H5)]B(C6H5)4

A: 926-66-9
2-ethoxyprop-1-ene

B: Ir(C5(CH3)5)(P(CH3)3)H(CHOCH3)(1+)*B(C6H5)4(1-)=[Ir(C5(CH3)5)(P(CH3)3)H(CHOCH3)]B(C6H5)4

Conditions

Conditions	Yield
	A 93% B 96%

...Expand

: 557-98-2
2-chloropropene

: 141-52-6
sodium ethanolate

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
at 180℃;

: 26198-63-0, 78-87-5
1,2-Dichloropropane

: 141-52-6
sodium ethanolate

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
at 180℃;

: 78-75-1
1,2-Dibromopropane

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
With potassium carbonate at 170℃;

: 463-49-0
1,2-propanediene

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
With ethanol; potassium carbonate at 170 - 180℃;

: 23465-32-9
1-bromo-2-ethoxy-propane

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
With potassium hydroxide

: 38624-58-7
Δ2-3-ethoxybutenoic acid

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
at 160 - 165℃;
at 160℃;
at 160 - 165℃;

: 126-84-1
2,2-diethoxypropane

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
With quinoline; toluene-4-sulfonic acid
With sodium trisilicate; magnesium hydrogen phosphate at 300℃;
With quinoline; phosphorus pentoxide

: 74-99-7
prop-1-yne

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
With ethanol; potassium carbonate at 170 - 180℃;

: 5390-74-9
1-chloro-2-ethoxy-propane

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
With potassium hydroxide In ethanol at 165℃; under 15960 Torr;

: 122-51-0
orthoformic acid triethyl ester

: 67-64-1
acetone

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
With quinoline; toluene-4-sulfonic acid Heating;

: 221647-72-9
(E)-3-ethoxy-but-2-enoic acid

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
(decarboxylation);

: 38624-58-7
3-ethoxycrotonic acid

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
at 160℃;

: 74-99-7
prop-1-yne

alcoholic potash: alcoholic potash

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
at 170 - 180℃;

: 91-22-5
quinoline

: 126-84-1
2,2-diethoxypropane

P2O5: P2O5

: 926-66-9
2-ethoxyprop-1-ene

...Expand

β-ethoxy-crotonic acid: β-ethoxy-crotonic acid

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
With calcium hydroxide

: 463-49-0
1,2-propanediene

alcoholic potash: alcoholic potash

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
at 160 - 170℃;

: 38624-58-7
3-ethoxycrotonic acid

lime/chalk/ hydrate: lime/chalk/ hydrate

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
Destillation;

: 64-17-5
ethanol

: 74-99-7
prop-1-yne

potassium hydroxide: potassium hydroxide

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
at 220℃;

...Expand

: 7647-01-0
hydrogenchloride

: 64-17-5
ethanol

: 698-91-9
2-phenoxypropene

A: 926-66-9
2-ethoxyprop-1-ene

B: 126-84-1
2,2-diethoxypropane

C: 108-95-2
phenol

...Expand

: 998-91-4
ethyl 3-ethoxy-2-butenoate

: 926-66-9
2-ethoxyprop-1-ene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: NaOH 2: 160 - 165 °C View Scheme

: 4358-26-3
tetraphenylborate anion

: {Pd(η3-2-C3H5)(Py-2-CHNC6H4OMe-4)}(1+)

: 624-49-7
dimethylfumarate

A: 300-57-2
allylbenzene

B: 926-66-9
2-ethoxyprop-1-ene

: (CH3OC(O)CHCHCOOCH3)Pd(C5NH4CHNC6H4(OCH3))

Conditions

Conditions	Yield
In methanol; water Kinetics; react. of Pd-compex with BPh4(1-) at 25°C in solvent in the presence of dimethylfumarate;	A n/a B 0% C n/a

...Expand

: 354-32-5
trifluoracetyl chloride

: 926-66-9
2-ethoxyprop-1-ene

: 144219-75-0
1,1,1-trifluoro-4-ethoxypent-3-en-2-one

Conditions

Conditions	Yield
With diethylamine In cyclohexane at 5 - 10℃; for 3h; Reagent/catalyst; Solvent; Temperature; Large scale;	96%

: 926-66-9
2-ethoxyprop-1-ene

: 29171-20-8
3,7-dimethyloct-6-en-1-yn-3-ol

: 141-10-6
pseudoionone

Conditions

Conditions	Yield
With sulfonic acid resin T239 at 90℃; for 8h; Reagent/catalyst; Autoclave; Inert atmosphere;	94.6%

: 941-55-9
4-toluenesulfonyl azide

: 926-66-9
2-ethoxyprop-1-ene

: 201230-82-2
carbon monoxide

: (E)-3-ethoxy-N-tosylbut-2-enamide

Conditions

Conditions	Yield
With palladium diacetate In acetonitrile at 80℃; under 760.051 Torr; for 12h; Schlenk technique;	87%

...Expand

: 926-66-9
2-ethoxyprop-1-ene

: 1-Phenylethynyl-1H-1λ3-benzo[d][1,2]iodoxol-3-one

: C20H19IO3

Conditions

Conditions	Yield
With 1-acetoxy-1,2-benziodoxol-3-one; (2r,4s,5r)-2,4,5,6-Tetrakis(3,6-dichloro-9H-carbazol-9-yl)isophthalonitrile In dichloromethane at 25 - 28℃; for 18h; Irradiation;	82%

: 926-66-9
2-ethoxyprop-1-ene

: (1-tosyl-1H-1,2,3-triazol-4-yl)methyl acetate

: 6-ethoxy-6-methyl-1-tosyl-1,4,5,6-tetrahydropyridin-3-yl acetate

Conditions

Conditions	Yield
With dirhodium tetraacetate In toluene at 80℃; for 11h; Diels-Alder Cycloaddition; Inert atmosphere; chemoselective reaction;	73%

: 926-66-9
2-ethoxyprop-1-ene

: 51608-60-7
N-(benzylidene)-p-methylbenzenesulfonamide

: 106419-27-6
N-(4-Ethoxy-1-phenyl-pent-4-enyl)-4-methyl-benzenesulfonamide

Conditions

Conditions	Yield
In acetonitrile at 50℃; under 9000720 Torr; for 20h;	70%

: 926-66-9
2-ethoxyprop-1-ene

: 141-78-6
ethyl acetate

Conditions

Conditions	Yield
With pyridinium chlorochromate In dichloromethane at 25℃; for 2h;	65%

: 926-66-9
2-ethoxyprop-1-ene

A: 97674-28-7
ethoxy-3-methyl-1,2-dioxolane

B: 90150-49-5
3-Ethoxy-3-methyl-[1,2,4]trioxolane

Conditions

Conditions	Yield
With ozone In pentane at -78℃;	A 63% B 3%
With ozone In pentane at -78℃;	A 56% B 5%

: 926-66-9
2-ethoxyprop-1-ene

: 1619-84-7
hexafluoroacetone azine

A: 82489-21-2
7-Ethoxy-1,1,1-trifluor-2,5,5-tris(trifluormethyl)-3,4-diazaocta-2,7-dien

B: N-((Z)-3-Ethoxy-1,1-bis-trifluoromethyl-but-2-enyl)-N'-(2,2,2-trifluoro-1-trifluoromethyl-ethylidene)-hydrazine

Conditions

Conditions	Yield
In diethyl ether at 0 - 5℃; for 192h;	A 56% B n/a

...Expand

: 6842-31-5
salicylaldehyde diethyl acetal

: 926-66-9
2-ethoxyprop-1-ene

A: C14H20O3

B: (2S,4S)-2,4-diethoxy-2-methylchromane

Conditions

Conditions	Yield
Stage #1: salicylaldehyde diethyl acetal; 2-ethoxyprop-1-ene With C75H86O15 In benzene at 20℃; for 16h; Diels-Alder Cycloaddition; Stage #2: With sodium tetrahydroborate In methanol for 0.5h; Overall yield = 50 %; Overall yield = 24.1 mg; enantioselective reaction;	A n/a B 50%

...Expand

: 926-66-9
2-ethoxyprop-1-ene

: 1663-67-8
malonoyl dichloride

A: 675-10-5
4-hydroxy-6-methyl-2-pyron

B: 28334-98-7
Phloroglucinmonoethylether

Conditions

Conditions	Yield
In diethyl ether	A 42% B 43%
With potassium hydroxide; N-benzyl-N,N,N-triethylammonium chloride 1) Et2O, -19 deg C, 2 h, 2) Et2O, r.t., 4 h; Yield given. Multistep reaction. Yields of byproduct given;

...Expand

: 926-66-9
2-ethoxyprop-1-ene

: 38622-91-2, 36635-61-7
[(p-methylphenyl)sulfonylmethyl]isonitrile

: 2-ethoxy-2-methyl-N-(tosylmethyl)propanamide

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In tetrahydrofuran at 20℃; for 30h;	41%

: 926-66-9
2-ethoxyprop-1-ene

: 107995-74-4
7-(diethylamino)-3-iodo-4-methyl-2H-chromen-2-one

A: 91-44-1
7-diethylamino-4-methylcoumarin

B: 132093-45-9
7-Diethylamino-3-((Z)-2-ethoxy-propenyl)-4-methyl-chromen-2-one

Conditions

Conditions	Yield
for 12h; Irradiation; Further byproducts given;	A n/a B 31%

...Expand

: 926-66-9
2-ethoxyprop-1-ene

: 107995-74-4
7-(diethylamino)-3-iodo-4-methyl-2H-chromen-2-one

A: 91-44-1
7-diethylamino-4-methylcoumarin

B: 132093-45-9
7-Diethylamino-3-((Z)-2-ethoxy-propenyl)-4-methyl-chromen-2-one

C N-de-ethylation products: N-de-ethylation products

Conditions

Conditions	Yield
for 12h; Quantum yield; Irradiation;	A n/a B 31% C n/a

...Expand

: 4096-20-2
N-phenyl piperidine

: 926-66-9
2-ethoxyprop-1-ene

: C25H34N2

Conditions

Conditions	Yield
With tris(pentafluorophenyl)borate at 110℃; for 8h; Sealed tube;	31%

: 926-66-9
2-ethoxyprop-1-ene

: N-(4-(4-(cyclopropylamino)-4-oxobutyl)-1-phenyl-1H-imidazol-2-yl)-3-(1H-pyrazol-4-yl)benzamide

: N-(4-(4-(cyclopropylamino)-4-oxobutyl)-1-phenyl-1H-imidazol-2-yl)-3-(1-(2-ethoxypropan-2-yl)-1H-pyrazol-4-yl)benzamide

Conditions

Conditions	Yield
Stage #1: 2-ethoxyprop-1-ene; N-(4-(4-(cyclopropylamino)-4-oxobutyl)-1-phenyl-1H-imidazol-2-yl)-3-(1H-pyrazol-4-yl)benzamide With toluene-4-sulfonic acid In chloroform at 0℃; for 1h; Stage #2: With triethylamine In chloroform at 0℃; for 0.5h;	30%

: 67-56-1
methanol

: 926-66-9
2-ethoxyprop-1-ene

: 29328-22-1
2-ethoxy-2-methoxy-propane

Conditions

Conditions	Yield
With Fuller's Earth

: 123-73-9
trans-Crotonaldehyde

: 926-66-9
2-ethoxyprop-1-ene

: 103263-48-5
(+/-)-4-ethoxy-hept-5t-en-2-one

Conditions

Conditions	Yield
With boric acid; oxalic acid

: 926-66-9
2-ethoxyprop-1-ene

: 94088-28-5
1,1-Diethoxyhexa-2,4-diene

: 16326-91-3
nona-3t,5t,7t-trien-2-one

Conditions

Conditions	Yield
With zinc(II) chloride und anschliessenden Erwaermen mit Natriumacetat enthaltender wss.Essigsaeure;

: 926-66-9
2-ethoxyprop-1-ene

: 63282-12-2
octa-2t,4t,6t-trienal-diethylacetal

: 75143-19-0
3,5,7,9-undecatetraen-2-one

Conditions

Conditions	Yield
With zinc(II) chloride und Erwaermen des Reaktionsprodukts mit Natriumacetat enthaltender wss.Essigsaeure;

: 926-66-9
2-ethoxyprop-1-ene

: 74-85-1
ethene

: 78-79-5
isoprene

Conditions

Conditions	Yield
at 130 - 135℃; under 3677.5 Torr; ueber einen Mischkatalysator aus Aluminium, SiO2, Nb2O5, WO3, und AgNO3;

: 926-66-9
2-ethoxyprop-1-ene

: 74-85-1
ethene

A: 504-60-9
penta-1,3-diene

B: 78-79-5
isoprene

Conditions

Conditions	Yield
at 150 - 160℃; beim Leiten ueber einen Mischkatalysator aus Aluminium und Oxiden des Bors, Wolframs, Urans und Silbers;
at 150 - 160℃; beim Leiten ueber einen Mischkatalysator aus Aluminium und Oxiden des Bors, Wolframs, Urans und Silbers;

...Expand

: 926-66-9
2-ethoxyprop-1-ene

: 617-37-8
oxalic acid monoethyl ester

: 68854-18-2
2,4,6-trioxo-heptanedioic acid diethyl ester

Conditions

Conditions	Yield
With diethyl ether; ethanol; potassium ethoxide

: 926-66-9
2-ethoxyprop-1-ene

: 1740-74-5
1,1-diethoxy-3-methyl-2-butene

: 106522-69-4
4,6,6-triethoxy-2-methyl-hept-2-ene

Conditions

Conditions	Yield
With diethyl ether; zinc(II) chloride

: 926-66-9
2-ethoxyprop-1-ene

: 774-48-1
(diethoxymethyl)benzene

: 93154-72-4
4-ethoxy-4-phenyl-butan-2-one-diethylacetal

Conditions

Conditions	Yield
With diethyl ether; zinc(II) chloride

: 926-66-9
2-ethoxyprop-1-ene

: 5660-91-3
1,3-diphenyl-2H-cyclopenta<1>phenanthren-2-one

: 2-ethoxy-2-methyl-1,4-diphenyl-1,2,3,4-tetrahydro-1,4-methano-triphenylen-13-one

Conditions

Conditions	Yield
With benzene

: 926-66-9
2-ethoxyprop-1-ene

: 29840-15-1
ethyl-(bromo-tert-butyl)-ether

Conditions

Conditions	Yield
With diethyl ether; bromine at -30℃; anschliessendes Behandeln mit Methylmagnesiumbromid in Aether bei 0grad;

: 926-66-9
2-ethoxyprop-1-ene

: 412013-01-5
2-ethoxy-1,2-dibromo-propane

Conditions

Conditions	Yield
With bromine at -10℃;

2-Ethoxypropene Chemical Properties

Molecular Structure of 2-Ethoxypropene (CAS NO.926-66-9):

IUPAC Name: 2-Ethoxyprop-1-ene
Molecular Formula: C₅H₁₀O
Molecular Weight: 86.13
XLogP3-AA: 1.6
H-Bond Donor: 0
H-Bond Acceptor: 1
Index of Refraction: 1.388
Molar Refractivity: 26.52 cm³
Molar Volume: 112.3 cm³
Surface Tension: 19.4 dyne/cm
Density: 0.766 g/cm³
Enthalpy of Vaporization: 29.35 kJ/mol
Boiling Point: 64.1 °C at 760 mmHg
Vapour Pressure: 179 mmHg at 25 °C
Appearance: colorless liquid
Canonical SMILES: CCOC(=C)C
InChI: InChI=1S/C5H10O/c1-4-6-5(2)3/h2,4H2,1,3H3
InChIKey: FSGHEPDRMHVUCQ-UHFFFAOYSA-N

2-Ethoxypropene Uses

2-Ethoxypropene (CAS NO.926-66-9) can be used as organic synthesize and antibiotics intermediates.

2-Ethoxypropene Specification

2-Ethoxypropene (CAS NO.926-66-9), its Synonyms are Ether,ethyl isopropenyl (6CI,7CI,8CI) ; 2-Ethoxy-1-propene; Ethyl1-methylvinyl ether ; Ethyl isopropenyl ether ; 1-Propene, 2-ethoxy- .

Product Name

2-Ethoxypropene

Synthetic route

2-Ethoxypropene Chemical Properties

2-Ethoxypropene Uses

2-Ethoxypropene Specification

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