As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis
Cas:116-11-0
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryItems Standard Result Assay 98%min ----------------------------------------------------------------------------------------------
Cas:116-11-0
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inquiryProduct description: Product name 2-Methoxypropene CAS number 116-11-0 Assay ≥99% Appearance Colorless transparent liquid Capacity 500mt/year Application Pharmaceutical inter
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiryOur Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con
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inquiryName: 2-Methoxypropene CAS:116-11-0 MF: C4H8O Appearance:colorless transparent liquid Storage:Preserve in well-closed, light-resistant and airtight containers. Package:25kg Application:Pharmaceutical Intermediate Transportation:By sea Port:Qingd
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inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
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inquiryProduct Name: 2-Methoxypropene CAS: 116-11-0 MF: C4H8O MW: 72.11 EINECS: 204-125-3 16-11-0.mol 2-Methoxypropene Structure 2-Methoxypropene Chemical Properties Melting point 25°C Boiling point 34-36 °C (lit.) density
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inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
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inquiryMinimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,
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inquiry2-Methoxypropene CAS: 116-11-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interme
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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Appearance:white powder Storage:Store in a cool,dry place and keep away from direct strong light Package:packaged in foil bags or tins Application:Use only for laboratory research Transportation:Sea,Air,DHL/TNT/FEdex/UPS/EMS Por
Cas:116-11-0
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inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
our strengths: 1: Fast and guaranteed shipment (TNT;EMS;FEDEX;DHL;UPS;EUB, special line) 2: Various payment items accepted (Btc; MoneyGram; WU) 3: Valued package (Paraffin coating; Double aluminum foil bag; Vacuum packaging) 4: Efficient delivery
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Product Name: 2-Methoxypropene Synonyms: Methyl isopropenyl ether;ISOPROPENYL METHYL ETHER;2-METHOXYPROPENE;2-METHOXY-1-PROPENE;MOP;1-Propene,2-methoxy-;2-methoxy-1-propen;2-methoxy-prop-1-ene CAS: 116-11-0 MF: C4H8O
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inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
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inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
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inquiryProduct name: 2-Methoxypropene CAS No.: 116-11-0 Molecule Formula:C4H8O Molecule Weight:72.11 Purity: 99.0% Package: 165kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard TES
Cas:116-11-0
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inquiryZhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed
Cas:116-11-0
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inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:116-11-0
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inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
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inquiry2-Methoxypropene [ CAS No. ] 116-11-0 [ structural formula ] CH3(COCH3)=CH2 [ appearance ] colorless transparent liquid [ content ] 99
Cas:116-11-0
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inquiryConditions | Yield |
---|---|
With potassium tert-butylate In 1-methyl-pyrrolidin-2-one at 120℃; | 97% |
With potassium hydroxide at 220℃; |
Conditions | Yield |
---|---|
With quinoline at 30 - 105℃; under 12751.3 Torr; Temperature; Pyrolysis; | 93.6% |
With quinoline; toluene-4-sulfonic acid at 90℃; for 9h; Catalytic behavior; Reagent/catalyst; Temperature; | 92.8% |
With (trimethylsilyl)manganese pentacarbonyl In acetonitrile at 50℃; for 2h; Mechanism; | 77 % Spectr. |
carbon dioxide
2,2-dimethoxy-propane
A
2-Methoxypropene
B
acetone
C
carbonic acid dimethyl ester
Conditions | Yield |
---|---|
With dibutyldimethoxytin at 180℃; under 1520000 Torr; for 24h; Product distribution; metal-catalyzed reaction of acetals with CO2; effect of catalyst structure; effect of additives; pressure effect; possible mechanism; | A n/a B 85% C 88% |
Conditions | Yield |
---|---|
With 1-methyl-pyrrolidin-2-one; potassium tert-butylate In methanol | 60% |
In methanol | 47% |
methylene
acetone
A
2-methyl-1,2-epoxypropane
B
2,2,4,4-tetramethyl-[1,3]dioxolane
C
2-Methoxypropene
D
butanone
pyridine
t-butyl heptafluoroperoxybutyrate
A
2-Methoxypropene
B
tert-butyl heptafluorobutyrate
C
pyridinium heptafluorobutyrate
D
1,1'-(1,2-ethanediyl)bisbenzene
Conditions | Yield |
---|---|
In toluene at 85℃; for 7h; Yield given. Further byproducts given. Yields of byproduct given; |
pyridine
t-butyl heptafluoroperoxybutyrate
A
2-Methoxypropene
B
tert-butyl heptafluorobutyrate
C
pyridinium heptafluorobutyrate
D
1,1'-(1,2-ethanediyl)bisbenzene
E
isobutene
Conditions | Yield |
---|---|
In toluene at 65 - 85℃; for 7h; Rate constant; Kinetics; Thermodynamic data; ΔH(act.), ΔS(act.), various temperature; |
methanol
1,2-propanediene
A
2-Methoxypropene
B
2,2-dimethoxy-propane
C
acetone
Conditions | Yield |
---|---|
sodium hydroxide at 190℃; Rate constant; other temperatures; |
2-acyl-2,3-dimethyl-3-methoxyoxetane
A
2-Methoxypropene
B
dimethylglyoxal
Conditions | Yield |
---|---|
In various solvent(s) Product distribution; Irradiation; infrared multiphoton induced photolysis; the luminescence of the reaction mixture was also investigated; |
t-butyl heptafluoroperoxybutyrate
A
heptafluorobutyric Acid
B
2-Methoxypropene
C
acetic acid methyl ester
Conditions | Yield |
---|---|
In pyridine at 50℃; for 12h; Product distribution; | A 0.91 % Turnov. B 0.46 % Turnov. C 0.03 % Turnov. D 0.21 % Turnov. |
t-butyl heptafluoroperoxybutyrate
A
heptafluorobutyric Acid
B
2-Methoxypropene
C
tert-butyl heptafluorobutyrate
D
2,2-dimethoxy-propane
Conditions | Yield |
---|---|
In nitrobenzene at 70℃; for 7h; Product distribution; | A 0.90 % Turnov. B 0.19 % Turnov. C 0.02 % Turnov. D 0.06 % Turnov. E 0.05 % Turnov. |
t-butyl heptafluoroperoxybutyrate
A
heptafluorobutyric Acid
B
Di-t-butyl ketone
C
2-Methoxypropene
D
tert-butyl heptafluorobutyrate
E
acetone
Conditions | Yield |
---|---|
With pyridine In benzene at 80℃; for 11h; Thermodynamic data; Rate constant; Product distribution; ΔH(excit.); ΔS(excit.); further solvents (octane, nitrobenzene, pyridine, methoxybenzene); other temperature; | A 0.63 % Turnov. B 0.04 % Turnov. C 0.15 % Turnov. D 0.02 % Turnov. E 0.02 % Turnov. |
methanol
1,2-propanediene
prop-1-yne
A
2-Methoxypropene
B
acetone
Conditions | Yield |
---|---|
sodium hydroxide; pyrographite at 150℃; Rate constant; Thermodynamic data; other temperatures; various molar ratios; other catalyst composition; |
methanol
prop-1-yne
A
2-Methoxypropene
B
2,2-dimethoxy-propane
C
acetone
Conditions | Yield |
---|---|
sodium hydroxide at 190℃; Rate constant; other temperatures; |
1-Butoxy radical
A
2,3-dihydro-2H-furan
B
4-butanolide
C
n-propyl hydroperoxide
D
2-Methoxypropene
E
butyraldehyde
F
butan-1-ol
Conditions | Yield |
---|---|
With oxygen at 69.9 - 229.9℃; Product distribution; Rate constant; Thermodynamic data; flow and static experiments; isomerization reactions in oxygen; oxidation, isomerization and decomposition; effect of reaction vessel wall conditions; reaction mechanism; |
methyl bromide
acetone enolate ion
A
2-Methoxypropene
B
butanone
Conditions | Yield |
---|---|
In gas at 39.9℃; Rate constant; |
t-butyl heptafluoroperoxybutyrate
A
heptafluorobutyric Acid
B
2-Methoxypropene
C
tert-butyl heptafluorobutyrate
D
acetone
Conditions | Yield |
---|---|
With methoxybenzene at 70℃; for 7h; Product distribution; | A 0.59 % Turnov. B 0.14 % Turnov. C 0.28 % Turnov. D 0.07 % Turnov. E n/a |
methanol
1,2-propanediene
2,2-dimethoxy-propane
prop-1-yne
2-Methoxypropene
Conditions | Yield |
---|---|
at 170℃; under 5250.53 Torr; |
Conditions | Yield |
---|---|
ZnO/SiO2 catalyst at 180 - 200℃; under 2625.26 Torr; Product distribution / selectivity; Gas phase; |
acetone
carbonic acid dimethyl ester
A
3,5,5-Trimethylcyclohex-2-en-1-one
B
4-methyl-pent-3-en-2-one
C
2-Methoxypropene
D
4-Hydroxy-4-methyl-2-pentanone
E
acetoacetic acid methyl ester
Conditions | Yield |
---|---|
With CO2 adsorbed on sodium doped MgO at 240℃; for 5h; |
2-(di-tert-butylphosphino)-1,1'-biphenylgold(I) chloride
A
2-Methoxypropene
Conditions | Yield |
---|---|
In dichloromethane-d2 at -78 - -65℃; for 0.175h; Equilibrium constant; Glovebox; Cooling with acetone-dry ice; |
acetic acid methyl ester
Methyltriphenylphosphonium bromide
2-Methoxypropene
Conditions | Yield |
---|---|
Stage #1: Methyltriphenylphosphonium bromide With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere; Stage #2: acetic acid methyl ester In tetrahydrofuran at 20℃; Inert atmosphere; |
methanol
2,2-dimethoxy-propane
A
tetramethylorthosilicate
B
2-Methoxypropene
C
acetone
Conditions | Yield |
---|---|
With carbon dioxide; silica gel; potassium hydroxide at 240℃; under 15001.5 Torr; for 24h; Autoclave; | A 83 %Chromat. B 7 %Chromat. C 27 %Chromat. |
Conditions | Yield |
---|---|
With silica gel; potassium hydroxide In methanol at 240℃; under 15001.5 Torr; for 24h; Autoclave; | A 7 %Chromat. B 10 %Chromat. |
(E)-3-phenylpropenal
2-Methoxypropene
[(E)-5-Methoxy-3-(1-methoxy-1-methyl-ethoxy)-hexa-1,5-dienyl]-benzene
Conditions | Yield |
---|---|
With tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium; acetic acid In dichloromethane for 18h; Ambient temperature; | 100% |
With tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium; silica gel; acetic acid at 25℃; | 83% |
With silica gel; acetic acid; tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium In dichloromethane at 25℃; Addition; | 83% |
2-Methoxypropene
ethyl 3-bromo-2-(hydroxyimino)propanoate
ethyl 3-bromo-2-<(1-methoxy-1-methylethoxy)imino>propanoate
Conditions | Yield |
---|---|
In dichloromethane for 6h; Ambient temperature; | 100% |
2-Methoxypropene
(1S,2R)-1-((4R,5S)-5-Benzhydryloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-phenylsulfanyl-propane-1,2-diol
(4S,5S,4'R,5'R)-5-Benzhydryloxymethyl-2,2,2',2'-tetramethyl-5'-phenylsulfanylmethyl-[4,4']bi[[1,3]dioxolanyl]
Conditions | Yield |
---|---|
With (+)-10-camphorsulfonic acid In dichloromethane for 0.5h; Ambient temperature; | 100% |
2-Methoxypropene
(3RS,4S)-4-<(tert-butyloxy)carbonyl>-5-(cyclohexylmethyl)-3-hydroxy-1-pentene
3-<(tert-butyloxy)carbonyl>-4-(cyclohexylmethyl)-2,2-dimethyl-5-vinyloxazolidine
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane for 1h; Ambient temperature; | 100% |
2-Methoxypropene
(3R,4S)-(t-butyloxycarbonyl)-4-amino-3-hydroxy-6-methylheptanoic acid ethyl ester
(4S,5R)-N-Boc-5-(carbethoxymethyl)-2,2-dimethyl-4-(2-methylpropyl)-1,3-oxazolidine
Conditions | Yield |
---|---|
With trichlorophosphate for 16h; Ambient temperature; | 100% |
Conditions | Yield |
---|---|
at 0℃; for 0.333333h; | 100% |
2-Methoxypropene
3-(4-Chloro-benzylidene)-1,5-dioxa-spiro[5.5]undecane-2,4-dione
Conditions | Yield |
---|---|
at 0℃; for 0.333333h; | 100% |
2-Methoxypropene
3-(4-Nitro-benzylidene)-1,5-dioxa-spiro[5.5]undecane-2,4-dione
Conditions | Yield |
---|---|
at 0℃; for 0.333333h; | 100% |
2-Methoxypropene
3-chlorobutan-2-ol
(S)-2-Chloro-3-(1-methoxy-1-methyl-ethoxy)-butane
Conditions | Yield |
---|---|
With oxalic acid In diethyl ether for 1h; | 100% |
2-Methoxypropene
4(S)-<(tert-butyloxycarbonyl)amino>-3-hydroxy-6-methyl-1-heptene
(4S)-3-(tert-butyloxycarbonyl)-2,2-dimethyl-5-ethenyl-4-(methylpropyl)oxazolidine
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane for 4h; Ambient temperature; | 100% |
2-Methoxypropene
(2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol
(4aR,6R,8aS)-6-Allyl-4,4a,6,8a-tetrahydro-2,2-dimethylpyrano<3,2-d>-m-dioxin
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane 1.) 0 deg C, 2 h, 2.) 3 h; | 100% |
2-Methoxypropene
1-β-D-Ribofuranosyl-3-hydroxy-4-ethoxycarbonylpyranose
1-(2,3-O-Isopropylidene-β-Dribofuranosyl)-3-hydroxy-4-ethoxycarbonylpyrazole
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate; mercury dichloride In acetone at 20℃; for 3h; | 100% |
2-Methoxypropene
3β-acetoxy-17β-pivaloylandrost-5-ene-19-ol
2,2-Dimethyl-propionic acid (3S,8R,9S,10S,13S,14S,17S)-3-acetoxy-10-(1-methoxy-1-methyl-ethoxymethyl)-13-methyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl ester
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In 1,4-dioxane | 100% |
2-Methoxypropene
(4S)-(-)-4,5-dihydroxy-3-methyl-2-butenoic acid 1,4-lactone
(4S)-(-)-4-hydroxy-5-<(2-methoxypropyl)oxy>-3-methyl-2-butenoic acid lactone
Conditions | Yield |
---|---|
With trichlorophosphate for 6h; Ambient temperature; | 100% |
2-Methoxypropene
(9S)-9-dihydro-3,5-O-(p-methoxybenzylidene)erythronolide A
(9S)-9-dihydro-9,11-O-isopropylidene-3,5-O-(p-methoxybenzylidene)erythronolide
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane at 25℃; for 1.5h; | 100% |
With pyridinium p-toluenesulfonate In dichloromethane at 25℃; for 1.5h; |
2-Methoxypropene
(1α,2α,4β,5β)-diethyl N,N'-(4,5-dihydroxy-1,2-cyclohexanediyl)bis
(3aα,5α,6α,7aα)-diethyl N,N'-(hexahydro-2,2-dimethyl-1,3-benzodioxole-5,6-diyl)bis
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In acetone for 1h; Ambient temperature; | 100% |
2-Methoxypropene
2-hydroxymethyl-4-phenylselenobutan-1-ol
2,2-dimethy-5-(2-phenylselenoethyl)-1,3-dioxane
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In dichloromethane for 1.5h; Ambient temperature; | 100% |
2-Methoxypropene
(1S,6R)-6-<(tert-butyldimethylsilyl)oxy>-1-<(1S,2S)-2-methyl-1,2,3-trihydroxypropyl>-5-methylene-7,9-diaza-2-oxabicyclo<4.2.2>decane-8,10-dione
(1S,6R)-6-<(tert-butyldimethylsilyl)oxy>-1-<(1S,2S)-2,3-O-isopropylidene-2-methyl-1,2,3-trihydroxypropyl>-5-methylene-7,9-diaza-2-oxabicyclo<4.2.2>decane-8,10-dione
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In acetone for 12h; Ambient temperature; | 100% |
2-Methoxypropene
(Z)-(1R,12S,13R,15S)-13,15-Bis-(tert-butyl-dimethyl-silanyloxy)-6,6-dimethyl-5,7,16-trioxa-tricyclo[10.3.1.04,8]hexadec-10-ene
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane at 0℃; for 3h; | 100% |
2-Methoxypropene
<1S-<1α(4R*,5R*),3α,4β,5α,6α(2E,4R*,6R*),7β>>-1-<4-(acetyloxy)-5-methyl-3-methylene-6-phenylhexyl>4,6,7-trihydroxy-2,8-dioxabicyclo<3.2.1>octane-3,4,5-tricarboxylic acid, 6-(4,6-dimethyl-2-octenoate), 3,4,5-tris(1,1-dimethylethyl) ester
(1S,3S,4S,5R,6R,7R)-1-((4S,5R)-4-Acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-6-((E)-(4S,6S)-4,6-dimethyl-oct-2-enoyloxy)-4-hydroxy-7-(1-methoxy-1-methyl-ethoxy)-2,8-dioxa-bicyclo[3.2.1]octane-3,4,5-tricarboxylic acid tri-tert-butyl ester
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane for 2h; Ambient temperature; | 100% |
With pyridinium p-toluenesulfonate In dichloromethane at 0℃; for 2h; | 95% |
2-Methoxypropene
(1S,2S,3S)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol
(1S,2S,3S)-1-(phenylthio)-2,3-O-isopropylidene-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane for 3.5h; | 100% |
2-Methoxypropene
(1R,2R,3R)-1-(phenylthio)-1-(trimethylsilyl)-4-O-(triphenylmethyl)butane-2,3,4-triol
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane for 3.5h; | 100% |
2-Methoxypropene
(2S,3S)-3-benzenethio-3-(trimethylosilyl)propane-1,2-diol
(2S,3S)-3-benzenethio-1,2-O-isopropylidene-3-(trimethylsilyl)propane-1,2-diol
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane for 1.5h; Ambient temperature; | 100% |
2-Methoxypropene
(1R,2S,1'S,2'S)-2-(2'-tert-butoxycarbonylamino-1'-hydroxy-3'-phenylpropyl)cyclopentane-1-carboxylic acid n-butylamide
(4S,5S,1'S,2'R)-4-benzyl-3-N-tert-butoxycarbonyl-5-(2'-n-butylaminocarbonyl)cyclopentyl-2,2-dimethyloxazolidine
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In dichloromethane for 1.5h; Ambient temperature; | 100% |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid | 100% |
2-Methoxypropene
benzaldehyde
[3-Methoxy-1-(1-methoxy-1-methyl-ethoxy)-but-3-enyl]-benzene
Conditions | Yield |
---|---|
With tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium; silica gel; acetic acid at 25℃; | 100% |
With silica gel; acetic acid; tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium In dichloromethane at 25℃; Addition; | 100% |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid | 100% |
Conditions | Yield |
---|---|
With tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium; silica gel; acetic acid at 25℃; | 100% |
With silica gel; acetic acid; tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium In dichloromethane at 25℃; Addition; | 99% |
2-Methoxypropene
5,6-anhydro-1,2-O-isopropylidene-α-D-glucofuranose
5,6-anhydro-1,2-O-isopropylidene-3-O-(1-methoxy-1-methyl ethyl)-α-D-glucofuranose
Conditions | Yield |
---|---|
With trifluoroacetic acid In chloroform | 100% |
With trifluoroacetic acid In dichloromethane for 4h; Ambient temperature; | 673 mg |
2-Methoxypropene
(S)-Methyl mandelate
(S)-(1-Methoxy-1-methyl-ethoxy)-phenyl-acetic acid methyl ester
Conditions | Yield |
---|---|
With dichloro-acetic acid at 20℃; for 60h; | 100% |
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