Product Name

  • Name

    3-Methacryloxypropyltrimethoxysilane

  • EINECS 219-785-8
  • CAS No. 2530-85-0
  • Article Data20
  • CAS DataBase
  • Density 1.006 g/cm3
  • Solubility Miscible with water.
  • Melting Point <-50 °C
  • Formula C10H20O5Si
  • Boiling Point 258.7 °C at 760 mmHg
  • Molecular Weight 248.351
  • Flash Point 92 °C
  • Transport Information
  • Appearance colorless transparent liquid
  • Safety 26-28-37/39
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 2530-85-0 (3-Methacryloxypropyltrimethoxysilane)
  • Hazard Symbols IrritantXi
  • Synonyms Methacrylicacid, 3-(trimethoxysilyl)propyl ester (8CI);(3-Methacryloxypropyl)trimethoxysilane;2-Methyl-2-propenoic acid 3-(trimethoxysilyl)propyl ester;A 174 (coupling agent);AZ6167;U 511;Unisilan 511;Z 6530;γ-Methacryloxypropyltrimethoxysilane;Dynasylan MEMO-E;Geniosil GF 31;KBM 503;KBM 508;KH 570;LS 3380;M 8550KG;MOPS-M;NUCA 174;Prosil 248;
  • PSA 53.99000
  • LogP 1.37390

Synthetic route

3-chloropropyltrimethoxysilane

3-chloropropyltrimethoxysilane

potassium methacrylate
6900-35-2

potassium methacrylate

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
With 4,4'-methylene-bis-(2,6-di-tert-butylphenol); tetra-n-butylphosphonium chloride In acetone at 115℃; Purification / work up;95%
trimethoxysilane
2487-90-3

trimethoxysilane

allyl methacrylate
96-05-9

allyl methacrylate

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate; 10H-phenothiazine at 85℃; under 1125.11 - 3000.3 Torr; for 4h; Catalytic behavior; Pressure; Autoclave; Inert atmosphere;94.3%
With 4-aminotriphenylamine; 2,6-di-tert-butyl-4-methyl-phenol; acetone; dihydrogen hexachloroplatinate(IV) hexahydrate at 75℃; under 18751.9 Torr; Inert atmosphere;
With dihydrogen hexachloroplatinate(IV) hexahydrate In acetylacetone at 105℃;
tert-butyl methyl ether
1634-04-4

tert-butyl methyl ether

3-(trichlorosilyl)propyl 2-methylprop-2-enoate
7351-61-3

3-(trichlorosilyl)propyl 2-methylprop-2-enoate

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
bismuth(III) chloride at 25℃; for 72h; Inert atmosphere;92%
With bismuth(III) chloride at 0 - 20℃; Neat (no solvent); Inert atmosphere;Ca. 92 %Spectr.
methanol
67-56-1

methanol

trichlorosilane
10025-78-2

trichlorosilane

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
Stage #1: allyl methacrylate; trichlorosilane With ANTAGE STDP-N; bis(η2:η2-1,3-divinyltetramethyl)platinum(0) at 80℃;
Stage #2: methanol Product distribution / selectivity;		74%
Stage #1: allyl methacrylate; trichlorosilane With 10-acetyl-10H-phenothiazine; bis(η2:η2-1,3-divinyltetramethyl)platinum(0) at 80℃;
Stage #2: methanol Product distribution / selectivity;		72%
Stage #1: allyl methacrylate; trichlorosilane With phenothazine oligomer; bis(η2:η2-1,3-divinyltetramethyl)platinum(0) at 80℃;
Stage #2: methanol Product distribution / selectivity;		70%
Stage #1: allyl methacrylate; trichlorosilane With 10H-phenothiazine; bis(η2:η2-1,3-divinyltetramethyl)platinum(0) at 80℃;
Stage #2: methanol Product distribution / selectivity;
methanol
67-56-1

methanol

allyl methacrylate
96-05-9

allyl methacrylate

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
Stage #1: allyl methacrylate With 2,6-di-tert-butyl-4-methyl-phenol; 1,3,5-trimethyl-2,4,6-tris-(3,5-di-tert-butyl-4-hydroxybenzyl)benzene; trichlorosilane; dihydrogen hexachloroplatinate In isopropyl alcohol; toluene
Stage #2: methanol With urea In isopropyl alcohol; toluene at 50℃;		36%
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

3-Chloropropyltrimethoxysilan
2530-87-2

3-Chloropropyltrimethoxysilan

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
Stage #1: poly(methacrylic acid) With potassium hydroxide In toluene
Stage #2: 3-Chloropropyltrimethoxysilan With 4,4'-bismethylene(2,6-di-tert-butylphenol); tetra-n-butylphosphonium chloride In toluene; butanone at 110℃; for 4h;
Reaxys ID: 11464821

Reaxys ID: 11464821

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; bis(dimethyldithiocarbamato)copper(II) at 130 - 160℃; under 5 - 23 Torr; for 3 - 39h; Purification / work up;
potassium methacrylate
6900-35-2

potassium methacrylate

3-Chloropropyltrimethoxysilan
2530-87-2

3-Chloropropyltrimethoxysilan

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
With 4,4'-Methylenebis(2,6-di-tert-butylphenol); tetra-n-butylphosphonium chloride In acetone at 115℃; for 4h;
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
In ethanol
sodium methacrylate
5536-61-8

sodium methacrylate

3-Chloropropyltrimethoxysilan
2530-87-2

3-Chloropropyltrimethoxysilan

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
hexaethylguanidinium chloride at 100℃; for 3h; Product distribution / selectivity;88 %Chromat.
With 4,4'-Methylenebis(2,6-di-tert-butylphenol); hexaethylguanidinium chloride In chlorobenzene; xylene at 100℃; for 5h; Product distribution / selectivity;94 %Chromat.
With 4,4'-Methylenebis(2,6-di-tert-butylphenol); hexaethylguanidinium chloride at 100℃; for 5.5h; Product distribution / selectivity;98 %Chromat.
With 2,6-di-tert-butyl-4-methyl-phenol; 4,4'-Methylenebis(2,6-di-tert-butylphenol); hexaethylguanidinium chloride In 1,2-dichloro-benzene at 100℃; for 4h; Product distribution / selectivity;98 %Chromat.
With 2,6-di-tert-butyl-4-methyl-phenol; 4,4'-Methylenebis(2,6-di-tert-butylphenol); hexaethylguanidinium chloride at 110℃; for 3h; Product distribution / selectivity;72.3 %Chromat.
methanol
67-56-1

methanol

3-(trichlorosilyl)propyl 2-methylprop-2-enoate
7351-61-3

3-(trichlorosilyl)propyl 2-methylprop-2-enoate

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Conditions
ConditionsYield
at 22℃; Kinetics; Gas phase;
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

sodium 4-acryloylaminophenyldiazosulfonate

sodium 4-acryloylaminophenyldiazosulfonate

terpolymer methyl methacrylate/sodium 4-acryloylaminophenyldiazosulfonate/3-(trimethoxysilyl)propyl methacrylate, monomer ratio: 75/20/5; monomers: methyl methacrylate; sodium 4-acryloylaminophenyldiazosulfonate; 3-(trimethoxysilyl)propyl methacrylate

terpolymer methyl methacrylate/sodium 4-acryloylaminophenyldiazosulfonate/3-(trimethoxysilyl)propyl methacrylate, monomer ratio: 75/20/5; monomers: methyl methacrylate; sodium 4-acryloylaminophenyldiazosulfonate; 3-(trimethoxysilyl)propyl methacrylate

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In dimethylsulfoxide-d6 at 70℃; for 20h;100%
...Expand
dimethyl(vinyl)silyl acetate

dimethyl(vinyl)silyl acetate

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

3-methacryloxypropyltris(vinyldimethylsiloxy)silane
17096-10-5

3-methacryloxypropyltris(vinyldimethylsiloxy)silane

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; 2,6-di-tert-butyl-4-methyl-phenol at 80℃; for 1h; Dean-Stark; Inert atmosphere;95.4%
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Poly(propyl methacrylate siloxane); Monomer(s): 3-(trimethoxysilyl)propyl methacrylate

Poly(propyl methacrylate siloxane); Monomer(s): 3-(trimethoxysilyl)propyl methacrylate

Conditions
ConditionsYield
With hydrogenchloride In ethanol at 50℃; for 2.5h; Polymerization;94%
trimethylsilyl acetate
2754-27-0

trimethylsilyl acetate

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl methacrylate
17096-07-0

3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl methacrylate

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; 2,6-di-tert-butyl-4-methyl-phenol at 80℃; for 1h; Dean-Stark; Inert atmosphere;93.7%
Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

A

3-MAPSi(OMe)(OSiMe3)2

3-MAPSi(OMe)(OSiMe3)2

B

3-MAPSi(OH)(OSiMe3)2

3-MAPSi(OH)(OSiMe3)2

C

3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl methacrylate
17096-07-0

3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl methacrylate

Conditions
ConditionsYield
Stage #1: Hexamethyldisiloxane With methanol; sulfuric acid at 5 - 10℃; for 1h;
Stage #2: [3-(methacryloyloxy)propyl]trimethoxysilane at 5 - 10℃; for 1.5h;
Stage #3: With sulfuric acid; water more than 3 stages;		A n/a
B n/a
C 93.1%
...Expand
K8[γ-SiW10O36]*12H2O

K8[γ-SiW10O36]*12H2O

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

sodium hydroxide
1310-73-2

sodium hydroxide

2.9Na(1+)*1.1H(1+)*SiW10O36(OSi(CH2)3OCOC(CH3)CH2)4(4-) = Na2.9H1.1[SiW10O36(OSi(CH2)3OCOC(CH3)CH2)4]

2.9Na(1+)*1.1H(1+)*SiW10O36(OSi(CH2)3OCOC(CH3)CH2)4(4-) = Na2.9H1.1[SiW10O36(OSi(CH2)3OCOC(CH3)CH2)4]

Conditions
ConditionsYield
With hydrogenchloride In water; acetonitrile addn. of the org. compound to the heteropoly compd. in MeCN/H2O, addn. of aq. HCl, stirring (4 h), evapn. disoln. (H2O), addn. of aq. NaOH to pH5.4; evapn., washing (EtOH; acetone), drying (vac.); elem. anal.;90.7%
...Expand
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

dicyclohexylsilanediol
18027-70-8

dicyclohexylsilanediol

poly(dicyclohexylsilanediol-co-3-methacryloxypropyltrimethoxysilane)

poly(dicyclohexylsilanediol-co-3-methacryloxypropyltrimethoxysilane)

Conditions
ConditionsYield
Stage #1: [3-(methacryloyloxy)propyl]trimethoxysilane; dicyclohexylsilanediol; tetrabutyl ammonium fluoride In 2-methylpropyl acetate at 20 - 80℃; for 216h;
Stage #2: With hydrogenchloride In water at 80℃; for 8h;		90%
Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl methacrylate
17096-07-0

3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl methacrylate

Conditions
ConditionsYield
Stage #1: Hexamethyldisiloxane; [3-(methacryloyloxy)propyl]trimethoxysilane With sulfuric acid; acetic acid; trifluorormethanesulfonic acid at -15 - 20℃;
Stage #2: With 1,1,1,3,3,3-hexamethyl-disilazane at 20℃; for 2h; Product distribution / selectivity;		83%
Stage #1: Hexamethyldisiloxane; [3-(methacryloyloxy)propyl]trimethoxysilane With acetic acid; trifluoroacetic acid at 45℃; for 2h;
Stage #2: With acetyl chloride at 45℃; for 0.333333h;
Stage #3: With 1,1,1,3,3,3-hexamethyl-disilazane Product distribution / selectivity;		80%
decapotassium α2-[P2W17O61](10-) nonadecahydrate complex

decapotassium α2-[P2W17O61](10-) nonadecahydrate complex

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

N,N-dimethylammonium chloride
506-59-2

N,N-dimethylammonium chloride

((CH3)2NH2)6[((CH2C(CH3)COO(CH2)3Si)2O-α2-P2W17O61]*6H2O

((CH3)2NH2)6[((CH2C(CH3)COO(CH2)3Si)2O-α2-P2W17O61]*6H2O

Conditions
ConditionsYield
With HCl In methanol; water 0.5 equiv. of solid W-compd. was added to Si-compd. (in MeOH/H2O=3:1, v/v, room temp.), stirring for 5 min, pH was adjusted to 1.8 (1 M aq. HCl), stirring for 30 min, ppt. was filtered off, soln. was concd. at 30 °C, excess of Me2NHCl was added; ppt. was filtered off, washed 3 times with EtOH, twice with Et2O, dryingin vac. for 2 h;81.6%
...Expand
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

poly(ethylene oxide) methyl ether 2-bromoisobutyrate, Mn 2000 Da

poly(ethylene oxide) methyl ether 2-bromoisobutyrate, Mn 2000 Da

poly([ethylene oxide]-block-[3-(trimethoxysilyl)propyl methacrylate]-random-[methyl methacrylate]), Mn 13600 Da, Mw/Mn 1.58 by SEC

poly([ethylene oxide]-block-[3-(trimethoxysilyl)propyl methacrylate]-random-[methyl methacrylate]), Mn 13600 Da, Mw/Mn 1.58 by SEC

Conditions
ConditionsYield
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(I) bromide In methoxybenzene at 70℃; for 3h;76%
...Expand
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

poly(ethylene oxide) methyl ether 2-bromoisobutyrate, Mn 2000 Da

poly(ethylene oxide) methyl ether 2-bromoisobutyrate, Mn 2000 Da

poly([ethylene oxide]-block-[3-(trimethoxysilyl)propyl methacrylate]-random-[methyl methacrylate])

poly([ethylene oxide]-block-[3-(trimethoxysilyl)propyl methacrylate]-random-[methyl methacrylate])

Conditions
ConditionsYield
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(I) bromide In toluene at 90℃; for 3h;73%
...Expand
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

poly(ethylene oxide) methyl ether 2-bromoisobutyrate, Mn 2000 Da

poly(ethylene oxide) methyl ether 2-bromoisobutyrate, Mn 2000 Da

poly([ethylene oxide]-block-[3-(trimethoxysilyl)propyl methacrylate]-random-[methyl methacrylate]), Mn 12700 Da, Mw/Mn 1.78 by SEC

poly([ethylene oxide]-block-[3-(trimethoxysilyl)propyl methacrylate]-random-[methyl methacrylate]), Mn 12700 Da, Mw/Mn 1.78 by SEC

Conditions
ConditionsYield
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(I) bromide In methoxybenzene at 70℃; for 3h;73%
...Expand
trimethylsilan
993-07-7

trimethylsilan

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

1-(2-(Trimethoxysilyl)propyl)-1-(trimethylsiloxy)-2-methylprop-1-ene
110972-25-3

1-(2-(Trimethoxysilyl)propyl)-1-(trimethylsiloxy)-2-methylprop-1-ene

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; rhodium(III) chloride In tetrahydrofuran at 40 - 50℃;66%
1,3,5,7,9,11,14-heptaphenyltricyclo[7.3.3.1(5,11)]heptasiloxane-endo-3,7,14-triol
444315-26-8

1,3,5,7,9,11,14-heptaphenyltricyclo[7.3.3.1(5,11)]heptasiloxane-endo-3,7,14-triol

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

C49H46O14Si8

C49H46O14Si8

Conditions
ConditionsYield
Stage #1: 1,3,5,7,9,11,14-heptaphenyltricyclo[7.3.3.1(5,11)]heptasiloxane-endo-3,7,14-triol In tetrahydrofuran at -20℃; for 0.25h;
Stage #2: [3-(methacryloyloxy)propyl]trimethoxysilane In tetrahydrofuran at -20 - 20℃; for 168h;		48.4%
tris(triphenylphosphine)ruthenium(II) chloride
15529-49-4, 41756-81-4

tris(triphenylphosphine)ruthenium(II) chloride

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

[RuCl2{κ2-O,O-O2CC=CH2(CH3)}(PPh3)2]

[RuCl2{κ2-O,O-O2CC=CH2(CH3)}(PPh3)2]

Conditions
ConditionsYield
Stage #1: [3-(methacryloyloxy)propyl]trimethoxysilane With triethylamine In tetrahydrofuran; water at 20℃; for 0.5h;
Stage #2: tris(triphenylphosphine)ruthenium(II) chloride In tetrahydrofuran; water for 2h; Reflux;		47%
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

polymethylphenylsilane, Mn: 2.54E4, Mw: 5.94E4; Monomer(s): methylphenyldichlorosilane

polymethylphenylsilane, Mn: 2.54E4, Mw: 5.94E4; Monomer(s): methylphenyldichlorosilane

polysilane-methacryloxypropyltrimethoxysilane copolymers, Mn: 9.3E3, Mw: 16.6E3; Monomer(s): methylphenyldichlorosilane; 3-methacryloxypropyltrimethoxysilane

polysilane-methacryloxypropyltrimethoxysilane copolymers, Mn: 9.3E3, Mw: 16.6E3; Monomer(s): methylphenyldichlorosilane; 3-methacryloxypropyltrimethoxysilane

Conditions
ConditionsYield
In toluene for 0.1h; Polymerization; UV-irradiation;45%
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

polymethylphenylsilane, Mn: 2.54E4, Mw: 5.94E4; Monomer(s): methylphenyldichlorosilane

polymethylphenylsilane, Mn: 2.54E4, Mw: 5.94E4; Monomer(s): methylphenyldichlorosilane

polysilane-methacryloxypropyltrimethoxysilane copolymers, Mn: 11.6E3, Mw: 19.4E3; Monomer(s): methylphenyldichlorosilane; 3-methacryloxypropyltrimethoxysilane

polysilane-methacryloxypropyltrimethoxysilane copolymers, Mn: 11.6E3, Mw: 19.4E3; Monomer(s): methylphenyldichlorosilane; 3-methacryloxypropyltrimethoxysilane

Conditions
ConditionsYield
In toluene for 0.1h; Polymerization; UV-irradiation;36%
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

polymethylphenylsilane, Mn: 2.54E4, Mw: 5.94E4; Monomer(s): methylphenyldichlorosilane

polymethylphenylsilane, Mn: 2.54E4, Mw: 5.94E4; Monomer(s): methylphenyldichlorosilane

polysilane-methacryloxypropyltrimethoxysilane copolymers, Mn: 12.6E3, Mw: 24.3E3; Monomer(s): methylphenyldichlorosilane; 3-methacryloxypropyltrimethoxysilane

polysilane-methacryloxypropyltrimethoxysilane copolymers, Mn: 12.6E3, Mw: 24.3E3; Monomer(s): methylphenyldichlorosilane; 3-methacryloxypropyltrimethoxysilane

Conditions
ConditionsYield
In toluene for 0.1h; Polymerization; UV-irradiation;36%
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

Crossliked poly(propyl methacrylate siloxane); Monomer(s): 3-(trimethoxysilyl)propyl methacrylate

Crossliked poly(propyl methacrylate siloxane); Monomer(s): 3-(trimethoxysilyl)propyl methacrylate

Conditions
ConditionsYield
With dibenzoyl peroxide In toluene for 20h; Polymerization; UV-irradiation;0.47 g
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

polymethylphenylsilane

polymethylphenylsilane

methylphenylsilane - 3-methacryloxypropyltrimethoxysilane copolymer

methylphenylsilane - 3-methacryloxypropyltrimethoxysilane copolymer

Conditions
ConditionsYield
In toluene Polymerization; Irradiation;
tetramethylorthosilicate
681-84-5

tetramethylorthosilicate

[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

Polymer; Monomer(s): methyl methacrylate; [3-(methacryloxy)propyl]trimethoxysilane; tetramethoxysilane

Polymer; Monomer(s): methyl methacrylate; [3-(methacryloxy)propyl]trimethoxysilane; tetramethoxysilane

Conditions
ConditionsYield
Stage #1: [3-(methacryloyloxy)propyl]trimethoxysilane; methacrylic acid methyl ester With 2,2'-azobis(isobutyronitrile) In tetrahydrofuran at 60℃;
Stage #2: tetramethylorthosilicate With hydrogenchloride In tetrahydrofuran at 20℃;
...Expand
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

A

3-(Trihydroxysilyl)propyl methacrylate

3-(Trihydroxysilyl)propyl methacrylate

B

C8H16O5Si

C8H16O5Si

C

C9H18O5Si

C9H18O5Si

Conditions
ConditionsYield
In water for 2.5h; pH=6; Product distribution; Further Variations:; pH-values; Reaction partners; time;
...Expand
[3-(methacryloyloxy)propyl]trimethoxysilane
2530-85-0

[3-(methacryloyloxy)propyl]trimethoxysilane

A

3-(Trihydroxysilyl)propyl methacrylate

3-(Trihydroxysilyl)propyl methacrylate

B

C8H16O5Si

C8H16O5Si

C

C9H18O5Si

C9H18O5Si

D

monocrosslinked oligomerdicrosslinked oligomer

monocrosslinked oligomerdicrosslinked oligomer

Conditions
ConditionsYield
In water for 2.5h; pH=6;
...Expand

3-Methacryloxypropyltrimethoxysilane Chemical Properties

Molecule structure of 3-Methacryloxypropyltrimethoxysilane (CAS NO.2530-85-0):

IUPAC Name: 3-Trimethoxysilylpropyl 2-methylprop-2-enoate 
Molecular Weight: 248.3483 g/mol
Molecular Formula: C10H20O5Si 
Density: 1.006 g/cm3 
Melting Point: <-50 °C
Boiling Point: 258.7 °C at 760 mmHg 
Flash Point: 92.2 °C
Index of Refraction: 1.429
Molar Refractivity: 63.67 cm3
Molar Volume: 246.8 cm3
Surface Tension: 26.1 dyne/cm 
Enthalpy of Vaporization: 49.64 kJ/mol
Vapour Pressure: 0.0135 mmHg at 25 °C 
Storage Temp.: 2-8 °C
Sensitive: moisture sensitive
H-Bond Acceptor: 5
Rotatable Bond Count: 9
Exact Mass: 248.108
MonoIsotopic Mass: 248.108
Topological Polar Surface Area: 54
Heavy Atom Count: 16
Canonical SMILES: CC(=C)C(=O)OCCC[Si](OC)(OC)OC
InChI: InChI=1S/C10H20O5Si/c1-9(2)10(11)15-7-6-8-16(12-3,13-4)14-5/h1,6-8H2,2-5H3
InChIKey: XDLMVUHYZWKMMD-UHFFFAOYSA-N
EINECS: 219-785-8
Product Categories: Industrial/Fine Chemicals; Acrylate; monomer; Chloroalkylsilanes, etc. (Silane Coupling Agents); Functional Materials; Si (Classes of Silicon Compounds); Silane Coupling Agents; Si-O Compounds; Trialkoxysilanes; Vinylsilanes, Allylsilanes; Adhesion Promoters; Coupling Agents; Dispersing Agents; Methacrylate Silanes; Surface Modifiers

3-Methacryloxypropyltrimethoxysilane Uses

 3-Methacryloxypropyltrimethoxysilane (CAS NO.2530-85-0) is used for improving the surface's adhesive properties of organic materials and inorganic materials, such as fiberglass in the glass steel, plastics, rubber, paint and coatings. It is also used for the bonding agent to increase bonding properties.

3-Methacryloxypropyltrimethoxysilane Toxicity Data With Reference

1.    

skn-rbt 500 mg/24H MOD

     28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,220.
2.    

eye-rbt 500 mg/24H MLD

     28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,220.

3-Methacryloxypropyltrimethoxysilane Consensus Reports

Reported in EPA TSCA Inventory.

3-Methacryloxypropyltrimethoxysilane Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-28-37/39 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S37/39:Wear suitable gloves and eye/face protection.
RIDADR: 3082
WGK Germany: 1
RTECS: UC0230000
F: 4.4-8-21
TSCA: Yes
A skin and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

3-Methacryloxypropyltrimethoxysilane Specification

 3-Methacryloxypropyltrimethoxysilane (CAS NO.2530-85-0) is also named as (3-(Methacryloxy)propyl)trimethoxysilane ; 1-Propanol, 3-(trimethoxysilyl)-, methacrylate ; 2-Propenoic acid, 2-methyl-, 3-(trimethoxysilyl)propyl ester ; 3-(Trimethoxysilyl)-1-propanol methacrylate ; 3-(Trimethoxysilyl)propyl methacrylate ; 3-Methacryloyloxypropyl-trimethoxysilane ; A 174 ; BRN 1952435 ; Dynasylan MEMO ; HSDB 5468 ; KBM 503 ; KDM 503 ; KH 570 ; M 8550 ; Methacrylic acid, 3-(trimethoxysilyl)propyl ester ; Methacryloyloxypropyltrimethoxysilane ; Mops-M ; NSC 93591 ; NUCA 174 ; Q 174 ; Silane adduct, allyl methacrylate trimethoxy- ; Silane, (3-hydroxypropyl)trimethoxy-, methacrylate ; Silane, 3-methacryloxypropyltrimethoxy- ; Silicone A-174 ; Silicone a-174 ; Trimethoxysilyl-3-propylester kyseliny methakrylove ; Trimethoxysilyl-3-propylester kyseliny methakrylove [Czech] ; Trimethoxysilylpropyl methacrylate ; Union carbide A-174 ; Union carbide a-174 ; Z 6030 ; alpha-Methylacryloxypropyltrimethoxysilane . 3-Methacryloxypropyltrimethoxysilane (CAS NO.2530-85-0) is colorless transparent liquid.

Related Products

Hot Products

Post buying leads

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View