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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Trichlorosilane supplier in China

Cas:10025-78-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance Colorless,transparent liquid Complies Content% ≥99.90

Top purity Trichlorosilane with high quality and best price cas:10025-78-2

Cas:10025-78-2

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Manufacturers

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EAST CHEMSOURCES LIMITED

Trichlorosilane Product Name Trichlorosilane Standard Of Product Q/320482DDH002-2011 CAS NO. 10025-78-2 Specification 99%

Trichlorosilane

Cas:10025-78-2

Min.Order:1 Kilogram

FOB Price: $3000.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Trichlorosilane

Cas:10025-78-2

Min.Order:1

Negotiable

Type:Other

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product specifica

Trichlorosilane

Cas:10025-78-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Trichlorosilane

Cas:10025-78-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

10025-78-2 Trichlorosilane

Cas:10025-78-2

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Name: Trichlorosilane CAS: 10025-78-2 Appearance: Liquid Application: The synthesis of organosilanes and alkyl, aryl and organofunctional chlorosilanes is the most basic monomer in organic silane coupling agents. It is also the r

Trichlorosilane

Cas:10025-78-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:liquid Storage:Store in sealed containers at cool & dry plac

silicon Hydrosilane Trichlorosilane CAS No 10025-78-2

Cas:10025-78-2

Min.Order:100 Gram

Negotiable

Type:Other

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Trichlorosilane/CAS:10025-78-2

Cas:10025-78-2

Min.Order:1 Kilogram

FOB Price: $20.0 / 30.0

Type:Trading Company

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis: Trading(Raw Mater

Silane,trichloro-

Cas:10025-78-2

Min.Order:0 Metric Ton

FOB Price: $18.0 / 20.0

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

Trichlorosilane CAS NO.10025-78-2

Cas:10025-78-2

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Trichlorosilane

Cas:10025-78-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Trichlorosilane

Cas:10025-78-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Trichlorosilane

Cas:10025-78-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Wuhan Kemi-Works Chemical Co., Ltd

10025-78-2 Chemical name:Trichlorosilane Synonyms:silici-chloroforme; siliciumchloroform Formula:HSiCl3 Description:Colorless transparent liquid Superiority 1.Powerful R & D team 2.The ability of quantized production,from grams to ton

Trichlorosilane

Cas:10025-78-2

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hebei yanxi chemical co.,LTD.

CHENGDU YANXI is a comprehensive manufacturer and an international distribution of products throughout the world. Specialized in Scrap metal, Chemical raw materials, Paper products and color industry. We aim to become leading position in global dis

10025-78-2 Trichlorosilane---Silane Coupling Agent--- Silibase-6101

Cas:10025-78-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Trichlorosilane

Cas:10025-78-2

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Trichlorosilane

Cas:10025-78-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Trichlorosilane

Cas:10025-78-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 10025-78-2 with best price

Cas:10025-78-2

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Trichlorosilane

Cas:10025-78-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Trichlorosilane

Cas:10025-78-2

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Prompt reaction, good quality and best service make us reliable and outstanding in this industry.Appearance:Colorless transparent liqui

Trichlorosilane manufacture

Cas:10025-78-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

Trichlorosilane CAS.10025-78-2Appearance:ask jude for details Storage:Dry and ventilated Package:in foil bag or customized Application:Pharmaceutical intermediates/Food additive Transportation:By express (Door to door) such as FEDEX, DHL, EMS for sm

Trichlorosilane CAS.10025-78-2

Cas:10025-78-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Trichlorosilane 10025-78-2

Cas:10025-78-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Beantown Chemical

in stock Application:10025-78-2

Trichlorosilane, 98%

Cas:10025-78-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Henan Sunlake Enterprise Corporation Our Advantages 1, Any inquiry about ch

Trichlorosilane

Cas:10025-78-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Weck Chemical Industry Co., Ltd.

span lang="EN-US" style="font-size: 9.0pt;font-family:"Arial",sans-serif;color:#4D4D4D">As a leading manufacturer and supplier of chemicals in china, weckchem not only supply popular chemicals, but also weckchem’s r&d center off

Trichlorosilane

Cas:10025-78-2

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

Zhengzhou Kingorgchem Chemical Technology Co., Ltd. was founded on the basis of Organophosphorus Chemistry Lab of Institute of Chemistry Henan Academy of Sciences in 2015. The laboratory covers 600 m2 and the pilot plant covers 2000 m2. Kingorgchem i

National Research Platform ISO 9001 10025-78-2

Cas:10025-78-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

silicon
7440-21-3

silicon

A

Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

B

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

C

trichlorosilane
10025-78-2

trichlorosilane

D

dimethylsilicon dichloride
75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
With methylene chloride; copper In neat (no solvent) mixt. of CH3Cl/N2 (2:5) and Si-Cu (9:1) at 300°C;;A 4%
B n/a
C n/a
D 86.5%
With methylene chloride; copper In neat (no solvent) mixt. of CH3Cl/N2 (2:5) and Si-Cu (9:1) at 300°C;;A 4%
B n/a
C n/a
D 86.5%
With methylene chloride; copper In neat (no solvent) CH3Cl and Si-Cu mixt. (8:2) at 350°C;;
n-propyltrichlorosilane
141-57-1

n-propyltrichlorosilane

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
With hydrogen; Rh, Re/C at 550℃; under 5807.73 Torr; for 10.1h; Product distribution / selectivity;82%
hydrogenchloride
7647-01-0

hydrogenchloride

Cu(b),Si(20) (X%)

Cu(b),Si(20) (X%)

A

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

B

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
In neat (no solvent) reaction at 300 °C;;A 20%
B 80%
In neat (no solvent) reaction at 300 °C;;A 20%
B 80%
ethyltrichlorosilane
115-21-9

ethyltrichlorosilane

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
With hydrogen; Rh, Re/C at 700℃; under 5947.36 Torr; for 17.8833h; Product distribution / selectivity;75.3%
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

A

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

B

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
With hydrogen; Rh/C at 800℃; Product distribution / selectivity;A 73.3%
B 25.1%
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

hydrogen
1333-74-0

hydrogen

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
In neat (no solvent) SiCl4 reacted with H2 in thermo-plasma at 50 kW at 3500-5000 K;72.9%
In neat (no solvent) Kinetics; byproducts: hydrogen chloride; bubbling H2 through liq. SiCl4 at constant temp.; introducing into the discharge zone; various product ratios yield various H2:SiCl4 molar ratio, molar energy input, and pressure; gas chromy.;60%
at 900 - 1300℃; under 1125.11 - 3750.38 Torr; Product distribution / selectivity;
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
With hydrogen; Rh, Re/C at 550℃; under 4556.19 Torr; for 4.55h; Product distribution / selectivity;70.8%
hydrogenchloride
7647-01-0

hydrogenchloride

silicon
7440-21-3

silicon

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
With CuO-ZnO-In2O3 mesocrystal microspheres Reagent/catalyst;61.2%
In not given heating of silicon washed with HCl and dried in a stream of HCl at 450-500 °C;;
In not given heating of silicon washed with HCl and dried in a stream of HCl at 450-500 °C;;
at 230 - 260℃;
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

A

Dichloromethylsilane
75-54-7

Dichloromethylsilane

B

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

C

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
With hydrogen; Rh/C at 700℃; Product distribution / selectivity;A 5.5%
B 28.2%
C 22.9%
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

hydrogen
1333-74-0

hydrogen

silicon
7440-21-3

silicon

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
copper(l) chloride at 525℃; Product distribution / selectivity;6.14%
at 525℃; Product distribution / selectivity;4.6%
at 500℃; under 22502.3 Torr; Product distribution / selectivity; Industry scale;
1,2-Dichloropropane
26198-63-0, 78-87-5

1,2-Dichloropropane

nitrogen

nitrogen

copper containing silicon

copper containing silicon

A

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

B

allyltrichlorosilane
107-37-9

allyltrichlorosilane

C

1,2-bis-trichlorosilanyl-propane
18171-37-4

1,2-bis-trichlorosilanyl-propane

D

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
at 300℃; Produkt 5: 2-Dichlorsilyl-1-trichlorsilyl-propan;
chloroform
67-66-3

chloroform

silicon-copper

silicon-copper

A

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

B

1,1,1,3,3,3-hexachloro-1,3-disilapropane
4142-85-2

1,1,1,3,3,3-hexachloro-1,3-disilapropane

C

tris(trichlorosilyl)methane
4775-56-8

tris(trichlorosilyl)methane

D

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
at 300℃;
hydrogenchloride
7647-01-0

hydrogenchloride

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

hydrogen
1333-74-0

hydrogen

silicon
7440-21-3

silicon

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
copper(l) chloride at 300℃; Product distribution / selectivity;
dibromochlorosilane
82146-27-8

dibromochlorosilane

trimethylstannane
1631-73-8

trimethylstannane

A

tribromosilane
7789-57-3

tribromosilane

B

SiClBrH2
21479-75-4

SiClBrH2

C

SiCl2HBr
82146-25-6

SiCl2HBr

D

trichlorosilane
10025-78-2

trichlorosilane

E

monosilane
7440-21-3

monosilane

Conditions
ConditionsYield
In neat (no solvent) condensing of equimolar amts. of tinhydride and SiClHBr2 (trace of SiCl2HBr present) into cold finger, reaction at room temp. (30 min); further products; not isolated; IR spectroscopy;
hydrogenchloride
7647-01-0

hydrogenchloride

chloroform
67-66-3

chloroform

silicon
7440-21-3

silicon

A

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

B

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
With methylene chloride; cadmium; copper mixing of Cu and Si; drying (300°C, 5 h, dry nitrogen), rising temp. to 350°C, addn. of MeCl (4 h), removal of MeSiCl3 and Me2SiCl2, Cd addn. at room temp., rising temp. to 300°C, CHCl3 and HCl addn., 40 h; product collection, distn., receiver cooled to -20.degree, dist. of remains in flask,;
hydrogenchloride
7647-01-0

hydrogenchloride

silicon
7440-21-3

silicon

A

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

B

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
In solid Kinetics; gas-solid react.; temp. 200 - 600°C; not isolated; detn. by DSC, XRD;
In gas Kinetics; (H2) reacted at pressure 9.0E+4 Pa, and at temp. 623, 673, or 723 K, Q=300 sccm and concd. HCl=1.0, 3.3, 10 vol %;
In neat (no solvent) dried HCl is used; glowing heat;; product mixture obtained;;
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

trimethylstannane
1631-73-8

trimethylstannane

A

trichlorosilane
10025-78-2

trichlorosilane

B

trimethyltin(IV)chloride
1066-45-1

trimethyltin(IV)chloride

C

monosilane
7440-21-3

monosilane

D

Dichlorosilane
4109-96-0

Dichlorosilane

Conditions
ConditionsYield
In neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 36 h; not isolated; IR spectroscopy (identified 25-30% SiCl3H, 15% SiCl2H2 and 10% SiH4 in product mixt.);
trimethylstannane
1631-73-8

trimethylstannane

bromo trichloro silane
13465-74-2

bromo trichloro silane

A

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

B

trichlorosilane
10025-78-2

trichlorosilane

C

monosilane
7440-21-3

monosilane

Conditions
ConditionsYield
In neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 3 h; not isolated; IR spectroscopy (identified 85% SiCl3H, 5% SiH4 and 5% SiCl4 in product mixt.);
trimethylstannane
1631-73-8

trimethylstannane

dibromo dichlorosilane
13465-75-3

dibromo dichlorosilane

A

SiCl2HBr
82146-25-6

SiCl2HBr

B

trichlorosilane
10025-78-2

trichlorosilane

C

trimethyltin bromide
1066-44-0

trimethyltin bromide

D

monosilane
7440-21-3

monosilane

Conditions
ConditionsYield
In neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, two equiv. of tinhydride, reactn. time 2 h; not isolated; IR spectroscopy (identified 35-40% SiCl3H, 40% SiH4 and 10% SiCl2HBr in product mixt.);
calcium hydride
7789-78-8

calcium hydride

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

A

trichlorosilane
10025-78-2

trichlorosilane

B

chlorosilane
13966-57-9

chlorosilane

C

Dichlorosilane
4109-96-0

Dichlorosilane

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2, HCl; passing SiCl4 vapor over CaH2 below red heat;;A n/a
B 0%
C 0%
In neat (no solvent) byproducts: H2, HCl; passing SiCl4 vapor over CaH2 below red heat;;A n/a
B 0%
C 0%
nitrogen trichloride
10025-85-1

nitrogen trichloride

monosilane
7440-21-3

monosilane

A

trichlorosilane
10025-78-2

trichlorosilane

B

chlorosilane
13966-57-9

chlorosilane

Conditions
ConditionsYield
In gaseous matrix byproducts: HCl, H2; Ar carrier gas, room temp., static vac. glass reactor with quartz window (reaction mixt. made up in reactor); manometric monitoring, chemiluminescence spectroscopy;
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
With Cu; H2S In neat (no solvent) byproducts: Cu sulfide, H2O; passing H2S through a mixture SiCl4 and Cu powder on boiling;;0%
With H2 In neat (no solvent) reaction at glowing heat;;
With Zn; HCl In neat (no solvent) byproducts: H2; heating of SiCl4 with Zn powder in a HCl stream up to boiling;;
With hydrogen; silica gel; zinc In water at 450℃; for 48h;
With hydrogen; copper at 750℃; for 1h;
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

monosilane
7440-21-3

monosilane

A

trichlorosilane
10025-78-2

trichlorosilane

B

chlorosilane
13966-57-9

chlorosilane

C

Dichlorosilane
4109-96-0

Dichlorosilane

Conditions
ConditionsYield
In gas reactor temp.: 250 - 500°C; detn. by gas chromy.;
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

hydrogen sulfide
7783-06-4

hydrogen sulfide

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
With Cu In neat (no solvent) byproducts: H2; treatment of the mixture in a liquid air cooled bomb tube;;0%
hydrogenchloride
7647-01-0

hydrogenchloride

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
With Zn In neat (no solvent) byproducts: H2; heating of SiCl4 with Zn and liquid HCl in a sealed tube at 100 °C;;0%
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

hydrogen
1333-74-0

hydrogen

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

trichlorosilane
10025-78-2

trichlorosilane

C

silicon
7440-21-3

silicon

Conditions
ConditionsYield
byproducts: HCl; equil. reaction, at 1170-1540 K;
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

hydrogen
1333-74-0

hydrogen

A

aluminium trichloride
7446-70-0

aluminium trichloride

B

trichlorosilane
10025-78-2

trichlorosilane

C

Dichlorosilane
4109-96-0

Dichlorosilane

Conditions
ConditionsYield
With aluminium In neat (no solvent) byproducts: SiCl4; reaction by passing SiCl4 vapor with H2 (1:1) over Al at 400 °C;; distn.;;
With Al In neat (no solvent) byproducts: SiCl4; reaction by passing SiCl4 vapor with H2 (1:1) over Al at 400 °C;; distn.;;
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

hydrogen
1333-74-0

hydrogen

A

trichlorosilane
10025-78-2

trichlorosilane

B

Dichlorosilane
4109-96-0

Dichlorosilane

Conditions
ConditionsYield
With co-catalyst: pyrimidine or P(OPh)3; tri-n-butyl-tin hydride In toluene absence of air; H2-stream; further alternate co-catalysts: PCy3 or PBu3 or N-methylimidazole or pyridine or chinoline; gas chromy.;
tri-n-butyl-tin hydride In acetonitrile absence of air; H2-stream; gas chromy.;
With Al or Mg or Zn In neat (no solvent, gas phase) passing SiCl4 vapor and H2 over granulated Al, Mg or Zn at 350-450 °C;; condensation of the gaseous reaction product by dry ice, separation of the mixture by fractionation;;
With Al or Mg or Zn In gas passing SiCl4 vapor and H2 over granulated Al, Mg or Zn at 350-450 °C;; condensation of the gaseous reaction product by dry ice, separation of the mixture by fractionation;;
trichlorosilane
10025-78-2

trichlorosilane

5-((4-dodec-11-en-1-yl)phenyl)-5’-(4-hexylphenyl)-2,2’-bithiophene

5-((4-dodec-11-en-1-yl)phenyl)-5’-(4-hexylphenyl)-2,2’-bithiophene

trichloro(12-(4-(5’-(4-hexylphenyl)-[2,2’-bithiophen]-5-yl)phenyl)dodecyl)silane

trichloro(12-(4-(5’-(4-hexylphenyl)-[2,2’-bithiophen]-5-yl)phenyl)dodecyl)silane

Conditions
ConditionsYield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 90℃; Glovebox; Sealed tube;100%
4-vinylpyridine
100-43-6

4-vinylpyridine

trichlorosilane
10025-78-2

trichlorosilane

trichloro(hydrido)bis(4-vinylpyridine)silicon
1154061-81-0

trichloro(hydrido)bis(4-vinylpyridine)silicon

Conditions
ConditionsYield
In toluene at -78 - 20℃;99.5%
2-octene
111-67-1

2-octene

trichlorosilane
10025-78-2

trichlorosilane

(n-hep-1-me)SiCl3
18225-07-5

(n-hep-1-me)SiCl3

Conditions
ConditionsYield
In not given HSiCl3 and 2-octene at 50-60°C with peroxide;;99%
oct-1-ene
111-66-0

oct-1-ene

trichlorosilane
10025-78-2

trichlorosilane

octyltrichlorosilane
5283-66-9

octyltrichlorosilane

Conditions
ConditionsYield
In not given HSiCl3 and 1-octene at about 55°C with diacetylperoxide;;99%
In neat (no solvent) HSiCl3 and 1-octene at 150°C in presence of Cu;;
In neat (no solvent) HSiCl3 and 1-octene at 300°C under pressure;;
In neat (no solvent) HSiCl3 and 1-octene at 300°C under pressure;;
1.2-CH2CHCH2-1.2-C2B10H10
30620-32-7

1.2-CH2CHCH2-1.2-C2B10H10

trichlorosilane
10025-78-2

trichlorosilane

1,2-[(CH2)3SiCl3]2-1,2-C2B10H10
888501-94-8

1,2-[(CH2)3SiCl3]2-1,2-C2B10H10

Conditions
ConditionsYield
With catalyst:Karstedt platinum catalyst (3-3.5percent Pt) In neat (no solvent) (Ar); stirred for 2 h at room temp.; evapd., obtained as oil;99%
p-phenylpyridine
939-23-1

p-phenylpyridine

trichlorosilane
10025-78-2

trichlorosilane

trichloro(hydrido)bis(4-phenylpyridine)silicon
1154061-84-3

trichloro(hydrido)bis(4-phenylpyridine)silicon

Conditions
ConditionsYield
In toluene at -78 - 20℃;99%
pyridine
110-86-1

pyridine

trichlorosilane
10025-78-2

trichlorosilane

trichloro(hydrido)bis(pyridine)silicon
17748-48-0, 38685-10-8

trichloro(hydrido)bis(pyridine)silicon

Conditions
ConditionsYield
In toluene at -78 - 20℃;98.8%
C5H10Cl4N2Si
1421683-29-5

C5H10Cl4N2Si

trichlorosilane
10025-78-2

trichlorosilane

C5H12Cl2N2Si
1610766-37-4

C5H12Cl2N2Si

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 12h; Inert atmosphere; Schlenk technique;98%
trichlorosilane
10025-78-2

trichlorosilane

trichlorobis[4-(dimethylamino)pyridine](hydrido)silicon
1154061-83-2

trichlorobis[4-(dimethylamino)pyridine](hydrido)silicon

Conditions
ConditionsYield
In tetrahydrofuran at -78 - 20℃;97.4%
[(1',1'-diallyloxycarbonyl)-1,2-methano]-1,2-dihydro-C60-fullerene
1355962-66-1

[(1',1'-diallyloxycarbonyl)-1,2-methano]-1,2-dihydro-C60-fullerene

trichlorosilane
10025-78-2

trichlorosilane

Conditions
ConditionsYield
With dicyclopentadienyl platinum dichloride In toluene at 70℃; for 24h; Inert atmosphere; Schlenk technique;97%
trichlorosilane
10025-78-2

trichlorosilane

silicon
7440-21-3

silicon

Conditions
ConditionsYield
Stage #1: trichlorosilane under 3.75038 Torr; for 6h; Pulsed microwave radiation (25-50W);
Stage #2: With hydrogen at 900℃;
96.7%
With hydrogen chemical vapor deposition (8% SiHCl3 in H2, 1100°C);
With hydrogen chemical vapor deposition (hot-wall reactor, basic pressure 10 or 76 Torr, 1223 K);
picoline
108-89-4

picoline

trichlorosilane
10025-78-2

trichlorosilane

trichloro(hydrido)bis(4-methylpyridine)silicon
1154061-79-6

trichloro(hydrido)bis(4-methylpyridine)silicon

Conditions
ConditionsYield
In toluene at -78 - 20℃;96.3%
4-tert-butylpyridine
3978-81-2

4-tert-butylpyridine

trichlorosilane
10025-78-2

trichlorosilane

bis(4-tert-butylpyridine)trichloro(hydrido)silicon
1154061-82-1

bis(4-tert-butylpyridine)trichloro(hydrido)silicon

Conditions
ConditionsYield
In toluene at -78 - 20℃;96.1%
trichlorosilane
10025-78-2

trichlorosilane

phenol
108-95-2

phenol

triphenoxysilane
3898-65-5

triphenoxysilane

Conditions
ConditionsYield
at 50℃; for 4h;96%
allyl methacrylate
96-05-9

allyl methacrylate

trichlorosilane
10025-78-2

trichlorosilane

3-(trichlorosilyl)propyl 2-methylprop-2-enoate
7351-61-3

3-(trichlorosilyl)propyl 2-methylprop-2-enoate

Conditions
ConditionsYield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 70℃; for 3h;96%
trichlorosilane
10025-78-2

trichlorosilane

hydrogen
1333-74-0

hydrogen

monosilane
7440-21-3

monosilane

Conditions
ConditionsYield
With titanium tetrachloride In melt melting NaCl, KCl and AlCl3 at ca. 150°C, heating to ca. 300°C, addn. of TiCl4 and Al under H2 within 2 h, addn. of more Al at 230°C, then addn. of SiHCl3 under H2 with stirring within 1 h; sepn. of the chlorosilane/silane mixture by fractional condensation and rectification;96%
(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)
157072-60-1, 61521-25-3, 166941-05-5, 16971-33-8

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

trichlorosilane
10025-78-2

trichlorosilane

Ru(SiCl3)Cl(CO)(P(C6H5)3)2

Ru(SiCl3)Cl(CO)(P(C6H5)3)2

Conditions
ConditionsYield
In toluene at 60℃; for 0.333333h; Inert atmosphere; Schlenk technique;96%
KRYTOX allyl ether KDP-4599

KRYTOX allyl ether KDP-4599

trichlorosilane
10025-78-2

trichlorosilane

KRYTOX 3-trichlorosilylpropyl KDP-4599

KRYTOX 3-trichlorosilylpropyl KDP-4599

Conditions
ConditionsYield
dihydrogen hexachloroplatinate at 165℃; for 6h;95%
dihydrogen hexachloroplatinate at 175℃; for 8h;95%
decacarbonyldirhenium(0)
14285-68-8

decacarbonyldirhenium(0)

trichlorosilane
10025-78-2

trichlorosilane

Re(CO)5(SiCl3)

Re(CO)5(SiCl3)

Conditions
ConditionsYield
In hexane under N2; Re2(CO)10 and the silane in hexane was pressurized with CO (70 atm., autoklave), heated at 200°C for 16 h; cooled, gases were vented, washed with hexane, dried with a stream of N2, sublimation;95%
trichlorosilane
10025-78-2

trichlorosilane

2,3,4,5,6-pentafluorophenylmagnesium bromide
879-05-0

2,3,4,5,6-pentafluorophenylmagnesium bromide

tris(pentafluorophenyl)silane
20160-40-1

tris(pentafluorophenyl)silane

Conditions
ConditionsYield
In diethyl ether reaction at -12°C (1hour) and heating under reflux for 12 hours;;95%
In diethyl ether reaction at -12°C (1hour) and heating under reflux for 12 hours;;95%
dodecacarbonyl-triangulo-triruthenium
15243-33-1

dodecacarbonyl-triangulo-triruthenium

trichlorosilane
10025-78-2

trichlorosilane

cis-Ru(CO)4(SiCl3)2
36570-60-2

cis-Ru(CO)4(SiCl3)2

Conditions
ConditionsYield
In hexane byproducts: CO; Irradiation (UV/VIS); in a closed quartz tube filled with CO gas (2 atm) irradiation during 3d with stirring; cooling at -78°C, 2h, drying the crystals in vac., sublimation at 40°C, 0.02 Torr onto a probe cooled to -78°C;95%
trichlorosilane
10025-78-2

trichlorosilane

water
7732-18-5

water

hidrogen-silsesquioxane

hidrogen-silsesquioxane

Conditions
ConditionsYield
In water addn. of water to silicon compd. at -78°C with stirring; filtration, washing ppt. with water, drying in vac. at 85°C overnight;95%
In diethyl ether cooling (ice), stirring (1 d, room temp.); filtn., washing, drying (vac. 1E-3 mbar, 2 d, 80°C);
bis(ethylene)(tricyclohexylphosphine)platinum
57158-83-5

bis(ethylene)(tricyclohexylphosphine)platinum

trichlorosilane
10025-78-2

trichlorosilane

[(Pt(μ-H)(SiCl3)[P(C6H11)3])2] * toluene

[(Pt(μ-H)(SiCl3)[P(C6H11)3])2] * toluene

Conditions
ConditionsYield
In toluene N2-atmosphere; condensing of excess silane into soln. of Pt-complex (-196°C), warming to room temp. (pptn.); filtration, washing (hexane), drying (vac.); elem. anal.;95%
4-Ethylpyridine
536-75-4

4-Ethylpyridine

trichlorosilane
10025-78-2

trichlorosilane

trichlorobis(4-ethylpyridine)(hydrido)silicon
1154061-80-9

trichlorobis(4-ethylpyridine)(hydrido)silicon

Conditions
ConditionsYield
In toluene at -78 - 20℃;95%
octadec-1-ene
112-88-9

octadec-1-ene

trichlorosilane
10025-78-2

trichlorosilane

octadecyltrichlorosilane
112-04-9

octadecyltrichlorosilane

Conditions
ConditionsYield
In neat (no solvent) HSiCl3 and 1-octadecene at about 300°C under pressure;;94%
In neat (no solvent) HSiCl3 and octadecene at 300°C under pressure;;94%
In neat (no solvent) HSiCl3 and 1-octadecene at about 300°C under pressure;;94%
In neat (no solvent) HSiCl3 and octadecene at 300°C under pressure;;94%
With SiliaCat Pt(0) - mesoporous organosilica microspheres doped with Pt nanoparticles In neat (no solvent) at 65℃; for 1h;87 %Spectr.
chloro-carbonyl-hydrido-bis(triphenylphosphine)osmium
129134-01-6

chloro-carbonyl-hydrido-bis(triphenylphosphine)osmium

trichlorosilane
10025-78-2

trichlorosilane

OsCl(triphenylphosphine)2(CO)(trichlorosilyl)
129133-98-8

OsCl(triphenylphosphine)2(CO)(trichlorosilyl)

Conditions
ConditionsYield
In toluene N2-atmosphere; addn. of excess HSiCl3 to soln. of Os-complex, stirring for 20 min at 60°C; concn., crystn. on addn. of hexane;94%
[Os(κ2-dimethyldithiocarbamate)H(CO)(PPh3)2]
56800-92-1

[Os(κ2-dimethyldithiocarbamate)H(CO)(PPh3)2]

trichlorosilane
10025-78-2

trichlorosilane

[Os(κ2-dimethyldithiocarbamate)(SiCl3)(CO)(PPh3)2]
895138-95-1

[Os(κ2-dimethyldithiocarbamate)(SiCl3)(CO)(PPh3)2]

Conditions
ConditionsYield
In toluene toluene and HSiCl3 were added to Os complex in Schlenk tube; sealed; cooled in liq. N2; evacuated; warmed to ambient temp.; heated at 100°C for 12 h; cooled; concd. (vac.); hexane added; filtered; recrystd. (CH2Cl2/hexane); elem. anal.;94%
(η5-cyclopentadienyl)methylbis(methyldiphenylphosphine)ruthenium
114674-46-3

(η5-cyclopentadienyl)methylbis(methyldiphenylphosphine)ruthenium

trichlorosilane
10025-78-2

trichlorosilane

Cp(PMePh2)2RuSiCl3
475635-32-6

Cp(PMePh2)2RuSiCl3

Conditions
ConditionsYield
In further solvent(s) byproducts: CH4; (Ar); mixing ruthenium complex with HSiCl3, freezing with liq. N2, swarming to room temp., sealing, heating at 100°C for 16 h, cooling toroom temp.; evapn., dissolving in CH2Cl2, filtration through glass wool, addn. of hexanes, concn., filtration, drying; elem. anal.;92%
styrene
292638-84-7

styrene

trichlorosilane
10025-78-2

trichlorosilane

1-phenyl-2-(trichlorosilyl)ethane
940-41-0

1-phenyl-2-(trichlorosilyl)ethane

Conditions
ConditionsYield
Stage #1: trichlorosilane; C17H36N2OPtSi2 for 0.0833333h; Inert atmosphere; Cooling with water bath;
Stage #2: styrene at 16℃; for 7h; Product distribution / selectivity; Inert atmosphere;
92%
C17H36N2OPtSi2 In dodecane for 7h; Product distribution / selectivity; Inert atmosphere;
trichlorosilane
10025-78-2

trichlorosilane

sodium dioctylphosphinate
67206-59-1

sodium dioctylphosphinate

dioctylphosphinyl chloride
7539-86-8

dioctylphosphinyl chloride

Conditions
ConditionsYield
In chloroform at 80℃; for 16h;91.5%
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