CAS No.75-54-7,Dichloromethylsilane Suppliers,MSDS download

Pure Chemistry Scientific Inc.

Dichloromethylsilane Application:822537

Dichloromethylsilane

Cas:75-54-7

Min.Order:1 Gram

FOB Price: $500.0

Type:Trading Company

inquiry

Synthetic route

: 4518-98-3
1,1,2,2-tetrachloro-1,2-dimethyldisilane

A: 75-54-7
Dichloromethylsilane

B: 75-79-6
Methyltrichlorosilane

Conditions

Conditions	Yield
silica gel; 3,5-Dimethyl-1-<(2-triethoxysilyl)ethyl>-1H-pyrazol Product distribution; Mechanism; Heating; var. of catalyst, also with HCl;	A 0.4% B 99.6%

: 992-94-9
methylsilane

A: 75-54-7
Dichloromethylsilane

B: 993-00-0
chloro-methyl-silane

Conditions

Conditions	Yield
With hydrogenchloride In diethyl ether at 80℃; for 36h; Temperature; Solvent; Reagent/catalyst;	A 7% B 87%
With hydrogenchloride In 1,4-dioxane at 100℃; for 49.33h; Time;	A 87% B 9%
With HCl In neat (no solvent) heating of CH3SiH3 and HCl in a closed tube at 100°C in presence of AlCl3 for several hours;;
With hydrogenchloride; diethyl ether In benzene-d6 at 80℃; Reagent/catalyst; Schlenk technique; Inert atmosphere;	A 7 %Spectr. B 87 %Spectr.

: 74-87-3
methylene chloride

: 7440-21-3
silicon

A: 75-54-7
Dichloromethylsilane

B: 75-79-6
Methyltrichlorosilane

C: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
tin; aluminum silicide; zinc(II) oxide; copper dichloride at 280 - 300℃; for 6h; Rochow reaction;	A 1.7% B n/a C 83.8%
zinc(II) oxide; copper dichloride at 280 - 300℃; for 6h; Rochow reaction;	A 4.5% B n/a C 83.7%
zinc(II) oxide; aluminium; copper dichloride at 280 - 300℃; for 6h; Rochow reaction;	A 2.8% B n/a C 82.1%
With PdSi at 400℃; for 6h;

...Expand

: 75-79-6
Methyltrichlorosilane

: 4518-98-3
1,1,2,2-tetrachloro-1,2-dimethyldisilane

A: 75-54-7
Dichloromethylsilane

B: 993-00-0
chloro-methyl-silane

Conditions

Conditions	Yield
With tetra-n-butylphosphonium chloride; lithium hydride In diethylene glycol dimethyl ether at -196 - 160℃; for 35h; Reagent/catalyst; Sealed tube;	A 64% B 24%
With tetra-n-butylphosphonium chloride; lithium hydride In diethylene glycol dimethyl ether at -196 - 160℃; Temperature; Reagent/catalyst; Sealed tube;	A 64 %Spectr. B 24 %Spectr.

...Expand

: 75-79-6
Methyltrichlorosilane

A: 75-54-7
Dichloromethylsilane

B: 993-00-0
chloro-methyl-silane

Conditions

Conditions	Yield
With tetra-n-butylphosphonium chloride; lithium hydride In diethylene glycol dimethyl ether at -196 - 160℃; for 62h; Temperature; Reagent/catalyst; Sealed tube;	A 63% B 19%
With lithium hydride; triphenylphosphine In diethylene glycol dimethyl ether at -196 - 160℃; for 62h; Time; Reagent/catalyst; Temperature; Sealed tube;	A 62% B 23%
With Dichlorosilane; Aliquat 336 at 70℃; under 1650.17 Torr; Product distribution / selectivity;
With Dichlorosilane; 1-butyl-3-methylimidazolium chloride at 80℃; under 1500.15 Torr; Product distribution / selectivity;
With tetra-n-butylphosphonium chloride; lithium hydride at -196 - 120℃; for 2.5h; Time; Temperature; Sealed tube;

: 75-79-6
Methyltrichlorosilane

A: 75-54-7
Dichloromethylsilane

B: 992-94-9
methylsilane

C: 993-00-0
chloro-methyl-silane

Conditions

Conditions	Yield
With Tetraethylene glycol dimethyl ether; tetra-n-butylphosphonium chloride; lithium hydride In 1,4-dioxane at -196 - 120℃; for 70.75h; Temperature; Reagent/catalyst; Sealed tube;	A 60% B 5% C 32%
With tri-n-butyl-tin hydride; [2,2]bipyridinyl In diethylene glycol dimethyl ether for 1h; Ambient temperature;	A n/a B n/a C 55%
With Tetraethylene glycol dimethyl ether; tetra-n-butylphosphonium chloride; lithium hydride In 1,4-dioxane at -196 - 120℃; for 70.75h; Sealed tube;	A 40% B 15% C 44%

...Expand

: 1066-35-9
dimethylmonochlorosilane

: 75-78-5
dimethylsilicon dichloride

A: 75-54-7
Dichloromethylsilane

B: 75-77-4
chloro-trimethyl-silane

C: 75-79-6
Methyltrichlorosilane

D: 993-00-0
chloro-methyl-silane

Conditions

Conditions	Yield
With aluminium trichloride at 140℃; for 15h;	A 0.092 mol B 59% C 0.01 mol D 0.055 mol

...Expand

: 75-79-6
Methyltrichlorosilane

: 75-54-7
Dichloromethylsilane

Conditions

Conditions	Yield
With Tetraethylene glycol dimethyl ether; tetra-n-butylphosphonium chloride; lithium hydride In 1,4-dioxane at -196 - 160℃; for 26h; Reagent/catalyst; Sealed tube;	57%
With hydrogen; aluminium at 450℃;
With trichlorosilane; chlorosilane; Dichlorosilane; tetra-n-butylphosphonium chloride at 78℃; under 1425.14 Torr; Product distribution / selectivity;

: 74-87-3
methylene chloride

A: 75-54-7
Dichloromethylsilane

B: 75-79-6
Methyltrichlorosilane

C: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With silicon; zinc at 325℃; for 24h; Reagent/catalyst; Inert atmosphere;	A n/a B n/a C 41.1%
With copper(II) oxide; silicon; zinc at 325℃; for 24h; Reagent/catalyst; Inert atmosphere;	A n/a B n/a C 17.5%
With silicon; bronze; cesium chloride; copper(l) chloride at 200 - 360℃; for 8h; Product distribution / selectivity;

...Expand

: 34557-54-5
methane

A: 75-54-7
Dichloromethylsilane

B: 1066-35-9
dimethylmonochlorosilane

Conditions

Conditions	Yield
With Si-Cu; HCl In neat (no solvent) Si-Cu (10:2) and a mixt. of CH4 and HCl at 350°C;;	A 38.8% B 9.4%
With hydrogenchloride; copper; silicon In neat (no solvent) Si-Cu (10:2) and a mixt. of CH4 and HCl at 350°C;;	A 38.8% B 9.4%

: 13683-11-9
trimethylsilyl(dimethylchlorosilyl)methane

: 5357-38-0
bis(chlorodimethylsilyl)methane

: 4519-04-4
dichloro[(chlorodimethylsilyl)methyl]methylsilane

: 4519-03-3
bis(methyldichlorosilyl)methane

: 75-78-5
dimethylsilicon dichloride

A: 75-54-7
Dichloromethylsilane

B: 1066-35-9
dimethylmonochlorosilane

C: 992-94-9
methylsilane

D: 1111-74-6
dimethylsilane

E: 993-00-0
chloro-methyl-silane

Conditions

Conditions	Yield
With tetra-n-butylphosphonium chloride; lithium hydride In diethylene glycol dimethyl ether at -196 - 220℃; for 31h; Sealed tube;	A 7% B 34% C 9% D 5% E 7%

...Expand

: 75-79-6
Methyltrichlorosilane

A: 75-54-7
Dichloromethylsilane

B: 10026-04-7, 53609-55-5
tetrachlorosilane

C: 10025-78-2
trichlorosilane

Conditions

Conditions	Yield
With hydrogen; Rh/C at 700℃; Product distribution / selectivity;	A 5.5% B 28.2% C 22.9%

...Expand

: 75-79-6
Methyltrichlorosilane

: 75-78-5
dimethylsilicon dichloride

A: 75-54-7
Dichloromethylsilane

B: 1066-35-9
dimethylmonochlorosilane

C: 992-94-9
methylsilane

D: 993-00-0
chloro-methyl-silane

Conditions

Conditions	Yield
With Tetraethylene glycol dimethyl ether; tetra-n-butylphosphonium chloride; lithium hydride at 80 - 120℃; for 86.25h;	A 17% B 19% C 11% D 23%

...Expand

: 1450-14-2
1,1,1,2,2,2-hexamethyldisilane

: 1560-28-7
pentamethylchlorodisilane

: 4342-61-4
1,2-dichlorotetramethylsilane

: 13528-88-6
1,1,2-trichloro-1,2,2-trimethyldisilane

: 4518-98-3
1,1,2,2-tetrachloro-1,2-dimethyldisilane

: 4518-99-4
1,1-dichlorotetramethyldisilane

A: 75-54-7
Dichloromethylsilane

B: 75-77-4
chloro-trimethyl-silane

C: 75-79-6
Methyltrichlorosilane

D: 1066-35-9
dimethylmonochlorosilane

E: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With hydrogenchloride at 430 - 750℃; for 72h; Conversion of starting material;	A 4 %Chromat. B 12 %Chromat. C 7 %Chromat. D 6 %Chromat. E 21%

...Expand

: 75-79-6
Methyltrichlorosilane

A: 75-54-7
Dichloromethylsilane

B: 10026-04-7, 53609-55-5
tetrachlorosilane

Conditions

Conditions	Yield
With hydrogen; Rh/C at 600℃; Product distribution / selectivity;	A 6.4% B 5.1%

: 75-79-6
Methyltrichlorosilane

: 992-94-9
methylsilane

: 75-54-7
Dichloromethylsilane

Conditions

Conditions	Yield
With aluminium trichloride at 100℃;

: 75-79-6
Methyltrichlorosilane

: 992-94-9
methylsilane

A: 75-54-7
Dichloromethylsilane

B: 993-00-0
chloro-methyl-silane

Conditions

Conditions	Yield
With aluminium trichloride
With triphenylphosphine In diethylene glycol dimethyl ether at -196 - 120℃; Reagent/catalyst; Solvent; Temperature; Sealed tube;

...Expand

: 74-87-3
methylene chloride

: 75-54-7
Dichloromethylsilane

Conditions

Conditions	Yield
With copper; silicon at 300℃;
With hydrogenchloride; copper-doped silicon at 300℃;
With hydrogen; copper; silicon at 390℃;

: 992-94-9
methylsilane

: 75-54-7
Dichloromethylsilane

Conditions

Conditions	Yield
With hydrogenchloride; aluminium trichloride at 100℃;

: 676-58-4
methylmagnesium chloride

: 75-54-7
Dichloromethylsilane

Conditions

Conditions	Yield
With dibutyl ether; trichlorosilane

: 74-87-3
methylene chloride

A: 75-54-7
Dichloromethylsilane

B: 75-79-6
Methyltrichlorosilane

C: 1066-35-9
dimethylmonochlorosilane

Conditions

Conditions	Yield
With trichlorosilane; silicon; copper In chloroform at 324.9℃; under 760 Torr; Product distribution; variation of catalists;

...Expand

: 993-00-0
chloro-methyl-silane

A: 75-54-7
Dichloromethylsilane

B: 75-79-6
Methyltrichlorosilane

Conditions

Conditions	Yield
at 100℃; Equilibrium constant; Thermodynamic data; -ΔG;

: 1873-92-3
allyldichloromethylsilane

: 100-52-7
benzaldehyde

A: 75-54-7
Dichloromethylsilane

B: 292638-84-7
styrene

C: 75-79-6
Methyltrichlorosilane

D: 75-78-5
dimethylsilicon dichloride

E: 108-88-3
toluene

Conditions

Conditions	Yield
at 725℃; for 0.00277778h; Product distribution;

...Expand

: 117776-14-4
C33H75ClSi8

A: 75-54-7
Dichloromethylsilane

B: 117776-19-9
C32H72Cl2Si8

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate; trichlorosilane Yield given. Yields of byproduct given;

: 117917-85-8
C34H78Si8

A: 75-54-7
Dichloromethylsilane

B: 117776-19-9
C32H72Cl2Si8

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate; trichlorosilane Yield given. Yields of byproduct given;

: 74-87-3
methylene chloride

: 106-99-0
buta-1,3-diene

A: 872-46-8
1,1-Dichloro-2,5-dihydro-1H-silole

B: 75-54-7
Dichloromethylsilane

C: 24429-73-0
1-chloro-1-methyl-silacyclopent-3-ene

D: 75-79-6
Methyltrichlorosilane

E: 18163-65-0
but-2-enyl-dichloro-methyl-silane

F: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With silicon powder with ca. 4percent copper loading at 291.9℃; Product distribution; Mechanism;

...Expand

: 75-79-6
Methyltrichlorosilane

A: 75-54-7
Dichloromethylsilane

B: 1066-35-9
dimethylmonochlorosilane

C: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With aluminium trichloride; titanium(II) hydride at 300℃; for 20h; Product distribution; var. reaction partners and times; other silicon compounds;	A 0.001 mol B 0.002 mol C 0.02 mol

...Expand

: 74-87-3
methylene chloride

A: 75-54-7
Dichloromethylsilane

B: 75-77-4
chloro-trimethyl-silane

C: 75-79-6
Methyltrichlorosilane

D: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With copper(l) chloride; zinc(II) chloride; silicon at 399.9℃; under 720.06 Torr; Further byproducts given;

...Expand

: 74-87-3
methylene chloride

A: 75-54-7
Dichloromethylsilane

B: 75-79-6
Methyltrichlorosilane

C: 1066-35-9
dimethylmonochlorosilane

D: 75-78-5
dimethylsilicon dichloride

Conditions

Conditions	Yield
With copper(l) chloride; zinc(II) chloride; silicon at 399.9℃; under 720.06 Torr; Further byproducts given;

...Expand

: 34557-54-5
methane

: 75-54-7
Dichloromethylsilane

Conditions

Conditions	Yield
With trichlorosilane at 647.9℃; under 8.5 Torr; Product distribution; Rate constant; Mechanism; other pressures;

: 75-54-7
Dichloromethylsilane

: 592-41-6
1-hexene

: 14799-94-1
n-hexylmethyldichlorosilane

Conditions

Conditions	Yield
at 90℃; for 5h; Inert atmosphere;	100%
at 90℃; for 5h; Inert atmosphere;	100%
Stage #1: 1-hexene With diethylenetriaminepentaacetic acid (DTPA)-functionalized silica supported Pt at 60℃; for 0.5h; Stage #2: Dichloromethylsilane at 60℃; for 4h; Catalytic behavior; Temperature; Reagent/catalyst;	99.6%

: 75-54-7
Dichloromethylsilane

: 592-76-7
1-Heptene

: 18395-93-2
dichloro-heptyl-methyl-silane

Conditions

Conditions	Yield
Pt-thiourea Product distribution; Ambient temperature; various catalysts;	100%
Pt-thiourea	100%
Stage #1: 1-Heptene With diethylenetriaminepentaacetic acid (DTPA)-functionalized silica supported Pt at 60℃; for 0.5h; Stage #2: Dichloromethylsilane at 60℃; for 4h; Reagent/catalyst;	98.9%

: 75-54-7
Dichloromethylsilane

: 594-19-4
tert.-butyl lithium

: 41879-33-8
tert-butylmethylsilyl chloride

Conditions

Conditions	Yield
In hexane at -5℃;	100%
In pentane at 0 - 20℃; Inert atmosphere;	90%
In pentane at -30 - 20℃; for 24h; Inert atmosphere;	87%
In diethyl ether
Inert atmosphere;

: 75-54-7
Dichloromethylsilane

: 173094-49-0
(4S,5S)-4-<(allyloxy)methyl>-2-methyl-5-phenyloxazol-2-ine

: (4S,5S)-4-<<3-(dichloromethylsilyl)propyloxy>methyl>-2-methyl-5-phenyloxazolin-2-ine

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate; isopropyl alcohol for 5h; Heating;	100%

: 75-54-7
Dichloromethylsilane

: 1112-55-6
tetravinylsilane

: 67776-45-8
tetra-2-(dichloromethylsilyl)ethylsilane

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In tetrahydrofuran at 20℃;	100%
bis(tetrabutylammonium) hexachloroplatinate(IV) In ethanol	97%
platinum Addition;

: 75-54-7
Dichloromethylsilane

: 18269-92-6
bis-allyloxy-dimethyl-silane

: 1-(dichloro-methyl-silanyl)-3-{[3-(dichloro-methyl-silanyl)-propoxy]-dimethyl-silanyloxy}-propane

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In diethyl ether at 25℃; for 1.25h;	100%

: 75-54-7
Dichloromethylsilane

: 17984-91-7
tris-allyloxy-methyl-silane

: 394737-64-5
C13H30Cl6O3Si4

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In diethyl ether at 25℃; for 3.25h;	100%

: 75-54-7
Dichloromethylsilane

: 394737-65-6
C31H60O9Si4

: C37H84Cl12O9Si10

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In diethyl ether at 25℃; for 3.25h;	100%

: 75-54-7
Dichloromethylsilane

: C73H144O21Si10

: C85H192Cl24O21Si22

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In diethyl ether at 25℃; for 3.25h;	100%

: 75-54-7
Dichloromethylsilane

: C106H212O30Si15

: C122H276Cl32O30Si31

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In diethyl ether at 25℃; for 1.25h;	100%

: 75-54-7
Dichloromethylsilane

: 394737-60-1
3-[allyloxy-(3-{[3-(bis-allyloxy-methyl-silanyl)-propoxy]-dimethyl-silanyloxy}-propyl)-methyl-silanyloxy]-propene

: 1-{bis-[3-(dichloro-methyl-silanyl)-propoxy]-methyl-silanyl}-3-[(3-{bis-[3-(dichloro-methyl-silanyl)-propoxy]-methyl-silanyl}-propoxy)-dimethyl-silanyloxy]-propane

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate at 25℃; for 1.25h;	100%

: 75-54-7
Dichloromethylsilane

: 3-{allyloxy-[3-([3-(bis-allyloxy-methyl-silanyl)-propoxy]-{3-[(3-{bis-[3-(bis-allyloxy-methyl-silanyl)-propoxy]-methyl-silanyl}-propoxy)-dimethyl-silanyloxy]-propyl}-methyl-silanyloxy)-propyl]-methyl-silanyloxy}-propene

: C58H132Cl16O14Si15

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate at 25℃; for 1.25h;	100%

: 75-54-7
Dichloromethylsilane

: 151626-10-7
tetrakis[2-(trivinylsilyl)ethyl]silane

: C44H100Cl24Si17

Conditions

Conditions	Yield
bis(tetrabutylammonium) hexachloroplatinate(IV) In ethanol	100%

: {tris-[3-(diallyl-methyl-silanyl)-propyl]-silanyl}-benzene

: 75-54-7
Dichloromethylsilane

: [tris-(3-{bis-[3-(dichloro-methyl-silanyl)-propyl]-methyl-silanyl}-propyl)-silanyl]-benzene

Conditions

Conditions	Yield
chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex In benzene at 55℃; for 16h;	100%

: [tris-(3-{bis-[3-(diallyl-methyl-silanyl)-propyl]-methyl-silanyl}-propyl)-silanyl]-benzene

: 75-54-7
Dichloromethylsilane

: C90H194Cl24Si22

Conditions

Conditions	Yield
chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex In benzene at 55℃; for 16h;	100%

: 75-54-7
Dichloromethylsilane

: 2633-57-0
tri(allyl)phenylsilane

: 231936-31-5
{tris-[3-(dichloro-methyl-silanyl)-propyl]-silanyl}-benzene

Conditions

Conditions	Yield
chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex In benzene at 55℃; for 16h;	100%

: 75-54-7
Dichloromethylsilane

: tris[(ethynyl)dimethylsilyl](trimethylsilyl)methane

: tris({2-[dichloro(methyl)silyl]ethenyl}dimethylsilyl)(trimethylsilyl)methane

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In 5,5-dimethyl-1,3-cyclohexadiene; diethyl ether at 40℃; for 72h; regioselective reaction;	100%

: 75-54-7
Dichloromethylsilane

: tris[dimethyl(vinyl)silyl](trimethylsilyl)methane

: tris({2-[dichloro(methyl)silyl]ethyl}dimethylsilyl)(trimethylsilyl)methane

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In 5,5-dimethyl-1,3-cyclohexadiene; diethyl ether at 40℃; for 72h; regioselective reaction;	100%

: 75-54-7
Dichloromethylsilane

: 992-94-9
methylsilane

Conditions

Conditions	Yield
With lithium aluminium tetrahydride; calcium hydride In diethylene glycol dimethyl ether at 50℃; for 7h; Inert atmosphere;	100%

: 75-54-7
Dichloromethylsilane

: 74-86-2
acetylene

: 65899-10-7
(E)-1,2-bis[dichloro(methyl)silyl]ethene

Conditions

Conditions	Yield
PtCl2*(III)2 In octane at 40 - 45℃; for 8h; Product distribution; examination of regio- and stereo-selectivity of products by catalytic activity;	99%

: 75-54-7
Dichloromethylsilane

: 2,4,6,8-tetramethyl-2,4,6,8-tetrakis-[2-(methyl-bis-prop-2-ynyloxy-silanyl)-ethyl]-[1,3,5,7,2,4,6,8]tetroxatetrasilocane

: C48H96Cl16O12Si16

Conditions

Conditions	Yield
platinum on activated charcoal In diethyl ether for 2.5h; Addition; Heating;	99%

: 75-54-7
Dichloromethylsilane

: C96H144O28Si16

: C112H208Cl32O28Si32

Conditions

Conditions	Yield
platinum on activated charcoal In diethyl ether for 2.5h; Addition; Heating;	99%

: 75-54-7
Dichloromethylsilane

: 1675-57-6
diethynyldiphenylsilane

: bis((dichloro(methyl)silyl)vinyl)diphenylsilane

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 20℃; for 2h;	99%

: 75-54-7
Dichloromethylsilane

: 123229-38-9
(3-chloropropyl)methyldivinylsilane

: C12H27Cl5Si3

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In hexane at 60℃; for 4h; Inert atmosphere;	99%

: 75-54-7
Dichloromethylsilane

: 7567-63-7
1,3,5-Triethynylbenzene

: 1,3,5-tris((dichloro(methyl)silyl)vinyl)benzene

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In 5,5-dimethyl-1,3-cyclohexadiene at 20℃; for 48h;	99%

: 75-54-7
Dichloromethylsilane

: 692-49-9
1,1,1,4,4,4-hexafluoro-2(Z)-butene

: dichloro(1,1,1,4,4,4-hexafluorobut-2-yl)(methyl)silane

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride In neat (no solvent) at 120℃; for 10h;	99%

: 75-54-7
Dichloromethylsilane

: 292638-84-7
styrene

: 772-65-6
(2-phenylethyl)methyldichlorosilane

Conditions

Conditions	Yield
Stage #1: styrene With Pt loaded on nitrolotriacetic acid-functionalized silica gel at 60℃; for 0.5h; Stage #2: Dichloromethylsilane at 60℃; for 4h; Reagent/catalyst;	98.8%
With tetrakis(triphenylphosphine)platinum at 90 - 130℃; for 2h; Reagent/catalyst; Large scale; regiospecific reaction;	93%
With N-heterocyclic carbene fuctionalized with methyl(trimethylsilane) and methoxypolyethylene glycol Pt(II) complex at 90℃; for 10h;	93.7%

: 75-54-7
Dichloromethylsilane

: 111-66-0
oct-1-ene

: 14799-93-0
dichloro-methyl-octyl-silane

Conditions

Conditions	Yield
Stage #1: oct-1-ene With diethylenetriaminepentaacetic acid (DTPA)-functionalized silica supported Pt at 60℃; for 0.5h; Stage #2: Dichloromethylsilane at 60℃; for 4h; Reagent/catalyst;	98.6%
at 300℃;
tetrakis(triphenylphosphine) palladium(0) at 120℃; for 6h;