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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

1-Hexene

Cas:592-41-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Jinan Finer Chemical Co., Ltd

Product description: Product name 1-Hexene CAS number 592-41-6 Assay ≥99% Appearance Colorless liquid Capacity 200mt/year Application Used in the manufacture of perfumes, dye

1-Hexene

Cas:592-41-6

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

1-Hexene CAS NO.592-41-6

Cas:592-41-6

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Manufacturers

inquiry

Hefei TNJ chemical industry co.,ltd

1. Quality Our products meet MSDS safe standard and we have ISO and other certificate so yan can get high quality products from our company. 2. Price We are the company which is the joint of trade and industry so we cao provide the competiti

Buy 1-Hexene CAS 592-41-6

Cas:592-41-6

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Hex-1-ene

Cas:592-41-6

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1-Hexene

Cas:592-41-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 1-Hexene Synonyms: 1-Hexene [Standard Material];N-HEXENE;Hexane-1-ene;1-Hexene,97%;1-Hexene [Standard Material for GC];1-Hexene, AcroSeal, 99%;1-Hexene, 97% 100ML;1-Hexene, 97% 1LT CAS: 592-41-6 MF: C6H12 MW: 84.16

592-41-6 1-Hexene

Cas:592-41-6

Min.Order:1 Kilogram

FOB Price: $8900.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

1-HexeneCAS NO.: 592-41-6

Cas:592-41-6

Min.Order:1 Gram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

Advantages: Hubei XinRunde Chemical Co., Ltd is a renowned pharmaceutical manufacturer. We can offer high quality products at competitive price in quick delivery with 100% custom pass guaranteed. Never stop striving to offer our best s

99%min 1-Hexene Manufacturer CAS:592-41-6

Cas:592-41-6

Min.Order:10 Gram

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-Hexene

Cas:592-41-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1-Hexene

Cas:592-41-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1-Hexene manufacturer

Cas:592-41-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermed

1-Hexene

Cas:592-41-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity 1-Hexene

Cas:592-41-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1-Hexene

Cas:592-41-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

manufacture Application:The refence standard products, for lab use, also we could produce bigger quantity on yr requirement.

1-hexene

Cas:592-41-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1-Hexene

Cas:592-41-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 592-41-6 with competitive price

Cas:592-41-6

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1-Hexene

Cas:592-41-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Hexene-1

Cas:592-41-6

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl

1-Hexene

Cas:592-41-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China

1-Hexene, 98% 592-41-6

Cas:592-41-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

1-Hexene//cas 592-41-6Appearance:Solid powder Storage:Sealed,light and oxygen resistant Package:Package: In double layer bags of 25 Kg or 50 Kg or 1000 Kg net. Application:Food Additives Transportation:By express (Door to door) such as FEDEX, DHL, EM

1-Hexene//cas 592-41-6

Cas:592-41-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

1-Hexene

Cas:592-41-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beantown Chemical

in stock Application:592-41-6

1-Hexene, 98%

Cas:592-41-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#592-41-6;CAT#A832221

Cas:592-41-6

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

1-Hexene Basic information Product Name: 1-Hexene Synonyms:

592-41-6 C6H12 1-Hexene

Cas:592-41-6

Min.Order:100 Gram

Negotiable

Type:Trading Company

inquiry

Shaanxi Mingqi Chemical Co., Ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Our advantages:1, High quality with competitive price:1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%3) We are manufacturer

1-Hexene factory

Cas:592-41-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HK Vast Medicinal Chemistry Int'l Group Limited

EBK sale CAS: 592-41-6 Formula: C17H27N02 Molec

EBK BMDP EU crystal

Cas:592-41-6

Min.Order:5 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Harmonious Natural Bio-Technology Co., Ltd.

Before-Sale Service:---Any inquiries will be replied within 12 hours.---Golden Manufactory under?ISO/GMP?with?large stock.---Dedication to quality,We?have?strict?quality?control?system.?---OEM/ODM Available.---Sample is available for your evaluation

1-Hexene

Cas:592-41-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

ethene
74-85-1

ethene

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With trimethylamine-N-oxide; [N(4-C6H4Br)3][B(C6F5)4]; triethylaluminum; [Cr(CO)4(2-C6H4(MeO))2PN(Me)P(2-C6H4(MeO))2] In toluene at 60℃; under 30002.4 Torr; for 1h;100%
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;99%
In chlorobenzene at 60℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;99%
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With triphenylphosphine at 200℃; for 6h;100%
With carbon monoxide; C29H32IrN5O; bis(trifluoromethane)sulfonimide lithium In benzene-d6 at 80℃; under 7500.75 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Time; Schlenk technique; chemoselective reaction;98%
With zirconium(IV) chloride; sodium iodide In acetonitrile for 0.0166667h; Heating;88%
1,2-dibromohexane
624-20-4

1,2-dibromohexane

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; ethylmagnesium bromide In tetrahydrofuran at 0℃;100%
With sodium tetrahydroborate; nickel dichloride In tetrahydrofuran at 20℃; for 1h;80%
With tetramethylammonium perchlorate In N,N-dimethyl-formamide Electrolysis;
trimethylstannyl sodium
16643-09-7

trimethylstannyl sodium

6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

(CH3)3Sn((CH2)4CH)

(CH3)3Sn((CH2)4CH)

C

(CH3)3Sn(CH2C5H9)
73017-75-1

(CH3)3Sn(CH2C5H9)

Conditions
ConditionsYield
With tert-butylamine In tetrahydrofuran react. at 0°C under Ar;A 0%
B 100%
C 0%
With DPCH In tetrahydrofuran react. at 0°C under Ar;A <1
B 98%
C 0%
In tetrahydrofuran react. at 0°C under Ar;A 0%
B 98%
C 0%
In tetrahydrofuran; benzene react. at 0°C under Ar;A <1
B 85%
C 10%
With DCPH In tetrahydrofuran; benzene react. at 0°C under Ar;A 15%
B 79%
C 1.5%
hex-1-yne
693-02-7

hex-1-yne

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With hydrogen; N,N′-bis(salicylidene)-ethylenediamino‑palladium In pyridine for 0.35h;98%
With hydrogen In methanol at 20℃; under 760.051 Torr; for 4.5h; Green chemistry;94%
With hydrogen In methanol under 760.051 Torr; for 5.5h;93%
trimethylstannane
1631-73-8

trimethylstannane

6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

lithium diisopropyl amide
4111-54-0

lithium diisopropyl amide

A

1-hexene
592-41-6

1-hexene

B

methyl-cyclopentane
96-37-7

methyl-cyclopentane

C

hexamethyldistannane
661-69-8

hexamethyldistannane

Conditions
ConditionsYield
In diethyl ether; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 2 equiv. of Me3SnH in Et2O at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;A 77%
B 16%
C 97%
In diethyl ether; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 1 equiv. of Me3SnH in Et2O at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;A 41%
B 18%
C 86%
In hexane; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 2 equiv. of Me3SnH in hexane at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;A 76%
B 18%
C 27%
In hexane; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 1 equiv. of Me3SnH in hexane at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC;A 45%
B 32%
C 48%
ethene
74-85-1

ethene

A

1-hexene
592-41-6

1-hexene

B

polyethylene

polyethylene

Conditions
ConditionsYield
In chlorobenzene at 60℃; for 4h; Product distribution / selectivity; Autoclave;A 96%
B n/a
In chlorobenzene at 60℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;A 91%
B n/a
methylaluminoxane; tantalum pentachloride In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;A 84%
B n/a
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;A 84%
B n/a
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity;A 26%
B n/a
6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

methyl-cyclopentane
96-37-7

methyl-cyclopentane

C

cyclohexane
110-82-7

cyclohexane

Conditions
ConditionsYield
With tris-(trimethylsilyl)silane; 2,2'-azobis(isobutyronitrile) at 70℃;A 4.1%
B 93%
C 2%
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) at 70℃;A 15%
B 83%
C 1.2%
With 9-borabicyclo[3.3.1]nonane dimer; tribenzyltin hydride In toluene at 0℃; Product distribution; variation of reagent;A 29%
B 68%
C 3%
ethene
74-85-1

ethene

A

1-hexene
592-41-6

1-hexene

B

1-Decene
872-05-9

1-Decene

Conditions
ConditionsYield
Cl(1-)*NPr4(1+) at 50℃; under 22502.3 Torr; for 1h;A 91.7%
B 5.5%
modified methylalumoxane; C28H24Cl2FeN2S In n-heptane at 30 - 52℃; under 21446.5 Torr; for 0.5h; Product distribution / selectivity;
With [η5-(3-SiMe3)C5H3CMe2-3,5-Me2C6H3]Ti(TEA) In toluene at 20℃; under 7500.75 Torr; for 0.25h; Pressure; Reagent/catalyst; Temperature; Inert atmosphere;
hex-1-yne
693-02-7

hex-1-yne

A

1-hexene
592-41-6

1-hexene

B

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics;A 91%
B n/a
With hydrogen; platinum In ethanol at 30℃; under 15200 Torr; Product distribution; 80 atm;A 41.7%
B 57.3%
With hydrogen; Ni(C17H35COO)2; triethylaluminum In toluene at 40℃; Kinetics; Object of study: selectivity;
ethene
74-85-1

ethene

A

1-hexene
592-41-6

1-hexene

B

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
With CrCl2(tetrahydrofuran)2; N,N'-bis(diphenylphosphino)-N,N'-dimethylpropane-1,3-diamine In methyl cyclohexane at 80℃; under 30003 Torr; for 0.5h; Inert atmosphere;A 9%
B 91%
bis(2-(decylthio)ethyl)amine; chromium chloride In toluene at 90℃; under 33753.4 Torr; for 0.502778 - 0.527778h; Product distribution / selectivity;A 90.85%
B 0.5%
chromium(III)2-ethylhexanoate; trimethylaluminum; N-[bis(2-methoxyphenyl)phosphino]-P,P-bis(2-methoxyphenyl)-N-methylphosphinous amide In methyl cyclohexane; toluene at 60℃; under 36003.6 - 37503.8 Torr; for 0.175h; Product distribution / selectivity;A 89.7%
B 8.5%
ethene
74-85-1

ethene

A

1-butylene
106-98-9

1-butylene

B

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
[Ph2PC6H4C(OB(C6F5)3)O-κ2P,O](η3-CH2CMeCH2) In toluene at 0℃; under 2280.15 Torr; for 1h; Product distribution; Further Variations:; Temperatures; Pressures; oligomerization;A 90%
B 6%
With tetraphenyl phosphonium chloride; chromium at 80℃; under 37503.8 Torr; for 1h; Product distribution / selectivity;A 7.5%
B 88.3%
With [6,6'-diphenyl-[2,2']-bipyridinyl]NiBr2; triethyl aluminum sesquichloride In toluene Catalytic behavior; Reagent/catalyst; Inert atmosphere; Schlenk technique;A 88%
B 9%
di-n-hexyl diselenide
52056-08-3

di-n-hexyl diselenide

A

1-hexene
592-41-6

1-hexene

B

dodecane
112-40-3

dodecane

Conditions
ConditionsYield
at 600℃; under 20 Torr; for 0.0333333h;A 90%
B 7%
1-(Dichloroamino)-n-hexane
64851-26-9

1-(Dichloroamino)-n-hexane

A

1-hexene
592-41-6

1-hexene

B

hexanenitrile
628-73-9

hexanenitrile

Conditions
ConditionsYield
A 7%
B 88%
2-(but-3-en-1-yl)-2-methyl-1,3-dioxolane
20449-21-2

2-(but-3-en-1-yl)-2-methyl-1,3-dioxolane

5-decene
19689-19-1

5-decene

A

1-hexene
592-41-6

1-hexene

B

2-Methyl-2-((E)-oct-3-enyl)-[1,3]dioxolane

2-Methyl-2-((E)-oct-3-enyl)-[1,3]dioxolane

Conditions
ConditionsYield
aluminum oxide; tetramethylstannane; rhenium(VII) oxide In chlorobenzene at 25℃; for 3h; Yields of byproduct given;A n/a
B 87%
n-hexan-2-ol
626-93-7

n-hexan-2-ol

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With hydrogen bromide; tetrabutyl phosphonium bromide at 200℃; for 0.25h; Menshutkin Reaction; Inert atmosphere;86%
{bis(triphenylphosphine)nitrogen}{cis-HW(CO)4P(OMe)3}
82963-28-8

{bis(triphenylphosphine)nitrogen}{cis-HW(CO)4P(OMe)3}

6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

BrW(CO)4P(OCH3)3(1-)
100504-27-6

BrW(CO)4P(OCH3)3(1-)

Conditions
ConditionsYield
In tetrahydrofuranA 85%
B n/a
1-hexene-3-one
1629-60-3

1-hexene-3-one

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With n-butylsilane; tris(pentafluorophenyl)borate In dichloromethane84%
ethene
74-85-1

ethene

A

homopolymer of ethylene

homopolymer of ethylene

B

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
methylaluminoxane; C33H29Cl3CrNP2 at 24 - 30℃; under 2250.23 - 22502.3 Torr; for 1 - 2h; Product distribution / selectivity;A 3%
B 83%
methylaluminoxane; C23H24Cl3CrNPS at 24 - 30℃; under 22502.3 Torr; for 1h; Product distribution / selectivity;A 18%
B 82%
[CrCl2Me(tetrahydrofuran)3]; C27H26N2; polyamethylaluminoxane-IP; trimethylaluminum In toluene at 50℃; under 7757.43 Torr; for 1h; Product distribution / selectivity;
n-decyl acetate
112-17-4

n-decyl acetate

A

1-hexene
592-41-6

1-hexene

B

1-Decene
872-05-9

1-Decene

D

1-Butyl-2-methylcyclopropane
2511-92-4

1-Butyl-2-methylcyclopropane

E

1-Methyl-2-pentylcyclopropane
41977-37-1

1-Methyl-2-pentylcyclopropane

F

cyclopentene
142-29-0

cyclopentene

Conditions
ConditionsYield
at 495℃; for 0.00727778h; Rate constant; Product distribution; various temp., also in toluene, also with 14C-labelled ester;A 1.03%
B 81.3%
C 1.91%
D 1.2%
E 0.497%
F 0.45%
ethene
74-85-1

ethene

A

homopolymer of ethylene

homopolymer of ethylene

B

1-hexene
592-41-6

1-hexene

C

oct-1-ene
111-66-0

oct-1-ene

Conditions
ConditionsYield
methylaluminoxane; C64H58Cl6Cr2N2O2P4 In dodecane; toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity;A 80%
B n/a
C n/a
methylaluminoxane, aged; C54H54Cl6Cr2N2P4 In dodecane; toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity;A 50%
B n/a
C n/a
methylaluminoxane; C64H58Cl6Cr2N2O2P4 In toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity;A 20%
B n/a
C n/a
1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

A

1-hexene
592-41-6

1-hexene

B

formic acid 1-bromomethylpentyl ester
39741-97-4

formic acid 1-bromomethylpentyl ester

Conditions
ConditionsYield
With bromine; triphenylphosphine at 0℃; for 0.583333h;A n/a
B 78%
trimethylstannane
1631-73-8

trimethylstannane

6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

methyl-cyclopentane
96-37-7

methyl-cyclopentane

C

n-butyltrimethyltin
1527-99-7

n-butyltrimethyltin

Conditions
ConditionsYield
With n-butyllithium In octane TMTH (1.00 mmol) and 6-bromo-1-hexene (1.08 mmol) in octane cooled to 0°C under Ar, n-BuLi (1.00 mmol, in octane) added via syringe, stirred for 15 min, quenched with water; analyzed by GC;A 56%
B 30%
C 78%
triethylbenzylammonium ethanolate
95903-96-1

triethylbenzylammonium ethanolate

1-Iodohexane
638-45-9

1-Iodohexane

A

1-hexene
592-41-6

1-hexene

B

ethyl n-hexyl ether
5756-43-4

ethyl n-hexyl ether

Conditions
ConditionsYield
at 20 - 25℃; for 1h; Product distribution; other halogenoalkanes, other alkoxides and alcoholates; var. reaction conditions;A 4.8%
B 75%
at 20 - 25℃; for 1h;A 4.8%
B 75%
1-Iodohexane
638-45-9

1-Iodohexane

A

1-hexene
592-41-6

1-hexene

B

ethyl n-hexyl ether
5756-43-4

ethyl n-hexyl ether

Conditions
ConditionsYield
With triethylbenzylammonium ethanolate at 20 - 25℃; for 1h;A 4.8%
B 75%
1 ,6-dibromohexane
629-03-8

1 ,6-dibromohexane

A

1-hexene
592-41-6

1-hexene

B

hexane
110-54-3

hexane

C

1,5-Hexadien
592-42-7

1,5-Hexadien

D

hexan-1-ol
111-27-3

hexan-1-ol

Conditions
ConditionsYield
With tetramethylammonium perchlorate In 2,2,2-trifluoroethanol; N,N-dimethyl-formamide Electrolysis;A 4%
B 75%
C 5%
D 18%
1 ,6-dibromohexane
629-03-8

1 ,6-dibromohexane

1-hexene
592-41-6

1-hexene

Conditions
ConditionsYield
With magnesium at 600℃;72%
trimethylstannane
1631-73-8

trimethylstannane

6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

methyl-cyclopentane
96-37-7

methyl-cyclopentane

Conditions
ConditionsYield
In diethyl ether Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 2 equiv. of Me3SnH in Et2O under Ar; analyzed by GLPC;A 71%
B 20%
In hexane Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 1 equiv. of Me3SnH in hexane under Ar; analyzed by GLPC;A 51%
B 46%
In diethyl ether Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 1 equiv. of Me3SnH in Et2O under Ar; analyzed by GLPC;A 51%
B 45%
2-trifluoromethylsulfonyloxy-1-hexene
37555-23-0

2-trifluoromethylsulfonyloxy-1-hexene

carbon dioxide
124-38-9

carbon dioxide

A

1-hexene
592-41-6

1-hexene

B

2-butylacrylic acid
4380-88-5

2-butylacrylic acid

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide at 20℃; under 760 Torr; electrolyses, carbon cathode, Mg anode, E=-2.2 V;A 8%
B 70%
With nBuNBF4; bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 20℃; electrochemical reaction;A 8%
B 70%
6-Bromo-1-hexene
2695-47-8

6-Bromo-1-hexene

A

1-hexene
592-41-6

1-hexene

B

1,11-dodecadiene
5876-87-9

1,11-dodecadiene

C

methyl-cyclopentane
96-37-7

methyl-cyclopentane

Conditions
ConditionsYield
With potassium In ammonia; tert-butyl alcohol Product distribution; Mechanism; Heating;A 63.6%
B 20.7%
C 0.7%
With potassium In ammonia; tert-butyl alcohol Heating;A 63.6%
B 20.7%
C 0.7%
Dichloromethylsilane
75-54-7

Dichloromethylsilane

1-hexene
592-41-6

1-hexene

n-hexylmethyldichlorosilane
14799-94-1

n-hexylmethyldichlorosilane

Conditions
ConditionsYield
at 90℃; for 5h; Inert atmosphere;100%
at 90℃; for 5h; Inert atmosphere;100%
Stage #1: 1-hexene With diethylenetriaminepentaacetic acid (DTPA)-functionalized silica supported Pt at 60℃; for 0.5h;
Stage #2: Dichloromethylsilane at 60℃; for 4h; Catalytic behavior; Temperature; Reagent/catalyst;
99.6%
1-hexene
592-41-6

1-hexene

1,2-Epoxyhexane
1436-34-6

1,2-Epoxyhexane

Conditions
ConditionsYield
With C20H24CoN2O6(1+)*NO3(1-)*H2O; oxygen; isobutyraldehyde In acetonitrile at 60℃; under 760.051 Torr; for 8h; Time; chemoselective reaction;100%
With dihydrogen peroxide; (Bu4N)3K[γ-SiW10O36(PhPO)2] In water at 65℃; for 2h; microwave irradiation;99%
With tert.-butylhydroperoxide In acetonitrile at 65 - 68℃; for 24h;99%
1-hexene
592-41-6

1-hexene

1,2-dibromohexane
624-20-4

1,2-dibromohexane

Conditions
ConditionsYield
With bromine In chloroform at 0℃; for 0.166667h;100%
With bromine In chloroform at 0 - 5℃;93%
With propane 3-bromo-1-(triphenylphosphonium) tribromide In dichloromethane at 20℃; for 0.5h;92%
1-hexene
592-41-6

1-hexene

Hexane-1,2-diol
6920-22-5

Hexane-1,2-diol

Conditions
ConditionsYield
With poly{[CuBa(pyridine-2,5-dicarboxylate)2(H2O)5]*H2O}; dihydrogen peroxide In acetonitrile at 60℃; for 6h; Catalytic behavior; Reagent/catalyst;100%
With N-methyl-2-indolinone; fluorous OsO4 In water; acetone; tert-butyl alcohol at 20℃; for 36h;97%
With N-methyl-2-indolinone; polysulfone microencapsulated OsO4 In water; acetone; acetonitrile at 20℃; for 0.416667h;96%
1-hexene
592-41-6

1-hexene

hexane
110-54-3

hexane

Conditions
ConditionsYield
With hydrogen; In tetrahydrofuran at 90℃; under 5250.4 Torr; for 0.166667h; Product distribution; other olefins, other catalysts; var. temp., solv., press., and time;100%
With hydrogen; (iPrPDI)Fe(N2)2 at 20℃; under 3040 Torr; for 19h;100%
With Wilkinson's catalyst; hydrogen In dichloromethane-d2 at 45℃; under 3000.3 Torr; for 6h; Concentration; Reagent/catalyst; Solvent; Temperature; Time; Sealed tube; Inert atmosphere;100%
1-hexene
592-41-6

1-hexene

n-hexan-2-one
591-78-6

n-hexan-2-one

Conditions
ConditionsYield
With water; palladium dichloride In N,N-dimethyl-formamide under 1300 Torr; for 5h; Rate constant; Mechanism; oxidation of different olefines by Wacker process; variation of solvent: formamide, tensioactive and cotensioactive component in microemulsions; reaction time;100%
With water; palladium dichloride In various solvent(s) under 1300 Torr; for 0.833333h; closed reactor, in microemulsion with formamide;100%
With Pd(II)(15-crown-5-phen)Cl2; dinitrogen monoxide In N,N-dimethyl acetamide; water at 150℃; under 2250.23 Torr; for 18h;99%
1-hexene
592-41-6

1-hexene

hexyltrichlorosilane
928-65-4

hexyltrichlorosilane

Conditions
ConditionsYield
With trichlorosilane at 90℃; for 5h; Inert atmosphere;100%
With trichlorosilane at 90℃; for 5h; Inert atmosphere;100%
With trichlorosilane; nickel In tetrahydrofuran at 20 - 25℃;94%
1-hexene
592-41-6

1-hexene

2-hexene
592-43-8

2-hexene

Conditions
ConditionsYield
With C10H19B11Cl11PPd In dichloromethane-d2 at 25℃; for 0.0833333h; Inert atmosphere;100%
With aluminum (III) chloride; [(2,6-iPrC6H3NC(Me)C(Me)N-2,6-iPrC6H3)Pd(CH3)(Cl)]; acetonitrile In dichloromethane at 25℃; for 18h; Reagent/catalyst; Darkness; Inert atmosphere;81%
With platinum on activated charcoal; carbon dioxide at 300 - 305℃;
triethylsilane
617-86-7

triethylsilane

1-hexene
592-41-6

1-hexene

n-hexyltriethylsilane
13810-04-3

n-hexyltriethylsilane

Conditions
ConditionsYield
at 90℃; for 5h; Inert atmosphere;100%
at 90℃; for 5h; Inert atmosphere;100%
With C26H31F5NZn(1+)*C24BF20(1-) In dichloromethane-d2 at 20℃; for 28h; Reagent/catalyst; Inert atmosphere; Glovebox;100%
1-hexene
592-41-6

1-hexene

dimethylmonochlorosilane
1066-35-9

dimethylmonochlorosilane

dimethylhexylsilyl chloride
3634-59-1

dimethylhexylsilyl chloride

Conditions
ConditionsYield
at 90℃; for 5h; Inert atmosphere;100%
With platinum on carbon nanotubes In neat (no solvent) at 20℃; for 24h;97%
dihydrogen hexachloroplatinate In diethyl ether for 15h; Heating;80%
1-hexene
592-41-6

1-hexene

trimethoxysilane
2487-90-3

trimethoxysilane

n-hexyltrimethoxysilane
3069-19-0

n-hexyltrimethoxysilane

Conditions
ConditionsYield
at 90℃; for 5h; Inert atmosphere;100%
at 90℃; for 5h; Inert atmosphere;100%
With dichlorobis-(ethylene)-μ,μ'-dichloroplatinum(II)
1-hexene
592-41-6

1-hexene

Triethoxysilane
998-30-1

Triethoxysilane

hexyltriethoxysilane
18166-37-5

hexyltriethoxysilane

Conditions
ConditionsYield
at 90℃; for 5h; Inert atmosphere;100%
at 90℃; for 5h; Inert atmosphere;100%
With platinum on carbon nanotubes In neat (no solvent) at 20℃; for 24h;98%
1-hexene
592-41-6

1-hexene

indantrione
938-24-9

indantrione

2-((E)-Hex-2-enyl)-2-hydroxy-indan-1,3-dione
145046-47-5

2-((E)-Hex-2-enyl)-2-hydroxy-indan-1,3-dione

Conditions
ConditionsYield
In chloroform at 80℃; for 4h;100%
1-hexene
592-41-6

1-hexene

triphenylmethylacetonitrile oxide
13412-55-0

triphenylmethylacetonitrile oxide

5-butyl-3-(triphenylmethyl)-2-isoxazoline
123622-72-0

5-butyl-3-(triphenylmethyl)-2-isoxazoline

Conditions
ConditionsYield
In benzene at 85℃; for 48h;100%
1-hexene
592-41-6

1-hexene

sodium 4-methylbenzenesulfinate
824-79-3

sodium 4-methylbenzenesulfinate

2-iodo-1-tosylhexane
71963-96-7

2-iodo-1-tosylhexane

Conditions
ConditionsYield
With iodine In water; ethyl acetate at 20℃; for 1.33333h; iodosulfonization;100%
With iodine In water; ethyl acetate for 2h; Ambient temperature;
1-hexene
592-41-6

1-hexene

α-bromopropionyl 2-oxazolidinone amide
114341-77-4

α-bromopropionyl 2-oxazolidinone amide

4-bromo-2-methyloctanoyl 2-oxazolidinone amide

4-bromo-2-methyloctanoyl 2-oxazolidinone amide

Conditions
ConditionsYield
With triethyl borane; scandium tris(trifluoromethanesulfonate) In hexane; 1,2-dichloro-ethane at 25℃; for 1h;100%
1-hexene
592-41-6

1-hexene

3-bromoacetyl-1,3-oxazolidin-2-one
141353-28-8

3-bromoacetyl-1,3-oxazolidin-2-one

4-bromooctanoyl 2-oxazolidinone amide
224804-26-6

4-bromooctanoyl 2-oxazolidinone amide

Conditions
ConditionsYield
With triethyl borane; ytterbium(III) triflate In hexane; 1,2-dichloro-ethane at 25℃; for 1h;100%
With air; triethyl borane In 2,2,2-trifluoroethanol at 25℃; for 1.5h;90%
With triethyl borane; oxygen; ytterbium(III) triflate In hexane; 1,2-dichloro-ethane at 20℃; for 0.5h;83%
1-hexene
592-41-6

1-hexene

(S)-4-Benzyl-3-((R)-2-bromo-propionyl)-oxazolidin-2-one
114341-80-9

(S)-4-Benzyl-3-((R)-2-bromo-propionyl)-oxazolidin-2-one

4-bromo-2-methyloctanoyl (5(S)-benzyl-2-oxazolidone) amide

4-bromo-2-methyloctanoyl (5(S)-benzyl-2-oxazolidone) amide

Conditions
ConditionsYield
With triethyl borane; scandium tris(trifluoromethanesulfonate) In hexane; 1,2-dichloro-ethane at 25℃; for 1h;100%
1-hexene
592-41-6

1-hexene

9-bora-bicyclo[3.3.1]nonane
280-64-8

9-bora-bicyclo[3.3.1]nonane

9-hexyl-9-borabicyclo[3.3.1]nonane
42371-64-2

9-hexyl-9-borabicyclo[3.3.1]nonane

Conditions
ConditionsYield
In tetrahydrofuran at 60℃; for 12h; Schlenk technique; Inert atmosphere;100%
In tetrahydrofuran at 25℃; for 24h; Schlenk technique; Inert atmosphere;100%
In tetrahydrofuran at 20℃; for 2h;87%
1-hexene
592-41-6

1-hexene

diisobutyl(2,6-di-tert-butyl-4- methylphenoxy)aluminum
56252-56-3

diisobutyl(2,6-di-tert-butyl-4- methylphenoxy)aluminum

C6H13Al(OC6H2(CH3)(C(CH3)3)2(CH2CH(CH3)2))
106751-52-4

C6H13Al(OC6H2(CH3)(C(CH3)3)2(CH2CH(CH3)2))

Conditions
ConditionsYield
With catalyst: ZrCl2(C5H5)2/AlH(CH2CH(CH3)2)2 In xylene react. of the Al compd. with the olefin (mol ratio 1:3) in dry xylene at 140°C for 5-7 h;100%
With catalyst: ZrCl4/AlH(CH2CH(CH3)2)2 In toluene react. of the Al compd. with the olefin (mol ratio 1:3) in toluene for 10 h;78%
With catalyst: (C5H5)2ZrCl2-iBu2AlH In xylene byproducts: isobutene; addn. of Cp2ZrCl2 to phenoxide at 20°C, mixt. stirred 0.5h, addn. of i-Bu2AlH, refluxed and addn. of olefin, reaction time 5 h at 140°C; isobutene condensed in a trap cooled to -78°C;
With catalyst: (C5H5)2ZrCl2-iBu2AlH In toluene byproducts: isobutene; addn. of Cp2ZrCl2 to phenoxide at 20°C, mixt. stirred 0.5h, addn. of i-Bu2AlH, refluxed and addn. of olefin, reaction time 10h at 140°C; isobutene condensed in a trap cooled to -78°C;
With catalyst: ZrCl4/AlH(CH2CH(CH3)2)2 In xylene react. of the Al compd. with the olefin (mol ratio 1:3) in dry xylene at 140°C for 5-7 h;<50
1-hexene
592-41-6

1-hexene

triphenylstannane
892-20-6

triphenylstannane

n-hexyltriphenylstannane
103047-76-3

n-hexyltriphenylstannane

Conditions
ConditionsYield
Irradiation (UV/VIS); UV-irradiation at 25-50 °C for 18 h;;100%
Irradiation (UV/VIS); UV-irradiation at 25-50 °C for 18 h;;100%
1-hexene
592-41-6

1-hexene

[Re(Br)(H)(NO)(PiPr3)2]
1145706-23-5

[Re(Br)(H)(NO)(PiPr3)2]

[Re(Br)(H)(NO)(Pi-Pr3)2(η2-CH2=CHBu)]
1260114-02-0

[Re(Br)(H)(NO)(Pi-Pr3)2(η2-CH2=CHBu)]

Conditions
ConditionsYield
In benzene-d6 (N2, Schlenk) complex and 1-hexane were mixed in C6D6; evapd. in vac. for 24 h; elem. anal.;100%
With BH3*THF or B(C6F5)3 or B(C2H5)3 or B(C6H5)3 (Ar) the complex and boron Lewis acid (B(C6F5)3 or BH3*THF or B(C2H5)3 or B(C6H5)3) were mixed in 1-hexane; detected by NMR spectra;
1-hexene
592-41-6

1-hexene

1,1,1,3,5,5,5-heptamethyltrisiloxan
1873-88-7

1,1,1,3,5,5,5-heptamethyltrisiloxan

3-n-hexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane
1873-90-1

3-n-hexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane

Conditions
ConditionsYield
With 1,3-bis(tert-buthylethynyl)-1,1,3,3-tetramethyldisiloxane platinum (0) at 50℃; for 16h; Time; Reagent/catalyst;100%
With C27H55NOPtSi5 In benzene-d6; toluene at 50℃; for 5h; Reagent/catalyst; Concentration; Schlenk technique; Inert atmosphere;95%
With C24H33N2ORh In tetrahydrofuran at 20℃; for 24h; Time; Inert atmosphere; Glovebox; regioselective reaction;86%
methanol
67-56-1

methanol

1-hexene
592-41-6

1-hexene

2-methoxyhexyltellurium tribromide
1514956-43-4

2-methoxyhexyltellurium tribromide

Conditions
ConditionsYield
With tellurium(IV) tetrabromide for 8h; Heating; regioselective reaction;100%
1-hexene
592-41-6

1-hexene

hydrogen
1333-74-0

hydrogen

hexane
110-54-3

hexane

Conditions
ConditionsYield
With C61H98ClN3P2Ru In dichloromethane-d2 at 50℃; under 3040.2 Torr; for 4h; Reagent/catalyst; Time;100%
With triethylsilane; ReH(NO)2(P(CH(CH3)2)3)2; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave;
With triethylsilane; [ReH(NO)2(P(C6H11)3)2]; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave;
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

1-hexene
592-41-6

1-hexene

1,2-bis(di-tert-butyl)phosphinoethane
4141-59-7

1,2-bis(di-tert-butyl)phosphinoethane

[(dtbpe)Ni(1-hexene)]

[(dtbpe)Ni(1-hexene)]

Conditions
ConditionsYield
In tetrahydrofuran-d8 at 60℃; for 24h; Inert atmosphere;100%
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