Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Product description: Product name 1-Hexene CAS number 592-41-6 Assay ≥99% Appearance Colorless liquid Capacity 200mt/year Application Used in the manufacture of perfumes, dye
hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm
Cas:592-41-6
Min.Order:1 Metric Ton
FOB Price: $1.0 / 3.0
Type:Manufacturers
inquiry1. Quality Our products meet MSDS safe standard and we have ISO and other certificate so yan can get high quality products from our company. 2. Price We are the company which is the joint of trade and industry so we cao provide the competiti
Cas:592-41-6
Min.Order:1 Metric Ton
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Type:Trading Company
inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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Product Name: 1-Hexene Synonyms: 1-Hexene [Standard Material];N-HEXENE;Hexane-1-ene;1-Hexene,97%;1-Hexene [Standard Material for GC];1-Hexene, AcroSeal, 99%;1-Hexene, 97% 100ML;1-Hexene, 97% 1LT CAS: 592-41-6 MF: C6H12 MW: 84.16
Cas:592-41-6
Min.Order:1 Kilogram
FOB Price: $8900.0
Type:Lab/Research institutions
inquiryWe are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED
Cas:592-41-6
Min.Order:1 Gram
FOB Price: $3.0
Type:Lab/Research institutions
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Cas:592-41-6
Min.Order:10 Gram
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:592-41-6
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquirySuperior quality, moderate price & quick delivery. Appearance:white crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermed
Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:592-41-6
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
manufacture Application:The refence standard products, for lab use, also we could produce bigger quantity on yr requirement.
high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:592-41-6
Min.Order:1 Kilogram
FOB Price: $112.0
Type:Trading Company
inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl
low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China
1-Hexene//cas 592-41-6Appearance:Solid powder Storage:Sealed,light and oxygen resistant Package:Package: In double layer bags of 25 Kg or 50 Kg or 1000 Kg net. Application:Food Additives Transportation:By express (Door to door) such as FEDEX, DHL, EM
bulk?production Application:Pharmaceutical intermediates
1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G
Cas:592-41-6
Min.Order:10 Milligram
Negotiable
Type:Lab/Research institutions
inquiryKnown for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Our advantages:1, High quality with competitive price:1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%3) We are manufacturer
Before-Sale Service:---Any inquiries will be replied within 12 hours.---Golden Manufactory under?ISO/GMP?with?large stock.---Dedication to quality,We?have?strict?quality?control?system.?---OEM/ODM Available.---Sample is available for your evaluation
Conditions | Yield |
---|---|
With trimethylamine-N-oxide; [N(4-C6H4Br)3][B(C6F5)4]; triethylaluminum; [Cr(CO)4(2-C6H4(MeO))2PN(Me)P(2-C6H4(MeO))2] In toluene at 60℃; under 30002.4 Torr; for 1h; | 100% |
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity; | 99% |
In chlorobenzene at 60℃; under 36201.3 Torr; for 4h; Product distribution / selectivity; | 99% |
Conditions | Yield |
---|---|
With triphenylphosphine at 200℃; for 6h; | 100% |
With carbon monoxide; C29H32IrN5O; bis(trifluoromethane)sulfonimide lithium In benzene-d6 at 80℃; under 7500.75 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Time; Schlenk technique; chemoselective reaction; | 98% |
With zirconium(IV) chloride; sodium iodide In acetonitrile for 0.0166667h; Heating; | 88% |
Conditions | Yield |
---|---|
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; ethylmagnesium bromide In tetrahydrofuran at 0℃; | 100% |
With sodium tetrahydroborate; nickel dichloride In tetrahydrofuran at 20℃; for 1h; | 80% |
With tetramethylammonium perchlorate In N,N-dimethyl-formamide Electrolysis; |
trimethylstannyl sodium
6-Bromo-1-hexene
A
1-hexene
C
(CH3)3Sn(CH2C5H9)
Conditions | Yield |
---|---|
With tert-butylamine In tetrahydrofuran react. at 0°C under Ar; | A 0% B 100% C 0% |
With DPCH In tetrahydrofuran react. at 0°C under Ar; | A <1 B 98% C 0% |
In tetrahydrofuran react. at 0°C under Ar; | A 0% B 98% C 0% |
In tetrahydrofuran; benzene react. at 0°C under Ar; | A <1 B 85% C 10% |
With DCPH In tetrahydrofuran; benzene react. at 0°C under Ar; | A 15% B 79% C 1.5% |
Conditions | Yield |
---|---|
With hydrogen; N,N′-bis(salicylidene)-ethylenediamino‑palladium In pyridine for 0.35h; | 98% |
With hydrogen In methanol at 20℃; under 760.051 Torr; for 4.5h; Green chemistry; | 94% |
With hydrogen In methanol under 760.051 Torr; for 5.5h; | 93% |
trimethylstannane
6-Bromo-1-hexene
lithium diisopropyl amide
A
1-hexene
B
methyl-cyclopentane
C
hexamethyldistannane
Conditions | Yield |
---|---|
In diethyl ether; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 2 equiv. of Me3SnH in Et2O at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC; | A 77% B 16% C 97% |
In diethyl ether; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 1 equiv. of Me3SnH in Et2O at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC; | A 41% B 18% C 86% |
In hexane; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 2 equiv. of Me3SnH in hexane at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC; | A 76% B 18% C 27% |
In hexane; cyclohexane to 6-bromo-1-hexene (1.04 mmol) and 1 equiv. of Me3SnH in hexane at 0°C added LDA (1.04 mmol, in cyclohexane) under Ar, react. time 20 min, quenched with water; analyzed by GLPC; | A 45% B 32% C 48% |
Conditions | Yield |
---|---|
In chlorobenzene at 60℃; for 4h; Product distribution / selectivity; Autoclave; | A 96% B n/a |
In chlorobenzene at 60℃; under 36201.3 Torr; for 4h; Product distribution / selectivity; | A 91% B n/a |
methylaluminoxane; tantalum pentachloride In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity; | A 84% B n/a |
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity; | A 84% B n/a |
In chlorobenzene at 45℃; under 36201.3 Torr; for 4h; Product distribution / selectivity; | A 26% B n/a |
Conditions | Yield |
---|---|
With tris-(trimethylsilyl)silane; 2,2'-azobis(isobutyronitrile) at 70℃; | A 4.1% B 93% C 2% |
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) at 70℃; | A 15% B 83% C 1.2% |
With 9-borabicyclo[3.3.1]nonane dimer; tribenzyltin hydride In toluene at 0℃; Product distribution; variation of reagent; | A 29% B 68% C 3% |
Conditions | Yield |
---|---|
Cl(1-)*NPr4(1+) at 50℃; under 22502.3 Torr; for 1h; | A 91.7% B 5.5% |
modified methylalumoxane; C28H24Cl2FeN2S In n-heptane at 30 - 52℃; under 21446.5 Torr; for 0.5h; Product distribution / selectivity; | |
With [η5-(3-SiMe3)C5H3CMe2-3,5-Me2C6H3]Ti(TEA) In toluene at 20℃; under 7500.75 Torr; for 0.25h; Pressure; Reagent/catalyst; Temperature; Inert atmosphere; |
Conditions | Yield |
---|---|
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics; | A 91% B n/a |
With hydrogen; platinum In ethanol at 30℃; under 15200 Torr; Product distribution; 80 atm; | A 41.7% B 57.3% |
With hydrogen; Ni(C17H35COO)2; triethylaluminum In toluene at 40℃; Kinetics; Object of study: selectivity; |
Conditions | Yield |
---|---|
With CrCl2(tetrahydrofuran)2; N,N'-bis(diphenylphosphino)-N,N'-dimethylpropane-1,3-diamine In methyl cyclohexane at 80℃; under 30003 Torr; for 0.5h; Inert atmosphere; | A 9% B 91% |
bis(2-(decylthio)ethyl)amine; chromium chloride In toluene at 90℃; under 33753.4 Torr; for 0.502778 - 0.527778h; Product distribution / selectivity; | A 90.85% B 0.5% |
chromium(III)2-ethylhexanoate; trimethylaluminum; N-[bis(2-methoxyphenyl)phosphino]-P,P-bis(2-methoxyphenyl)-N-methylphosphinous amide In methyl cyclohexane; toluene at 60℃; under 36003.6 - 37503.8 Torr; for 0.175h; Product distribution / selectivity; | A 89.7% B 8.5% |
Conditions | Yield |
---|---|
[Ph2PC6H4C(OB(C6F5)3)O-κ2P,O](η3-CH2CMeCH2) In toluene at 0℃; under 2280.15 Torr; for 1h; Product distribution; Further Variations:; Temperatures; Pressures; oligomerization; | A 90% B 6% |
With tetraphenyl phosphonium chloride; chromium at 80℃; under 37503.8 Torr; for 1h; Product distribution / selectivity; | A 7.5% B 88.3% |
With [6,6'-diphenyl-[2,2']-bipyridinyl]NiBr2; triethyl aluminum sesquichloride In toluene Catalytic behavior; Reagent/catalyst; Inert atmosphere; Schlenk technique; | A 88% B 9% |
Conditions | Yield |
---|---|
at 600℃; under 20 Torr; for 0.0333333h; | A 90% B 7% |
Conditions | Yield |
---|---|
A 7% B 88% |
Conditions | Yield |
---|---|
aluminum oxide; tetramethylstannane; rhenium(VII) oxide In chlorobenzene at 25℃; for 3h; Yields of byproduct given; | A n/a B 87% |
Conditions | Yield |
---|---|
With hydrogen bromide; tetrabutyl phosphonium bromide at 200℃; for 0.25h; Menshutkin Reaction; Inert atmosphere; | 86% |
{bis(triphenylphosphine)nitrogen}{cis-HW(CO)4P(OMe)3}
6-Bromo-1-hexene
A
1-hexene
B
BrW(CO)4P(OCH3)3(1-)
Conditions | Yield |
---|---|
In tetrahydrofuran | A 85% B n/a |
Conditions | Yield |
---|---|
With n-butylsilane; tris(pentafluorophenyl)borate In dichloromethane | 84% |
Conditions | Yield |
---|---|
methylaluminoxane; C33H29Cl3CrNP2 at 24 - 30℃; under 2250.23 - 22502.3 Torr; for 1 - 2h; Product distribution / selectivity; | A 3% B 83% |
methylaluminoxane; C23H24Cl3CrNPS at 24 - 30℃; under 22502.3 Torr; for 1h; Product distribution / selectivity; | A 18% B 82% |
[CrCl2Me(tetrahydrofuran)3]; C27H26N2; polyamethylaluminoxane-IP; trimethylaluminum In toluene at 50℃; under 7757.43 Torr; for 1h; Product distribution / selectivity; |
n-decyl acetate
A
1-hexene
B
1-Decene
C
1,2-dimethylcyclopentane
D
1-Butyl-2-methylcyclopropane
E
1-Methyl-2-pentylcyclopropane
F
cyclopentene
Conditions | Yield |
---|---|
at 495℃; for 0.00727778h; Rate constant; Product distribution; various temp., also in toluene, also with 14C-labelled ester; | A 1.03% B 81.3% C 1.91% D 1.2% E 0.497% F 0.45% |
Conditions | Yield |
---|---|
methylaluminoxane; C64H58Cl6Cr2N2O2P4 In dodecane; toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity; | A 80% B n/a C n/a |
methylaluminoxane, aged; C54H54Cl6Cr2N2P4 In dodecane; toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity; | A 50% B n/a C n/a |
methylaluminoxane; C64H58Cl6Cr2N2O2P4 In toluene at 25℃; under 3040.2 Torr; for 1.5h; Product distribution / selectivity; | A 20% B n/a C n/a |
1,2-Epoxyhexane
N,N-dimethyl-formamide
A
1-hexene
B
formic acid 1-bromomethylpentyl ester
Conditions | Yield |
---|---|
With bromine; triphenylphosphine at 0℃; for 0.583333h; | A n/a B 78% |
trimethylstannane
6-Bromo-1-hexene
A
1-hexene
B
methyl-cyclopentane
C
n-butyltrimethyltin
Conditions | Yield |
---|---|
With n-butyllithium In octane TMTH (1.00 mmol) and 6-bromo-1-hexene (1.08 mmol) in octane cooled to 0°C under Ar, n-BuLi (1.00 mmol, in octane) added via syringe, stirred for 15 min, quenched with water; analyzed by GC; | A 56% B 30% C 78% |
triethylbenzylammonium ethanolate
1-Iodohexane
A
1-hexene
B
ethyl n-hexyl ether
Conditions | Yield |
---|---|
at 20 - 25℃; for 1h; Product distribution; other halogenoalkanes, other alkoxides and alcoholates; var. reaction conditions; | A 4.8% B 75% |
at 20 - 25℃; for 1h; | A 4.8% B 75% |
Conditions | Yield |
---|---|
With triethylbenzylammonium ethanolate at 20 - 25℃; for 1h; | A 4.8% B 75% |
1 ,6-dibromohexane
A
1-hexene
B
hexane
C
1,5-Hexadien
D
hexan-1-ol
Conditions | Yield |
---|---|
With tetramethylammonium perchlorate In 2,2,2-trifluoroethanol; N,N-dimethyl-formamide Electrolysis; | A 4% B 75% C 5% D 18% |
Conditions | Yield |
---|---|
With magnesium at 600℃; | 72% |
trimethylstannane
6-Bromo-1-hexene
A
1-hexene
B
methyl-cyclopentane
Conditions | Yield |
---|---|
In diethyl ether Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 2 equiv. of Me3SnH in Et2O under Ar; analyzed by GLPC; | A 71% B 20% |
In hexane Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 1 equiv. of Me3SnH in hexane under Ar; analyzed by GLPC; | A 51% B 46% |
In diethyl ether Irradiation (UV/VIS); photoinduced react. of 6-bromo-1-hexene (1.04 mmol) with 1 equiv. of Me3SnH in Et2O under Ar; analyzed by GLPC; | A 51% B 45% |
2-trifluoromethylsulfonyloxy-1-hexene
carbon dioxide
A
1-hexene
B
2-butylacrylic acid
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide at 20℃; under 760 Torr; electrolyses, carbon cathode, Mg anode, E=-2.2 V; | A 8% B 70% |
With nBuNBF4; bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 20℃; electrochemical reaction; | A 8% B 70% |
6-Bromo-1-hexene
A
1-hexene
B
1,11-dodecadiene
C
methyl-cyclopentane
Conditions | Yield |
---|---|
With potassium In ammonia; tert-butyl alcohol Product distribution; Mechanism; Heating; | A 63.6% B 20.7% C 0.7% |
With potassium In ammonia; tert-butyl alcohol Heating; | A 63.6% B 20.7% C 0.7% |
Conditions | Yield |
---|---|
at 90℃; for 5h; Inert atmosphere; | 100% |
at 90℃; for 5h; Inert atmosphere; | 100% |
Stage #1: 1-hexene With diethylenetriaminepentaacetic acid (DTPA)-functionalized silica supported Pt at 60℃; for 0.5h; Stage #2: Dichloromethylsilane at 60℃; for 4h; Catalytic behavior; Temperature; Reagent/catalyst; | 99.6% |
Conditions | Yield |
---|---|
With C20H24CoN2O6(1+)*NO3(1-)*H2O; oxygen; isobutyraldehyde In acetonitrile at 60℃; under 760.051 Torr; for 8h; Time; chemoselective reaction; | 100% |
With dihydrogen peroxide; (Bu4N)3K[γ-SiW10O36(PhPO)2] In water at 65℃; for 2h; microwave irradiation; | 99% |
With tert.-butylhydroperoxide In acetonitrile at 65 - 68℃; for 24h; | 99% |
Conditions | Yield |
---|---|
With bromine In chloroform at 0℃; for 0.166667h; | 100% |
With bromine In chloroform at 0 - 5℃; | 93% |
With propane 3-bromo-1-(triphenylphosphonium) tribromide In dichloromethane at 20℃; for 0.5h; | 92% |
Conditions | Yield |
---|---|
With poly{[CuBa(pyridine-2,5-dicarboxylate)2(H2O)5]*H2O}; dihydrogen peroxide In acetonitrile at 60℃; for 6h; Catalytic behavior; Reagent/catalyst; | 100% |
With N-methyl-2-indolinone; fluorous OsO4 In water; acetone; tert-butyl alcohol at 20℃; for 36h; | 97% |
With N-methyl-2-indolinone; polysulfone microencapsulated OsO4 In water; acetone; acetonitrile at 20℃; for 0.416667h; | 96% |
Conditions | Yield |
---|---|
With hydrogen; In tetrahydrofuran at 90℃; under 5250.4 Torr; for 0.166667h; Product distribution; other olefins, other catalysts; var. temp., solv., press., and time; | 100% |
With hydrogen; (iPrPDI)Fe(N2)2 at 20℃; under 3040 Torr; for 19h; | 100% |
With Wilkinson's catalyst; hydrogen In dichloromethane-d2 at 45℃; under 3000.3 Torr; for 6h; Concentration; Reagent/catalyst; Solvent; Temperature; Time; Sealed tube; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With water; palladium dichloride In N,N-dimethyl-formamide under 1300 Torr; for 5h; Rate constant; Mechanism; oxidation of different olefines by Wacker process; variation of solvent: formamide, tensioactive and cotensioactive component in microemulsions; reaction time; | 100% |
With water; palladium dichloride In various solvent(s) under 1300 Torr; for 0.833333h; closed reactor, in microemulsion with formamide; | 100% |
With Pd(II)(15-crown-5-phen)Cl2; dinitrogen monoxide In N,N-dimethyl acetamide; water at 150℃; under 2250.23 Torr; for 18h; | 99% |
Conditions | Yield |
---|---|
With trichlorosilane at 90℃; for 5h; Inert atmosphere; | 100% |
With trichlorosilane at 90℃; for 5h; Inert atmosphere; | 100% |
With trichlorosilane; nickel In tetrahydrofuran at 20 - 25℃; | 94% |
Conditions | Yield |
---|---|
With C10H19B11Cl11PPd In dichloromethane-d2 at 25℃; for 0.0833333h; Inert atmosphere; | 100% |
With aluminum (III) chloride; [(2,6-iPrC6H3NC(Me)C(Me)N-2,6-iPrC6H3)Pd(CH3)(Cl)]; acetonitrile In dichloromethane at 25℃; for 18h; Reagent/catalyst; Darkness; Inert atmosphere; | 81% |
With platinum on activated charcoal; carbon dioxide at 300 - 305℃; |
Conditions | Yield |
---|---|
at 90℃; for 5h; Inert atmosphere; | 100% |
at 90℃; for 5h; Inert atmosphere; | 100% |
With C26H31F5NZn(1+)*C24BF20(1-) In dichloromethane-d2 at 20℃; for 28h; Reagent/catalyst; Inert atmosphere; Glovebox; | 100% |
Conditions | Yield |
---|---|
at 90℃; for 5h; Inert atmosphere; | 100% |
With platinum on carbon nanotubes In neat (no solvent) at 20℃; for 24h; | 97% |
dihydrogen hexachloroplatinate In diethyl ether for 15h; Heating; | 80% |
Conditions | Yield |
---|---|
at 90℃; for 5h; Inert atmosphere; | 100% |
at 90℃; for 5h; Inert atmosphere; | 100% |
With dichlorobis-(ethylene)-μ,μ'-dichloroplatinum(II) |
Conditions | Yield |
---|---|
at 90℃; for 5h; Inert atmosphere; | 100% |
at 90℃; for 5h; Inert atmosphere; | 100% |
With platinum on carbon nanotubes In neat (no solvent) at 20℃; for 24h; | 98% |
Conditions | Yield |
---|---|
In chloroform at 80℃; for 4h; | 100% |
1-hexene
triphenylmethylacetonitrile oxide
5-butyl-3-(triphenylmethyl)-2-isoxazoline
Conditions | Yield |
---|---|
In benzene at 85℃; for 48h; | 100% |
Conditions | Yield |
---|---|
With iodine In water; ethyl acetate at 20℃; for 1.33333h; iodosulfonization; | 100% |
With iodine In water; ethyl acetate for 2h; Ambient temperature; |
1-hexene
α-bromopropionyl 2-oxazolidinone amide
Conditions | Yield |
---|---|
With triethyl borane; scandium tris(trifluoromethanesulfonate) In hexane; 1,2-dichloro-ethane at 25℃; for 1h; | 100% |
1-hexene
3-bromoacetyl-1,3-oxazolidin-2-one
4-bromooctanoyl 2-oxazolidinone amide
Conditions | Yield |
---|---|
With triethyl borane; ytterbium(III) triflate In hexane; 1,2-dichloro-ethane at 25℃; for 1h; | 100% |
With air; triethyl borane In 2,2,2-trifluoroethanol at 25℃; for 1.5h; | 90% |
With triethyl borane; oxygen; ytterbium(III) triflate In hexane; 1,2-dichloro-ethane at 20℃; for 0.5h; | 83% |
1-hexene
(S)-4-Benzyl-3-((R)-2-bromo-propionyl)-oxazolidin-2-one
Conditions | Yield |
---|---|
With triethyl borane; scandium tris(trifluoromethanesulfonate) In hexane; 1,2-dichloro-ethane at 25℃; for 1h; | 100% |
1-hexene
9-bora-bicyclo[3.3.1]nonane
9-hexyl-9-borabicyclo[3.3.1]nonane
Conditions | Yield |
---|---|
In tetrahydrofuran at 60℃; for 12h; Schlenk technique; Inert atmosphere; | 100% |
In tetrahydrofuran at 25℃; for 24h; Schlenk technique; Inert atmosphere; | 100% |
In tetrahydrofuran at 20℃; for 2h; | 87% |
1-hexene
diisobutyl(2,6-di-tert-butyl-4- methylphenoxy)aluminum
C6H13Al(OC6H2(CH3)(C(CH3)3)2(CH2CH(CH3)2))
Conditions | Yield |
---|---|
With catalyst: ZrCl2(C5H5)2/AlH(CH2CH(CH3)2)2 In xylene react. of the Al compd. with the olefin (mol ratio 1:3) in dry xylene at 140°C for 5-7 h; | 100% |
With catalyst: ZrCl4/AlH(CH2CH(CH3)2)2 In toluene react. of the Al compd. with the olefin (mol ratio 1:3) in toluene for 10 h; | 78% |
With catalyst: (C5H5)2ZrCl2-iBu2AlH In xylene byproducts: isobutene; addn. of Cp2ZrCl2 to phenoxide at 20°C, mixt. stirred 0.5h, addn. of i-Bu2AlH, refluxed and addn. of olefin, reaction time 5 h at 140°C; isobutene condensed in a trap cooled to -78°C; | |
With catalyst: (C5H5)2ZrCl2-iBu2AlH In toluene byproducts: isobutene; addn. of Cp2ZrCl2 to phenoxide at 20°C, mixt. stirred 0.5h, addn. of i-Bu2AlH, refluxed and addn. of olefin, reaction time 10h at 140°C; isobutene condensed in a trap cooled to -78°C; | |
With catalyst: ZrCl4/AlH(CH2CH(CH3)2)2 In xylene react. of the Al compd. with the olefin (mol ratio 1:3) in dry xylene at 140°C for 5-7 h; | <50 |
Conditions | Yield |
---|---|
Irradiation (UV/VIS); UV-irradiation at 25-50 °C for 18 h;; | 100% |
Irradiation (UV/VIS); UV-irradiation at 25-50 °C for 18 h;; | 100% |
1-hexene
[Re(Br)(H)(NO)(PiPr3)2]
[Re(Br)(H)(NO)(Pi-Pr3)2(η2-CH2=CHBu)]
Conditions | Yield |
---|---|
In benzene-d6 (N2, Schlenk) complex and 1-hexane were mixed in C6D6; evapd. in vac. for 24 h; elem. anal.; | 100% |
With BH3*THF or B(C6F5)3 or B(C2H5)3 or B(C6H5)3 (Ar) the complex and boron Lewis acid (B(C6F5)3 or BH3*THF or B(C2H5)3 or B(C6H5)3) were mixed in 1-hexane; detected by NMR spectra; |
1-hexene
1,1,1,3,5,5,5-heptamethyltrisiloxan
3-n-hexyl-1,1,1,3,5,5,5-heptamethyltrisiloxane
Conditions | Yield |
---|---|
With 1,3-bis(tert-buthylethynyl)-1,1,3,3-tetramethyldisiloxane platinum (0) at 50℃; for 16h; Time; Reagent/catalyst; | 100% |
With C27H55NOPtSi5 In benzene-d6; toluene at 50℃; for 5h; Reagent/catalyst; Concentration; Schlenk technique; Inert atmosphere; | 95% |
With C24H33N2ORh In tetrahydrofuran at 20℃; for 24h; Time; Inert atmosphere; Glovebox; regioselective reaction; | 86% |
Conditions | Yield |
---|---|
With tellurium(IV) tetrabromide for 8h; Heating; regioselective reaction; | 100% |
Conditions | Yield |
---|---|
With C61H98ClN3P2Ru In dichloromethane-d2 at 50℃; under 3040.2 Torr; for 4h; Reagent/catalyst; Time; | 100% |
With triethylsilane; ReH(NO)2(P(CH(CH3)2)3)2; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave; | |
With triethylsilane; [ReH(NO)2(P(C6H11)3)2]; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave; |
bis(1,5-cyclooctadiene)nickel (0)
1-hexene
1,2-bis(di-tert-butyl)phosphinoethane
Conditions | Yield |
---|---|
In tetrahydrofuran-d8 at 60℃; for 24h; Inert atmosphere; | 100% |
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