he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:
As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch
Cas:1436-34-6
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
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Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:1436-34-6
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:1436-34-6
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
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Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiry1,2-EPOXYHEXANE CAS:1436-34-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia
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Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:1436-34-6
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:1436-34-6
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h
factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:1436-34-6
Min.Order:1 Kilogram
FOB Price: $18.0 / 20.0
Type:Trading Company
inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:1436-34-6
Min.Order:1 Metric Ton
FOB Price: $1.5
Type:Trading Company
inquirySAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in
Cas:1436-34-6
Min.Order:0 Metric Ton
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Type:Lab/Research institutions
inquiryWe are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:1436-34-6
Min.Order:1 Metric Ton
FOB Price: $1.0
Type:Trading Company
inquiryWe produce carbomer by our own factory,carbomer 940 is our best seller.It is used for cosmetic and medical.And we also become agent for lubrizol.Our carbomer 940 get high viscosity and good transparency.The price will depond on the market,surely supp
Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
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R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates
Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea
Cas:1436-34-6
Min.Order:1 bottle
Negotiable
Type:Lab/Research institutions
inquiryProduct Name: 1,2-EPOXYHEXANE Synonyms: BUTYLOXIRAN;BUTYLOXIRANE;1-HEXENE OXIDE;1,2-HEXYLENE OXIDE;1,2-EPOXYHEXAN;1,2-EPOXYHEXANE;1,2-Hexene oxide;1,2-hexeneoxide CAS: 1436-34-6 MF: C6H12O MW: 100.16 Appearance:white powder Storage:Room tem
Cas:1436-34-6
Min.Order:1 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou
1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re
Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
SAGECHEM/ 1,2-Epoxyhexane /Manufacturer in China Application:SAGECHEM/ 1,2-Epoxyhexane /Manufacturer in China
Cas:1436-34-6
Min.Order:0
Negotiable
Type:Other
inquiryConditions | Yield |
---|---|
With C20H24CoN2O6(1+)*NO3(1-)*H2O; oxygen; isobutyraldehyde In acetonitrile at 60℃; under 760.051 Torr; for 8h; Time; chemoselective reaction; | 100% |
With dihydrogen peroxide; (Bu4N)3K[γ-SiW10O36(PhPO)2] In water at 65℃; for 2h; microwave irradiation; | 99% |
With tert.-butylhydroperoxide In acetonitrile at 65 - 68℃; for 24h; | 99% |
1,2-Epoxyhexane
Conditions | Yield |
---|---|
With Al2O3-Na2CO3 catalyst at 40 - 45℃; for 0.00833333h; Microwave irradiation; | 98% |
1,2-epoxy-5-hexene
1,2-Epoxyhexane
Conditions | Yield |
---|---|
With [Fe(nacnac)dippCH2SiMe3]; N-butylamine; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In benzene-d6 at 20℃; for 1h; Sealed tube; Schlenk technique; Glovebox; Inert atmosphere; | 91% |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; Y2(N3)(nic)2(OH)3(Hnic)(H2O) In acetonitrile at 68 - 70℃; for 24h; | A 85% B 10% |
trans-2-hexene
A
1,2-Epoxyhexane
trans-2,3-epoxyhexane
cis-2,3-epoxyhexane
D
butyraldehyde
Conditions | Yield |
---|---|
With oxygen; titanium(IV) oxide for 19h; Irradiation; | A n/a B 66% C n/a D n/a |
1,2-epoxy-2-hexyl(triphenyl)silane
1,2-Epoxyhexane
Conditions | Yield |
---|---|
With potassium fluoride; N-benzyl-N,N,N-triethylammonium chloride In dimethyl sulfoxide for 2h; Ambient temperature; | 65% |
Conditions | Yield |
---|---|
With poly{[CuMg(pyridine-2,5-dicarboxylate)2(H2O)4]*2H2O}; dihydrogen peroxide In acetonitrile at 60℃; for 24h; Catalytic behavior; | A 22% B 61% |
With dihydrogen peroxide; large pore titanium silicate (MCM-41) In methanol at 55.9℃; for 5h; Product distribution; other hydrocarbon; var. oxidation compounds; var. time; | |
With urea-hydrogen peroxide; tegafur In methanol at 39.85℃; for 12h; Product distribution; Further Variations:; Reagents; |
cis-2-hexene
A
1,2-Epoxyhexane
trans-2,3-epoxyhexane
cis-2,3-epoxyhexane
D
butyraldehyde
Conditions | Yield |
---|---|
With oxygen; titanium(IV) oxide for 19h; Irradiation; | A n/a B n/a C 61% D n/a |
Conditions | Yield |
---|---|
With iodosylbenzene; (n-Bu4N)4H(Mn)PW11O39 In acetonitrile at 24℃; for 2h; Product distribution; other reagent, other catalysts, other time; | A 58% B n/a C 3.5% |
With sodium tetrahydroborate; 5,10,15,20-tetra(4-methoxyphenyl) porphyrinato manganese chloride; oxygen In ethanol; benzene for 24h; Product distribution; |
Conditions | Yield |
---|---|
With iodosylbenzene; (n-Bu4N)4H(Mn)PW11O39 In acetonitrile at 24℃; for 2h; | A 58% B 3.5% |
With tert.-butylhydroperoxide; 2C21H13N3O6(2-)*4Co(2+)*HO(1-)*17H2O In neat (no solvent) at 50℃; for 4h; Green chemistry; | A 80 %Chromat. B 20 %Chromat. |
With C60H62Fe2Li2N10O7(2+)*2ClO4(1-); dihydrogen peroxide; acetic acid In water; acetonitrile at 30℃; for 3h; | A 15 %Chromat. B n/a |
1-hexene
A
1,2-Epoxyhexane
B
rac-2-hydroxyhexanoic acid
C
valeric acid
Conditions | Yield |
---|---|
With [γ-W10SiO36(PhPO)2][TBA]4; dihydrogen peroxide In acetonitrile at 90 - 120℃; for 0.833333h; microwave irradiation; | A 50% B n/a C n/a |
Conditions | Yield |
---|---|
With iodosylbenzene; meso-tetrakis(tetraphenyl)porphyrin iron(III) chloride In benzene at 20℃; for 1h; | A 40% B 3% |
With 1H-imidazole; C44H28MnN4O12S4(1+)*C2H3O2(1-); tetrabutylammonium periodite In dichloromethane at 20℃; for 4h; Reagent/catalyst; | A 14% B 7% |
With P450 In phosphate buffer at 37℃; pH=7.4; Enzyme kinetics; |
Conditions | Yield |
---|---|
With dihydrogen peroxide In acetonitrile at 65 - 68℃; for 24h; | A 35% B 13% |
1-hexene
A
1,2-Epoxyhexane
B
1-hexene-3-ol
C
1-hexene-3-one
D
hexanal
Conditions | Yield |
---|---|
With iodosylbenzene; 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride In benzene for 2h; Ambient temperature; anaerobic cond.; | A 29% B 4% C 3% D 1% |
With iodosylbenzene; 5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride In benzene at 20℃; for 1h; Product distribution; regioselectivity of the oxidation of olefins in presence of various metalloporphyrins; | A 29% B 4% C 3% D 1% |
5,10,15,20-tetraphenyl-21 H,23-H-porphine manganese(III)chloride In benzene for 2h; Product distribution; Mechanism; Ambient temperature; variations of pH, reagents, pO2, T; | A 29% B 4% C 3% D 1% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; iron(III) chloride In acetonitrile at -5℃; for 0.166667h; Product distribution; Mechanism; other alkenes, alkanes, alcohols, ethers, aldehydes, thioethers and sulfoxides; other temperature, other time; | A 71 % Chromat. B 10 % Chromat. |
6-iodo-1,2-epoxyhexane
1,2-Epoxyhexane
Conditions | Yield |
---|---|
With methanol; tert.-butyl lithium 1.) Et2O, pentane, -78 deg C.; Yield given. Multistep reaction; |
methanol
1-hexene
A
1,2-Epoxyhexane
B
2-n-hexyl methyl ether
C
hexyl methyl ether
Conditions | Yield |
---|---|
With dihydrogen peroxide; Ti-β zeolite at 59.9℃; for 5h; Product distribution; var. of catalyst; |
1-hexene
A
1,2-Epoxyhexane
B
n-hexan-2-ol
C
Hexane-1,2-diol
D
1-hexene-3-ol
E
hexanal
F
hexan-1-ol
Conditions | Yield |
---|---|
With europioum(III) chloride; oxygen; propionic acid; zinc In 1,2-dichloro-ethane at 40℃; for 1h; Product distribution; various catalysts, various solvents, other alkenes; |
methanol
1-hexene
A
1,2-Epoxyhexane
B
1-hydroxy-2-methoxyhexane
C
1-methoxy-2-hexanol
Conditions | Yield |
---|---|
With Ti-Beta catalyst; dihydrogen peroxide at 50℃; for 2h; Product distribution; selectivity to epoxide; var. olefins; other catalyst and oxidating agent; var. reaction time; |
1-hexene
A
1,2-Epoxyhexane
B
n-hexan-2-one
C
hexanal
D
hexanoic acid
E
valeric acid
Conditions | Yield |
---|---|
Product distribution; Ambient temperature; electrochemical oxidation, var. voltage, var. anodes; |
1,2-Epoxyhexane
Conditions | Yield |
---|---|
With sodium hydroxide; diethyl ether | |
With sodium hydroxide; water |
Conditions | Yield |
---|---|
With dihydrogen peroxide; peroxy-niobic acid In water at 34.85℃; for 24h; | A 27 % Chromat. B 20 % Chromat. C 15 % Chromat. |
1-bromohexan-2-ol
1,2-Epoxyhexane
Conditions | Yield |
---|---|
With ammonia |
1-hexene
A
1,2-Epoxyhexane
B
Hexane-1,2-diol
C
1-hexene-3-ol
D
1-hexene-3-one
Conditions | Yield |
---|---|
With dihydrogen peroxide; [Ti,Al]-Beta In methanol at -240.15℃; for 3h; Product distribution; Further Variations:; Catalysts; |
1,2-Epoxyhexane
Conditions | Yield |
---|---|
With 18-crown-6 ether; potassium tert-butylate In benzene-d6 at 25℃; for 0.0833333h; |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 82 percent / NBS / H2O 2: NH3*H2O View Scheme |
Conditions | Yield |
---|---|
With sodium hydroxide; sodium chloride In water |
1,3-Dichloropropane
1-chloro-3-hydroxypropane
A
glycidyl methyl ether
B
1,2-Epoxyhexane
C
2,3-Dichloroprop-1-ene
D
2-chloroallyl alcohol
E
1,2,2-trichloropropane
F
1,2-Dichloropropane
G
(Z)-1,3-dichloropropene
H
1,2,3-trichloro-1-propene
I
(1Z)-1,2,3-trichloroprop-1-ene
J
1,3,3-trichloro-propene
K
1t,3,3-trichloro-propene
L
chlorodibromomethane
M
1,1,2-trichloropropane
N
2,3-Dichloro-1-propanol
O
1,3-Dichloro-2-propanol
P
1,2,3-trichloropropane
Q
3,3-dichloropropene
R
3,3-dichloroallyl chloride
S
acetaldehyde
T
allyl alcohol
U
hydroxy-2-propanone
V
chloroacetone
W
cyclopentanone
X
chlorobenzene
Y
isopropyl alcohol
Z
3-monochloro-1,2-propanediol
[
acrolein
\
epichlorohydrin
]
(E)-1,3-dichloro-prop-1-ene
Conditions | Yield |
---|---|
With sodium hydroxide; water at 45 - 62.4℃; under 112.511 - 750.075 Torr; Product distribution / selectivity; |
Rh(III)(tetra(p-sulfonatophenyl)porphyrinato)(CH2CH(OD)CH2CH2CH2CH3)(OD2)(4-)
A
1,2-Epoxyhexane
Conditions | Yield |
---|---|
With potassium hydroxide In dimethyl sulfoxide at 20℃; for 0.0833333h; |
Conditions | Yield |
---|---|
With water; erbium(III) triflate In acetonitrile at 25℃; for 1h; | 100% |
With poly{[CuBa(pyridine-2,5-dicarboxylate)2(H2O)5]*H2O}; dihydrogen peroxide In water; acetonitrile at 40℃; for 2h; Catalytic behavior; Reagent/catalyst; | 100% |
With water at 40℃; for 8h; Autoclave; | 99% |
Conditions | Yield |
---|---|
With triphenylphosphine at 200℃; for 6h; | 100% |
With carbon monoxide; C29H32IrN5O; bis(trifluoromethane)sulfonimide lithium In benzene-d6 at 80℃; under 7500.75 Torr; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Time; Schlenk technique; chemoselective reaction; | 98% |
With zirconium(IV) chloride; sodium iodide In acetonitrile for 0.0166667h; Heating; | 88% |
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide; 1,3,5-trimethyl-benzene; 2-hydroxyresorcinol In butanone at 45℃; under 3750.38 - 7500.75 Torr; for 18h; Autoclave; | 100% |
With C26H42N5(3+)*3Br(1-); 1,1'-hexane-1,6-diylbis(1-methylpyrrolidinium) bis(trifluromethane)sulfonamide at 80℃; under 30003 Torr; for 3h; Autoclave; Green chemistry; | 100% |
With potassium iodide In neat (no solvent) at 80℃; under 5250.53 Torr; Catalytic behavior; Autoclave; | 100% |
Conditions | Yield |
---|---|
With chiral oligo-(salen)Co(OTs) complexes; lutidinium p-toluene sulfonate In acetonitrile at 4℃; for 24h; | 100% |
With Co(salen) macrocycles 1(OTs) In acetonitrile at 4℃; for 24h; optical yield given as %ee; enantioselective reaction; | 97% |
Conditions | Yield |
---|---|
With calcium bistrifluoroacetate In neat (no solvent) at 40℃; for 31h; regioselective reaction; | 100% |
With zinc(II) chloride In acetonitrile for 12h; Heating; | 66% |
With C8H18N2(2+)*2C2F6NO4S2(1-) In dichloromethane at 20℃; for 24h; Reagent/catalyst; Molecular sieve; Schlenk technique; Inert atmosphere; regioselective reaction; |
1,2-Epoxyhexane
diethoxyphosphoryl-acetic acid ethyl ester
trans-2-butylcyclopropanecarboxylic acid ethyl ester
Conditions | Yield |
---|---|
With n-butyllithium In 1,2-dimethoxyethane; hexane at 130℃; for 16h; Sealed tube; | 100% |
With n-butyllithium In 1,2-dimethoxyethane at 130℃; for 18h; Sealed tube; Inert atmosphere; | 68% |
Conditions | Yield |
---|---|
With calcium bistrifluoroacetate In neat (no solvent) at 40℃; for 31h; regioselective reaction; | 100% |
In methanol; water at 140℃; under 15514.9 Torr; for 0.166667h; Flow reactor; | 75% |
1,2-Epoxyhexane
2-butyl thiirane
Conditions | Yield |
---|---|
With ruthenium trichloride; ammonium thiocyanate In acetonitrile at 25℃; for 0.25h; | 99% |
With ammonium thiocyanate at 60℃; for 0.366667h; Neat (no solvent); | 97% |
With cross-linked polystyrene supported aluminium chloride; thiourea In acetonitrile for 2h; Heating; | 95% |
Conditions | Yield |
---|---|
erbium(III) triflate at 20℃; for 1h; | 99% |
With trichloro(trifluoromethanesulfonato)titanium(IV); n-tetrabutylammonium hydroxide In water for 0.166667h; Ambient temperature; | 93% |
With 12-molybdo phosphoric acid n-hydrate at 20℃; for 0.0166667h; neat (no solvent); | 93% |
Conditions | Yield |
---|---|
With (R,R)-(salen)Co(H2O); 3 A molecular sieve In various solvent(s) at 25℃; for 16h; | 99% |
With 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol; polysytrene-immobilized chiral Co-salen complex In tetrahydrofuran at 20℃; for 24h; | 96% |
In acetonitrile at 23℃; for 14h; enantioselective reaction; | 95% |
With Co(salen) macrocycles 1(OTs) In tert-butyl methyl ether at 20℃; for 19h; optical yield given as %ee; enantioselective reaction; | 91% |
Conditions | Yield |
---|---|
With 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol; polystyrene-immobilized chiral Co-salen complex In tetrahydrofuran at 20℃; for 17h; | 99% |
With (R,R)-(salen)Co(H2O); 3 A molecular sieve In various solvent(s) at 25℃; for 12h; | 97% |
With Co(salen) macrocycles 1(OTs) In tert-butyl methyl ether at 4℃; for 24h; optical yield given as %ee; enantioselective reaction; | 97% |
In acetonitrile at 23℃; for 16h; enantioselective reaction; | 92% |
Stage #1: 1,2-Epoxyhexane With 3 A molecular sieve; fluorous (R,R)-(salen)cobalt(III) In various solvent(s) for 0.0833333h; Stage #2: phenol In various solvent(s) for 18h; | 53% |
1,2-Epoxyhexane
tert-butyl carbamate
A
(R)-1,2-epoxyhexane
Conditions | Yield |
---|---|
With air; 4-nitro-benzoic acid; (R,R)-((t-Bu)4-salen)Co(II) In various solvent(s) at 20℃; for 24h; | A n/a B 99% |
With (1R,2R)-(-)-N,N'-bis(3,5-di-tert-butylsalicydene)-1,2-cyclohexanediaminocobalt(II); 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; 4-nitro-benzoic acid at 20℃; for 10h; optical yield given as %ee; enantioselective reaction; |
1,2-Epoxyhexane
Conditions | Yield |
---|---|
C64H74Cl2Co2N4O4; bis(triphenylphosphoranylidene)-ammonium acetate In toluene at 0℃; for 15h; | 99% |
Conditions | Yield |
---|---|
With Co(salen) macrocycles 1(OTs) In acetonitrile at 20℃; for 4h; optical yield given as %ee; enantioselective reaction; | 99% |
1,2-Epoxyhexane
1-chloro-hexan-2-ol
Conditions | Yield |
---|---|
With chloro-trimethyl-silane; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate at 20℃; for 1h; ring opening reaction; | 98% |
With magnesium; tin(ll) chloride In tetrahydrofuran for 0.5h; Ambient temperature; | 77% |
With water; silica gel; lithium chloride for 17h; Ambient temperature; | 76% |
Conditions | Yield |
---|---|
With chiral oligo-(salen)Co(OTs) complexes; lutidinium p-toluene sulfonate In acetonitrile at 4℃; for 6h; | 98% |
In acetonitrile at 23℃; for 6h; enantioselective reaction; | 97% |
With water; macrocyclic salen type Co In acetonitrile at 4℃; for 10h; | 95% |
With 4 A molecular sieve; lutidinium p-toluene sulfonate; chiral oligo-(salen)Co(OTs) complexes In acetonitrile at 30℃; Kinetics; Further Variations:; concentration of catalyst; concentration of reagent; |
Conditions | Yield |
---|---|
With chiral oligo-(salen)Co(OTs) complexes; lutidinium p-toluene sulfonate In acetonitrile at 4℃; for 24h; | 98% |
1,2-Epoxyhexane
1,3-dithiol-2-thione
2-Butyl-1-oxa-4,6,9-trithiaspiro<4.4>non-7-en
Conditions | Yield |
---|---|
With magnesium(II) perchlorate In acetonitrile for 12h; Heating; | 97% |
Conditions | Yield |
---|---|
With water; macrocyclic salen-type Co-complex In acetonitrile at 4℃; for 2h; | 97% |
With chiral oligo-(salen)Co(OTs) complexes; lutidinium p-toluene sulfonate In acetonitrile at 4℃; for 3h; | 97% |
Conditions | Yield |
---|---|
With calcium bistrifluoroacetate In neat (no solvent) at 40℃; for 31h; regioselective reaction; | 97% |
With sulfated zirconia at 60℃; for 6h; | 82% |
1,2-Epoxyhexane
Conditions | Yield |
---|---|
In chlorobenzene at 100℃; for 2h; | 97% |
1,2-Epoxyhexane
2-Hydroxyhexylazide
Conditions | Yield |
---|---|
With sodium azide; cerium(III) chloride In water; acetonitrile for 6h; Heating; | 96% |
With PEG-400; sodium azide at 20℃; for 0.75h; | 95% |
With sodium azide; ammonium chloride In methanol; water at 20℃; for 24h; | 94% |
1,2-Epoxyhexane
acetic anhydride
pentane-1,2-diyl diacetate
Conditions | Yield |
---|---|
With tributylphosphine In toluene Heating; | 96% |
With zeolite HY at 20℃; for 9.5h; | 95% |
With sodium phosphate dibasic dodecahydrate for 2h; Catalytic behavior; Reagent/catalyst; Reflux; | 90% |
With antimony(III) fluoride for 2h; Reflux; regioselective reaction; | 80% |
Conditions | Yield |
---|---|
With Co(salen) macrocycles 1(OTs) In acetonitrile at 20℃; for 3h; optical yield given as %ee; enantioselective reaction; | 96% |
1,2-Epoxyhexane
2-hydroxybromobenzene
(2S)-1-(2-bromophenoxy)hexan-2-ol
Conditions | Yield |
---|---|
In acetonitrile at 23℃; for 6h; Reagent/catalyst; enantioselective reaction; | 96% |
Conditions | Yield |
---|---|
With 1-n-butyl-3-methylimidazolim bromide; potassium hydroxide; lithium bromide In neat (no solvent) at 70℃; for 24h; chemoselective reaction; | 96% |
Conditions | Yield |
---|---|
orthosilicic acid tetrakis-2,2,6,6-tetramethyl-4-hydroxy-1-oxylpiperidyl ester at 120℃; for 6h; | 95.2% |
Conditions | Yield |
---|---|
With (R,R)-(salen)Co(H2O); 3 A molecular sieve In various solvent(s) at 25℃; for 12h; | 95% |
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