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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1,3-Butadiene Manufacturer/High quality/Best price/In stock

Cas:106-99-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay 98%min ----------------------------------------------------------------------------------------------

High purity Various Specifications 1,3-butadiene CAS:106-99-0

Cas:106-99-0

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

1 ,3-butadiene

Cas:106-99-0

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Buta-1,3-diene

Cas:106-99-0

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,3-Butadiene

Cas:106-99-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Sinotech Import&Export Corporation

Product Name Biethylene Synonyms Biethylene;Vinylethylene CAS: 106-99-0 Product Categories: Agrochemical Intermediates;Intermediates & Fine Chemicals;Dyestuff

Butadiene

Cas:106-99-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Lonwin Chemical Group Limited

1,3-Butadiene CAS:106-99-0 Specification proname: 1,3-butadiene manufacturer/high qualit... casno: 106-99-0 molecular formula: c4h6 appearance: crystal, powder application: pharmaceutical intermediates deliverytime: 1-2 days package: a

Factory supply 1,3-Butadiene

Cas:106-99-0

Min.Order:1 Kilogram

Negotiable

Type:Other

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Triumph International Development Limilted

Appearance:white powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common products:Sea/Air/Courie

1,3-butadiene

Cas:106-99-0

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,3-Butadiene

Cas:106-99-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,3-Butadiene

Cas:106-99-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,3-butadiene

Cas:106-99-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:colourless gas Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates Transportation:BY

1,3-BUTADIENE

Cas:106-99-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 1,3-BUTADIENE Synonyms: alpha-butadiene;Buta-1,3-dieen;Buta-1,3-dien;Butadieen;Butadien;butadien(polish);butadiene(non-specificname);butadiene-1,3 CAS: 106-99-0 MF: C4H6 MW: 54.09 EINECS: 203-450-8

106-99-0 1,3-BUTADIENE

Cas:106-99-0

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

1,3-Butadiene

Cas:106-99-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)

1,3-BUTADIENE CAS NO.: 106-99-0

Cas:106-99-0

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

1,3-Butadiene

Cas:106-99-0

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1,3-butadiene

Cas:106-99-0

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,3-BUTADIENE

Cas:106-99-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 106-99-0 with competitive price

Cas:106-99-0

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,3-Butadiene

Cas:106-99-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

1,3-BUTADIENE Application:1,3-BUTADIENE

1,3-BUTADIENE

Cas:106-99-0

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl

1,3-Butadiene

Cas:106-99-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

1,3-BUTADIENEAppearance:powder Storage:200MT Package:as your requirement Application:Pharmaceutical Intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea LCL/FCL for larg

1,3-BUTADIENE

Cas:106-99-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Henan Sunlake Enterprise Corporation Our Advantages 1, Any inquiry about ch

1,3-BUTADIENE

Cas:106-99-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

1,3-Butadiene solution 20 wt. % in toluene

Cas:106-99-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Mingqi Chemical Co., Ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Our advantages:1, High quality with competitive price:1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%3) We are manufacturer

1,3-Butadiene factory

Cas:106-99-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Harmonious Natural Bio-Technology Co., Ltd.

Before-Sale Service:---Any inquiries will be replied within 12 hours.---Golden Manufactory under?ISO/GMP?with?large stock.---Dedication to quality,We?have?strict?quality?control?system.?---OEM/ODM Available.---Sample is available for your evaluation

1,3-BUTADIENE

Cas:106-99-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ningbo Huajia Chemicals

Product Name: 1,3-BUTADIENE Synonyms: alpha-butadiene;Buta-1,3-dieen;Buta-1,3-dien;Butadieen;Butadien;butadien(polish);butadiene(non-specificname);butadiene-1,3 CAS: 106-99-0 MF: C4H6 MW: 54.09 EINECS: 203-450-8 Melting poi

1,3-Butadiene

Cas:106-99-0

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

inquiry

HuBei Ipure Biotech CO.,ltd

More than 8 years chemical exporting experience. We have produced chemical more than 8 years., 90% products are for export . More than 8 years chemical exporting experience. best service and unbeatable price! Appearance:crystal, powder Storag

1,3-Butadiene

Cas:106-99-0

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

TIANJIN TIGER INTERNATIONAL CO.,LTD.

Properties Has a weak sweet smelling a colorless gas liquefaction easily. Boiling point 4.41 degrees Product DescriptionChemical p…

1,3-Butadiene

Cas:106-99-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-hydroxy-3-butene
598-32-3

2-hydroxy-3-butene

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With gadolinium(III) phosphate at 230℃; Flow reactor; Inert atmosphere;99%
With scandium aluminium oxide; hydrogen at 318℃; Temperature; Flow reactor;95.4%
With water; trimethylamine at 230℃; Leiten ueber einen aus Aluminium, SiO2 und W2O5 hergestellten Katalysator;
1-butylene
106-98-9

1-butylene

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With oxygen; Bi-Mo oxide (1/1) at 400℃; Rate constant; also without O2;99%
With oxygen Gas phase;99.4%
With oxygen Flow reactor; Inert atmosphere;99.4%
2.3-butanediol
513-85-9

2.3-butanediol

A

buta-1,3-diene
106-99-0

buta-1,3-diene

B

butanone
78-93-3

butanone

Conditions
ConditionsYield
In water at 500℃; Reagent/catalyst; Temperature;A 61.4%
B 24.8%
With scandium(III) oxide; hydrogen at 425℃; for 5h; Flow reactor;
With lutetium(III) oxide; hydrogen at 425℃; for 5h; Flow reactor;
(E/Z)-2-buten-1-ol
6117-91-5

(E/Z)-2-buten-1-ol

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With silica-alumina In hexane at 175 - 200℃; under 760.051 Torr; for 39h; Time; Inert atmosphere;96%
With 4-toluidinium hydrogen sulfate at 140 - 160℃;
With trichloroacetic acid
2.3-butanediol
513-85-9

2.3-butanediol

A

2-hydroxy-3-butene
598-32-3

2-hydroxy-3-butene

B

buta-1,3-diene
106-99-0

buta-1,3-diene

C

butanone
78-93-3

butanone

Conditions
ConditionsYield
In water at 500℃; Reagent/catalyst;A 12.6%
B 17.6%
C 45.4%
With scandium(III) oxide In water at 700℃; Reagent/catalyst;A 9.7%
B 22%
C 20.3%
With Sc1.5Yb0.5O3; hydrogen at 411℃; for 5h; Flow reactor;
1-butylene
106-98-9

1-butylene

A

carbon dioxide
124-38-9

carbon dioxide

B

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With oxygen at 370℃; for 20h;A 5.1%
B 57.3%
With oxygen In water at 420℃; under 760.051 Torr; for 8h; Reagent/catalyst; Flow reactor;
tetrahydrofuran
109-99-9

tetrahydrofuran

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With hydrogen bromide; tetrabutyl phosphonium bromide at 200℃; for 0.25h; Menshutkin Reaction; Inert atmosphere;13%
With fired clay
With aluminum oxide; phosphoric acid; sodium phosphate In water at 250 - 270℃; under 750.075 Torr;31.4 %Chromat.
2.3-butanediol
513-85-9

2.3-butanediol

A

2-hydroxy-3-butene
598-32-3

2-hydroxy-3-butene

B

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
In water at 500℃; Reagent/catalyst; Temperature;A 27.3%
B 56%
With Al, La and Zr mixed oxide In water at 500℃; Reagent/catalyst; Temperature; Overall yield = 61.4 %;
With lithium dihydrogenphosphate at 500℃; for 6h; Reagent/catalyst; Inert atmosphere;
2.3-butanediol
513-85-9

2.3-butanediol

A

2-hydroxy-3-butene
598-32-3

2-hydroxy-3-butene

B

buta-1,3-diene
106-99-0

buta-1,3-diene

C

isobutyraldehyde
78-84-2

isobutyraldehyde

D

butanone
78-93-3

butanone

Conditions
ConditionsYield
at 293 - 365℃;A n/a
B 21%
C n/a
D n/a
With silica-supported phosphorous at 180℃; Inert atmosphere;
With alumina In water at 380℃; Reagent/catalyst; Inert atmosphere; Gas phase;
With Cesium oxide- Silica composite at 400℃; for 6h; Inert atmosphere;
With 1 Na phosphate on silica at 400℃; under 760.051 Torr; for 20h; Reagent/catalyst; Inert atmosphere;
1.3-butanediol
18826-95-4, 107-88-0

1.3-butanediol

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With silica-alumina at 300℃; under 750.075 Torr;99.8%
In dichloromethane at 320℃; Reagent/catalyst; Temperature;72%
With hydrogen bromide; tetrabutyl phosphonium bromide at 200℃; for 0.25h; Menshutkin Reaction; Inert atmosphere;33%
dichloromethane
75-09-2

dichloromethane

allylmagnesium bromide
2622-05-1

allylmagnesium bromide

A

1,6-heptadiene
3070-53-9

1,6-heptadiene

B

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With C31H37ClN3NiO2(1-)*Li(1+) In tetrahydrofuran at 25℃; for 0.333333h; Inert atmosphere; Overall yield = 79 %;A 52%
B 27%
With C31H37ClFeN3O2 In tetrahydrofuran at 25℃; for 0.0833333h; Inert atmosphere;
Butane-1,4-diol
110-63-4

Butane-1,4-diol

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With water at 300 - 350℃; Leiten ueber einen aus NaH2PO4, saurem n-Butylaminphosphat, Graphit und Wasser durch Eindampfen und Erhitzen auf 160grad hergestellten Katalysator;
durch stufenweise katalytische Wasserabspaltung ueber Tetrahydrofuran als Zwischenprodukt;
With Yb2O3 at 360℃; Temperature; Flow reactor; Inert atmosphere;
With water at 300 - 350℃; Leiten ueber einen aus NaH2PO4, saurem n-Butylaminphosphat, Graphit und Wasser durch Eindampfen und Erhitzen auf 160grad hergestellten Katalysator;
durch stufenweise katalytische Wasserabspaltung ueber Tetrahydrofuran als Zwischenprodukt;
butene-2
107-01-7

butene-2

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With oxygen at 320℃; Gas phase;78%
With BDP-142 at 340℃; Reagent/catalyst; Temperature; Concentration;77.5%
With oxygen at 340℃; under 760.051 Torr; Temperature; Flow reactor;71.62%
2.3-butanediol
513-85-9

2.3-butanediol

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With scandium aluminium oxide; hydrogen at 318℃; for 5h; Reagent/catalyst; Temperature; Flow reactor;94%
With water; triethylamine; 2,4-dimethylpentan-3-one at 225 - 235℃; Leiten ueber Al+SiO2+W2O5;
With thorium dioxide at 350℃; unter vermindertem Druck, andere Katalysatoren;
1.3-butanediol
18826-95-4, 107-88-0

1.3-butanediol

A

2-hydroxy-3-butene
598-32-3

2-hydroxy-3-butene

B

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With silicon carbide In water at 350℃; under 760.051 Torr; for 8h; Inert atmosphere;A 17.5%
B 53.5%
2-vinylthiirane
5954-75-6

2-vinylthiirane

A

buta-1,3-diene
106-99-0

buta-1,3-diene

B

3,6-dihydro-[1,2]dithiine
17547-93-2

3,6-dihydro-[1,2]dithiine

Conditions
ConditionsYield
With pentacarbonyl(acetonitrile)tungsten In dichloromethane-d2 at 25℃; for 24h;A n/a
B 86%
With pentacarbonyl(acetonitrile)tungsten In dichloromethane-d2 for 24h; Ambient temperature;A n/a
B 82 % Spectr.
homoalylic alcohol
627-27-0

homoalylic alcohol

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
at 270 - 290℃; Leiten ueber saure Katalysatoren;
With neodymium(III) orthophosphate at 286℃; Reagent/catalyst; Inert atmosphere;
With 3-buten-1-ol dehydratase Enzymatic reaction;
With Yb2O3 at 340℃; Flow reactor; Inert atmosphere;
n-butane
106-97-8

n-butane

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
magnesium-molybdenum98%
With water; oxygen at 25 - 550℃; under 1800.18 - 11251.1 Torr;95%
With water; hydrogen; oxygen at 25 - 555℃; under 1800.18 - 15001.5 Torr; Product distribution / selectivity;95%
1.3-butanediol
18826-95-4, 107-88-0

1.3-butanediol

A

2-hydroxy-3-butene
598-32-3

2-hydroxy-3-butene

B

propene
187737-37-7

propene

C

(E/Z)-2-buten-1-ol
6117-91-5

(E/Z)-2-buten-1-ol

D

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With silicon carbide In water at 300℃; under 760.051 Torr; for 8h; Inert atmosphere;A 22.5%
B 5.3%
C 15.8%
D 51.7%
1.3-butanediol
18826-95-4, 107-88-0

1.3-butanediol

A

2-hydroxy-3-butene
598-32-3

2-hydroxy-3-butene

B

(E/Z)-2-buten-1-ol
6117-91-5

(E/Z)-2-buten-1-ol

C

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With silicon carbide In water at 300℃; under 760.051 Torr; for 8h; Temperature; Inert atmosphere;A 19.5%
B 12.9%
C 63.6%
ethanol
64-17-5

ethanol

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
sodium oxide; magnesium oxide; silica gel at 350℃; for 0.166667h;87%
sodium oxide; magnesium oxide; silica gel at 350℃; for 0.166667h; Product distribution; other catalysts;87%
With zinc at 350℃; for 1h; Reagent/catalyst; Inert atmosphere;75.2%
ethene
74-85-1

ethene

di-n-butyl hexa-2,4-dienedioate

di-n-butyl hexa-2,4-dienedioate

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With tris(N-tert-butyl-3,5-dimethylanilino)molybdenum(III) In toluene at 80℃; under 7500.75 Torr; Temperature; Pressure; Reagent/catalyst; Inert atmosphere;
ethene
74-85-1

ethene

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
at 750℃; 0.6-2.0 sec Kontaktzeit;
at 755 - 885℃; 0.2-1.5 sec Kontaktzeit;
at 725℃; under 152 Torr;
butan-1-ol
71-36-3

butan-1-ol

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
durch unvollstaendige Verbrennung;
Liefert beim Durchleiten durch ein rotgluehendes Quarzrohr;
Bei der unvollstaendigen Verbrennung;
ethene
74-85-1

ethene

di-n-butyl hexa-2,4-dienedioate

di-n-butyl hexa-2,4-dienedioate

A

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

B

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 60℃; under 12929 - 15514.9 Torr; for 1.5h; Concentration; Temperature; Time; Pressure; Reagent/catalyst; Inert atmosphere;
ethene
74-85-1

ethene

hexa-2,4-diene
592-46-1

hexa-2,4-diene

A

propene
187737-37-7

propene

B

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With Grubbs catalyst first generation In toluene at 30℃; under 30003 Torr; Temperature; Pressure; Inert atmosphere;
ethene
74-85-1

ethene

(2Z,4Z)-di-n-butyl hexa-2,4-dienedioate
170967-96-1

(2Z,4Z)-di-n-butyl hexa-2,4-dienedioate

A

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

B

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In toluene at 60℃; under 12929 - 15514.9 Torr; for 1.5h; Inert atmosphere;
1-butylene
106-98-9

1-butylene

isobutene
115-11-7

isobutene

A

2-methylpropenal
78-85-3

2-methylpropenal

B

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With nitrogen; Mo12Co5.7Fe3.8Bi0.5Ce0.1Tl0.3Sb0.5O49.1; water; oxygen at 380℃; for 10005h; Reagent/catalyst;A 65%
B 89%
ethene
74-85-1

ethene

di-n-butyl hexa-2,4-dienedioate

di-n-butyl hexa-2,4-dienedioate

A

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

B

n-butyl penta-2,4-dienoate
16809-91-9

n-butyl penta-2,4-dienoate

C

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With 1,3-bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene-dichloro(o-isopropoxyphenylmethylene)ruthenium In toluene at 30℃; under 7500.75 Torr; Temperature; Pressure; Reagent/catalyst; Inert atmosphere;
ethanol
64-17-5

ethanol

A

butene-2
107-01-7

butene-2

B

buta-1,3-diene
106-99-0

buta-1,3-diene

Conditions
ConditionsYield
With indium at 350℃; for 1h; Reagent/catalyst; Inert atmosphere;A n/a
B 65.61%
buta-1,3-diene
106-99-0

buta-1,3-diene

(E)-1,4-dibromobutene
821-06-7

(E)-1,4-dibromobutene

Conditions
ConditionsYield
With bromine In chloroform at -78 - 23℃;100%
With bromine In tetrachloromethane at -78 - 20℃; for 16h;58%
With bromine In tetrachloromethane at -78 - 20℃; for 16h;58%
3-methoxy-19-norpregna-1,3,5(10),16-tetraene-20-one
21321-91-5

3-methoxy-19-norpregna-1,3,5(10),16-tetraene-20-one

buta-1,3-diene
106-99-0

buta-1,3-diene

3-methoxy-16α,17α-cyclohex-3',4'-eno-19-norpregna-1,3,5(10)-trien-20-one
101766-58-9

3-methoxy-16α,17α-cyclohex-3',4'-eno-19-norpregna-1,3,5(10)-trien-20-one

Conditions
ConditionsYield
With TEMPO In dichloromethane at 80℃; under 10500800 Torr; for 5h;100%
With aluminum (III) chloride In dichloromethane at 20℃; for 18h; Diels-Alder Cycloaddition;68%
16-methylpregna-5,16-dien-3β-ol-20-one acetate
982-06-9

16-methylpregna-5,16-dien-3β-ol-20-one acetate

buta-1,3-diene
106-99-0

buta-1,3-diene

16α,17α-cyclohex-3'-eno-16-methylpregn-5-en-3β-ol-20-one acetate
146303-84-6

16α,17α-cyclohex-3'-eno-16-methylpregn-5-en-3β-ol-20-one acetate

Conditions
ConditionsYield
aluminium trichloride In dichloromethane at 40℃; under 10500800 Torr; for 5h;100%
With aluminium trichloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical In dichloromethane at 40℃; under 11250900 Torr; for 5h;95%
16α,17α-cyclohexane-5α-pregn-1-ene-3,20-dione
122605-80-5

16α,17α-cyclohexane-5α-pregn-1-ene-3,20-dione

buta-1,3-diene
106-99-0

buta-1,3-diene

1α,2α-cyclohex-3'-eno-16α,17α-cyclohexano-5α-pregnane-3,20-dione
122605-81-6

1α,2α-cyclohex-3'-eno-16α,17α-cyclohexano-5α-pregnane-3,20-dione

Conditions
ConditionsYield
aluminium trichloride In dichloromethane at 40℃; under 10500800 Torr; for 5h;100%
With aluminium trichloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical In dichloromethane at 40℃; under 11250900 Torr; for 5h;93%
sodium 4-methylbenzenesulfinate
824-79-3

sodium 4-methylbenzenesulfinate

buta-1,3-diene
106-99-0

buta-1,3-diene

(E)-1-iodo-4-tosyl-2-butene
115147-52-9

(E)-1-iodo-4-tosyl-2-butene

Conditions
ConditionsYield
With iodine In water; ethyl acetate at 20℃; for 3h; iodosulfonization;100%
With iodine In dichloromethane for 6h; Ambient temperature;93%
16,19-Dioxo-2,5,8,11,14-pentaoxabicyclo[13.4.0]-115,1718-nonadecadien
103215-11-8

16,19-Dioxo-2,5,8,11,14-pentaoxabicyclo[13.4.0]-115,1718-nonadecadien

buta-1,3-diene
106-99-0

buta-1,3-diene

2,5,8,11,14-Pentaoxa-tricyclo[13.8.0.017,22]tricosa-1(15),19-diene-16,23-dione
117357-98-9

2,5,8,11,14-Pentaoxa-tricyclo[13.8.0.017,22]tricosa-1(15),19-diene-16,23-dione

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 0℃; for 2.5h;100%
19,22-Dioxo-2,5,8,11,14,17-hexaoxabicyclo<16.4.0>-118,2021-docosadien
103215-12-9

19,22-Dioxo-2,5,8,11,14,17-hexaoxabicyclo<16.4.0>-118,2021-docosadien

buta-1,3-diene
106-99-0

buta-1,3-diene

2,5,8,11,14,17-Hexaoxa-tricyclo[16.8.0.020,25]hexacosa-1(18),22-diene-19,26-dione
117357-99-0

2,5,8,11,14,17-Hexaoxa-tricyclo[16.8.0.020,25]hexacosa-1(18),22-diene-19,26-dione

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane for 2.5h;100%
benzyl ethyl diazene-1,2-dicarboxylate
111508-33-9

benzyl ethyl diazene-1,2-dicarboxylate

buta-1,3-diene
106-99-0

buta-1,3-diene

benzyl ethyl 1,2,3,6-tetrahydropyridazine-1,2-dicarboxylate
111508-34-0

benzyl ethyl 1,2,3,6-tetrahydropyridazine-1,2-dicarboxylate

Conditions
ConditionsYield
In benzene for 24h;100%
In benzene at -10 - 20℃; for 18h;
5-acetoxy-1,4-anthraquinone
74856-76-1

5-acetoxy-1,4-anthraquinone

buta-1,3-diene
106-99-0

buta-1,3-diene

Acetic acid 6,11-dioxo-6,6a,7,10,10a,11-hexahydro-naphthacen-1-yl ester

Acetic acid 6,11-dioxo-6,6a,7,10,10a,11-hexahydro-naphthacen-1-yl ester

Conditions
ConditionsYield
In benzene at 100℃;100%
buta-1,3-diene
106-99-0

buta-1,3-diene

N,N-dimethyl-(3,5-di-tert-butyl-4-hydroxybenzyl)amine
88-27-7

N,N-dimethyl-(3,5-di-tert-butyl-4-hydroxybenzyl)amine

2,4-di-tert-butylspiro<5.5>undeca-1,4,7-trien-3-one
94817-72-8

2,4-di-tert-butylspiro<5.5>undeca-1,4,7-trien-3-one

Conditions
ConditionsYield
In ethyl acetate100%
With methyl iodide 1.) ethyl acetate, 2.) 100 - 120 deg C, 18 h; Yield given. Multistep reaction;
2-acetyl-3-chloro-1,4-benzoquinone
52095-13-3

2-acetyl-3-chloro-1,4-benzoquinone

buta-1,3-diene
106-99-0

buta-1,3-diene

2-acetil-3-cloro-4a,5,8,8a-tetrahidro-1,4-naftoquinona
180508-64-9

2-acetil-3-cloro-4a,5,8,8a-tetrahidro-1,4-naftoquinona

Conditions
ConditionsYield
With hydroquinone In benzene for 8h; Heating;100%
buta-1,3-diene
106-99-0

buta-1,3-diene

polybutadiene

polybutadiene

Conditions
ConditionsYield
With triisobutylaluminum; C48H58NOP2Si2Y; trityl tetrakis(pentafluorophenyl)borate In toluene at 25℃; for 0.166667h; Product distribution / selectivity;100%
C48H58NOP2Si2Y; trityl tetrakis(pentafluorophenyl)borate In toluene at 25℃; for 0.166667h; Product distribution / selectivity;100%
With triisobutylaluminum; C48H58NOP2Si2Y; trityl tetrakis(pentafluorophenyl)borate In toluene at 25℃; for 0.166667h; Product distribution / selectivity;100%
buta-1,3-diene
106-99-0

buta-1,3-diene

poly(1,3-butadiene), Mn = 50000 g/mol, Mw/Mn = 2.6, cis:trans:1,2-units ratio = 90:8:2

poly(1,3-butadiene), Mn = 50000 g/mol, Mw/Mn = 2.6, cis:trans:1,2-units ratio = 90:8:2

Conditions
ConditionsYield
With [Y{(μ-Me2)2(AlMe2)}3]; triisobutylaluminum; N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate In toluene at 25℃; for 14h;100%
buta-1,3-diene
106-99-0

buta-1,3-diene

poly(1,3-butadiene), Mn = 100000 g/mol, Mw/Mn = 2.1, cis:trans:1,2-units ratio = 97:2:1

poly(1,3-butadiene), Mn = 100000 g/mol, Mw/Mn = 2.1, cis:trans:1,2-units ratio = 97:2:1

Conditions
ConditionsYield
With [Y{(μ-Me2)2(AlMe2)}3]; triisobutylaluminum; N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate In toluene at 25℃; for 14h;100%
buta-1,3-diene
106-99-0

buta-1,3-diene

polybutadiene, 99% of Z-1,4-double bonds, Mn 117000, Mw/Mn 1.07 by GPC; monomer(s): 1,3-butadiene

polybutadiene, 99% of Z-1,4-double bonds, Mn 117000, Mw/Mn 1.07 by GPC; monomer(s): 1,3-butadiene

Conditions
ConditionsYield
With triisobutylaluminum; trityl tetrakis(pentafluorophenyl)borate; bis(2-diphenylphosphinophenyl)amine-based yttrium complex In toluene at -10 - 25℃;100%
buta-1,3-diene
106-99-0

buta-1,3-diene

isoprene
78-79-5

isoprene

poly(isoprene-block-butadiene), with 33 mol% polyisoprene and 67 mol% polybutadiene, > 99% of Z-1,4-double bonds in polyisoprene and 99% of Z-1,4-double bonds in polybutadiene, Mn 160000, Mw/Mn 1.13 by GPC; monomer(s): 1,3-butadiene; isoprene

poly(isoprene-block-butadiene), with 33 mol% polyisoprene and 67 mol% polybutadiene, > 99% of Z-1,4-double bonds in polyisoprene and 99% of Z-1,4-double bonds in polybutadiene, Mn 160000, Mw/Mn 1.13 by GPC; monomer(s): 1,3-butadiene; isoprene

Conditions
ConditionsYield
Stage #1: buta-1,3-diene With triisobutylaluminum; trityl tetrakis(pentafluorophenyl)borate; bis(2-diphenylphosphinophenyl)amine-based yttrium complex In toluene at -10 - 25℃;
Stage #2: isoprene In toluene at 20℃; for 0.333333h; Further stages.;
100%
dichlorocarbene
1605-72-7

dichlorocarbene

buta-1,3-diene
106-99-0

buta-1,3-diene

1,1-dichloro-2-vinyl-cyclopropane
694-33-7

1,1-dichloro-2-vinyl-cyclopropane

Conditions
ConditionsYield
100%
ytterbium

ytterbium

buta-1,3-diene
106-99-0

buta-1,3-diene

C4H6Yb

C4H6Yb

Conditions
ConditionsYield
With C2H4I2 In 1,2-dimethoxyethane activation of Yb with C2H4I2 soln.(2h,room temp.) , flask cooled to -20°C and charged with 1,3-butadiene, after 2h reaction time the flask was warmed to room temp. and the mixt. stirred overnight ; suspension; not isolated , GC anal.;100%
buta-1,3-diene
106-99-0

buta-1,3-diene

palladium dichloride

palladium dichloride

bis(μ-chloro)bis{(1,2,3,-η)-4-acetoxy-2-butenyl}dipalladium

bis(μ-chloro)bis{(1,2,3,-η)-4-acetoxy-2-butenyl}dipalladium

Conditions
ConditionsYield
With acetic acid; copper dichloride In acetic acid100%
tetravinylgermane
1185-61-1

tetravinylgermane

buta-1,3-diene
106-99-0

buta-1,3-diene

3-cyclohexenyltrivinylgermane
81353-47-1

3-cyclohexenyltrivinylgermane

Conditions
ConditionsYield
With aluminium trichloride 5 h at 170 °C;;100%
trans-bis{1,2-bis(dimethylphosphino)ethane}bis(dinitrogen)chromium(0)
1346646-51-2, 86765-89-1

trans-bis{1,2-bis(dimethylphosphino)ethane}bis(dinitrogen)chromium(0)

buta-1,3-diene
106-99-0

buta-1,3-diene

bis{1,2-bis(dimethylphosphino)ethane}(η4-buta-1,3-diene)chromium(0)
97349-39-8

bis{1,2-bis(dimethylphosphino)ethane}(η4-buta-1,3-diene)chromium(0)

Conditions
ConditionsYield
In hexane under inert atmosphere; soln. of Cr complex in hexane was pressurised with C4H6 (5 atm) and warmed slowly with vigorous stirring to 75 °C; filtered, concd., pptd. by cooling to -20 °C;100%
[Pd2(acetonitrile)4(P(C6H5)3)2](PF6)2

[Pd2(acetonitrile)4(P(C6H5)3)2](PF6)2

buta-1,3-diene
106-99-0

buta-1,3-diene

[Pd2(μ-η(2):η(2)-s-trans-1,3-butadiene)2(P(C6H5)3)2](PF6)2

[Pd2(μ-η(2):η(2)-s-trans-1,3-butadiene)2(P(C6H5)3)2](PF6)2

Conditions
ConditionsYield
In dichloromethane100%
Grubbs catalyst first generation

Grubbs catalyst first generation

buta-1,3-diene
106-99-0

buta-1,3-diene

RuCl2(=CH-CH=CH2)(PCy3)2

RuCl2(=CH-CH=CH2)(PCy3)2

Conditions
ConditionsYield
In dichloromethane byproducts: PhCH=CH2;100%
In dichloromethane byproducts: PhCH=CH2; (Ar); -20°C, warming to room temp.; solvent removal (vac.), washing (acetone or pentane), drying (vac.) elem. anal.;95%
styrene
292638-84-7

styrene

buta-1,3-diene
106-99-0

buta-1,3-diene

poly(1,3-butadiene-co-styrene)

poly(1,3-butadiene-co-styrene)

Conditions
ConditionsYield
(2-Me-indenyl)2Sc(N(SiMe3)2); triisobutylaluminum; N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate In toluene at 20℃; for 0.5h; Product distribution / selectivity;100%
(2-Me-indenyl)2Sc(N(SiMe3)2); triisobutylaluminum; N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate In toluene at 20℃; for 0.5h; Product distribution / selectivity;80%
With triisobutylaluminum; methylaluminoxane; [((η5-C5Me5)TiCl2)3(tris(4-hydroxy-3,5-diisopropyl)amine(-3H))] In toluene at 25℃; for 2h; Product distribution / selectivity;
C12H13NO3

C12H13NO3

buta-1,3-diene
106-99-0

buta-1,3-diene

C16H19NO3

C16H19NO3

Conditions
ConditionsYield
With hydroquinone In toluene at 155℃; for 46h; Diels-Alder reaction; Inert atmosphere;100%
ethyl 4-oxo-4-(pyridin-2-yl)but-2-enoate

ethyl 4-oxo-4-(pyridin-2-yl)but-2-enoate

buta-1,3-diene
106-99-0

buta-1,3-diene

ethyl 6-(picolinoyl)cyclohex-3-en-1-carboxylate

ethyl 6-(picolinoyl)cyclohex-3-en-1-carboxylate

Conditions
ConditionsYield
With hydroquinone In toluene at 155℃; for 24h; Diels-Alder reaction; Inert atmosphere;100%
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